diff --git a/.github/workflows/makefile.yml b/.github/workflows/makefile.yml
index f39a88716..309bddbff 100644
--- a/.github/workflows/makefile.yml
+++ b/.github/workflows/makefile.yml
@@ -2,9 +2,9 @@ name: Makefile CI
on:
push:
- branches: [ "develop" ]
+ branches: [ "develop", "f-exx-opt" ]
pull_request:
- branches: [ "develop" ]
+ branches: [ "develop", "f-exx-opt" ]
# Manual dispatch for including all multiply kernels in matrix.
# We don't want this to run on every commit, but it's useful
# to be able to launch it manually
@@ -70,11 +70,9 @@ jobs:
multiply_kernel: ompDojk
- test_all_multiply_kernels: false
multiply_kernel: ompGemm
- - test_all_multiply_kernels: false
- multiply_kernel: ompGemm_m
steps:
- - uses: actions/checkout@v3
+ - uses: actions/checkout@v4
with:
fetch-depth: '0'
@@ -84,7 +82,7 @@ jobs:
sudo apt install openmpi-bin libopenmpi-dev libfftw3-dev libblas3 liblapack3 libscalapack-openmpi-dev libxc-dev
- name: Set up Python
- uses: actions/setup-python@v4
+ uses: actions/setup-python@v5
with:
python-version: '3.10'
@@ -119,7 +117,31 @@ jobs:
run: |
mpirun -np ${{matrix.np}} ../../bin/Conquest
cat Conquest_out
-
+
+ - name: Run test 004
+ working-directory: ${{github.workspace}}/testsuite/test_004_isol_C2H4_4proc_PBE0CRI
+ run: |
+ mpirun -np ${{matrix.np}} ../../bin/Conquest
+ cat Conquest_out
+
+ - name: Run test 005
+ working-directory: ${{github.workspace}}/testsuite/test_005_isol_C2H4_4proc_PBE0GTO
+ run: |
+ mpirun -np ${{matrix.np}} ../../bin/Conquest
+ cat Conquest_out
+
+ - name: Run test 006
+ working-directory: ${{github.workspace}}/testsuite/test_006_isol_C2H4_4proc_PBE0ERI
+ run: |
+ mpirun -np ${{matrix.np}} ../../bin/Conquest
+ cat Conquest_out
+
+ - name: Run test 007
+ working-directory: ${{github.workspace}}/testsuite/test_007_isol_CH_spinpol_1proc_PBE0CRI
+ run: |
+ mpirun -np ${{matrix.np}} ../../bin/Conquest
+ cat Conquest_out
+
- name: Check test results
working-directory: ${{github.workspace}}/testsuite
run: pytest test_check_output.py
diff --git a/.gitignore b/.gitignore
index 5e147fff1..29cd389b1 100644
--- a/.gitignore
+++ b/.gitignore
@@ -1,4 +1,7 @@
bin/*
deps.obj.inc
*~
-src/system/system.make
\ No newline at end of file
+src/system/system.make
+
+# Ignore folders within each benchmark but not files
+benchmarks/*/**/
diff --git a/README.md b/README.md
index 01cd052df..a0e032853 100644
--- a/README.md
+++ b/README.md
@@ -50,4 +50,4 @@ DOI for the specific version you have used in any given study.
## Version number
-CONQUEST is now at version 1.3 (tag:v1.3)
+CONQUEST is now at version 1.4 (tag:v1.4)
diff --git a/benchmarks/.gitignore b/benchmarks/.gitignore
new file mode 100644
index 000000000..2d316f004
--- /dev/null
+++ b/benchmarks/.gitignore
@@ -0,0 +1,8 @@
+__pycache__
+Conquest_o*
+Conquest_w*
+*.i00*
+*.bib
+*.dat
+*.log
+fort.*
\ No newline at end of file
diff --git a/benchmarks/reframe/exx_runonly.py b/benchmarks/reframe/exx_runonly.py
new file mode 100644
index 000000000..08739bb34
--- /dev/null
+++ b/benchmarks/reframe/exx_runonly.py
@@ -0,0 +1,220 @@
+# Import modules from reframe and excalibur-tests
+import reframe as rfm
+import reframe.utility.sanity as sn
+
+class ConquestBaseBenchmark(rfm.RunOnlyRegressionTest):
+
+ # Run configuration
+ ## Mandatory ReFrame setup
+ valid_systems = ['-gpu']
+ valid_prog_environs = ['default']
+
+ ## Executable
+ executable_opts = ['']
+
+ ## Scheduler options
+ time_limit = '30m'
+
+ conquest_base_dir = variable(str, value='foo')
+
+ @run_after('setup')
+ def setup_variables(self):
+ self.executable = f"{self.conquest_base_dir}/bin/Conquest"
+ self.num_tasks = self.num_tasks_param
+ self.num_cpus_per_task = self.num_cpus_per_task_param
+ self.env_vars['OMP_NUM_THREADS'] = f'{self.num_cpus_per_task}'
+ self.env_vars['OMP_STACKSIZE'] = '100M'
+
+ if self.current_partition.scheduler.registered_name == 'sge':
+ # `self.num_tasks` or `self.num_cpus_per_task` may be `None`, here
+ # we default to `1` if not set.
+ num_tasks = self.num_tasks or 1
+ num_cpus_per_task = self.num_cpus_per_task or 1
+ # Set the total number of CPUs to be requested for the SGE scheduler.
+ # Set to a full node size to reduce runtime variance.
+ self.extra_resources['mpi'] = {'num_slots': self.current_partition.processor.num_cpus} #num_tasks * num_cpus_per_task}
+
+ @sanity_function
+ def validate_solution(self):
+ return sn.assert_found(r'Total run time was:.*', self.stdout)
+
+ @performance_function('s', perf_key='Runtime')
+ def extract_runtime_perf(self):
+ return sn.extractsingle(r'Total run time was:\s+(\S+)\s+seconds', self.stdout, 1, float)
+
+ @performance_function('s', perf_key='exx_setup_runtime')
+ def extract_exx_setup_runtime_perf(self):
+ return sn.extractsingle(r'Time spent in exx_setup\s+time:\s+=\s+(\S+)\ss', self.stdout, 1, float)
+
+ @performance_function('s', perf_key='exx_fetch_runtime')
+ def extract_exx_fetch_runtime_perf(self):
+ return sn.extractsingle(r'Time spent in exx_fetch\s+time:\s+=\s+(\S+)\ss', self.stdout, 1, float)
+
+ @performance_function('s', perf_key='exx_evalpao_runtime')
+ def extract_exx_evalpao_runtime_perf(self):
+ return sn.extractsingle(r'Time spent in exx_evalpao\s+time:\s+=\s+(\S+)\ss', self.stdout, 1, float)
+
+ @performance_function('s', perf_key='exx_allocat_runtime')
+ def extract_exx_allocat_runtime_perf(self):
+ return sn.extractsingle(r'Time spent in exx_allocat\s+time:\s+=\s+(\S+)\ss', self.stdout, 1, float)
+
+ @performance_function('s', perf_key='exx_dealloc_runtime')
+ def extract_exx_dealloc_runtime_perf(self):
+ return sn.extractsingle(r'Time spent in exx_dealloc\s+time:\s+=\s+(\S+)\ss', self.stdout, 1, float)
+
+ @performance_function('s', perf_key='exx_kernel_runtime')
+ def extract_exx_kernel_runtime_perf(self):
+ return sn.extractsingle(r'Time spent in exx_kernel\s+time:\s+=\s+(\S+)\ss', self.stdout, 1, float)
+
+ @performance_function('s', perf_key='exx_total_runtime')
+ def extract_exx_total_runtime_perf(self):
+ return sn.extractsingle(r'Time spent in exx_total\s+time:\s+=\s+(\S+)\ss', self.stdout, 1, float)
+
+ @performance_function('MB', perf_key='Memory')
+ def extract_memory_perf(self):
+ return sn.extractsingle(r'Max total mem use is\s+(\S+)\s+MB', self.stdout, 1, float)
+
+@rfm.simple_test
+class test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0_2(ConquestBaseBenchmark):
+
+ tags = {"test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2"}
+ num_tasks_param = parameter([2,4])
+ num_cpus_per_task_param = parameter([1,2,4,8])
+
+ @run_before('run')
+ def get_input(self):
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/C_PBE_DZP_CQ.ion .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/Conquest_coord .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/Conquest_input .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/H_PBE_DZP_CQ.ion .")
+
+@rfm.simple_test
+class test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0_4(ConquestBaseBenchmark):
+
+ tags = {"test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4"}
+ num_tasks_param = parameter([2,4])
+ num_cpus_per_task_param = parameter([1,2,4,8])
+
+ @run_before('run')
+ def get_input(self):
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/C_PBE_DZP_CQ.ion .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/Conquest_coord .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/Conquest_input .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/H_PBE_DZP_CQ.ion .")
+
+@rfm.simple_test
+class test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0_6(ConquestBaseBenchmark):
+
+ tags = {"test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6"}
+ num_tasks_param = parameter([2,4])
+ num_cpus_per_task_param = parameter([1,2,4,8])
+
+ @run_before('run')
+ def get_input(self):
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/C_PBE_DZP_CQ.ion .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/Conquest_coord .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/Conquest_input .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/H_PBE_DZP_CQ.ion .")
+
+@rfm.simple_test
+class test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0_4_SCF(ConquestBaseBenchmark):
+
+ tags = {"test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF"}
+ num_tasks_param = parameter([2,4])
+ num_cpus_per_task_param = parameter([1,2,4,8])
+
+ @run_before('run')
+ def get_input(self):
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/C_PBE_SZP_CQ.ion .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/Conquest_coord .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/Conquest_input .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/H_PBE_SZP_CQ.ion .")
+
+@rfm.simple_test
+class test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0_6(ConquestBaseBenchmark):
+
+ tags = {"test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6"}
+ num_tasks_param = parameter([2,4])
+ num_cpus_per_task_param = parameter([1,2,4,8])
+
+ @run_before('run')
+ def get_input(self):
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/C_PBE_TZTP_CQ.ion .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/Conquest_coord .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/Conquest_input .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/H_PBE_TZTP_CQ.ion .")
+
+@rfm.simple_test
+class test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0_4_SCF(ConquestBaseBenchmark):
+
+ tags = {"test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF"}
+ num_tasks_param = parameter([2,4])
+ num_cpus_per_task_param = parameter([1,2,4,8])
+
+ @run_before('run')
+ def get_input(self):
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/C_PBE_SZP_CQ.ion .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/Conquest_coord .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/Conquest_input .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/H_PBE_SZP_CQ.ion .")
+
+@rfm.simple_test
+class test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF(ConquestBaseBenchmark):
+
+ tags = {"test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF"}
+ num_tasks_param = parameter([2,4])
+ num_cpus_per_task_param = parameter([1,2,4,8])
+
+ @run_before('run')
+ def get_input(self):
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/C_PBE_SZP_CQ.ion .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/C.gto .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/Conquest_coord .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/Conquest_input .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/H_PBE_SZP_CQ.ion .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/H.gto .")
+
+@rfm.simple_test
+class test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0_6(ConquestBaseBenchmark):
+
+ tags = {"test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6"}
+ num_tasks_param = parameter([2,4])
+ num_cpus_per_task_param = parameter([1,2,4,8])
+
+ @run_before('run')
+ def get_input(self):
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/C_PBE_DZP_CQ.ion .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/Conquest_coord .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/Conquest_input .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/H_PBE_DZP_CQ.ion .")
+
+@rfm.simple_test
+class test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0_6(ConquestBaseBenchmark):
+
+ tags = {"test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6"}
+ num_tasks_param = parameter([2,4])
+ num_cpus_per_task_param = parameter([1,2,4,8])
+
+ @run_before('run')
+ def get_input(self):
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/C_PBE_SZP_CQ.ion .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/Conquest_coord .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/Conquest_input .")
+ self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/H_PBE_SZP_CQ.ion .")
+
+
+# @rfm.simple_test
+# class Water64(ConquestBaseBenchmark):
+
+# tags = {"water64"}
+# num_tasks_param = 8
+# num_cpus_per_task = 4
+
+# @run_before('run')
+# def get_input(self):
+# self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/water_64mols/Conquest_input .")
+# self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/water_64mols/H2O_coord.in .")
+# self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/water_64mols/H_SZ.ion .")
+# self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/water_64mols/H_SZP.ion .")
+# self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/water_64mols/O_SZ.ion .")
+# self.prerun_cmds.append(f"cp {self.conquest_base_dir}/benchmarks/water_64mols/O_SZP.ion .")
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/C_PBE_DZP_CQ.ion b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/C_PBE_DZP_CQ.ion
new file mode 100644
index 000000000..a671a58e1
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/C_PBE_DZP_CQ.ion
@@ -0,0 +1,4621 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2023/11/30 at 18:12
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: C.in (appended at end of file)
+ Core radii (bohr) : l=0 1.200 l=1 1.250
+ 2 valence shells : 2s 2p
+ XC functional code : 000101
+ XC description : GGA PBE96
+ Includes partial core corrections
+
+
+C basis set with GGA PBE96 functional
+n = 2, l = 0, 2 zetas
+ Radii: 6.25 3.17
+n = 2, l = 1, 2 zetas
+ Radii: 6.25 3.17
+n = 3, l = 2, 1 zetas, perturbative polarisation shell
+ Radii: 6.25
+
+
+ C pb nrl pcec
+
+
+C # Element symbol
+C # Label
+ 6.00 # Atomic number
+ 4.0000000000 # Valence charge
+ 12.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 2 5 # Lmax for basis, no of orbitals
+ 1 4 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 2 1 0 2.000000 #orbital l, n, z, is_polarized, population
+ 625 0.0100114372662820 6.2471368541599936
+ 0.00000000000 0.36399167361
+ 0.01001143727 0.36419984924
+ 0.02002287453 0.36482394184
+ 0.03003431180 0.36586265061
+ 0.04004574907 0.36731381168
+ 0.05005718633 0.36917440439
+ 0.06006862360 0.37144056001
+ 0.07008006086 0.37410757294
+ 0.08009149813 0.37716991423
+ 0.09010293540 0.38062124745
+ 0.10011437266 0.38445444689
+ 0.11012580993 0.38866161785
+ 0.12013724720 0.39323411912
+ 0.13014868446 0.39816258747
+ 0.14016012173 0.40343696403
+ 0.15017155899 0.40904652250
+ 0.16018299626 0.41497989916
+ 0.17019443353 0.42122512431
+ 0.18020587079 0.42776965532
+ 0.19021730806 0.43460041100
+ 0.20022874533 0.44170380712
+ 0.21024018259 0.44906579307
+ 0.22025161986 0.45667188949
+ 0.23026305712 0.46450722667
+ 0.24027449439 0.47255658362
+ 0.25028593166 0.48080442768
+ 0.26029736892 0.48923495457
+ 0.27030880619 0.49783212865
+ 0.28032024346 0.50657972332
+ 0.29033168072 0.51546136139
+ 0.30034311799 0.52446055533
+ 0.31035455525 0.53356074727
+ 0.32036599252 0.54274534856
+ 0.33037742979 0.55199777883
+ 0.34038886705 0.56130150444
+ 0.35040030432 0.57064007616
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+ 1.61320283267 0.00000418852
+ 1.62322272604 0.00000345144
+ 1.63324261941 0.00000279292
+ 1.64326251278 0.00000221314
+ 1.65328240615 0.00000171084
+ 1.66330229953 0.00000128349
+ 1.67332219290 0.00000092750
+ 1.68334208627 0.00000063847
+ 1.69336197964 0.00000041130
+ 1.70338187301 0.00000024046
+ 1.71340176638 0.00000012009
+ 1.72342165975 0.00000004416
+ 1.73344155312 0.00000000663
+ 1.74346144649 0.00000000155
+ 1.75348133986 0.00000002317
+ 1.76350123323 0.00000006601
+ 1.77352112660 0.00000012495
+ 1.78354101997 0.00000019525
+ 1.79356091334 0.00000027265
+ 1.80358080671 0.00000035331
+ 1.81360070009 0.00000043392
+ 1.82362059346 0.00000051163
+ 1.83364048683 0.00000058407
+ 1.84366038020 0.00000064934
+ 1.85368027357 0.00000070599
+ 1.86370016694 0.00000075297
+ 1.87372006031 0.00000078962
+ 1.88373995368 0.00000081563
+ 1.89375984705 0.00000083100
+ 1.90377974042 0.00000083600
+ 1.91379963379 0.00000083113
+ 1.92381952716 0.00000081707
+ 1.93383942053 0.00000079466
+ 1.94385931390 0.00000076485
+ 1.95387920727 0.00000072869
+ 1.96389910064 0.00000068725
+ 1.97391899402 0.00000064163
+ 1.98393888739 0.00000059292
+ 1.99395878076 0.00000054217
+ 2.00397867413 0.00000049040
+ 2.01399856750 0.00000043854
+ 2.02401846087 0.00000038746
+ 2.03403835424 0.00000033790
+ 2.04405824761 0.00000029055
+ 2.05407814098 0.00000024597
+ 2.06409803435 0.00000020461
+ 2.07411792772 0.00000016683
+ 2.08413782109 0.00000013288
+ 2.09415771446 0.00000010294
+ 2.10417760783 0.00000007705
+ 2.11419750120 0.00000005521
+ 2.12421739457 0.00000003733
+ 2.13423728795 0.00000002324
+ 2.14425718132 0.00000001275
+ 2.15427707469 0.00000000558
+ 2.16429696806 0.00000000144
+ 2.17431686143 0.00000000001
+ 2.18433675480 0.00000000093
+ 2.19435664817 0.00000000387
+ 2.20437654154 0.00000000845
+ 2.21439643491 0.00000001433
+ 2.22441632828 0.00000002116
+ 2.23443622165 0.00000002863
+ 2.24445611502 0.00000003644
+ 2.25447600839 0.00000004429
+ 2.26449590176 0.00000005196
+ 2.27451579513 0.00000005922
+ 2.28453568850 0.00000006589
+ 2.29455558188 0.00000007182
+ 2.30457547525 0.00000007688
+ 2.31459536862 0.00000008100
+ 2.32461526199 0.00000008411
+ 2.33463515536 0.00000008620
+ 2.34465504873 0.00000008725
+ 2.35467494210 0.00000008729
+ 2.36469483547 0.00000008637
+ 2.37471472884 0.00000008455
+ 2.38473462221 0.00000008191
+ 2.39475451558 0.00000007854
+ 2.40477440895 0.00000007454
+ 2.41479430232 0.00000007002
+ 2.42481419569 0.00000006508
+ 2.43483408906 0.00000005983
+ 2.44485398244 0.00000005439
+ 2.45487387581 0.00000004886
+ 2.46489376918 0.00000004334
+ 2.47491366255 0.00000003791
+ 2.48493355592 0.00000003267
+ 2.49495344929 0.00000002768
+ 2.50497334266 0.00000002302
+ 2.51499323603 0.00000001872
+ 2.52501312940 0.00000001484
+ 2.53503302277 0.00000001139
+ 2.54505291614 0.00000000841
+ 2.55507280951 0.00000000590
+ 2.56509270288 0.00000000385
+ 2.57511259625 0.00000000226
+ 2.58513248962 0.00000000113
+ 2.59515238299 0.00000000044
+ 2.60517227637 0.00000000010
+ 2.61519216974 0.00000000000
+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+C 6.00 1 2 4 upf
+#
+# n l f energy (Ha)
+1 0 2.00
+2 0 2.00
+2 1 2.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.20000 -0.50533 4 7 9.00000
+1 1.25000 -0.19424 4 8 9.40000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 1.20000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 2.00000
+1 2 1.50000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+3 4.00000 1.55000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+6.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/Conquest_coord b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/Conquest_coord
new file mode 100644
index 000000000..ce2e9ebf2
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/Conquest_coord
@@ -0,0 +1,10 @@
+22.676714 0.000000 0.000000
+0.000000 22.676714 0.000000
+0.000000 0.000000 22.676714
+6
+ 0.50000000 0.50000000 0.44437500 2 T T T
+ 0.50000000 0.50000000 0.55562500 2 T T T
+ 0.57859183 0.50000000 0.39900000 1 T T T
+ 0.57859183 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.39900000 1 T T T
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/Conquest_input b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/Conquest_input
new file mode 100644
index 000000000..14ce6374c
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/Conquest_input
@@ -0,0 +1,40 @@
+IO.Title isolated C2H4 with PBE0
+IO.Coordinates Conquest_coord
+IO.FractionalCoordinates T
+IO.Iprint 0
+IO.WriteOutToFile F
+IO.Iprint_exx 4
+IO.TimingOn T
+
+## General Parameters
+General.NumberOfSpecies 2
+General.DifferentFunctional T
+General.FunctionalType 201
+General.PAOFromFiles T
+
+## Moving Atoms
+AtomMove.TypeOfRun static
+
+## Basis Sets
+Basis.BasisSet PAOs
+
+## Energy Minimisation
+minE.SelfConsistent T
+minE.SCTolerance 0.2e-1
+
+## Integration Grid
+Grid.GridCutoff 90
+
+## Finding Density Matrix
+DM.SolutionMethod diagon
+
+## EXX Parameters
+EXX.GridSpacing 0.2
+EXX.Scheme 1
+
+## Atomic Information
+%block ChemicalSpeciesLabel
+1 1.0080 H H_PBE_DZP_CQ.ion
+2 12.0110 C C_PBE_DZP_CQ.ion
+%endblock
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/Conquest_out.ref b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/Conquest_out.ref
new file mode 100644
index 000000000..abfdcd213
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/Conquest_out.ref
@@ -0,0 +1,120 @@
+ ________________________________________________________________________
+
+ CONQUEST
+
+ Concurrent Order N QUantum Electronic STructure
+ ________________________________________________________________________
+
+ Conquest lead developers:
+ D.R.Bowler (UCL, NIMS), T.Miyazaki (NIMS), A.Nakata (NIMS),
+ L. Truflandier (U. Bordeaux)
+
+ Developers:
+ M.Arita (NIMS), J.S.Baker (UCL), V.Brazdova (UCL), R.Choudhury (UCL),
+ S.Y.Mujahed (UCL), J.T.Poulton (UCL), Z.Raza (NIMS), A.Sena (UCL),
+ U.Terranova (UCL), L.Tong (UCL), A.Torralba (NIMS)
+
+ Early development:
+ I.J.Bush (STFC), C.M.Goringe (Keele), E.H.Hernandez (Keele)
+
+ Original inspiration and project oversight:
+ M.J.Gillan (Keele, UCL)
+ ________________________________________________________________________
+
+WARNING: Functional in input file differs to pseudopotential but proceeding: 201 101
+
+
+WARNING: Functional in input file differs to pseudopotential but proceeding: 201 101
+
+
+ Simulation cell dimensions: 22.6767 a0 x 22.6767 a0 x 22.6767 a0
+
+ Atomic coordinates (a0)
+ Atom X Y Z Species
+ 1 11.3384 11.3384 10.0770 2
+ 2 11.3384 11.3384 12.5997 2
+ 3 13.1206 11.3384 9.0480 1
+ 4 13.1206 11.3384 13.6287 1
+ 5 9.5562 11.3384 13.6287 1
+ 6 9.5562 11.3384 9.0480 1
+
+ Default k-point sampling of Gamma point only
+ All 1 Kpoints in fractional coordinates:
+ 1 0.000000 0.000000 0.000000 1.000
+
+ This calculation includes non-local pseudopotentials,
+ with a maximum core radius of 6.72726398
+
+ This job was run on 2024/02/13 at 11:02 +0100
+ Code was compiled on 2023/12/01 at 15:01 +0100
+ Version comment: Git Branch: f-exx-opt; tag, hash: v1.2-167-gddc9e439
+
+ Job title: isolated C2H4 with PBE0
+ Job to be run: static calculation
+
+ Ground state search:
+ Support functions represented with PAO basis
+ 1:1 PAO to SF mapping
+ Non-spin-polarised electrons
+ Solving for the K matrix using diagonalisation
+ Using Fermi-Dirac smearing
+
+ Integration grid size: 100 x 100 x 100
+
+ Integration grid spacing: 0.227 a0 x 0.227 a0 x 0.227 a0
+
+ Number of species: 2
+ --------------------------------------------------------
+ | # mass (au) Charge (e) SF Rad (a0) NSF Label |
+ --------------------------------------------------------
+ | 1 1.008 1.000 7.030 5 H |
+ | 2 12.011 4.000 6.576 13 C |
+ --------------------------------------------------------
+ SCF tolerance: 0.02000000
+ SCF iterations: 50
+
+ The calculation will be performed on 4 processes
+
+ The calculation will be performed on 1 thread
+
+ The functional used will be hyb PBE0
+
+ set_atom_dens: In set_atomic_density, electrons : 12.000000000000
+ PulayMixSC: Starting Pulay mixing, A_up = 0.500 A_dn = 0.500
+ PulayMixSC: Spin non-polarised calculation.
+ Harris-Foulkes Energy : -13.136777326671156 Ha
+ PulayMixSC: Pulay iteration 1 residual: 0.14729E-01
+ PulayMixSC: reached SCF residual of 0.14729E-01 after 1 iterations
+ | Number of electrons = 12.000000
+ |* Harris-Foulkes energy = -13.136777326671156 Ha
+ |* DFT total energy = -13.014081856667078 Ha
+
+ force: Forces on atoms (Ha/a0)
+ force: Atom X Y Z
+ force: 1 0.0000000000 -0.0000000000 -0.1030405190
+ force: 2 0.0000000000 0.0000000000 0.1030405190
+ force: 3 0.1598274352 -0.0000000000 -0.0940971289
+ force: 4 0.1598274352 0.0000000000 0.0940971289
+ force: 5 -0.1598274352 0.0000000000 0.0940971289
+ force: 6 -0.1598274352 0.0000000000 -0.0940971289
+
+ force: Maximum force : 0.15982744(Ha/a0) on atom 4 in x direction
+ force: Force Residual: 0.16270168 Ha/a0
+ force: Total stress: -2.91337974 -0.21561294 -3.05409448 GPa
+ force: Average pressure: 2.06102905 GPa
+
+ get_E_and_F: Change in energy during last step of electronic optimisation: -0.13137E+02
+
+ BIBLIOGRAPHY: Please consider citing the following references in the conquest.bib file
+
+ CONQUEST: Bowler2002pt, Miyazaki2004, Nakata2020
+ Basis: Bowler2019
+ DM: Bowler:2006xr
+ Pseudopotentials: Hamann2013, Bowler2019
+
+
+ Warnings written to file Conquest_warnings; please check
+
+ Max total mem use is 2041.578 MB
+
+ Total run time was: 215.211 seconds
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/H_PBE_DZP_CQ.ion b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/H_PBE_DZP_CQ.ion
new file mode 100644
index 000000000..f02fe9759
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.2/H_PBE_DZP_CQ.ion
@@ -0,0 +1,3371 @@
+
+
+ Git Branch: f-exx-opt; tag, hash: v1.2-169-g41cf7e2b
+ Date generated : 2024/02/09 at 18:32
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: H.in (appended at end of file)
+ Core radii (bohr) : l=0 1.000 l=1 0.700
+ 1 valence shells : 1s
+ XC functional code : 000101
+ XC description : GGA PBE96
+
+
+H basis set with GGA PBE96 functional
+n = 1, l = 0, 2 zetas
+ Radii: 6.73 3.14
+n = 3, l = 1, 1 zetas, perturbative polarisation shell
+ Radii: 6.73
+
+
+ H pb nrl nc
+
+
+H # Element symbol
+H # Label
+ 1.00 # Atomic number
+ 1.0000000000 # Valence charge
+ 1.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 1 3 # Lmax for basis, no of orbitals
+ 1 3 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 1 1 0 1.000000 #orbital l, n, z, is_polarized, population
+ 673 0.0100108094935117 6.7272639796398339
+ 0.00000000000 1.56155255225
+ 0.01001080949 1.56134081579
+ 0.02002161899 1.56070586103
+ 0.03003242848 1.55964896338
+ 0.04004323797 1.55817219676
+ 0.05005404747 1.55627843492
+ 0.06006485696 1.55397133802
+ 0.07007566645 1.55125532942
+ 0.08008647595 1.54813556702
+ 0.09009728544 1.54461791016
+ 0.10010809494 1.54070888255
+ 0.11011890443 1.53641563176
+ 0.12012971392 1.53174588577
+ 0.13014052342 1.52670790712
+ 0.14015133291 1.52131044519
+ 0.15016214240 1.51556268735
+ 0.16017295190 1.50947420926
+ 0.17018376139 1.50305492529
+ 0.18019457088 1.49631503919
+ 0.19020538038 1.48926499595
+ 0.20021618987 1.48191543510
+ 0.21022699936 1.47427714601
+ 0.22023780886 1.46636102560
+ 0.23024861835 1.45817803890
+ 0.24025942784 1.44973918268
+ 0.25027023734 1.44105545246
+ 0.26028104683 1.43213781311
+ 0.27029185632 1.42299717314
+ 0.28030266582 1.41364436277
+ 0.29031347531 1.40409011574
+ 0.30032428481 1.39434505482
+ 0.31033509430 1.38441968091
+ 0.32034590379 1.37432436547
+ 0.33035671329 1.36406934614
+ 0.34036752278 1.35366472507
+ 0.35037833227 1.34312046995
+ 0.36038914177 1.33244641698
+ 0.37039995126 1.32165227563
+ 0.38041076075 1.31074763480
+ 0.39042157025 1.29974196964
+ 0.40043237974 1.28864464905
+ 0.41044318923 1.27746494296
+ 0.42045399873 1.26621202936
+ 0.43046480822 1.25489500038
+ 0.44047561771 1.24352286722
+ 0.45048642721 1.23210456360
+ 0.46049723670 1.22064894730
+ 0.47050804620 1.20916479960
+ 0.48051885569 1.19766082252
+ 0.49052966518 1.18614563362
+ 0.50054047468 1.17462775819
+ 0.51055128417 1.16311561896
+ 0.52056209366 1.15161752334
+ 0.53057290316 1.14014164812
+ 0.54058371265 1.12869602198
+ 0.55059452214 1.11728850594
+ 0.56060533164 1.10592677176
+ 0.57061614113 1.09461827923
+ 0.58062695062 1.08337025177
+ 0.59063776012 1.07218965161
+ 0.60064856961 1.06108315432
+ 0.61065937910 1.05005712345
+ 0.62067018860 1.03911758559
+ 0.63068099809 1.02827020618
+ 0.64069180758 1.01752026688
+ 0.65070261708 1.00687264443
+ 0.66071342657 0.99633179185
+ 0.67072423607 0.98590172198
+ 0.68073504556 0.97558599407
+ 0.69074585505 0.96538770341
+ 0.70075666455 0.95530947455
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+ 0.72077828353 0.93552133092
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+ 0.75081071201 0.90677808017
+ 0.76082152151 0.89744905638
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+ 0.78084314049 0.87916648941
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+ 0.80086475948 0.86137657557
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+# Vna:_______________
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+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+H 1.00 0 1 4 upf
+#
+# n l f energy (Ha)
+1 0 1.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.00000 -0.23860 4 7 8.50000
+1 0.70000 0.05000 4 7 11.00000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 0.70000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 1.00000
+1 1 1.00000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+0 0.00000 0.00000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+3.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/C_PBE_DZP_CQ.ion b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/C_PBE_DZP_CQ.ion
new file mode 100644
index 000000000..a671a58e1
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/C_PBE_DZP_CQ.ion
@@ -0,0 +1,4621 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2023/11/30 at 18:12
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: C.in (appended at end of file)
+ Core radii (bohr) : l=0 1.200 l=1 1.250
+ 2 valence shells : 2s 2p
+ XC functional code : 000101
+ XC description : GGA PBE96
+ Includes partial core corrections
+
+
+C basis set with GGA PBE96 functional
+n = 2, l = 0, 2 zetas
+ Radii: 6.25 3.17
+n = 2, l = 1, 2 zetas
+ Radii: 6.25 3.17
+n = 3, l = 2, 1 zetas, perturbative polarisation shell
+ Radii: 6.25
+
+
+ C pb nrl pcec
+
+
+C # Element symbol
+C # Label
+ 6.00 # Atomic number
+ 4.0000000000 # Valence charge
+ 12.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 2 5 # Lmax for basis, no of orbitals
+ 1 4 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 2 1 0 2.000000 #orbital l, n, z, is_polarized, population
+ 625 0.0100114372662820 6.2471368541599936
+ 0.00000000000 0.36399167361
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+# Vna:_______________
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+ 5.18592450393 -0.77131950371
+ 5.19593594120 -0.76983333892
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+ 5.55634768279 -0.71989819565
+ 5.56635912005 -0.71860341431
+ 5.57637055732 -0.71731328209
+ 5.58638199459 -0.71602777398
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+ 5.61641630638 -0.71219874708
+ 5.62642774365 -0.71093148904
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+ 5.67648492998 -0.70466224938
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+ 5.69650780451 -0.70218540383
+ 5.70651924178 -0.70095349906
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+ 5.72654211631 -0.69850261156
+ 5.73655355358 -0.69728358374
+ 5.74656499085 -0.69606880339
+ 5.75657642811 -0.69485824835
+ 5.76658786538 -0.69365189662
+ 5.77659930264 -0.69244972635
+ 5.78661073991 -0.69125171582
+ 5.79662217718 -0.69005784349
+ 5.80663361444 -0.68886808795
+ 5.81664505171 -0.68768242794
+ 5.82665648898 -0.68650084235
+ 5.83666792624 -0.68532331022
+ 5.84667936351 -0.68414981073
+ 5.85669080077 -0.68298032318
+ 5.86670223804 -0.68181482705
+ 5.87671367531 -0.68065330194
+ 5.88672511257 -0.67949572758
+ 5.89673654984 -0.67834208385
+ 5.90674798711 -0.67719235077
+ 5.91675942437 -0.67604650848
+ 5.92677086164 -0.67490453727
+ 5.93678229891 -0.67376641756
+ 5.94679373617 -0.67263212990
+ 5.95680517344 -0.67150165495
+ 5.96681661070 -0.67037497355
+ 5.97682804797 -0.66925206661
+ 5.98683948524 -0.66813291520
+ 5.99685092250 -0.66701750053
+ 6.00686235977 -0.66590580389
+ 6.01687379704 -0.66479780674
+ 6.02688523430 -0.66369349063
+ 6.03689667157 -0.66259283725
+ 6.04690810883 -0.66149582841
+ 6.05691954610 -0.66040244603
+ 6.06693098337 -0.65931267217
+ 6.07694242063 -0.65822648899
+ 6.08695385790 -0.65714387877
+ 6.09696529517 -0.65606482391
+ 6.10697673243 -0.65498930693
+ 6.11698816970 -0.65391731045
+ 6.12699960696 -0.65284881723
+ 6.13701104423 -0.65178381010
+ 6.14702248150 -0.65072227205
+ 6.15703391876 -0.64966418615
+ 6.16704535603 -0.64860953558
+ 6.17705679330 -0.64755830364
+ 6.18706823056 -0.64651047374
+ 6.19707966783 -0.64546602939
+ 6.20709110509 -0.64442495420
+ 6.21710254236 -0.64338723191
+ 6.22711397963 -0.64235284634
+ 6.23712541689 -0.64132178143
+ 6.24713685416 -0.64029332051
+# Core:__________________________
+ 262 0.01001989337 2.61519216974 # npts, delta, cutoff
+ 0.00000000000 0.87236701390
+ 0.01001989337 0.87200154737
+ 0.02003978674 0.87090598593
+ 0.03005968011 0.86908291315
+ 0.04007957348 0.86653661495
+ 0.05009946685 0.86327306742
+ 0.06011936022 0.85929991675
+ 0.07013925359 0.85462645159
+ 0.08015914697 0.84926356764
+ 0.09017904034 0.84322372913
+ 0.10019893371 0.83652092332
+ 0.11021882708 0.82917060772
+ 0.12023872045 0.82118965753
+ 0.13025861382 0.81259630320
+ 0.14027850719 0.80341006345
+ 0.15029840056 0.79365167872
+ 0.16031829393 0.78334303544
+ 0.17033818730 0.77250708996
+ 0.18035808067 0.76116778731
+ 0.19037797404 0.74934997856
+ 0.20039786741 0.73707933484
+ 0.21041776078 0.72438225958
+ 0.22043765415 0.71128579873
+ 0.23045754752 0.69781755035
+ 0.24047744090 0.68400557257
+ 0.25049733427 0.66987829152
+ 0.26051722764 0.65546440905
+ 0.27053712101 0.64079281080
+ 0.28055701438 0.62589247505
+ 0.29057690775 0.61079238242
+ 0.30059680112 0.59552142736
+ 0.31061669449 0.58010833106
+ 0.32063658786 0.56458155717
+ 0.33065648123 0.54896922904
+ 0.34067637460 0.53329905098
+ 0.35069626797 0.51759823149
+ 0.36071616134 0.50189341054
+ 0.37073605471 0.48621059043
+ 0.38075594808 0.47057507003
+ 0.39077584145 0.45501138358
+ 0.40079573483 0.43954324378
+ 0.41081562820 0.42419348861
+ 0.42083552157 0.40898403352
+ 0.43085541494 0.39393582767
+ 0.44087530831 0.37906881496
+ 0.45089520168 0.36440190024
+ 0.46091509505 0.34995291995
+ 0.47093498842 0.33573861753
+ 0.48095488179 0.32177462386
+ 0.49097477516 0.30807544244
+ 0.50099466853 0.29465443916
+ 0.51101456190 0.28152383667
+ 0.52103445527 0.26869471321
+ 0.53105434864 0.25617700635
+ 0.54107424201 0.24397952001
+ 0.55109413538 0.23210993636
+ 0.56111402876 0.22057483164
+ 0.57113392213 0.20937969491
+ 0.58115381550 0.19852895104
+ 0.59117370887 0.18802598696
+ 0.60119360224 0.17787318067
+ 0.61121349561 0.16807193307
+ 0.62123338898 0.15862270282
+ 0.63125328235 0.14952504313
+ 0.64127317572 0.14077764091
+ 0.65129306909 0.13237835758
+ 0.66131296246 0.12432427135
+ 0.67133285583 0.11661172160
+ 0.68135274920 0.10923635341
+ 0.69137264257 0.10219316340
+ 0.70139253594 0.09547654613
+ 0.71141242932 0.08908034108
+ 0.72143232269 0.08299787923
+ 0.73145221606 0.07722203008
+ 0.74147210943 0.07174524830
+ 0.75149200280 0.06655961951
+ 0.76151189617 0.06165690581
+ 0.77153178954 0.05702859026
+ 0.78155168291 0.05266592032
+ 0.79157157628 0.04855995014
+ 0.80159146965 0.04470158148
+ 0.81161136302 0.04108160322
+ 0.82163125639 0.03769072926
+ 0.83165114976 0.03451963474
+ 0.84167104313 0.03155899046
+ 0.85169093650 0.02879949555
+ 0.86171082987 0.02623190812
+ 0.87173072325 0.02384707401
+ 0.88175061662 0.02163595358
+ 0.89177050999 0.01958964636
+ 0.90179040336 0.01769941385
+ 0.91181029673 0.01595670015
+ 0.92183019010 0.01435315056
+ 0.93185008347 0.01288062835
+ 0.94186997684 0.01153122939
+ 0.95188987021 0.01029729490
+ 0.96190976358 0.00917142238
+ 0.97192965695 0.00814647470
+ 0.98194955032 0.00721558735
+ 0.99196944369 0.00637217411
+ 1.00198933706 0.00560993109
+ 1.01200923043 0.00492283916
+ 1.02202912380 0.00430516504
+ 1.03204901718 0.00375146093
+ 1.04206891055 0.00325656297
+ 1.05208880392 0.00281558844
+ 1.06210869729 0.00242393191
+ 1.07212859066 0.00207726038
+ 1.08214848403 0.00177150758
+ 1.09216837740 0.00150286736
+ 1.10218827077 0.00126778645
+ 1.11220816414 0.00106295661
+ 1.12222805751 0.00088530612
+ 1.13224795088 0.00073199097
+ 1.14226784425 0.00060038558
+ 1.15228773762 0.00048807328
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+ 1.18234741774 0.00024565554
+ 1.19236731111 0.00019018248
+ 1.20238720448 0.00014470722
+ 1.21240709785 0.00010785867
+ 1.22242699122 0.00007840544
+ 1.23244688459 0.00005524630
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+ 1.25248667133 0.00002400071
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+ 1.27252645807 0.00000756884
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+ 1.29256624481 0.00000091481
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+ 1.78354101997 0.00000019525
+ 1.79356091334 0.00000027265
+ 1.80358080671 0.00000035331
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+ 1.82362059346 0.00000051163
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+ 1.88373995368 0.00000081563
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+ 1.90377974042 0.00000083600
+ 1.91379963379 0.00000083113
+ 1.92381952716 0.00000081707
+ 1.93383942053 0.00000079466
+ 1.94385931390 0.00000076485
+ 1.95387920727 0.00000072869
+ 1.96389910064 0.00000068725
+ 1.97391899402 0.00000064163
+ 1.98393888739 0.00000059292
+ 1.99395878076 0.00000054217
+ 2.00397867413 0.00000049040
+ 2.01399856750 0.00000043854
+ 2.02401846087 0.00000038746
+ 2.03403835424 0.00000033790
+ 2.04405824761 0.00000029055
+ 2.05407814098 0.00000024597
+ 2.06409803435 0.00000020461
+ 2.07411792772 0.00000016683
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+ 2.11419750120 0.00000005521
+ 2.12421739457 0.00000003733
+ 2.13423728795 0.00000002324
+ 2.14425718132 0.00000001275
+ 2.15427707469 0.00000000558
+ 2.16429696806 0.00000000144
+ 2.17431686143 0.00000000001
+ 2.18433675480 0.00000000093
+ 2.19435664817 0.00000000387
+ 2.20437654154 0.00000000845
+ 2.21439643491 0.00000001433
+ 2.22441632828 0.00000002116
+ 2.23443622165 0.00000002863
+ 2.24445611502 0.00000003644
+ 2.25447600839 0.00000004429
+ 2.26449590176 0.00000005196
+ 2.27451579513 0.00000005922
+ 2.28453568850 0.00000006589
+ 2.29455558188 0.00000007182
+ 2.30457547525 0.00000007688
+ 2.31459536862 0.00000008100
+ 2.32461526199 0.00000008411
+ 2.33463515536 0.00000008620
+ 2.34465504873 0.00000008725
+ 2.35467494210 0.00000008729
+ 2.36469483547 0.00000008637
+ 2.37471472884 0.00000008455
+ 2.38473462221 0.00000008191
+ 2.39475451558 0.00000007854
+ 2.40477440895 0.00000007454
+ 2.41479430232 0.00000007002
+ 2.42481419569 0.00000006508
+ 2.43483408906 0.00000005983
+ 2.44485398244 0.00000005439
+ 2.45487387581 0.00000004886
+ 2.46489376918 0.00000004334
+ 2.47491366255 0.00000003791
+ 2.48493355592 0.00000003267
+ 2.49495344929 0.00000002768
+ 2.50497334266 0.00000002302
+ 2.51499323603 0.00000001872
+ 2.52501312940 0.00000001484
+ 2.53503302277 0.00000001139
+ 2.54505291614 0.00000000841
+ 2.55507280951 0.00000000590
+ 2.56509270288 0.00000000385
+ 2.57511259625 0.00000000226
+ 2.58513248962 0.00000000113
+ 2.59515238299 0.00000000044
+ 2.60517227637 0.00000000010
+ 2.61519216974 0.00000000000
+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+C 6.00 1 2 4 upf
+#
+# n l f energy (Ha)
+1 0 2.00
+2 0 2.00
+2 1 2.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.20000 -0.50533 4 7 9.00000
+1 1.25000 -0.19424 4 8 9.40000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 1.20000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 2.00000
+1 2 1.50000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+3 4.00000 1.55000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+6.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/Conquest_coord b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/Conquest_coord
new file mode 100644
index 000000000..ce2e9ebf2
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/Conquest_coord
@@ -0,0 +1,10 @@
+22.676714 0.000000 0.000000
+0.000000 22.676714 0.000000
+0.000000 0.000000 22.676714
+6
+ 0.50000000 0.50000000 0.44437500 2 T T T
+ 0.50000000 0.50000000 0.55562500 2 T T T
+ 0.57859183 0.50000000 0.39900000 1 T T T
+ 0.57859183 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.39900000 1 T T T
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/Conquest_input b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/Conquest_input
new file mode 100644
index 000000000..527520629
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/Conquest_input
@@ -0,0 +1,40 @@
+IO.Title isolated C2H4 with PBE0
+IO.Coordinates Conquest_coord
+IO.FractionalCoordinates T
+IO.Iprint 0
+IO.WriteOutToFile F
+IO.Iprint_exx 4
+IO.TimingOn T
+
+## General Parameters
+General.NumberOfSpecies 2
+General.DifferentFunctional T
+General.FunctionalType 201
+General.PAOFromFiles T
+
+## Moving Atoms
+AtomMove.TypeOfRun static
+
+## Basis Sets
+Basis.BasisSet PAOs
+
+## Energy Minimisation
+minE.SelfConsistent T
+minE.SCTolerance 0.2e-1
+
+## Integration Grid
+Grid.GridCutoff 90
+
+## Finding Density Matrix
+DM.SolutionMethod diagon
+
+## EXX Parameters
+EXX.GridSpacing 0.4
+EXX.Scheme 1
+
+## Atomic Information
+%block ChemicalSpeciesLabel
+1 1.0080 H H_PBE_DZP_CQ.ion
+2 12.0110 C C_PBE_DZP_CQ.ion
+%endblock
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/Conquest_out.ref b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/Conquest_out.ref
new file mode 100644
index 000000000..c04701390
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/Conquest_out.ref
@@ -0,0 +1,120 @@
+ ________________________________________________________________________
+
+ CONQUEST
+
+ Concurrent Order N QUantum Electronic STructure
+ ________________________________________________________________________
+
+ Conquest lead developers:
+ D.R.Bowler (UCL, NIMS), T.Miyazaki (NIMS), A.Nakata (NIMS),
+ L. Truflandier (U. Bordeaux)
+
+ Developers:
+ M.Arita (NIMS), J.S.Baker (UCL), V.Brazdova (UCL), R.Choudhury (UCL),
+ S.Y.Mujahed (UCL), J.T.Poulton (UCL), Z.Raza (NIMS), A.Sena (UCL),
+ U.Terranova (UCL), L.Tong (UCL), A.Torralba (NIMS)
+
+ Early development:
+ I.J.Bush (STFC), C.M.Goringe (Keele), E.H.Hernandez (Keele)
+
+ Original inspiration and project oversight:
+ M.J.Gillan (Keele, UCL)
+ ________________________________________________________________________
+
+WARNING: Functional in input file differs to pseudopotential but proceeding: 201 101
+
+
+WARNING: Functional in input file differs to pseudopotential but proceeding: 201 101
+
+
+ Simulation cell dimensions: 22.6767 a0 x 22.6767 a0 x 22.6767 a0
+
+ Atomic coordinates (a0)
+ Atom X Y Z Species
+ 1 11.3384 11.3384 10.0770 2
+ 2 11.3384 11.3384 12.5997 2
+ 3 13.1206 11.3384 9.0480 1
+ 4 13.1206 11.3384 13.6287 1
+ 5 9.5562 11.3384 13.6287 1
+ 6 9.5562 11.3384 9.0480 1
+
+ Default k-point sampling of Gamma point only
+ All 1 Kpoints in fractional coordinates:
+ 1 0.000000 0.000000 0.000000 1.000
+
+ This calculation includes non-local pseudopotentials,
+ with a maximum core radius of 6.72726398
+
+ This job was run on 2024/02/12 at 19:04 +0100
+ Code was compiled on 2023/12/01 at 15:01 +0100
+ Version comment: Git Branch: f-exx-opt; tag, hash: v1.2-167-gddc9e439
+
+ Job title: isolated C2H4 with PBE0
+ Job to be run: static calculation
+
+ Ground state search:
+ Support functions represented with PAO basis
+ 1:1 PAO to SF mapping
+ Non-spin-polarised electrons
+ Solving for the K matrix using diagonalisation
+ Using Fermi-Dirac smearing
+
+ Integration grid size: 100 x 100 x 100
+
+ Integration grid spacing: 0.227 a0 x 0.227 a0 x 0.227 a0
+
+ Number of species: 2
+ --------------------------------------------------------
+ | # mass (au) Charge (e) SF Rad (a0) NSF Label |
+ --------------------------------------------------------
+ | 1 1.008 1.000 7.030 5 H |
+ | 2 12.011 4.000 6.576 13 C |
+ --------------------------------------------------------
+ SCF tolerance: 0.02000000
+ SCF iterations: 50
+
+ The calculation will be performed on 4 processes
+
+ The calculation will be performed on 1 thread
+
+ The functional used will be hyb PBE0
+
+ set_atom_dens: In set_atomic_density, electrons : 12.000000000000
+ PulayMixSC: Starting Pulay mixing, A_up = 0.500 A_dn = 0.500
+ PulayMixSC: Spin non-polarised calculation.
+ Harris-Foulkes Energy : -13.136777326671154 Ha
+ PulayMixSC: Pulay iteration 1 residual: 0.14729E-01
+ PulayMixSC: reached SCF residual of 0.14729E-01 after 1 iterations
+ | Number of electrons = 12.000000
+ |* Harris-Foulkes energy = -13.136777326671154 Ha
+ |* DFT total energy = -13.014081856667081 Ha
+
+ force: Forces on atoms (Ha/a0)
+ force: Atom X Y Z
+ force: 1 0.0000000000 -0.0000000000 -0.1030405190
+ force: 2 0.0000000000 0.0000000000 0.1030405190
+ force: 3 0.1598274352 -0.0000000000 -0.0940971289
+ force: 4 0.1598274352 0.0000000000 0.0940971289
+ force: 5 -0.1598274352 0.0000000000 0.0940971289
+ force: 6 -0.1598274352 0.0000000000 -0.0940971289
+
+ force: Maximum force : 0.15982744(Ha/a0) on atom 4 in x direction
+ force: Force Residual: 0.16270168 Ha/a0
+ force: Total stress: -2.91337974 -0.21561294 -3.05409448 GPa
+ force: Average pressure: 2.06102905 GPa
+
+ get_E_and_F: Change in energy during last step of electronic optimisation: -0.13137E+02
+
+ BIBLIOGRAPHY: Please consider citing the following references in the conquest.bib file
+
+ CONQUEST: Bowler2002pt, Miyazaki2004, Nakata2020
+ Basis: Bowler2019
+ DM: Bowler:2006xr
+ Pseudopotentials: Hamann2013, Bowler2019
+
+
+ Warnings written to file Conquest_warnings; please check
+
+ Max total mem use is 169.694 MB
+
+ Total run time was: 30.312 seconds
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/H_PBE_DZP_CQ.ion b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/H_PBE_DZP_CQ.ion
new file mode 100644
index 000000000..f02fe9759
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.4/H_PBE_DZP_CQ.ion
@@ -0,0 +1,3371 @@
+
+
+ Git Branch: f-exx-opt; tag, hash: v1.2-169-g41cf7e2b
+ Date generated : 2024/02/09 at 18:32
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: H.in (appended at end of file)
+ Core radii (bohr) : l=0 1.000 l=1 0.700
+ 1 valence shells : 1s
+ XC functional code : 000101
+ XC description : GGA PBE96
+
+
+H basis set with GGA PBE96 functional
+n = 1, l = 0, 2 zetas
+ Radii: 6.73 3.14
+n = 3, l = 1, 1 zetas, perturbative polarisation shell
+ Radii: 6.73
+
+
+ H pb nrl nc
+
+
+H # Element symbol
+H # Label
+ 1.00 # Atomic number
+ 1.0000000000 # Valence charge
+ 1.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 1 3 # Lmax for basis, no of orbitals
+ 1 3 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 1 1 0 1.000000 #orbital l, n, z, is_polarized, population
+ 673 0.0100108094935117 6.7272639796398339
+ 0.00000000000 1.56155255225
+ 0.01001080949 1.56134081579
+ 0.02002161899 1.56070586103
+ 0.03003242848 1.55964896338
+ 0.04004323797 1.55817219676
+ 0.05005404747 1.55627843492
+ 0.06006485696 1.55397133802
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+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+H 1.00 0 1 4 upf
+#
+# n l f energy (Ha)
+1 0 1.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.00000 -0.23860 4 7 8.50000
+1 0.70000 0.05000 4 7 11.00000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 0.70000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 1.00000
+1 1 1.00000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+0 0.00000 0.00000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+3.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/C_PBE_DZP_CQ.ion b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/C_PBE_DZP_CQ.ion
new file mode 100644
index 000000000..a671a58e1
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/C_PBE_DZP_CQ.ion
@@ -0,0 +1,4621 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2023/11/30 at 18:12
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: C.in (appended at end of file)
+ Core radii (bohr) : l=0 1.200 l=1 1.250
+ 2 valence shells : 2s 2p
+ XC functional code : 000101
+ XC description : GGA PBE96
+ Includes partial core corrections
+
+
+C basis set with GGA PBE96 functional
+n = 2, l = 0, 2 zetas
+ Radii: 6.25 3.17
+n = 2, l = 1, 2 zetas
+ Radii: 6.25 3.17
+n = 3, l = 2, 1 zetas, perturbative polarisation shell
+ Radii: 6.25
+
+
+ C pb nrl pcec
+
+
+C # Element symbol
+C # Label
+ 6.00 # Atomic number
+ 4.0000000000 # Valence charge
+ 12.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 2 5 # Lmax for basis, no of orbitals
+ 1 4 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 2 1 0 2.000000 #orbital l, n, z, is_polarized, population
+ 625 0.0100114372662820 6.2471368541599936
+ 0.00000000000 0.36399167361
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+ 0.64127317572 0.14077764091
+ 0.65129306909 0.13237835758
+ 0.66131296246 0.12432427135
+ 0.67133285583 0.11661172160
+ 0.68135274920 0.10923635341
+ 0.69137264257 0.10219316340
+ 0.70139253594 0.09547654613
+ 0.71141242932 0.08908034108
+ 0.72143232269 0.08299787923
+ 0.73145221606 0.07722203008
+ 0.74147210943 0.07174524830
+ 0.75149200280 0.06655961951
+ 0.76151189617 0.06165690581
+ 0.77153178954 0.05702859026
+ 0.78155168291 0.05266592032
+ 0.79157157628 0.04855995014
+ 0.80159146965 0.04470158148
+ 0.81161136302 0.04108160322
+ 0.82163125639 0.03769072926
+ 0.83165114976 0.03451963474
+ 0.84167104313 0.03155899046
+ 0.85169093650 0.02879949555
+ 0.86171082987 0.02623190812
+ 0.87173072325 0.02384707401
+ 0.88175061662 0.02163595358
+ 0.89177050999 0.01958964636
+ 0.90179040336 0.01769941385
+ 0.91181029673 0.01595670015
+ 0.92183019010 0.01435315056
+ 0.93185008347 0.01288062835
+ 0.94186997684 0.01153122939
+ 0.95188987021 0.01029729490
+ 0.96190976358 0.00917142238
+ 0.97192965695 0.00814647470
+ 0.98194955032 0.00721558735
+ 0.99196944369 0.00637217411
+ 1.00198933706 0.00560993109
+ 1.01200923043 0.00492283916
+ 1.02202912380 0.00430516504
+ 1.03204901718 0.00375146093
+ 1.04206891055 0.00325656297
+ 1.05208880392 0.00281558844
+ 1.06210869729 0.00242393191
+ 1.07212859066 0.00207726038
+ 1.08214848403 0.00177150758
+ 1.09216837740 0.00150286736
+ 1.10218827077 0.00126778645
+ 1.11220816414 0.00106295661
+ 1.12222805751 0.00088530612
+ 1.13224795088 0.00073199097
+ 1.14226784425 0.00060038558
+ 1.15228773762 0.00048807328
+ 1.16230763099 0.00039283650
+ 1.17232752436 0.00031264695
+ 1.18234741774 0.00024565554
+ 1.19236731111 0.00019018248
+ 1.20238720448 0.00014470722
+ 1.21240709785 0.00010785867
+ 1.22242699122 0.00007840544
+ 1.23244688459 0.00005524630
+ 1.24246677796 0.00003740090
+ 1.25248667133 0.00002400071
+ 1.26250656470 0.00001428028
+ 1.27252645807 0.00000756884
+ 1.28254635144 0.00000328214
+ 1.29256624481 0.00000091481
+ 1.30258613818 0.00000003296
+ 1.31260603155 0.00000026724
+ 1.32262592492 0.00000130623
+ 1.33264581829 0.00000289033
+ 1.34266571167 0.00000480590
+ 1.35268560504 0.00000687997
+ 1.36270549841 0.00000897514
+ 1.37272539178 0.00001098506
+ 1.38274528515 0.00001283015
+ 1.39276517852 0.00001445373
+ 1.40278507189 0.00001581848
+ 1.41280496526 0.00001690332
+ 1.42282485863 0.00001770047
+ 1.43284475200 0.00001821292
+ 1.44286464537 0.00001845219
+ 1.45288453874 0.00001843626
+ 1.46290443211 0.00001818793
+ 1.47292432548 0.00001773321
+ 1.48294421885 0.00001710009
+ 1.49296411222 0.00001631746
+ 1.50298400560 0.00001541417
+ 1.51300389897 0.00001441832
+ 1.52302379234 0.00001335666
+ 1.53304368571 0.00001225415
+ 1.54306357908 0.00001113361
+ 1.55308347245 0.00001001551
+ 1.56310336582 0.00000891785
+ 1.57312325919 0.00000785604
+ 1.58314315256 0.00000684298
+ 1.59316304593 0.00000588905
+ 1.60318293930 0.00000500231
+ 1.61320283267 0.00000418852
+ 1.62322272604 0.00000345144
+ 1.63324261941 0.00000279292
+ 1.64326251278 0.00000221314
+ 1.65328240615 0.00000171084
+ 1.66330229953 0.00000128349
+ 1.67332219290 0.00000092750
+ 1.68334208627 0.00000063847
+ 1.69336197964 0.00000041130
+ 1.70338187301 0.00000024046
+ 1.71340176638 0.00000012009
+ 1.72342165975 0.00000004416
+ 1.73344155312 0.00000000663
+ 1.74346144649 0.00000000155
+ 1.75348133986 0.00000002317
+ 1.76350123323 0.00000006601
+ 1.77352112660 0.00000012495
+ 1.78354101997 0.00000019525
+ 1.79356091334 0.00000027265
+ 1.80358080671 0.00000035331
+ 1.81360070009 0.00000043392
+ 1.82362059346 0.00000051163
+ 1.83364048683 0.00000058407
+ 1.84366038020 0.00000064934
+ 1.85368027357 0.00000070599
+ 1.86370016694 0.00000075297
+ 1.87372006031 0.00000078962
+ 1.88373995368 0.00000081563
+ 1.89375984705 0.00000083100
+ 1.90377974042 0.00000083600
+ 1.91379963379 0.00000083113
+ 1.92381952716 0.00000081707
+ 1.93383942053 0.00000079466
+ 1.94385931390 0.00000076485
+ 1.95387920727 0.00000072869
+ 1.96389910064 0.00000068725
+ 1.97391899402 0.00000064163
+ 1.98393888739 0.00000059292
+ 1.99395878076 0.00000054217
+ 2.00397867413 0.00000049040
+ 2.01399856750 0.00000043854
+ 2.02401846087 0.00000038746
+ 2.03403835424 0.00000033790
+ 2.04405824761 0.00000029055
+ 2.05407814098 0.00000024597
+ 2.06409803435 0.00000020461
+ 2.07411792772 0.00000016683
+ 2.08413782109 0.00000013288
+ 2.09415771446 0.00000010294
+ 2.10417760783 0.00000007705
+ 2.11419750120 0.00000005521
+ 2.12421739457 0.00000003733
+ 2.13423728795 0.00000002324
+ 2.14425718132 0.00000001275
+ 2.15427707469 0.00000000558
+ 2.16429696806 0.00000000144
+ 2.17431686143 0.00000000001
+ 2.18433675480 0.00000000093
+ 2.19435664817 0.00000000387
+ 2.20437654154 0.00000000845
+ 2.21439643491 0.00000001433
+ 2.22441632828 0.00000002116
+ 2.23443622165 0.00000002863
+ 2.24445611502 0.00000003644
+ 2.25447600839 0.00000004429
+ 2.26449590176 0.00000005196
+ 2.27451579513 0.00000005922
+ 2.28453568850 0.00000006589
+ 2.29455558188 0.00000007182
+ 2.30457547525 0.00000007688
+ 2.31459536862 0.00000008100
+ 2.32461526199 0.00000008411
+ 2.33463515536 0.00000008620
+ 2.34465504873 0.00000008725
+ 2.35467494210 0.00000008729
+ 2.36469483547 0.00000008637
+ 2.37471472884 0.00000008455
+ 2.38473462221 0.00000008191
+ 2.39475451558 0.00000007854
+ 2.40477440895 0.00000007454
+ 2.41479430232 0.00000007002
+ 2.42481419569 0.00000006508
+ 2.43483408906 0.00000005983
+ 2.44485398244 0.00000005439
+ 2.45487387581 0.00000004886
+ 2.46489376918 0.00000004334
+ 2.47491366255 0.00000003791
+ 2.48493355592 0.00000003267
+ 2.49495344929 0.00000002768
+ 2.50497334266 0.00000002302
+ 2.51499323603 0.00000001872
+ 2.52501312940 0.00000001484
+ 2.53503302277 0.00000001139
+ 2.54505291614 0.00000000841
+ 2.55507280951 0.00000000590
+ 2.56509270288 0.00000000385
+ 2.57511259625 0.00000000226
+ 2.58513248962 0.00000000113
+ 2.59515238299 0.00000000044
+ 2.60517227637 0.00000000010
+ 2.61519216974 0.00000000000
+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+C 6.00 1 2 4 upf
+#
+# n l f energy (Ha)
+1 0 2.00
+2 0 2.00
+2 1 2.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.20000 -0.50533 4 7 9.00000
+1 1.25000 -0.19424 4 8 9.40000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 1.20000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 2.00000
+1 2 1.50000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+3 4.00000 1.55000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+6.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/Conquest_coord b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/Conquest_coord
new file mode 100644
index 000000000..ce2e9ebf2
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/Conquest_coord
@@ -0,0 +1,10 @@
+22.676714 0.000000 0.000000
+0.000000 22.676714 0.000000
+0.000000 0.000000 22.676714
+6
+ 0.50000000 0.50000000 0.44437500 2 T T T
+ 0.50000000 0.50000000 0.55562500 2 T T T
+ 0.57859183 0.50000000 0.39900000 1 T T T
+ 0.57859183 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.39900000 1 T T T
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/Conquest_input b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/Conquest_input
new file mode 100644
index 000000000..24efb8f65
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/Conquest_input
@@ -0,0 +1,40 @@
+IO.Title isolated C2H4 with PBE0
+IO.Coordinates Conquest_coord
+IO.FractionalCoordinates T
+IO.Iprint 0
+IO.WriteOutToFile F
+IO.Iprint_exx 4
+IO.TimingOn T
+
+## General Parameters
+General.NumberOfSpecies 2
+General.DifferentFunctional T
+General.FunctionalType 201
+General.PAOFromFiles T
+
+## Moving Atoms
+AtomMove.TypeOfRun static
+
+## Basis Sets
+Basis.BasisSet PAOs
+
+## Energy Minimisation
+minE.SelfConsistent T
+minE.SCTolerance 0.2e-1
+
+## Integration Grid
+Grid.GridCutoff 90
+
+## Finding Density Matrix
+DM.SolutionMethod diagon
+
+## EXX Parameters
+EXX.GridSpacing 0.6
+EXX.Scheme 1
+
+## Atomic Information
+%block ChemicalSpeciesLabel
+1 1.0080 H H_PBE_DZP_CQ.ion
+2 12.0110 C C_PBE_DZP_CQ.ion
+%endblock
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/Conquest_out.ref_2proc b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/Conquest_out.ref_2proc
new file mode 100644
index 000000000..34f2982e4
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/Conquest_out.ref_2proc
@@ -0,0 +1,120 @@
+ ________________________________________________________________________
+
+ CONQUEST
+
+ Concurrent Order N QUantum Electronic STructure
+ ________________________________________________________________________
+
+ Conquest lead developers:
+ D.R.Bowler (UCL, NIMS), T.Miyazaki (NIMS), A.Nakata (NIMS),
+ L. Truflandier (U. Bordeaux)
+
+ Developers:
+ M.Arita (NIMS), J.S.Baker (UCL), V.Brazdova (UCL), R.Choudhury (UCL),
+ S.Y.Mujahed (UCL), J.T.Poulton (UCL), Z.Raza (NIMS), A.Sena (UCL),
+ U.Terranova (UCL), L.Tong (UCL), A.Torralba (NIMS)
+
+ Early development:
+ I.J.Bush (STFC), C.M.Goringe (Keele), E.H.Hernandez (Keele)
+
+ Original inspiration and project oversight:
+ M.J.Gillan (Keele, UCL)
+ ________________________________________________________________________
+
+WARNING: Functional in input file differs to pseudopotential but proceeding: 201 101
+
+
+WARNING: Functional in input file differs to pseudopotential but proceeding: 201 101
+
+
+ Simulation cell dimensions: 22.6767 a0 x 22.6767 a0 x 22.6767 a0
+
+ Atomic coordinates (a0)
+ Atom X Y Z Species
+ 1 11.3384 11.3384 10.0770 2
+ 2 11.3384 11.3384 12.5997 2
+ 3 13.1206 11.3384 9.0480 1
+ 4 13.1206 11.3384 13.6287 1
+ 5 9.5562 11.3384 13.6287 1
+ 6 9.5562 11.3384 9.0480 1
+
+ Default k-point sampling of Gamma point only
+ All 1 Kpoints in fractional coordinates:
+ 1 0.000000 0.000000 0.000000 1.000
+
+ This calculation includes non-local pseudopotentials,
+ with a maximum core radius of 6.72726398
+
+ This job was run on 2024/02/12 at 19:02 +0100
+ Code was compiled on 2023/12/01 at 15:01 +0100
+ Version comment: Git Branch: f-exx-opt; tag, hash: v1.2-167-gddc9e439
+
+ Job title: isolated C2H4 with PBE0
+ Job to be run: static calculation
+
+ Ground state search:
+ Support functions represented with PAO basis
+ 1:1 PAO to SF mapping
+ Non-spin-polarised electrons
+ Solving for the K matrix using diagonalisation
+ Using Fermi-Dirac smearing
+
+ Integration grid size: 100 x 100 x 100
+
+ Integration grid spacing: 0.227 a0 x 0.227 a0 x 0.227 a0
+
+ Number of species: 2
+ --------------------------------------------------------
+ | # mass (au) Charge (e) SF Rad (a0) NSF Label |
+ --------------------------------------------------------
+ | 1 1.008 1.000 7.030 5 H |
+ | 2 12.011 4.000 6.576 13 C |
+ --------------------------------------------------------
+ SCF tolerance: 0.02000000
+ SCF iterations: 50
+
+ The calculation will be performed on 2 processes
+
+ The calculation will be performed on 1 thread
+
+ The functional used will be hyb PBE0
+
+ set_atom_dens: In set_atomic_density, electrons : 12.000000000000
+ PulayMixSC: Starting Pulay mixing, A_up = 0.500 A_dn = 0.500
+ PulayMixSC: Spin non-polarised calculation.
+ Harris-Foulkes Energy : -13.136777326671099 Ha
+ PulayMixSC: Pulay iteration 1 residual: 0.14729E-01
+ PulayMixSC: reached SCF residual of 0.14729E-01 after 1 iterations
+ | Number of electrons = 12.000000
+ |* Harris-Foulkes energy = -13.136777326671099 Ha
+ |* DFT total energy = -13.014081856666639 Ha
+
+ force: Forces on atoms (Ha/a0)
+ force: Atom X Y Z
+ force: 1 0.0000000000 -0.0000000000 -0.1030405190
+ force: 2 -0.0000000000 -0.0000000000 0.1030405190
+ force: 3 0.1598274352 0.0000000000 -0.0940971289
+ force: 4 0.1598274352 0.0000000000 0.0940971289
+ force: 5 -0.1598274352 0.0000000000 0.0940971289
+ force: 6 -0.1598274352 0.0000000000 -0.0940971289
+
+ force: Maximum force : 0.15982744(Ha/a0) on atom 3 in x direction
+ force: Force Residual: 0.16270168 Ha/a0
+ force: Total stress: -2.91337974 -0.21561294 -3.05409448 GPa
+ force: Average pressure: 2.06102905 GPa
+
+ get_E_and_F: Change in energy during last step of electronic optimisation: -0.13137E+02
+
+ BIBLIOGRAPHY: Please consider citing the following references in the conquest.bib file
+
+ CONQUEST: Bowler2002pt, Miyazaki2004, Nakata2020
+ Basis: Bowler2019
+ DM: Bowler:2006xr
+ Pseudopotentials: Hamann2013, Bowler2019
+
+
+ Warnings written to file Conquest_warnings; please check
+
+ Max total mem use is 281.884 MB
+
+ Total run time was: 10.121 seconds
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/Conquest_out.ref_4proc b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/Conquest_out.ref_4proc
new file mode 100644
index 000000000..b3f8f2a91
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/Conquest_out.ref_4proc
@@ -0,0 +1,120 @@
+ ________________________________________________________________________
+
+ CONQUEST
+
+ Concurrent Order N QUantum Electronic STructure
+ ________________________________________________________________________
+
+ Conquest lead developers:
+ D.R.Bowler (UCL, NIMS), T.Miyazaki (NIMS), A.Nakata (NIMS),
+ L. Truflandier (U. Bordeaux)
+
+ Developers:
+ M.Arita (NIMS), J.S.Baker (UCL), V.Brazdova (UCL), R.Choudhury (UCL),
+ S.Y.Mujahed (UCL), J.T.Poulton (UCL), Z.Raza (NIMS), A.Sena (UCL),
+ U.Terranova (UCL), L.Tong (UCL), A.Torralba (NIMS)
+
+ Early development:
+ I.J.Bush (STFC), C.M.Goringe (Keele), E.H.Hernandez (Keele)
+
+ Original inspiration and project oversight:
+ M.J.Gillan (Keele, UCL)
+ ________________________________________________________________________
+
+WARNING: Functional in input file differs to pseudopotential but proceeding: 201 101
+
+
+WARNING: Functional in input file differs to pseudopotential but proceeding: 201 101
+
+
+ Simulation cell dimensions: 22.6767 a0 x 22.6767 a0 x 22.6767 a0
+
+ Atomic coordinates (a0)
+ Atom X Y Z Species
+ 1 11.3384 11.3384 10.0770 2
+ 2 11.3384 11.3384 12.5997 2
+ 3 13.1206 11.3384 9.0480 1
+ 4 13.1206 11.3384 13.6287 1
+ 5 9.5562 11.3384 13.6287 1
+ 6 9.5562 11.3384 9.0480 1
+
+ Default k-point sampling of Gamma point only
+ All 1 Kpoints in fractional coordinates:
+ 1 0.000000 0.000000 0.000000 1.000
+
+ This calculation includes non-local pseudopotentials,
+ with a maximum core radius of 6.72726398
+
+ This job was run on 2024/02/12 at 19:01 +0100
+ Code was compiled on 2023/12/01 at 15:01 +0100
+ Version comment: Git Branch: f-exx-opt; tag, hash: v1.2-167-gddc9e439
+
+ Job title: isolated C2H4 with PBE0
+ Job to be run: static calculation
+
+ Ground state search:
+ Support functions represented with PAO basis
+ 1:1 PAO to SF mapping
+ Non-spin-polarised electrons
+ Solving for the K matrix using diagonalisation
+ Using Fermi-Dirac smearing
+
+ Integration grid size: 100 x 100 x 100
+
+ Integration grid spacing: 0.227 a0 x 0.227 a0 x 0.227 a0
+
+ Number of species: 2
+ --------------------------------------------------------
+ | # mass (au) Charge (e) SF Rad (a0) NSF Label |
+ --------------------------------------------------------
+ | 1 1.008 1.000 7.030 5 H |
+ | 2 12.011 4.000 6.576 13 C |
+ --------------------------------------------------------
+ SCF tolerance: 0.02000000
+ SCF iterations: 50
+
+ The calculation will be performed on 4 processes
+
+ The calculation will be performed on 1 thread
+
+ The functional used will be hyb PBE0
+
+ set_atom_dens: In set_atomic_density, electrons : 12.000000000000
+ PulayMixSC: Starting Pulay mixing, A_up = 0.500 A_dn = 0.500
+ PulayMixSC: Spin non-polarised calculation.
+ Harris-Foulkes Energy : -13.136777326671154 Ha
+ PulayMixSC: Pulay iteration 1 residual: 0.14729E-01
+ PulayMixSC: reached SCF residual of 0.14729E-01 after 1 iterations
+ | Number of electrons = 12.000000
+ |* Harris-Foulkes energy = -13.136777326671154 Ha
+ |* DFT total energy = -13.014081856667081 Ha
+
+ force: Forces on atoms (Ha/a0)
+ force: Atom X Y Z
+ force: 1 0.0000000000 -0.0000000000 -0.1030405190
+ force: 2 0.0000000000 0.0000000000 0.1030405190
+ force: 3 0.1598274352 -0.0000000000 -0.0940971289
+ force: 4 0.1598274352 0.0000000000 0.0940971289
+ force: 5 -0.1598274352 0.0000000000 0.0940971289
+ force: 6 -0.1598274352 0.0000000000 -0.0940971289
+
+ force: Maximum force : 0.15982744(Ha/a0) on atom 4 in x direction
+ force: Force Residual: 0.16270168 Ha/a0
+ force: Total stress: -2.91337974 -0.21561294 -3.05409448 GPa
+ force: Average pressure: 2.06102905 GPa
+
+ get_E_and_F: Change in energy during last step of electronic optimisation: -0.13137E+02
+
+ BIBLIOGRAPHY: Please consider citing the following references in the conquest.bib file
+
+ CONQUEST: Bowler2002pt, Miyazaki2004, Nakata2020
+ Basis: Bowler2019
+ DM: Bowler:2006xr
+ Pseudopotentials: Hamann2013, Bowler2019
+
+
+ Warnings written to file Conquest_warnings; please check
+
+ Max total mem use is 157.053 MB
+
+ Total run time was: 7.688 seconds
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/H_PBE_DZP_CQ.ion b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/H_PBE_DZP_CQ.ion
new file mode 100644
index 000000000..f02fe9759
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullDZP_0.6/H_PBE_DZP_CQ.ion
@@ -0,0 +1,3371 @@
+
+
+ Git Branch: f-exx-opt; tag, hash: v1.2-169-g41cf7e2b
+ Date generated : 2024/02/09 at 18:32
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: H.in (appended at end of file)
+ Core radii (bohr) : l=0 1.000 l=1 0.700
+ 1 valence shells : 1s
+ XC functional code : 000101
+ XC description : GGA PBE96
+
+
+H basis set with GGA PBE96 functional
+n = 1, l = 0, 2 zetas
+ Radii: 6.73 3.14
+n = 3, l = 1, 1 zetas, perturbative polarisation shell
+ Radii: 6.73
+
+
+ H pb nrl nc
+
+
+H # Element symbol
+H # Label
+ 1.00 # Atomic number
+ 1.0000000000 # Valence charge
+ 1.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 1 3 # Lmax for basis, no of orbitals
+ 1 3 # Lmax for projectors, no of proj
+# PAOs:_______________
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+# KBs:_______________
+ 0 1 -3.4022469484000002 #kb l, n (seq), energy in Ry
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+ 1 1 -1.0066422298000000 #kb l, n (seq), energy in Ry
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+# Vna:_______________
+ 673 0.01001080949 6.72726397964 # npts, delta, cutoff
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+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+H 1.00 0 1 4 upf
+#
+# n l f energy (Ha)
+1 0 1.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.00000 -0.23860 4 7 8.50000
+1 0.70000 0.05000 4 7 11.00000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 0.70000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 1.00000
+1 1 1.00000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+0 0.00000 0.00000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+3.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/C_PBE_SZP_CQ.ion b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/C_PBE_SZP_CQ.ion
new file mode 100644
index 000000000..d02721f29
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/C_PBE_SZP_CQ.ion
@@ -0,0 +1,3983 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2023/11/30 at 18:44
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: C.in (appended at end of file)
+ Core radii (bohr) : l=0 1.200 l=1 1.250
+ 2 valence shells : 2s 2p
+ XC functional code : 000101
+ XC description : GGA PBE96
+ Includes partial core corrections
+
+
+C basis set with GGA PBE96 functional
+n = 2, l = 0, 1 zetas
+ Radii: 6.25
+n = 2, l = 1, 1 zetas
+ Radii: 6.25
+n = 3, l = 2, 1 zetas, perturbative polarisation shell
+ Radii: 6.25
+
+
+ C pb nrl pcec
+
+
+C # Element symbol
+C # Label
+ 6.00 # Atomic number
+ 4.0000000000 # Valence charge
+ 12.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 2 3 # Lmax for basis, no of orbitals
+ 1 4 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 2 1 0 2.000000 #orbital l, n, z, is_polarized, population
+ 625 0.0100114372662820 6.2471368541599936
+ 0.00000000000 0.36399167361
+ 0.01001143727 0.36419984924
+ 0.02002287453 0.36482394184
+ 0.03003431180 0.36586265061
+ 0.04004574907 0.36731381168
+ 0.05005718633 0.36917440439
+ 0.06006862360 0.37144056001
+ 0.07008006086 0.37410757294
+ 0.08009149813 0.37716991423
+ 0.09010293540 0.38062124745
+ 0.10011437266 0.38445444689
+ 0.11012580993 0.38866161785
+ 0.12013724720 0.39323411912
+ 0.13014868446 0.39816258747
+ 0.14016012173 0.40343696403
+ 0.15017155899 0.40904652250
+ 0.16018299626 0.41497989916
+ 0.17019443353 0.42122512431
+ 0.18020587079 0.42776965532
+ 0.19021730806 0.43460041100
+ 0.20022874533 0.44170380712
+ 0.21024018259 0.44906579307
+ 0.22025161986 0.45667188949
+ 0.23026305712 0.46450722667
+ 0.24027449439 0.47255658362
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+ 0.27030880619 0.49783212865
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+ 0.29033168072 0.51546136139
+ 0.30034311799 0.52446055533
+ 0.31035455525 0.53356074727
+ 0.32036599252 0.54274534856
+ 0.33037742979 0.55199777883
+ 0.34038886705 0.56130150444
+ 0.35040030432 0.57064007616
+ 0.36041174159 0.57999716604
+ 0.37042317885 0.58935660331
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+# Vna:_______________
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+ 6.24713685416 -0.64029332051
+# Core:__________________________
+ 262 0.01001989337 2.61519216974 # npts, delta, cutoff
+ 0.00000000000 0.87236701390
+ 0.01001989337 0.87200154737
+ 0.02003978674 0.87090598593
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+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+C 6.00 1 2 4 upf
+#
+# n l f energy (Ha)
+1 0 2.00
+2 0 2.00
+2 1 2.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.20000 -0.50533 4 7 9.00000
+1 1.25000 -0.19424 4 8 9.40000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 1.20000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 2.00000
+1 2 1.50000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+3 4.00000 1.55000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+6.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/Conquest_coord b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/Conquest_coord
new file mode 100644
index 000000000..ce2e9ebf2
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/Conquest_coord
@@ -0,0 +1,10 @@
+22.676714 0.000000 0.000000
+0.000000 22.676714 0.000000
+0.000000 0.000000 22.676714
+6
+ 0.50000000 0.50000000 0.44437500 2 T T T
+ 0.50000000 0.50000000 0.55562500 2 T T T
+ 0.57859183 0.50000000 0.39900000 1 T T T
+ 0.57859183 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.39900000 1 T T T
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/Conquest_input b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/Conquest_input
new file mode 100644
index 000000000..9e5e895b0
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/Conquest_input
@@ -0,0 +1,41 @@
+IO.Title isolated C2H4 with PBE0
+IO.Coordinates Conquest_coord
+IO.FractionalCoordinates T
+IO.Iprint 0
+IO.WriteOutToFile F
+IO.Iprint_exx 4
+IO.TimingOn T
+
+## General Parameters
+General.NumberOfSpecies 2
+General.DifferentFunctional T
+General.FunctionalType 201
+General.PAOFromFiles T
+
+## Moving Atoms
+AtomMove.TypeOfRun static
+
+## Basis Sets
+Basis.BasisSet PAOs
+
+## Energy Minimisation
+minE.SelfConsistent T
+minE.SCTolerance 0.1e-6
+
+## Integration Grid
+Grid.GridCutoff 90
+
+## Finding Density Matrix
+DM.SolutionMethod diagon
+
+## EXX Parameters
+EXX.Scheme 1
+EXX.GridSpacing 0.4
+EXX.GTO F
+
+## Atomic Information
+%block ChemicalSpeciesLabel
+1 1.0080 H H_PBE_SZP_CQ.ion
+2 12.0110 C C_PBE_SZP_CQ.ion
+%endblock
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/Conquest_out.ref b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/Conquest_out.ref
new file mode 100644
index 000000000..826d773d4
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/Conquest_out.ref
@@ -0,0 +1,95 @@
+ ________________________________________________________________________
+
+ CONQUEST
+
+ Concurrent Order N QUantum Electronic STructure
+ ________________________________________________________________________
+
+ Conquest lead developers:
+ D.R.Bowler (UCL, NIMS), T.Miyazaki (NIMS), A.Nakata (NIMS),
+ L. Truflandier (U. Bordeaux)
+
+ Developers:
+ M.Arita (NIMS), J.S.Baker (UCL), V.Brazdova (UCL), R.Choudhury (UCL),
+ S.Y.Mujahed (UCL), J.T.Poulton (UCL), Z.Raza (NIMS), A.Sena (UCL),
+ U.Terranova (UCL), L.Tong (UCL), A.Torralba (NIMS)
+
+ Early development:
+ I.J.Bush (STFC), C.M.Goringe (Keele), E.H.Hernandez (Keele)
+
+ Original inspiration and project oversight:
+ M.J.Gillan (Keele, UCL)
+ ________________________________________________________________________
+
+ Simulation cell dimensions: 22.6767 a0 x 22.6767 a0 x 22.6767 a0
+
+ Atomic coordinates (a0)
+ Atom X Y Z Species
+ 1 11.3384 11.3384 10.0770 2
+ 2 11.3384 11.3384 12.5997 2
+ 3 13.1206 11.3384 9.0480 1
+ 4 13.1206 11.3384 13.6287 1
+ 5 9.5562 11.3384 13.6287 1
+ 6 9.5562 11.3384 9.0480 1
+
+ Default k-point sampling of Gamma point only
+
+ This job was run on 2024/04/24 at 18:38 +0200
+ Code was compiled on 2024/03/25 at 16:34 +0100
+ Version comment: Git Branch: f-exx-opt; tag, hash: v1.2-215-gc00a071c
+
+ Job title: isolated C2H4 with PBE0
+ Job to be run: static calculation
+
+ Ground state search:
+ Support functions represented with PAO basis
+ 1:1 PAO to SF mapping
+ Non-spin-polarised electrons
+ Solving for the K matrix using diagonalisation
+
+ Integration grid spacing: 0.227 a0 x 0.227 a0 x 0.227 a0
+
+ Number of species: 2
+ --------------------------------------------------------
+ | # mass (au) Charge (e) SF Rad (a0) NSF Label |
+ --------------------------------------------------------
+ | 1 1.008 1.000 7.030 4 H |
+ | 2 12.011 4.000 6.576 9 C |
+ --------------------------------------------------------
+
+ The calculation will be performed on 4 processes
+
+ The calculation will be performed on 2 threads
+
+ The functional used will be hyb PBE0
+
+ PulayMixSC: Reached SCF tolerance of 0.55970E-07 after 11 iterations
+ | Number of electrons = 12.000000
+ |* Harris-Foulkes energy = -14.028830939468913 Ha
+
+ force: Forces on atoms (Ha/a0)
+ force: Atom X Y Z
+ force: 1 -0.0006939243 0.0000000000 -0.0384822038
+ force: 2 -0.0006235821 0.0000000000 0.0384957819
+ force: 3 0.0538283496 0.0000000000 -0.0297448753
+ force: 4 0.0536942132 0.0000000000 0.0296363377
+ force: 5 -0.0531308562 0.0000000000 0.0292335571
+ force: 6 -0.0530780764 0.0000000000 -0.0291384102
+
+ force: Maximum force : 0.05382835(Ha/a0) on atom 3 in x direction
+ force: Force Residual: 0.05454528 Ha/a0
+ force: Total stress: -0.95572370 -0.00138926 -0.92184508 GPa
+
+ BIBLIOGRAPHY: Please consider citing the following references in the conquest.bib file
+
+ CONQUEST: Bowler2002pt, Miyazaki2004, Nakata2020
+ Basis: Bowler2019
+ DM: Bowler:2006xr
+ Pseudopotentials: Hamann2013, Bowler2019
+
+
+ Warnings written to file Conquest_warnings; please check
+
+ Max total mem use is 166.996 MB
+
+ Total run time was: 96.750 seconds
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/H_PBE_SZP_CQ.ion b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/H_PBE_SZP_CQ.ion
new file mode 100644
index 000000000..0faa93ce1
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullSZP_0.4_SCF/H_PBE_SZP_CQ.ion
@@ -0,0 +1,3055 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2024/04/24 at 18:15
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: H.in (appended at end of file)
+ Core radii (bohr) : l=0 1.000 l=1 0.700
+ 1 valence shells : 1s
+ XC functional code : 000101
+ XC description : GGA PBE96
+
+
+H basis set with GGA PBE96 functional
+n = 1, l = 0, 1 zetas
+ Radii: 6.73
+n = 3, l = 1, 1 zetas, perturbative polarisation shell
+ Radii: 6.73
+
+
+ H pb nrl nc
+
+
+H # Element symbol
+H # Label
+ 1.00 # Atomic number
+ 1.0000000000 # Valence charge
+ 1.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 1 2 # Lmax for basis, no of orbitals
+ 1 3 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 1 1 0 1.000000 #orbital l, n, z, is_polarized, population
+ 673 0.0100108094935117 6.7272639796398339
+ 0.00000000000 1.56155255225
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+ 0 1 -3.4022469484000002 #kb l, n (seq), energy in Ry
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+# Vna:_______________
+ 673 0.01001080949 6.72726397964 # npts, delta, cutoff
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+# Vlocal:_______________________
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+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+H 1.00 0 1 4 upf
+#
+# n l f energy (Ha)
+1 0 1.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.00000 -0.23860 4 7 8.50000
+1 0.70000 0.05000 4 7 11.00000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 0.70000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 1.00000
+1 1 1.00000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+0 0.00000 0.00000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+3.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/C_PBE_TZTP_CQ.ion b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/C_PBE_TZTP_CQ.ion
new file mode 100644
index 000000000..7aaf83636
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/C_PBE_TZTP_CQ.ion
@@ -0,0 +1,6356 @@
+
+
+ Git Branch: f-exx-opt; tag, hash: v1.2-169-g41cf7e2b
+ Date generated : 2024/02/09 at 18:46
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: C.in (appended at end of file)
+ Core radii (bohr) : l=0 1.200 l=1 1.250
+ 2 valence shells : 2s 2p
+ XC functional code : 000101
+ XC description : GGA PBE96
+ Includes partial core corrections
+
+
+C basis set with GGA PBE96 functional
+n = 2, l = 0, 3 zetas
+ Radii: 6.25 4.69 3.17
+n = 2, l = 1, 3 zetas
+ Radii: 6.25 4.69 3.17
+n = 3, l = 2, 3 zetas, perturbative polarisation shell
+ Radii: 6.25 4.69 3.17
+
+
+ C pb nrl pcec
+
+
+C # Element symbol
+C # Label
+ 6.00 # Atomic number
+ 4.0000000000 # Valence charge
+ 12.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 2 9 # Lmax for basis, no of orbitals
+ 1 4 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 2 1 0 2.000000 #orbital l, n, z, is_polarized, population
+ 625 0.0100114372662820 6.2471368541599936
+ 0.00000000000 0.36399167361
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+ 1.03204901718 0.00375146093
+ 1.04206891055 0.00325656297
+ 1.05208880392 0.00281558844
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+ 1.07212859066 0.00207726038
+ 1.08214848403 0.00177150758
+ 1.09216837740 0.00150286736
+ 1.10218827077 0.00126778645
+ 1.11220816414 0.00106295661
+ 1.12222805751 0.00088530612
+ 1.13224795088 0.00073199097
+ 1.14226784425 0.00060038558
+ 1.15228773762 0.00048807328
+ 1.16230763099 0.00039283650
+ 1.17232752436 0.00031264695
+ 1.18234741774 0.00024565554
+ 1.19236731111 0.00019018248
+ 1.20238720448 0.00014470722
+ 1.21240709785 0.00010785867
+ 1.22242699122 0.00007840544
+ 1.23244688459 0.00005524630
+ 1.24246677796 0.00003740090
+ 1.25248667133 0.00002400071
+ 1.26250656470 0.00001428028
+ 1.27252645807 0.00000756884
+ 1.28254635144 0.00000328214
+ 1.29256624481 0.00000091481
+ 1.30258613818 0.00000003296
+ 1.31260603155 0.00000026724
+ 1.32262592492 0.00000130623
+ 1.33264581829 0.00000289033
+ 1.34266571167 0.00000480590
+ 1.35268560504 0.00000687997
+ 1.36270549841 0.00000897514
+ 1.37272539178 0.00001098506
+ 1.38274528515 0.00001283015
+ 1.39276517852 0.00001445373
+ 1.40278507189 0.00001581848
+ 1.41280496526 0.00001690332
+ 1.42282485863 0.00001770047
+ 1.43284475200 0.00001821292
+ 1.44286464537 0.00001845219
+ 1.45288453874 0.00001843626
+ 1.46290443211 0.00001818793
+ 1.47292432548 0.00001773321
+ 1.48294421885 0.00001710009
+ 1.49296411222 0.00001631746
+ 1.50298400560 0.00001541417
+ 1.51300389897 0.00001441832
+ 1.52302379234 0.00001335666
+ 1.53304368571 0.00001225415
+ 1.54306357908 0.00001113361
+ 1.55308347245 0.00001001551
+ 1.56310336582 0.00000891785
+ 1.57312325919 0.00000785604
+ 1.58314315256 0.00000684298
+ 1.59316304593 0.00000588905
+ 1.60318293930 0.00000500231
+ 1.61320283267 0.00000418852
+ 1.62322272604 0.00000345144
+ 1.63324261941 0.00000279292
+ 1.64326251278 0.00000221314
+ 1.65328240615 0.00000171084
+ 1.66330229953 0.00000128349
+ 1.67332219290 0.00000092750
+ 1.68334208627 0.00000063847
+ 1.69336197964 0.00000041130
+ 1.70338187301 0.00000024046
+ 1.71340176638 0.00000012009
+ 1.72342165975 0.00000004416
+ 1.73344155312 0.00000000663
+ 1.74346144649 0.00000000155
+ 1.75348133986 0.00000002317
+ 1.76350123323 0.00000006601
+ 1.77352112660 0.00000012495
+ 1.78354101997 0.00000019525
+ 1.79356091334 0.00000027265
+ 1.80358080671 0.00000035331
+ 1.81360070009 0.00000043392
+ 1.82362059346 0.00000051163
+ 1.83364048683 0.00000058407
+ 1.84366038020 0.00000064934
+ 1.85368027357 0.00000070599
+ 1.86370016694 0.00000075297
+ 1.87372006031 0.00000078962
+ 1.88373995368 0.00000081563
+ 1.89375984705 0.00000083100
+ 1.90377974042 0.00000083600
+ 1.91379963379 0.00000083113
+ 1.92381952716 0.00000081707
+ 1.93383942053 0.00000079466
+ 1.94385931390 0.00000076485
+ 1.95387920727 0.00000072869
+ 1.96389910064 0.00000068725
+ 1.97391899402 0.00000064163
+ 1.98393888739 0.00000059292
+ 1.99395878076 0.00000054217
+ 2.00397867413 0.00000049040
+ 2.01399856750 0.00000043854
+ 2.02401846087 0.00000038746
+ 2.03403835424 0.00000033790
+ 2.04405824761 0.00000029055
+ 2.05407814098 0.00000024597
+ 2.06409803435 0.00000020461
+ 2.07411792772 0.00000016683
+ 2.08413782109 0.00000013288
+ 2.09415771446 0.00000010294
+ 2.10417760783 0.00000007705
+ 2.11419750120 0.00000005521
+ 2.12421739457 0.00000003733
+ 2.13423728795 0.00000002324
+ 2.14425718132 0.00000001275
+ 2.15427707469 0.00000000558
+ 2.16429696806 0.00000000144
+ 2.17431686143 0.00000000001
+ 2.18433675480 0.00000000093
+ 2.19435664817 0.00000000387
+ 2.20437654154 0.00000000845
+ 2.21439643491 0.00000001433
+ 2.22441632828 0.00000002116
+ 2.23443622165 0.00000002863
+ 2.24445611502 0.00000003644
+ 2.25447600839 0.00000004429
+ 2.26449590176 0.00000005196
+ 2.27451579513 0.00000005922
+ 2.28453568850 0.00000006589
+ 2.29455558188 0.00000007182
+ 2.30457547525 0.00000007688
+ 2.31459536862 0.00000008100
+ 2.32461526199 0.00000008411
+ 2.33463515536 0.00000008620
+ 2.34465504873 0.00000008725
+ 2.35467494210 0.00000008729
+ 2.36469483547 0.00000008637
+ 2.37471472884 0.00000008455
+ 2.38473462221 0.00000008191
+ 2.39475451558 0.00000007854
+ 2.40477440895 0.00000007454
+ 2.41479430232 0.00000007002
+ 2.42481419569 0.00000006508
+ 2.43483408906 0.00000005983
+ 2.44485398244 0.00000005439
+ 2.45487387581 0.00000004886
+ 2.46489376918 0.00000004334
+ 2.47491366255 0.00000003791
+ 2.48493355592 0.00000003267
+ 2.49495344929 0.00000002768
+ 2.50497334266 0.00000002302
+ 2.51499323603 0.00000001872
+ 2.52501312940 0.00000001484
+ 2.53503302277 0.00000001139
+ 2.54505291614 0.00000000841
+ 2.55507280951 0.00000000590
+ 2.56509270288 0.00000000385
+ 2.57511259625 0.00000000226
+ 2.58513248962 0.00000000113
+ 2.59515238299 0.00000000044
+ 2.60517227637 0.00000000010
+ 2.61519216974 0.00000000000
+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+C 6.00 1 2 4 upf
+#
+# n l f energy (Ha)
+1 0 2.00
+2 0 2.00
+2 1 2.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.20000 -0.50533 4 7 9.00000
+1 1.25000 -0.19424 4 8 9.40000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 1.20000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 2.00000
+1 2 1.50000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+3 4.00000 1.55000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+6.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/Conquest_coord b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/Conquest_coord
new file mode 100644
index 000000000..ce2e9ebf2
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/Conquest_coord
@@ -0,0 +1,10 @@
+22.676714 0.000000 0.000000
+0.000000 22.676714 0.000000
+0.000000 0.000000 22.676714
+6
+ 0.50000000 0.50000000 0.44437500 2 T T T
+ 0.50000000 0.50000000 0.55562500 2 T T T
+ 0.57859183 0.50000000 0.39900000 1 T T T
+ 0.57859183 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.39900000 1 T T T
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/Conquest_input b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/Conquest_input
new file mode 100644
index 000000000..d77804198
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/Conquest_input
@@ -0,0 +1,40 @@
+IO.Title isolated C2H4 with PBE0
+IO.Coordinates Conquest_coord
+IO.FractionalCoordinates T
+IO.Iprint 0
+IO.WriteOutToFile F
+IO.Iprint_exx 4
+IO.TimingOn T
+
+## General Parameters
+General.NumberOfSpecies 2
+General.DifferentFunctional T
+General.FunctionalType 201
+General.PAOFromFiles T
+
+## Moving Atoms
+AtomMove.TypeOfRun static
+
+## Basis Sets
+Basis.BasisSet PAOs
+
+## Energy Minimisation
+minE.SelfConsistent T
+minE.SCTolerance 0.2e-1
+
+## Integration Grid
+Grid.GridCutoff 90
+
+## Finding Density Matrix
+DM.SolutionMethod diagon
+
+## EXX Parameters
+EXX.GridSpacing 0.6
+EXX.Scheme 1
+
+## Atomic Information
+%block ChemicalSpeciesLabel
+1 1.0080 H H_PBE_TZTP_CQ.ion
+2 12.0110 C C_PBE_TZTP_CQ.ion
+%endblock
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/Conquest_out.ref b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/Conquest_out.ref
new file mode 100644
index 000000000..3e3e39e25
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/Conquest_out.ref
@@ -0,0 +1,120 @@
+ ________________________________________________________________________
+
+ CONQUEST
+
+ Concurrent Order N QUantum Electronic STructure
+ ________________________________________________________________________
+
+ Conquest lead developers:
+ D.R.Bowler (UCL, NIMS), T.Miyazaki (NIMS), A.Nakata (NIMS),
+ L. Truflandier (U. Bordeaux)
+
+ Developers:
+ M.Arita (NIMS), J.S.Baker (UCL), V.Brazdova (UCL), R.Choudhury (UCL),
+ S.Y.Mujahed (UCL), J.T.Poulton (UCL), Z.Raza (NIMS), A.Sena (UCL),
+ U.Terranova (UCL), L.Tong (UCL), A.Torralba (NIMS)
+
+ Early development:
+ I.J.Bush (STFC), C.M.Goringe (Keele), E.H.Hernandez (Keele)
+
+ Original inspiration and project oversight:
+ M.J.Gillan (Keele, UCL)
+ ________________________________________________________________________
+
+WARNING: Functional in input file differs to pseudopotential but proceeding: 201 101
+
+
+WARNING: Functional in input file differs to pseudopotential but proceeding: 201 101
+
+
+ Simulation cell dimensions: 22.6767 a0 x 22.6767 a0 x 22.6767 a0
+
+ Atomic coordinates (a0)
+ Atom X Y Z Species
+ 1 11.3384 11.3384 10.0770 2
+ 2 11.3384 11.3384 12.5997 2
+ 3 13.1206 11.3384 9.0480 1
+ 4 13.1206 11.3384 13.6287 1
+ 5 9.5562 11.3384 13.6287 1
+ 6 9.5562 11.3384 9.0480 1
+
+ Default k-point sampling of Gamma point only
+ All 1 Kpoints in fractional coordinates:
+ 1 0.000000 0.000000 0.000000 1.000
+
+ This calculation includes non-local pseudopotentials,
+ with a maximum core radius of 6.72726398
+
+ This job was run on 2024/02/12 at 19:16 +0100
+ Code was compiled on 2023/12/01 at 15:01 +0100
+ Version comment: Git Branch: f-exx-opt; tag, hash: v1.2-167-gddc9e439
+
+ Job title: isolated C2H4 with PBE0
+ Job to be run: static calculation
+
+ Ground state search:
+ Support functions represented with PAO basis
+ 1:1 PAO to SF mapping
+ Non-spin-polarised electrons
+ Solving for the K matrix using diagonalisation
+ Using Fermi-Dirac smearing
+
+ Integration grid size: 100 x 100 x 100
+
+ Integration grid spacing: 0.227 a0 x 0.227 a0 x 0.227 a0
+
+ Number of species: 2
+ --------------------------------------------------------
+ | # mass (au) Charge (e) SF Rad (a0) NSF Label |
+ --------------------------------------------------------
+ | 1 1.008 1.000 7.030 12 H |
+ | 2 12.011 4.000 6.576 27 C |
+ --------------------------------------------------------
+ SCF tolerance: 0.02000000
+ SCF iterations: 50
+
+ The calculation will be performed on 4 processes
+
+ The calculation will be performed on 1 thread
+
+ The functional used will be hyb PBE0
+
+ set_atom_dens: In set_atomic_density, electrons : 12.000000000000
+ PulayMixSC: Starting Pulay mixing, A_up = 0.500 A_dn = 0.500
+ PulayMixSC: Spin non-polarised calculation.
+ Harris-Foulkes Energy : -13.149821398119368 Ha
+ PulayMixSC: Pulay iteration 1 residual: 0.15240E-01
+ PulayMixSC: reached SCF residual of 0.15240E-01 after 1 iterations
+ | Number of electrons = 12.000000
+ |* Harris-Foulkes energy = -13.149821398119368 Ha
+ |* DFT total energy = -13.019777906727267 Ha
+
+ force: Forces on atoms (Ha/a0)
+ force: Atom X Y Z
+ force: 1 -0.0000000000 -0.0000000000 -0.1053214359
+ force: 2 0.0000000000 0.0000000000 0.1053214359
+ force: 3 0.1615601845 -0.0000000000 -0.0944301535
+ force: 4 0.1615601845 -0.0000000000 0.0944301535
+ force: 5 -0.1615601845 0.0000000000 0.0944301535
+ force: 6 -0.1615601845 0.0000000000 -0.0944301535
+
+ force: Maximum force : 0.16156018(Ha/a0) on atom 4 in x direction
+ force: Force Residual: 0.16444867 Ha/a0
+ force: Total stress: -2.92273604 -0.20424302 -3.04167466 GPa
+ force: Average pressure: 2.05621791 GPa
+
+ get_E_and_F: Change in energy during last step of electronic optimisation: -0.13150E+02
+
+ BIBLIOGRAPHY: Please consider citing the following references in the conquest.bib file
+
+ CONQUEST: Bowler2002pt, Miyazaki2004, Nakata2020
+ Basis: Bowler2019
+ DM: Bowler:2006xr
+ Pseudopotentials: Hamann2013, Bowler2019
+
+
+ Warnings written to file Conquest_warnings; please check
+
+ Max total mem use is 237.410 MB
+
+ Total run time was: 34.270 seconds
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/H_PBE_TZTP_CQ.ion b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/H_PBE_TZTP_CQ.ion
new file mode 100644
index 000000000..9d1eb63b0
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0CRI_fullTZTP_0.6/H_PBE_TZTP_CQ.ion
@@ -0,0 +1,4679 @@
+
+
+ Git Branch: f-exx-opt; tag, hash: v1.2-169-g41cf7e2b
+ Date generated : 2024/02/09 at 18:45
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: H.in (appended at end of file)
+ Core radii (bohr) : l=0 1.000 l=1 0.700
+ 1 valence shells : 1s
+ XC functional code : 000101
+ XC description : GGA PBE96
+
+
+H basis set with GGA PBE96 functional
+n = 1, l = 0, 3 zetas
+ Radii: 6.73 4.93 3.14
+n = 3, l = 1, 3 zetas, perturbative polarisation shell
+ Radii: 6.73 4.93 3.14
+
+
+ H pb nrl nc
+
+
+H # Element symbol
+H # Label
+ 1.00 # Atomic number
+ 1.0000000000 # Valence charge
+ 1.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 1 6 # Lmax for basis, no of orbitals
+ 1 3 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 1 1 0 1.000000 #orbital l, n, z, is_polarized, population
+ 673 0.0100108094935117 6.7272639796398339
+ 0.00000000000 1.56155255225
+ 0.01001080949 1.56134081579
+ 0.02002161899 1.56070586103
+ 0.03003242848 1.55964896338
+ 0.04004323797 1.55817219676
+ 0.05005404747 1.55627843492
+ 0.06006485696 1.55397133802
+ 0.07007566645 1.55125532942
+ 0.08008647595 1.54813556702
+ 0.09009728544 1.54461791016
+ 0.10010809494 1.54070888255
+ 0.11011890443 1.53641563176
+ 0.12012971392 1.53174588577
+ 0.13014052342 1.52670790712
+ 0.14015133291 1.52131044519
+ 0.15016214240 1.51556268735
+ 0.16017295190 1.50947420926
+ 0.17018376139 1.50305492529
+ 0.18019457088 1.49631503919
+ 0.19020538038 1.48926499595
+ 0.20021618987 1.48191543510
+ 0.21022699936 1.47427714601
+ 0.22023780886 1.46636102560
+ 0.23024861835 1.45817803890
+ 0.24025942784 1.44973918268
+ 0.25027023734 1.44105545246
+ 0.26028104683 1.43213781311
+ 0.27029185632 1.42299717314
+ 0.28030266582 1.41364436277
+ 0.29031347531 1.40409011574
+ 0.30032428481 1.39434505482
+ 0.31033509430 1.38441968091
+ 0.32034590379 1.37432436547
+ 0.33035671329 1.36406934614
+ 0.34036752278 1.35366472507
+ 0.35037833227 1.34312046995
+ 0.36038914177 1.33244641698
+ 0.37039995126 1.32165227563
+ 0.38041076075 1.31074763480
+ 0.39042157025 1.29974196964
+ 0.40043237974 1.28864464905
+ 0.41044318923 1.27746494296
+ 0.42045399873 1.26621202936
+ 0.43046480822 1.25489500038
+ 0.44047561771 1.24352286722
+ 0.45048642721 1.23210456360
+ 0.46049723670 1.22064894730
+ 0.47050804620 1.20916479960
+ 0.48051885569 1.19766082252
+ 0.49052966518 1.18614563362
+ 0.50054047468 1.17462775819
+ 0.51055128417 1.16311561896
+ 0.52056209366 1.15161752334
+ 0.53057290316 1.14014164812
+ 0.54058371265 1.12869602198
+ 0.55059452214 1.11728850594
+ 0.56060533164 1.10592677176
+ 0.57061614113 1.09461827923
+ 0.58062695062 1.08337025177
+ 0.59063776012 1.07218965161
+ 0.60064856961 1.06108315432
+ 0.61065937910 1.05005712345
+ 0.62067018860 1.03911758559
+ 0.63068099809 1.02827020618
+ 0.64069180758 1.01752026688
+ 0.65070261708 1.00687264443
+ 0.66071342657 0.99633179185
+ 0.67072423607 0.98590172198
+ 0.68073504556 0.97558599407
+ 0.69074585505 0.96538770341
+ 0.70075666455 0.95530947455
+ 0.71076747404 0.94535345800
+ 0.72077828353 0.93552133092
+ 0.73078909303 0.92581430161
+ 0.74079990252 0.91623311803
+ 0.75081071201 0.90677808017
+ 0.76082152151 0.89744905638
+ 0.77083233100 0.88824550330
+ 0.78084314049 0.87916648941
+ 0.79085394999 0.87021072173
+ 0.80086475948 0.86137657557
+ 0.81087556897 0.85266212680
+ 0.82088637847 0.84406518633
+ 0.83089718796 0.83558333644
+ 0.84090799745 0.82721396833
+ 0.85091880695 0.81895432052
+ 0.86092961644 0.81080151767
+ 0.87094042594 0.80275260911
+ 0.88095123543 0.79480460685
+ 0.89096204492 0.78695452231
+ 0.90097285442 0.77919940158
+ 0.91098366391 0.77153635846
+ 0.92099447340 0.76396260519
+ 0.93100528290 0.75647548019
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+ 0.97104852087 0.72734572700
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+ 0.99107013986 0.71324422257
+ 1.00108094935 0.70630382231
+ 1.01109175884 0.69943547975
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+ 1.03111337783 0.68591151436
+ 1.04112418733 0.67925431698
+ 1.05113499682 0.67266594246
+ 1.06114580631 0.66614562738
+ 1.07115661581 0.65969261707
+ 1.08116742530 0.65330616551
+ 1.09117823479 0.64698553538
+ 1.10118904429 0.64072999795
+ 1.11119985378 0.63453883298
+ 1.12121066327 0.62841132865
+ 1.13122147277 0.62234678148
+ 1.14123228226 0.61634449622
+ 1.15124309175 0.61040378579
+ 1.16125390125 0.60452397114
+ 1.17126471074 0.59870438124
+ 1.18127552023 0.59294435291
+ 1.19128632973 0.58724323082
+ 1.20129713922 0.58160036732
+ 1.21130794871 0.57601512241
+ 1.22131875821 0.57048686364
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+ 1.34144847213 0.50837239264
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+# KBs:_______________
+ 0 1 -3.4022469484000002 #kb l, n (seq), energy in Ry
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+# Vna:_______________
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+ 6.17666945750 -0.16190006227
+ 6.18668026699 -0.16163808752
+ 6.19669107648 -0.16137695922
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+ 6.58711264673 -0.15181203971
+ 6.59712345622 -0.15158167173
+ 6.60713426572 -0.15135200182
+ 6.61714507521 -0.15112302683
+ 6.62715588470 -0.15089474361
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+ 6.70724236065 -0.14909300957
+ 6.71725317015 -0.14887081359
+ 6.72726397964 -0.14864884194
+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+H 1.00 0 1 4 upf
+#
+# n l f energy (Ha)
+1 0 1.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.00000 -0.23860 4 7 8.50000
+1 0.70000 0.05000 4 7 11.00000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 0.70000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 1.00000
+1 1 1.00000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+0 0.00000 0.00000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+3.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/C_PBE_SZP_CQ.ion b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/C_PBE_SZP_CQ.ion
new file mode 100644
index 000000000..d02721f29
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/C_PBE_SZP_CQ.ion
@@ -0,0 +1,3983 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2023/11/30 at 18:44
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: C.in (appended at end of file)
+ Core radii (bohr) : l=0 1.200 l=1 1.250
+ 2 valence shells : 2s 2p
+ XC functional code : 000101
+ XC description : GGA PBE96
+ Includes partial core corrections
+
+
+C basis set with GGA PBE96 functional
+n = 2, l = 0, 1 zetas
+ Radii: 6.25
+n = 2, l = 1, 1 zetas
+ Radii: 6.25
+n = 3, l = 2, 1 zetas, perturbative polarisation shell
+ Radii: 6.25
+
+
+ C pb nrl pcec
+
+
+C # Element symbol
+C # Label
+ 6.00 # Atomic number
+ 4.0000000000 # Valence charge
+ 12.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 2 3 # Lmax for basis, no of orbitals
+ 1 4 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 2 1 0 2.000000 #orbital l, n, z, is_polarized, population
+ 625 0.0100114372662820 6.2471368541599936
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+ 1.64326251278 0.00000221314
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+ 1.66330229953 0.00000128349
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+ 1.68334208627 0.00000063847
+ 1.69336197964 0.00000041130
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+ 1.71340176638 0.00000012009
+ 1.72342165975 0.00000004416
+ 1.73344155312 0.00000000663
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+ 1.79356091334 0.00000027265
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+ 1.85368027357 0.00000070599
+ 1.86370016694 0.00000075297
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+ 1.88373995368 0.00000081563
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+ 1.90377974042 0.00000083600
+ 1.91379963379 0.00000083113
+ 1.92381952716 0.00000081707
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+ 1.94385931390 0.00000076485
+ 1.95387920727 0.00000072869
+ 1.96389910064 0.00000068725
+ 1.97391899402 0.00000064163
+ 1.98393888739 0.00000059292
+ 1.99395878076 0.00000054217
+ 2.00397867413 0.00000049040
+ 2.01399856750 0.00000043854
+ 2.02401846087 0.00000038746
+ 2.03403835424 0.00000033790
+ 2.04405824761 0.00000029055
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+ 2.13423728795 0.00000002324
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+ 2.15427707469 0.00000000558
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+ 2.19435664817 0.00000000387
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+ 2.21439643491 0.00000001433
+ 2.22441632828 0.00000002116
+ 2.23443622165 0.00000002863
+ 2.24445611502 0.00000003644
+ 2.25447600839 0.00000004429
+ 2.26449590176 0.00000005196
+ 2.27451579513 0.00000005922
+ 2.28453568850 0.00000006589
+ 2.29455558188 0.00000007182
+ 2.30457547525 0.00000007688
+ 2.31459536862 0.00000008100
+ 2.32461526199 0.00000008411
+ 2.33463515536 0.00000008620
+ 2.34465504873 0.00000008725
+ 2.35467494210 0.00000008729
+ 2.36469483547 0.00000008637
+ 2.37471472884 0.00000008455
+ 2.38473462221 0.00000008191
+ 2.39475451558 0.00000007854
+ 2.40477440895 0.00000007454
+ 2.41479430232 0.00000007002
+ 2.42481419569 0.00000006508
+ 2.43483408906 0.00000005983
+ 2.44485398244 0.00000005439
+ 2.45487387581 0.00000004886
+ 2.46489376918 0.00000004334
+ 2.47491366255 0.00000003791
+ 2.48493355592 0.00000003267
+ 2.49495344929 0.00000002768
+ 2.50497334266 0.00000002302
+ 2.51499323603 0.00000001872
+ 2.52501312940 0.00000001484
+ 2.53503302277 0.00000001139
+ 2.54505291614 0.00000000841
+ 2.55507280951 0.00000000590
+ 2.56509270288 0.00000000385
+ 2.57511259625 0.00000000226
+ 2.58513248962 0.00000000113
+ 2.59515238299 0.00000000044
+ 2.60517227637 0.00000000010
+ 2.61519216974 0.00000000000
+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+C 6.00 1 2 4 upf
+#
+# n l f energy (Ha)
+1 0 2.00
+2 0 2.00
+2 1 2.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.20000 -0.50533 4 7 9.00000
+1 1.25000 -0.19424 4 8 9.40000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 1.20000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 2.00000
+1 2 1.50000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+3 4.00000 1.55000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+6.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/Conquest_coord b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/Conquest_coord
new file mode 100644
index 000000000..ce2e9ebf2
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/Conquest_coord
@@ -0,0 +1,10 @@
+22.676714 0.000000 0.000000
+0.000000 22.676714 0.000000
+0.000000 0.000000 22.676714
+6
+ 0.50000000 0.50000000 0.44437500 2 T T T
+ 0.50000000 0.50000000 0.55562500 2 T T T
+ 0.57859183 0.50000000 0.39900000 1 T T T
+ 0.57859183 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.39900000 1 T T T
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/Conquest_input b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/Conquest_input
new file mode 100644
index 000000000..ba227e413
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/Conquest_input
@@ -0,0 +1,41 @@
+IO.Title isolated C2H4 with PBE0
+IO.Coordinates Conquest_coord
+IO.FractionalCoordinates T
+IO.Iprint 0
+IO.WriteOutToFile F
+IO.Iprint_exx 4
+IO.TimingOn T
+
+## General Parameters
+General.NumberOfSpecies 2
+General.DifferentFunctional T
+General.FunctionalType 201
+General.PAOFromFiles T
+
+## Moving Atoms
+AtomMove.TypeOfRun static
+
+## Basis Sets
+Basis.BasisSet PAOs
+
+## Energy Minimisation
+minE.SelfConsistent T
+minE.SCTolerance 0.1e-6
+
+## Integration Grid
+Grid.GridCutoff 90
+
+## Finding Density Matrix
+DM.SolutionMethod diagon
+
+## EXX Parameters
+EXX.Scheme 3
+EXX.GridSpacing 0.4
+EXX.GTO F
+
+## Atomic Information
+%block ChemicalSpeciesLabel
+1 1.0080 H H_PBE_SZP_CQ.ion
+2 12.0110 C C_PBE_SZP_CQ.ion
+%endblock
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/Conquest_out.ref b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/Conquest_out.ref
new file mode 100644
index 000000000..dcb4c93c2
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/Conquest_out.ref
@@ -0,0 +1,95 @@
+ ________________________________________________________________________
+
+ CONQUEST
+
+ Concurrent Order N QUantum Electronic STructure
+ ________________________________________________________________________
+
+ Conquest lead developers:
+ D.R.Bowler (UCL, NIMS), T.Miyazaki (NIMS), A.Nakata (NIMS),
+ L. Truflandier (U. Bordeaux)
+
+ Developers:
+ M.Arita (NIMS), J.S.Baker (UCL), V.Brazdova (UCL), R.Choudhury (UCL),
+ S.Y.Mujahed (UCL), J.T.Poulton (UCL), Z.Raza (NIMS), A.Sena (UCL),
+ U.Terranova (UCL), L.Tong (UCL), A.Torralba (NIMS)
+
+ Early development:
+ I.J.Bush (STFC), C.M.Goringe (Keele), E.H.Hernandez (Keele)
+
+ Original inspiration and project oversight:
+ M.J.Gillan (Keele, UCL)
+ ________________________________________________________________________
+
+ Simulation cell dimensions: 22.6767 a0 x 22.6767 a0 x 22.6767 a0
+
+ Atomic coordinates (a0)
+ Atom X Y Z Species
+ 1 11.3384 11.3384 10.0770 2
+ 2 11.3384 11.3384 12.5997 2
+ 3 13.1206 11.3384 9.0480 1
+ 4 13.1206 11.3384 13.6287 1
+ 5 9.5562 11.3384 13.6287 1
+ 6 9.5562 11.3384 9.0480 1
+
+ Default k-point sampling of Gamma point only
+
+ This job was run on 2024/04/24 at 18:46 +0200
+ Code was compiled on 2024/03/25 at 16:34 +0100
+ Version comment: Git Branch: f-exx-opt; tag, hash: v1.2-215-gc00a071c
+
+ Job title: isolated C2H4 with PBE0
+ Job to be run: static calculation
+
+ Ground state search:
+ Support functions represented with PAO basis
+ 1:1 PAO to SF mapping
+ Non-spin-polarised electrons
+ Solving for the K matrix using diagonalisation
+
+ Integration grid spacing: 0.227 a0 x 0.227 a0 x 0.227 a0
+
+ Number of species: 2
+ --------------------------------------------------------
+ | # mass (au) Charge (e) SF Rad (a0) NSF Label |
+ --------------------------------------------------------
+ | 1 1.008 1.000 7.030 4 H |
+ | 2 12.011 4.000 6.576 9 C |
+ --------------------------------------------------------
+
+ The calculation will be performed on 4 processes
+
+ The calculation will be performed on 2 threads
+
+ The functional used will be hyb PBE0
+
+ PulayMixSC: Reached SCF tolerance of 0.55970E-07 after 11 iterations
+ | Number of electrons = 12.000000
+ |* Harris-Foulkes energy = -14.028830939468907 Ha
+
+ force: Forces on atoms (Ha/a0)
+ force: Atom X Y Z
+ force: 1 -0.0006939243 0.0000000000 -0.0384822038
+ force: 2 -0.0006235821 -0.0000000000 0.0384957819
+ force: 3 0.0538283496 0.0000000000 -0.0297448753
+ force: 4 0.0536942132 0.0000000000 0.0296363377
+ force: 5 -0.0531308562 0.0000000000 0.0292335571
+ force: 6 -0.0530780764 0.0000000000 -0.0291384102
+
+ force: Maximum force : 0.05382835(Ha/a0) on atom 3 in x direction
+ force: Force Residual: 0.05454528 Ha/a0
+ force: Total stress: -0.95572370 -0.00138926 -0.92184508 GPa
+
+ BIBLIOGRAPHY: Please consider citing the following references in the conquest.bib file
+
+ CONQUEST: Bowler2002pt, Miyazaki2004, Nakata2020
+ Basis: Bowler2019
+ DM: Bowler:2006xr
+ Pseudopotentials: Hamann2013, Bowler2019
+
+
+ Warnings written to file Conquest_warnings; please check
+
+ Max total mem use is 169.528 MB
+
+ Total run time was: 539.323 seconds
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/H_PBE_SZP_CQ.ion b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/H_PBE_SZP_CQ.ion
new file mode 100644
index 000000000..0faa93ce1
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_0.4_SCF/H_PBE_SZP_CQ.ion
@@ -0,0 +1,3055 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2024/04/24 at 18:15
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: H.in (appended at end of file)
+ Core radii (bohr) : l=0 1.000 l=1 0.700
+ 1 valence shells : 1s
+ XC functional code : 000101
+ XC description : GGA PBE96
+
+
+H basis set with GGA PBE96 functional
+n = 1, l = 0, 1 zetas
+ Radii: 6.73
+n = 3, l = 1, 1 zetas, perturbative polarisation shell
+ Radii: 6.73
+
+
+ H pb nrl nc
+
+
+H # Element symbol
+H # Label
+ 1.00 # Atomic number
+ 1.0000000000 # Valence charge
+ 1.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 1 2 # Lmax for basis, no of orbitals
+ 1 3 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 1 1 0 1.000000 #orbital l, n, z, is_polarized, population
+ 673 0.0100108094935117 6.7272639796398339
+ 0.00000000000 1.56155255225
+ 0.01001080949 1.56134081579
+ 0.02002161899 1.56070586103
+ 0.03003242848 1.55964896338
+ 0.04004323797 1.55817219676
+ 0.05005404747 1.55627843492
+ 0.06006485696 1.55397133802
+ 0.07007566645 1.55125532942
+ 0.08008647595 1.54813556702
+ 0.09009728544 1.54461791016
+ 0.10010809494 1.54070888255
+ 0.11011890443 1.53641563176
+ 0.12012971392 1.53174588577
+ 0.13014052342 1.52670790712
+ 0.14015133291 1.52131044519
+ 0.15016214240 1.51556268735
+ 0.16017295190 1.50947420926
+ 0.17018376139 1.50305492529
+ 0.18019457088 1.49631503919
+ 0.19020538038 1.48926499595
+ 0.20021618987 1.48191543510
+ 0.21022699936 1.47427714601
+ 0.22023780886 1.46636102560
+ 0.23024861835 1.45817803890
+ 0.24025942784 1.44973918268
+ 0.25027023734 1.44105545246
+ 0.26028104683 1.43213781311
+ 0.27029185632 1.42299717314
+ 0.28030266582 1.41364436277
+ 0.29031347531 1.40409011574
+ 0.30032428481 1.39434505482
+ 0.31033509430 1.38441968091
+ 0.32034590379 1.37432436547
+ 0.33035671329 1.36406934614
+ 0.34036752278 1.35366472507
+ 0.35037833227 1.34312046995
+ 0.36038914177 1.33244641698
+ 0.37039995126 1.32165227563
+ 0.38041076075 1.31074763480
+ 0.39042157025 1.29974196964
+ 0.40043237974 1.28864464905
+ 0.41044318923 1.27746494296
+ 0.42045399873 1.26621202936
+ 0.43046480822 1.25489500038
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+# KBs:_______________
+ 0 1 -3.4022469484000002 #kb l, n (seq), energy in Ry
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+ 1 1 -1.0066422298000000 #kb l, n (seq), energy in Ry
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+# Vna:_______________
+ 673 0.01001080949 6.72726397964 # npts, delta, cutoff
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+ 6.71725317015 -0.14887081359
+ 6.72726397964 -0.14864884194
+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+H 1.00 0 1 4 upf
+#
+# n l f energy (Ha)
+1 0 1.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.00000 -0.23860 4 7 8.50000
+1 0.70000 0.05000 4 7 11.00000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 0.70000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 1.00000
+1 1 1.00000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+0 0.00000 0.00000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+3.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/C.gto b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/C.gto
new file mode 100644
index 000000000..fb84513f9
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/C.gto
@@ -0,0 +1,14 @@
+C
+3
+2S 3 2.0 0
+ 3.0500154803 -0.8718503385 0.0000000000
+ 0.1599863956 0.3605314379 0.0000000000
+ 0.5242567425 0.8731953379 0.0000000000
+2P 3 2.0 0
+ 0.1720417090 0.1855258456 0.0000000000
+ 2.7272258524 1.7315939925 0.0000000000
+ 0.7055493743 0.8775500569 0.0000000000
+3D 3 0.0 1
+ 86.0321546336 0.6114404190 0.0000000000
+ 3.6206685167 1.5850293864 0.0000000000
+ 0.5229417354 0.5889629298 0.0000000000
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/C_PBE_SZP_CQ.ion b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/C_PBE_SZP_CQ.ion
new file mode 100644
index 000000000..d02721f29
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/C_PBE_SZP_CQ.ion
@@ -0,0 +1,3983 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2023/11/30 at 18:44
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: C.in (appended at end of file)
+ Core radii (bohr) : l=0 1.200 l=1 1.250
+ 2 valence shells : 2s 2p
+ XC functional code : 000101
+ XC description : GGA PBE96
+ Includes partial core corrections
+
+
+C basis set with GGA PBE96 functional
+n = 2, l = 0, 1 zetas
+ Radii: 6.25
+n = 2, l = 1, 1 zetas
+ Radii: 6.25
+n = 3, l = 2, 1 zetas, perturbative polarisation shell
+ Radii: 6.25
+
+
+ C pb nrl pcec
+
+
+C # Element symbol
+C # Label
+ 6.00 # Atomic number
+ 4.0000000000 # Valence charge
+ 12.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 2 3 # Lmax for basis, no of orbitals
+ 1 4 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 2 1 0 2.000000 #orbital l, n, z, is_polarized, population
+ 625 0.0100114372662820 6.2471368541599936
+ 0.00000000000 0.36399167361
+ 0.01001143727 0.36419984924
+ 0.02002287453 0.36482394184
+ 0.03003431180 0.36586265061
+ 0.04004574907 0.36731381168
+ 0.05005718633 0.36917440439
+ 0.06006862360 0.37144056001
+ 0.07008006086 0.37410757294
+ 0.08009149813 0.37716991423
+ 0.09010293540 0.38062124745
+ 0.10011437266 0.38445444689
+ 0.11012580993 0.38866161785
+ 0.12013724720 0.39323411912
+ 0.13014868446 0.39816258747
+ 0.14016012173 0.40343696403
+ 0.15017155899 0.40904652250
+ 0.16018299626 0.41497989916
+ 0.17019443353 0.42122512431
+ 0.18020587079 0.42776965532
+ 0.19021730806 0.43460041100
+ 0.20022874533 0.44170380712
+ 0.21024018259 0.44906579307
+ 0.22025161986 0.45667188949
+ 0.23026305712 0.46450722667
+ 0.24027449439 0.47255658362
+ 0.25028593166 0.48080442768
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+# Vna:_______________
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+# Core:__________________________
+ 262 0.01001989337 2.61519216974 # npts, delta, cutoff
+ 0.00000000000 0.87236701390
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+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+C 6.00 1 2 4 upf
+#
+# n l f energy (Ha)
+1 0 2.00
+2 0 2.00
+2 1 2.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.20000 -0.50533 4 7 9.00000
+1 1.25000 -0.19424 4 8 9.40000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 1.20000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 2.00000
+1 2 1.50000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+3 4.00000 1.55000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+6.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/Conquest_coord b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/Conquest_coord
new file mode 100644
index 000000000..ce2e9ebf2
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/Conquest_coord
@@ -0,0 +1,10 @@
+22.676714 0.000000 0.000000
+0.000000 22.676714 0.000000
+0.000000 0.000000 22.676714
+6
+ 0.50000000 0.50000000 0.44437500 2 T T T
+ 0.50000000 0.50000000 0.55562500 2 T T T
+ 0.57859183 0.50000000 0.39900000 1 T T T
+ 0.57859183 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.39900000 1 T T T
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/Conquest_input b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/Conquest_input
new file mode 100644
index 000000000..f33481174
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/Conquest_input
@@ -0,0 +1,41 @@
+IO.Title isolated C2H4 with PBE0
+IO.Coordinates Conquest_coord
+IO.FractionalCoordinates T
+IO.Iprint 0
+IO.WriteOutToFile F
+IO.Iprint_exx 4
+IO.TimingOn T
+
+## General Parameters
+General.NumberOfSpecies 2
+General.DifferentFunctional T
+General.FunctionalType 201
+General.PAOFromFiles T
+
+## Moving Atoms
+AtomMove.TypeOfRun static
+
+## Basis Sets
+Basis.BasisSet PAOs
+
+## Energy Minimisation
+minE.SelfConsistent T
+minE.SCTolerance 0.1e-6
+
+## Integration Grid
+Grid.GridCutoff 90
+
+## Finding Density Matrix
+DM.SolutionMethod diagon
+
+## EXX Parameters
+EXX.Scheme 3
+EXX.GridSpacing 0.4
+EXX.GTO T
+
+## Atomic Information
+%block ChemicalSpeciesLabel
+1 1.0080 H H_PBE_SZP_CQ.ion
+2 12.0110 C C_PBE_SZP_CQ.ion
+%endblock
+
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/Conquest_out.ref b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/Conquest_out.ref
new file mode 100644
index 000000000..539996738
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/Conquest_out.ref
@@ -0,0 +1,95 @@
+ ________________________________________________________________________
+
+ CONQUEST
+
+ Concurrent Order N QUantum Electronic STructure
+ ________________________________________________________________________
+
+ Conquest lead developers:
+ D.R.Bowler (UCL, NIMS), T.Miyazaki (NIMS), A.Nakata (NIMS),
+ L. Truflandier (U. Bordeaux)
+
+ Developers:
+ M.Arita (NIMS), J.S.Baker (UCL), V.Brazdova (UCL), R.Choudhury (UCL),
+ S.Y.Mujahed (UCL), J.T.Poulton (UCL), Z.Raza (NIMS), A.Sena (UCL),
+ U.Terranova (UCL), L.Tong (UCL), A.Torralba (NIMS)
+
+ Early development:
+ I.J.Bush (STFC), C.M.Goringe (Keele), E.H.Hernandez (Keele)
+
+ Original inspiration and project oversight:
+ M.J.Gillan (Keele, UCL)
+ ________________________________________________________________________
+
+ Simulation cell dimensions: 22.6767 a0 x 22.6767 a0 x 22.6767 a0
+
+ Atomic coordinates (a0)
+ Atom X Y Z Species
+ 1 11.3384 11.3384 10.0770 2
+ 2 11.3384 11.3384 12.5997 2
+ 3 13.1206 11.3384 9.0480 1
+ 4 13.1206 11.3384 13.6287 1
+ 5 9.5562 11.3384 13.6287 1
+ 6 9.5562 11.3384 9.0480 1
+
+ Default k-point sampling of Gamma point only
+
+ This job was run on 2024/04/24 at 18:42 +0200
+ Code was compiled on 2024/03/25 at 16:34 +0100
+ Version comment: Git Branch: f-exx-opt; tag, hash: v1.2-215-gc00a071c
+
+ Job title: isolated C2H4 with PBE0
+ Job to be run: static calculation
+
+ Ground state search:
+ Support functions represented with PAO basis
+ 1:1 PAO to SF mapping
+ Non-spin-polarised electrons
+ Solving for the K matrix using diagonalisation
+
+ Integration grid spacing: 0.227 a0 x 0.227 a0 x 0.227 a0
+
+ Number of species: 2
+ --------------------------------------------------------
+ | # mass (au) Charge (e) SF Rad (a0) NSF Label |
+ --------------------------------------------------------
+ | 1 1.008 1.000 7.030 4 H |
+ | 2 12.011 4.000 6.576 9 C |
+ --------------------------------------------------------
+
+ The calculation will be performed on 4 processes
+
+ The calculation will be performed on 2 threads
+
+ The functional used will be hyb PBE0
+
+ PulayMixSC: Reached SCF tolerance of 0.73165E-07 after 10 iterations
+ | Number of electrons = 12.000001
+ |* Harris-Foulkes energy = -14.019940353472691 Ha
+
+ force: Forces on atoms (Ha/a0)
+ force: Atom X Y Z
+ force: 1 -0.0000000000 0.0000000000 -0.0048633431
+ force: 2 -0.0000000000 0.0000000000 0.0048633431
+ force: 3 0.0584281998 0.0000000000 -0.0345831989
+ force: 4 0.0584281998 0.0000000000 0.0345831989
+ force: 5 -0.0584281998 0.0000000000 0.0345831989
+ force: 6 -0.0584281998 0.0000000000 -0.0345831989
+
+ force: Maximum force : 0.05842820(Ha/a0) on atom 4 in x direction
+ force: Force Residual: 0.05550783 Ha/a0
+ force: Total stress: -1.04689257 -0.00134924 -0.82870843 GPa
+
+ BIBLIOGRAPHY: Please consider citing the following references in the conquest.bib file
+
+ CONQUEST: Bowler2002pt, Miyazaki2004, Nakata2020
+ Basis: Bowler2019
+ DM: Bowler:2006xr
+ Pseudopotentials: Hamann2013, Bowler2019
+
+
+ Warnings written to file Conquest_warnings; please check
+
+ Max total mem use is 167.596 MB
+
+ Total run time was: 147.643 seconds
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/H.gto b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/H.gto
new file mode 100644
index 000000000..973321d65
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/H.gto
@@ -0,0 +1,10 @@
+H
+2
+1S 3 1.0 0
+ 0.5275548006 0.6715259615 0.0000000000
+ 2.7696753856 0.5826356660 0.0000000000
+ 0.1171533205 0.3049461091 0.0000000000
+1P 3 0.0 1
+ 0.0808680015 0.1247069341 0.0000000000
+ 0.6090316947 0.0705490915 0.0000000000
+ 3.9474039152 0.0358671499 0.0000000000
diff --git a/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/H_PBE_SZP_CQ.ion b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/H_PBE_SZP_CQ.ion
new file mode 100644
index 000000000..0faa93ce1
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C2H4_4proc_PBE0ERI_fullSZP_GTO_SCF/H_PBE_SZP_CQ.ion
@@ -0,0 +1,3055 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2024/04/24 at 18:15
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: H.in (appended at end of file)
+ Core radii (bohr) : l=0 1.000 l=1 0.700
+ 1 valence shells : 1s
+ XC functional code : 000101
+ XC description : GGA PBE96
+
+
+H basis set with GGA PBE96 functional
+n = 1, l = 0, 1 zetas
+ Radii: 6.73
+n = 3, l = 1, 1 zetas, perturbative polarisation shell
+ Radii: 6.73
+
+
+ H pb nrl nc
+
+
+H # Element symbol
+H # Label
+ 1.00 # Atomic number
+ 1.0000000000 # Valence charge
+ 1.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 1 2 # Lmax for basis, no of orbitals
+ 1 3 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 1 1 0 1.000000 #orbital l, n, z, is_polarized, population
+ 673 0.0100108094935117 6.7272639796398339
+ 0.00000000000 1.56155255225
+ 0.01001080949 1.56134081579
+ 0.02002161899 1.56070586103
+ 0.03003242848 1.55964896338
+ 0.04004323797 1.55817219676
+ 0.05005404747 1.55627843492
+ 0.06006485696 1.55397133802
+ 0.07007566645 1.55125532942
+ 0.08008647595 1.54813556702
+ 0.09009728544 1.54461791016
+ 0.10010809494 1.54070888255
+ 0.11011890443 1.53641563176
+ 0.12012971392 1.53174588577
+ 0.13014052342 1.52670790712
+ 0.14015133291 1.52131044519
+ 0.15016214240 1.51556268735
+ 0.16017295190 1.50947420926
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+ 0.18019457088 1.49631503919
+ 0.19020538038 1.48926499595
+ 0.20021618987 1.48191543510
+ 0.21022699936 1.47427714601
+ 0.22023780886 1.46636102560
+ 0.23024861835 1.45817803890
+ 0.24025942784 1.44973918268
+ 0.25027023734 1.44105545246
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+# KBs:_______________
+ 0 1 -3.4022469484000002 #kb l, n (seq), energy in Ry
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+# Vna:_______________
+ 673 0.01001080949 6.72726397964 # npts, delta, cutoff
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+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+H 1.00 0 1 4 upf
+#
+# n l f energy (Ha)
+1 0 1.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.00000 -0.23860 4 7 8.50000
+1 0.70000 0.05000 4 7 11.00000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 0.70000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 1.00000
+1 1 1.00000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+0 0.00000 0.00000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+3.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/C_PBE_DZP_CQ.ion b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/C_PBE_DZP_CQ.ion
new file mode 100644
index 000000000..a671a58e1
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/C_PBE_DZP_CQ.ion
@@ -0,0 +1,4621 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2023/11/30 at 18:12
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: C.in (appended at end of file)
+ Core radii (bohr) : l=0 1.200 l=1 1.250
+ 2 valence shells : 2s 2p
+ XC functional code : 000101
+ XC description : GGA PBE96
+ Includes partial core corrections
+
+
+C basis set with GGA PBE96 functional
+n = 2, l = 0, 2 zetas
+ Radii: 6.25 3.17
+n = 2, l = 1, 2 zetas
+ Radii: 6.25 3.17
+n = 3, l = 2, 1 zetas, perturbative polarisation shell
+ Radii: 6.25
+
+
+ C pb nrl pcec
+
+
+C # Element symbol
+C # Label
+ 6.00 # Atomic number
+ 4.0000000000 # Valence charge
+ 12.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 2 5 # Lmax for basis, no of orbitals
+ 1 4 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 2 1 0 2.000000 #orbital l, n, z, is_polarized, population
+ 625 0.0100114372662820 6.2471368541599936
+ 0.00000000000 0.36399167361
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+# Vna:_______________
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+ 6.24713685416 -0.64029332051
+# Core:__________________________
+ 262 0.01001989337 2.61519216974 # npts, delta, cutoff
+ 0.00000000000 0.87236701390
+ 0.01001989337 0.87200154737
+ 0.02003978674 0.87090598593
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+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+C 6.00 1 2 4 upf
+#
+# n l f energy (Ha)
+1 0 2.00
+2 0 2.00
+2 1 2.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.20000 -0.50533 4 7 9.00000
+1 1.25000 -0.19424 4 8 9.40000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 1.20000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 2.00000
+1 2 1.50000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+3 4.00000 1.55000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+6.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/Conquest_coord b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/Conquest_coord
new file mode 100644
index 000000000..1ec35a695
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/Conquest_coord
@@ -0,0 +1,16 @@
+ 18.897261245651 0.000000000000 0.000000000000
+ 0.000000000000 11.338356747390 0.000000000000
+ 0.000000000000 0.000000000000 18.897261245651
+ 12 C H
+ 0.3787565515 0.5000001426 0.4300001226 1 T T T
+ 0.3787565515 0.5000001426 0.5700001625 1 T T T
+ 0.5000001426 0.5000001426 0.6400001825 1 T T T
+ 0.6212437337 0.5000001426 0.5700001625 1 T T T
+ 0.6212437337 0.5000001426 0.4300001226 1 T T T
+ 0.5000001426 0.5000001426 0.3600001027 1 T T T
+ 0.2844463581 0.5000001426 0.6244501781 2 T T T
+ 0.5000001426 0.5000001426 0.7489002136 2 T T T
+ 0.7155539270 0.5000001426 0.6244501781 2 T T T
+ 0.7155539270 0.5000001426 0.3755501071 2 T T T
+ 0.5000001426 0.5000001426 0.2511000716 2 T T T
+ 0.2844463593 0.5000001426 0.3755501078 2 T T T
diff --git a/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/Conquest_input b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/Conquest_input
new file mode 100644
index 000000000..a311402ec
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/Conquest_input
@@ -0,0 +1,40 @@
+IO.Title isolated C6H6 with PBE0
+IO.Coordinates Conquest_coord
+IO.FractionalCoordinates T
+IO.Iprint 0
+IO.WriteOutToFile F
+IO.Iprint_exx 4
+IO.TimingOn T
+
+## General Parameters
+General.NumberOfSpecies 2
+General.DifferentFunctional T
+General.FunctionalType 201
+General.PAOFromFiles T
+
+## Moving Atoms
+AtomMove.TypeOfRun static
+
+## Basis Sets
+Basis.BasisSet PAOs
+
+## Energy Minimisation
+minE.SelfConsistent T
+minE.SCTolerance 1.0e-2
+
+## Integration Grid
+Grid.GridCutoff 90
+
+## Finding Density Matrix
+DM.SolutionMethod diagon
+
+## EXX Parameters
+EXX.GridSpacing 0.6
+EXX.Scheme 1
+
+## Atomic Information
+%block ChemicalSpeciesLabel
+1 1.0080 H H_PBE_DZP_CQ.ion
+2 12.0110 C C_PBE_DZP_CQ.ion
+%endblock
+
diff --git a/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/Conquest_out.ref b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/Conquest_out.ref
new file mode 100644
index 000000000..ce1a90f74
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/Conquest_out.ref
@@ -0,0 +1,135 @@
+ ________________________________________________________________________
+
+ CONQUEST
+
+ Concurrent Order N QUantum Electronic STructure
+ ________________________________________________________________________
+
+ Conquest lead developers:
+ D.R.Bowler (UCL, NIMS), T.Miyazaki (NIMS), A.Nakata (NIMS),
+ L. Truflandier (U. Bordeaux)
+
+ Developers:
+ M.Arita (NIMS), J.S.Baker (UCL), V.Brazdova (UCL), R.Choudhury (UCL),
+ S.Y.Mujahed (UCL), J.T.Poulton (UCL), Z.Raza (NIMS), A.Sena (UCL),
+ U.Terranova (UCL), L.Tong (UCL), A.Torralba (NIMS)
+
+ Early development:
+ I.J.Bush (STFC), C.M.Goringe (Keele), E.H.Hernandez (Keele)
+
+ Original inspiration and project oversight:
+ M.J.Gillan (Keele, UCL)
+ ________________________________________________________________________
+
+WARNING: Functional in input file differs to pseudopotential but proceeding: 201 101
+
+
+WARNING: Functional in input file differs to pseudopotential but proceeding: 201 101
+
+
+ Simulation cell dimensions: 18.8973 a0 x 11.3384 a0 x 18.8973 a0
+
+ Atomic coordinates (a0)
+ Atom X Y Z Species
+ 1 7.1575 5.6692 8.1258 1
+ 2 7.1575 5.6692 10.7714 1
+ 3 9.4486 5.6692 12.0943 1
+ 4 11.7398 5.6692 10.7714 1
+ 5 11.7398 5.6692 8.1258 1
+ 6 9.4486 5.6692 6.8030 1
+ 7 5.3753 5.6692 11.8004 2
+ 8 9.4486 5.6692 14.1522 2
+ 9 13.5220 5.6692 11.8004 2
+ 10 13.5220 5.6692 7.0969 2
+ 11 9.4486 5.6692 4.7451 2
+ 12 5.3753 5.6692 7.0969 2
+
+ Default k-point sampling of Gamma point only
+ All 1 Kpoints in fractional coordinates:
+ 1 0.000000 0.000000 0.000000 1.000
+
+ This calculation includes non-local pseudopotentials,
+ with a maximum core radius of 6.72726398
+
+ This job was run on 2024/02/12 at 18:47 +0100
+ Code was compiled on 2023/12/01 at 15:01 +0100
+ Version comment: Git Branch: f-exx-opt; tag, hash: v1.2-167-gddc9e439
+
+ Job title: isolated C6H6 with PBE0
+ Job to be run: static calculation
+
+ Ground state search:
+ Support functions represented with PAO basis
+ 1:1 PAO to SF mapping
+ Non-spin-polarised electrons
+ Solving for the K matrix using diagonalisation
+ Using Fermi-Dirac smearing
+
+ Integration grid size: 96 x 60 x 96
+
+ Integration grid spacing: 0.197 a0 x 0.189 a0 x 0.197 a0
+
+ Number of species: 2
+ --------------------------------------------------------
+ | # mass (au) Charge (e) SF Rad (a0) NSF Label |
+ --------------------------------------------------------
+ | 1 1.008 1.000 7.086 5 H |
+ | 2 12.011 4.000 6.496 13 C |
+ --------------------------------------------------------
+ SCF tolerance: 0.01000000
+ SCF iterations: 50
+
+ The calculation will be performed on 4 processes
+
+ The calculation will be performed on 1 thread
+
+ The functional used will be hyb PBE0
+
+ set_atom_dens: In set_atomic_density, electrons : 30.000000000000
+ PulayMixSC: Starting Pulay mixing, A_up = 0.500 A_dn = 0.500
+ PulayMixSC: Spin non-polarised calculation.
+ Harris-Foulkes Energy : -35.202064560147747 Ha
+ Free Energy (E-TS) : -35.206335247435526 Ha
+ PulayMixSC: Pulay iteration 1 residual: 0.96679E-02
+ PulayMixSC: reached SCF residual of 0.96679E-02 after 1 iterations
+ | Number of electrons = 30.000000
+ | GS Energy as E-(1/2)TS = -35.204199903791633 Ha
+ | Free Energy as E-TS = -35.206335247435526 Ha
+ |* Harris-Foulkes energy = -35.202064560147747 Ha
+ |* DFT total energy = -35.068257982177883 Ha
+
+ force: Forces on atoms (Ha/a0)
+ force: Atom X Y Z
+ force: 1 0.1385913738 -0.0000000021 0.0799389085
+ force: 2 0.1385913528 -0.0000000021 -0.0799389006
+ force: 3 -0.0000001061 0.0000001311 -0.1598205876
+ force: 4 -0.1385913439 -0.0000000021 -0.0799389067
+ force: 5 -0.1385913546 -0.0000000021 0.0799389084
+ force: 6 -0.0000001061 0.0000001311 0.1598206053
+ force: 7 0.0725401894 -0.0000000032 -0.0446206450
+ force: 8 -0.0000037216 -0.0000009304 -0.0836180813
+ force: 9 -0.0725400858 -0.0000000032 -0.0446206841
+ force: 10 -0.0725400863 -0.0000000032 0.0446206939
+ force: 11 -0.0000037227 -0.0000009304 0.0836180823
+ force: 12 0.0725401730 -0.0000000032 0.0446206429
+
+ force: Maximum force : 0.15982061(Ha/a0) on atom 6 in z direction
+ force: Force Residual: 0.12795594 Ha/a0
+ force: Total stress: -6.75548210 11.18670233 -6.67715096 GPa
+ force: Average pressure: 0.74864357 GPa
+
+ get_E_and_F: Change in energy during last step of electronic optimisation: -0.35202E+02
+
+ BIBLIOGRAPHY: Please consider citing the following references in the conquest.bib file
+
+ CONQUEST: Bowler2002pt, Miyazaki2004, Nakata2020
+ Basis: Bowler2019
+ DM: Bowler:2006xr
+ Pseudopotentials: Hamann2013, Bowler2019
+
+
+ Warnings written to file Conquest_warnings; please check
+
+ Max total mem use is 2047.494 MB
+
+ Total run time was: 271.101 seconds
diff --git a/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/H_PBE_DZP_CQ.ion b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/H_PBE_DZP_CQ.ion
new file mode 100644
index 000000000..f02fe9759
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullDZP_0.6/H_PBE_DZP_CQ.ion
@@ -0,0 +1,3371 @@
+
+
+ Git Branch: f-exx-opt; tag, hash: v1.2-169-g41cf7e2b
+ Date generated : 2024/02/09 at 18:32
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: H.in (appended at end of file)
+ Core radii (bohr) : l=0 1.000 l=1 0.700
+ 1 valence shells : 1s
+ XC functional code : 000101
+ XC description : GGA PBE96
+
+
+H basis set with GGA PBE96 functional
+n = 1, l = 0, 2 zetas
+ Radii: 6.73 3.14
+n = 3, l = 1, 1 zetas, perturbative polarisation shell
+ Radii: 6.73
+
+
+ H pb nrl nc
+
+
+H # Element symbol
+H # Label
+ 1.00 # Atomic number
+ 1.0000000000 # Valence charge
+ 1.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 1 3 # Lmax for basis, no of orbitals
+ 1 3 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 1 1 0 1.000000 #orbital l, n, z, is_polarized, population
+ 673 0.0100108094935117 6.7272639796398339
+ 0.00000000000 1.56155255225
+ 0.01001080949 1.56134081579
+ 0.02002161899 1.56070586103
+ 0.03003242848 1.55964896338
+ 0.04004323797 1.55817219676
+ 0.05005404747 1.55627843492
+ 0.06006485696 1.55397133802
+ 0.07007566645 1.55125532942
+ 0.08008647595 1.54813556702
+ 0.09009728544 1.54461791016
+ 0.10010809494 1.54070888255
+ 0.11011890443 1.53641563176
+ 0.12012971392 1.53174588577
+ 0.13014052342 1.52670790712
+ 0.14015133291 1.52131044519
+ 0.15016214240 1.51556268735
+ 0.16017295190 1.50947420926
+ 0.17018376139 1.50305492529
+ 0.18019457088 1.49631503919
+ 0.19020538038 1.48926499595
+ 0.20021618987 1.48191543510
+ 0.21022699936 1.47427714601
+ 0.22023780886 1.46636102560
+ 0.23024861835 1.45817803890
+ 0.24025942784 1.44973918268
+ 0.25027023734 1.44105545246
+ 0.26028104683 1.43213781311
+ 0.27029185632 1.42299717314
+ 0.28030266582 1.41364436277
+ 0.29031347531 1.40409011574
+ 0.30032428481 1.39434505482
+ 0.31033509430 1.38441968091
+ 0.32034590379 1.37432436547
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+ 0.34036752278 1.35366472507
+ 0.35037833227 1.34312046995
+ 0.36038914177 1.33244641698
+ 0.37039995126 1.32165227563
+ 0.38041076075 1.31074763480
+ 0.39042157025 1.29974196964
+ 0.40043237974 1.28864464905
+ 0.41044318923 1.27746494296
+ 0.42045399873 1.26621202936
+ 0.43046480822 1.25489500038
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+# Vna:_______________
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+ 6.57710183724 -0.15204310896
+ 6.58711264673 -0.15181203971
+ 6.59712345622 -0.15158167173
+ 6.60713426572 -0.15135200182
+ 6.61714507521 -0.15112302683
+ 6.62715588470 -0.15089474361
+ 6.63716669420 -0.15066714901
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+ 6.65718831319 -0.15021401330
+ 6.66719912268 -0.14998846601
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+ 6.70724236065 -0.14909300957
+ 6.71725317015 -0.14887081359
+ 6.72726397964 -0.14864884194
+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+H 1.00 0 1 4 upf
+#
+# n l f energy (Ha)
+1 0 1.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.00000 -0.23860 4 7 8.50000
+1 0.70000 0.05000 4 7 11.00000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 0.70000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 1.00000
+1 1 1.00000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+0 0.00000 0.00000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+3.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/C_PBE_SZP_CQ.ion b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/C_PBE_SZP_CQ.ion
new file mode 100644
index 000000000..b9821a238
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/C_PBE_SZP_CQ.ion
@@ -0,0 +1,3983 @@
+
+
+ Git Branch: f-exx-opt; tag, hash: v1.2-169-g41cf7e2b
+ Date generated : 2024/02/13 at 17:40
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: C.in (appended at end of file)
+ Core radii (bohr) : l=0 1.200 l=1 1.250
+ 2 valence shells : 2s 2p
+ XC functional code : 000101
+ XC description : GGA PBE96
+ Includes partial core corrections
+
+
+C basis set with GGA PBE96 functional
+n = 2, l = 0, 1 zetas
+ Radii: 6.25
+n = 2, l = 1, 1 zetas
+ Radii: 6.25
+n = 3, l = 2, 1 zetas, perturbative polarisation shell
+ Radii: 6.25
+
+
+ C pb nrl pcec
+
+
+C # Element symbol
+C # Label
+ 6.00 # Atomic number
+ 4.0000000000 # Valence charge
+ 12.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 2 3 # Lmax for basis, no of orbitals
+ 1 4 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 2 1 0 2.000000 #orbital l, n, z, is_polarized, population
+ 625 0.0100114372662820 6.2471368541599936
+ 0.00000000000 0.36399167361
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+ 1.20238720448 0.00014470722
+ 1.21240709785 0.00010785867
+ 1.22242699122 0.00007840544
+ 1.23244688459 0.00005524630
+ 1.24246677796 0.00003740090
+ 1.25248667133 0.00002400071
+ 1.26250656470 0.00001428028
+ 1.27252645807 0.00000756884
+ 1.28254635144 0.00000328214
+ 1.29256624481 0.00000091481
+ 1.30258613818 0.00000003296
+ 1.31260603155 0.00000026724
+ 1.32262592492 0.00000130623
+ 1.33264581829 0.00000289033
+ 1.34266571167 0.00000480590
+ 1.35268560504 0.00000687997
+ 1.36270549841 0.00000897514
+ 1.37272539178 0.00001098506
+ 1.38274528515 0.00001283015
+ 1.39276517852 0.00001445373
+ 1.40278507189 0.00001581848
+ 1.41280496526 0.00001690332
+ 1.42282485863 0.00001770047
+ 1.43284475200 0.00001821292
+ 1.44286464537 0.00001845219
+ 1.45288453874 0.00001843626
+ 1.46290443211 0.00001818793
+ 1.47292432548 0.00001773321
+ 1.48294421885 0.00001710009
+ 1.49296411222 0.00001631746
+ 1.50298400560 0.00001541417
+ 1.51300389897 0.00001441832
+ 1.52302379234 0.00001335666
+ 1.53304368571 0.00001225415
+ 1.54306357908 0.00001113361
+ 1.55308347245 0.00001001551
+ 1.56310336582 0.00000891785
+ 1.57312325919 0.00000785604
+ 1.58314315256 0.00000684298
+ 1.59316304593 0.00000588905
+ 1.60318293930 0.00000500231
+ 1.61320283267 0.00000418852
+ 1.62322272604 0.00000345144
+ 1.63324261941 0.00000279292
+ 1.64326251278 0.00000221314
+ 1.65328240615 0.00000171084
+ 1.66330229953 0.00000128349
+ 1.67332219290 0.00000092750
+ 1.68334208627 0.00000063847
+ 1.69336197964 0.00000041130
+ 1.70338187301 0.00000024046
+ 1.71340176638 0.00000012009
+ 1.72342165975 0.00000004416
+ 1.73344155312 0.00000000663
+ 1.74346144649 0.00000000155
+ 1.75348133986 0.00000002317
+ 1.76350123323 0.00000006601
+ 1.77352112660 0.00000012495
+ 1.78354101997 0.00000019525
+ 1.79356091334 0.00000027265
+ 1.80358080671 0.00000035331
+ 1.81360070009 0.00000043392
+ 1.82362059346 0.00000051163
+ 1.83364048683 0.00000058407
+ 1.84366038020 0.00000064934
+ 1.85368027357 0.00000070599
+ 1.86370016694 0.00000075297
+ 1.87372006031 0.00000078962
+ 1.88373995368 0.00000081563
+ 1.89375984705 0.00000083100
+ 1.90377974042 0.00000083600
+ 1.91379963379 0.00000083113
+ 1.92381952716 0.00000081707
+ 1.93383942053 0.00000079466
+ 1.94385931390 0.00000076485
+ 1.95387920727 0.00000072869
+ 1.96389910064 0.00000068725
+ 1.97391899402 0.00000064163
+ 1.98393888739 0.00000059292
+ 1.99395878076 0.00000054217
+ 2.00397867413 0.00000049040
+ 2.01399856750 0.00000043854
+ 2.02401846087 0.00000038746
+ 2.03403835424 0.00000033790
+ 2.04405824761 0.00000029055
+ 2.05407814098 0.00000024597
+ 2.06409803435 0.00000020461
+ 2.07411792772 0.00000016683
+ 2.08413782109 0.00000013288
+ 2.09415771446 0.00000010294
+ 2.10417760783 0.00000007705
+ 2.11419750120 0.00000005521
+ 2.12421739457 0.00000003733
+ 2.13423728795 0.00000002324
+ 2.14425718132 0.00000001275
+ 2.15427707469 0.00000000558
+ 2.16429696806 0.00000000144
+ 2.17431686143 0.00000000001
+ 2.18433675480 0.00000000093
+ 2.19435664817 0.00000000387
+ 2.20437654154 0.00000000845
+ 2.21439643491 0.00000001433
+ 2.22441632828 0.00000002116
+ 2.23443622165 0.00000002863
+ 2.24445611502 0.00000003644
+ 2.25447600839 0.00000004429
+ 2.26449590176 0.00000005196
+ 2.27451579513 0.00000005922
+ 2.28453568850 0.00000006589
+ 2.29455558188 0.00000007182
+ 2.30457547525 0.00000007688
+ 2.31459536862 0.00000008100
+ 2.32461526199 0.00000008411
+ 2.33463515536 0.00000008620
+ 2.34465504873 0.00000008725
+ 2.35467494210 0.00000008729
+ 2.36469483547 0.00000008637
+ 2.37471472884 0.00000008455
+ 2.38473462221 0.00000008191
+ 2.39475451558 0.00000007854
+ 2.40477440895 0.00000007454
+ 2.41479430232 0.00000007002
+ 2.42481419569 0.00000006508
+ 2.43483408906 0.00000005983
+ 2.44485398244 0.00000005439
+ 2.45487387581 0.00000004886
+ 2.46489376918 0.00000004334
+ 2.47491366255 0.00000003791
+ 2.48493355592 0.00000003267
+ 2.49495344929 0.00000002768
+ 2.50497334266 0.00000002302
+ 2.51499323603 0.00000001872
+ 2.52501312940 0.00000001484
+ 2.53503302277 0.00000001139
+ 2.54505291614 0.00000000841
+ 2.55507280951 0.00000000590
+ 2.56509270288 0.00000000385
+ 2.57511259625 0.00000000226
+ 2.58513248962 0.00000000113
+ 2.59515238299 0.00000000044
+ 2.60517227637 0.00000000010
+ 2.61519216974 0.00000000000
+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+C 6.00 1 2 4 upf
+#
+# n l f energy (Ha)
+1 0 2.00
+2 0 2.00
+2 1 2.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.20000 -0.50533 4 7 9.00000
+1 1.25000 -0.19424 4 8 9.40000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 1.20000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 2.00000
+1 2 1.50000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+3 4.00000 1.55000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+6.00 0.01
+
diff --git a/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/Conquest_coord b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/Conquest_coord
new file mode 100644
index 000000000..1ec35a695
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/Conquest_coord
@@ -0,0 +1,16 @@
+ 18.897261245651 0.000000000000 0.000000000000
+ 0.000000000000 11.338356747390 0.000000000000
+ 0.000000000000 0.000000000000 18.897261245651
+ 12 C H
+ 0.3787565515 0.5000001426 0.4300001226 1 T T T
+ 0.3787565515 0.5000001426 0.5700001625 1 T T T
+ 0.5000001426 0.5000001426 0.6400001825 1 T T T
+ 0.6212437337 0.5000001426 0.5700001625 1 T T T
+ 0.6212437337 0.5000001426 0.4300001226 1 T T T
+ 0.5000001426 0.5000001426 0.3600001027 1 T T T
+ 0.2844463581 0.5000001426 0.6244501781 2 T T T
+ 0.5000001426 0.5000001426 0.7489002136 2 T T T
+ 0.7155539270 0.5000001426 0.6244501781 2 T T T
+ 0.7155539270 0.5000001426 0.3755501071 2 T T T
+ 0.5000001426 0.5000001426 0.2511000716 2 T T T
+ 0.2844463593 0.5000001426 0.3755501078 2 T T T
diff --git a/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/Conquest_input b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/Conquest_input
new file mode 100644
index 000000000..886064ed4
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/Conquest_input
@@ -0,0 +1,40 @@
+IO.Title isolated C6H6 with PBE0
+IO.Coordinates Conquest_coord
+IO.FractionalCoordinates T
+IO.Iprint 0
+IO.WriteOutToFile F
+IO.Iprint_exx 4
+IO.TimingOn T
+
+## General Parameters
+General.NumberOfSpecies 2
+General.DifferentFunctional T
+General.FunctionalType 201
+General.PAOFromFiles T
+
+## Moving Atoms
+AtomMove.TypeOfRun static
+
+## Basis Sets
+Basis.BasisSet PAOs
+
+## Energy Minimisation
+minE.SelfConsistent T
+minE.SCTolerance 1.0e-2
+
+## Integration Grid
+Grid.GridCutoff 90
+
+## Finding Density Matrix
+DM.SolutionMethod diagon
+
+## EXX Parameters
+EXX.GridSpacing 0.6
+EXX.Scheme 1
+
+## Atomic Information
+%block ChemicalSpeciesLabel
+1 1.0080 H H_PBE_SZP_CQ.ion
+2 12.0110 C C_PBE_SZP_CQ.ion
+%endblock
+
diff --git a/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/Conquest_out.ref b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/Conquest_out.ref
new file mode 100644
index 000000000..84f5fe732
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/Conquest_out.ref
@@ -0,0 +1,135 @@
+ ________________________________________________________________________
+
+ CONQUEST
+
+ Concurrent Order N QUantum Electronic STructure
+ ________________________________________________________________________
+
+ Conquest lead developers:
+ D.R.Bowler (UCL, NIMS), T.Miyazaki (NIMS), A.Nakata (NIMS),
+ L. Truflandier (U. Bordeaux)
+
+ Developers:
+ M.Arita (NIMS), J.S.Baker (UCL), V.Brazdova (UCL), R.Choudhury (UCL),
+ S.Y.Mujahed (UCL), J.T.Poulton (UCL), Z.Raza (NIMS), A.Sena (UCL),
+ U.Terranova (UCL), L.Tong (UCL), A.Torralba (NIMS)
+
+ Early development:
+ I.J.Bush (STFC), C.M.Goringe (Keele), E.H.Hernandez (Keele)
+
+ Original inspiration and project oversight:
+ M.J.Gillan (Keele, UCL)
+ ________________________________________________________________________
+
+WARNING: Functional in input file differs to pseudopotential but proceeding: 201 101
+
+
+WARNING: Functional in input file differs to pseudopotential but proceeding: 201 101
+
+
+ Simulation cell dimensions: 18.8973 a0 x 11.3384 a0 x 18.8973 a0
+
+ Atomic coordinates (a0)
+ Atom X Y Z Species
+ 1 7.1575 5.6692 8.1258 1
+ 2 7.1575 5.6692 10.7714 1
+ 3 9.4486 5.6692 12.0943 1
+ 4 11.7398 5.6692 10.7714 1
+ 5 11.7398 5.6692 8.1258 1
+ 6 9.4486 5.6692 6.8030 1
+ 7 5.3753 5.6692 11.8004 2
+ 8 9.4486 5.6692 14.1522 2
+ 9 13.5220 5.6692 11.8004 2
+ 10 13.5220 5.6692 7.0969 2
+ 11 9.4486 5.6692 4.7451 2
+ 12 5.3753 5.6692 7.0969 2
+
+ Default k-point sampling of Gamma point only
+ All 1 Kpoints in fractional coordinates:
+ 1 0.000000 0.000000 0.000000 1.000
+
+ This calculation includes non-local pseudopotentials,
+ with a maximum core radius of 6.72726398
+
+ This job was run on 2024/02/13 at 17:42 +0100
+ Code was compiled on 2023/12/01 at 15:01 +0100
+ Version comment: Git Branch: f-exx-opt; tag, hash: v1.2-167-gddc9e439
+
+ Job title: isolated C6H6 with PBE0
+ Job to be run: static calculation
+
+ Ground state search:
+ Support functions represented with PAO basis
+ 1:1 PAO to SF mapping
+ Non-spin-polarised electrons
+ Solving for the K matrix using diagonalisation
+ Using Fermi-Dirac smearing
+
+ Integration grid size: 96 x 60 x 96
+
+ Integration grid spacing: 0.197 a0 x 0.189 a0 x 0.197 a0
+
+ Number of species: 2
+ --------------------------------------------------------
+ | # mass (au) Charge (e) SF Rad (a0) NSF Label |
+ --------------------------------------------------------
+ | 1 1.008 1.000 7.086 4 H |
+ | 2 12.011 4.000 6.496 9 C |
+ --------------------------------------------------------
+ SCF tolerance: 0.01000000
+ SCF iterations: 50
+
+ The calculation will be performed on 4 processes
+
+ The calculation will be performed on 1 thread
+
+ The functional used will be hyb PBE0
+
+ set_atom_dens: In set_atomic_density, electrons : 30.000000000000
+ PulayMixSC: Starting Pulay mixing, A_up = 0.500 A_dn = 0.500
+ PulayMixSC: Spin non-polarised calculation.
+ Harris-Foulkes Energy : -35.023401126219227 Ha
+ Free Energy (E-TS) : -35.027728454246770 Ha
+ PulayMixSC: Pulay iteration 1 residual: 0.89186E-02
+ PulayMixSC: reached SCF residual of 0.89186E-02 after 1 iterations
+ | Number of electrons = 30.000000
+ | GS Energy as E-(1/2)TS = -35.025564790232998 Ha
+ | Free Energy as E-TS = -35.027728454246770 Ha
+ |* Harris-Foulkes energy = -35.023401126219227 Ha
+ |* DFT total energy = -34.925187220063577 Ha
+
+ force: Forces on atoms (Ha/a0)
+ force: Atom X Y Z
+ force: 1 0.1389219568 0.0000000016 0.0801333409
+ force: 2 0.1389219410 0.0000000016 -0.0801333398
+ force: 3 -0.0000000128 0.0000000930 -0.1602534887
+ force: 4 -0.1389219434 0.0000000016 -0.0801333465
+ force: 5 -0.1389219486 0.0000000016 0.0801333414
+ force: 6 -0.0000000127 0.0000000930 0.1602534966
+ force: 7 0.1833789566 -0.0000000035 -0.1085875785
+ force: 8 -0.0000033996 -0.0000008259 -0.2118217135
+ force: 9 -0.1833788284 -0.0000000035 -0.1085876127
+ force: 10 -0.1833788299 -0.0000000035 0.1085876301
+ force: 11 -0.0000034010 -0.0000008259 0.2118217208
+ force: 12 0.1833789427 -0.0000000035 0.1085875842
+
+ force: Maximum force : 0.21182172(Ha/a0) on atom 11 in z direction
+ force: Force Residual: 0.18833884 Ha/a0
+ force: Total stress: -7.52780366 9.87307493 -7.45480733 GPa
+ force: Average pressure: 1.70317868 GPa
+
+ get_E_and_F: Change in energy during last step of electronic optimisation: -0.35023E+02
+
+ BIBLIOGRAPHY: Please consider citing the following references in the conquest.bib file
+
+ CONQUEST: Bowler2002pt, Miyazaki2004, Nakata2020
+ Basis: Bowler2019
+ DM: Bowler:2006xr
+ Pseudopotentials: Hamann2013, Bowler2019
+
+
+ Warnings written to file Conquest_warnings; please check
+
+ Max total mem use is 2047.177 MB
+
+ Total run time was: 107.266 seconds
diff --git a/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/H_PBE_SZP_CQ.ion b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/H_PBE_SZP_CQ.ion
new file mode 100644
index 000000000..036660027
--- /dev/null
+++ b/benchmarks/test_EXX_isol_C6H6_4proc_PBE0CRI_fullSZP_0.6/H_PBE_SZP_CQ.ion
@@ -0,0 +1,3055 @@
+
+
+ Git Branch: f-exx-opt; tag, hash: v1.2-169-g41cf7e2b
+ Date generated : 2024/02/13 at 17:39
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: H.in (appended at end of file)
+ Core radii (bohr) : l=0 1.000 l=1 0.700
+ 1 valence shells : 1s
+ XC functional code : 000101
+ XC description : GGA PBE96
+
+
+H basis set with GGA PBE96 functional
+n = 1, l = 0, 1 zetas
+ Radii: 6.73
+n = 3, l = 1, 1 zetas, perturbative polarisation shell
+ Radii: 6.73
+
+
+ H pb nrl nc
+
+
+H # Element symbol
+H # Label
+ 1.00 # Atomic number
+ 1.0000000000 # Valence charge
+ 1.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 1 2 # Lmax for basis, no of orbitals
+ 1 3 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 1 1 0 1.000000 #orbital l, n, z, is_polarized, population
+ 673 0.0100108094935117 6.7272639796398339
+ 0.00000000000 1.56155255225
+ 0.01001080949 1.56134081579
+ 0.02002161899 1.56070586103
+ 0.03003242848 1.55964896338
+ 0.04004323797 1.55817219676
+ 0.05005404747 1.55627843492
+ 0.06006485696 1.55397133802
+ 0.07007566645 1.55125532942
+ 0.08008647595 1.54813556702
+ 0.09009728544 1.54461791016
+ 0.10010809494 1.54070888255
+ 0.11011890443 1.53641563176
+ 0.12012971392 1.53174588577
+ 0.13014052342 1.52670790712
+ 0.14015133291 1.52131044519
+ 0.15016214240 1.51556268735
+ 0.16017295190 1.50947420926
+ 0.17018376139 1.50305492529
+ 0.18019457088 1.49631503919
+ 0.19020538038 1.48926499595
+ 0.20021618987 1.48191543510
+ 0.21022699936 1.47427714601
+ 0.22023780886 1.46636102560
+ 0.23024861835 1.45817803890
+ 0.24025942784 1.44973918268
+ 0.25027023734 1.44105545246
+ 0.26028104683 1.43213781311
+ 0.27029185632 1.42299717314
+ 0.28030266582 1.41364436277
+ 0.29031347531 1.40409011574
+ 0.30032428481 1.39434505482
+ 0.31033509430 1.38441968091
+ 0.32034590379 1.37432436547
+ 0.33035671329 1.36406934614
+ 0.34036752278 1.35366472507
+ 0.35037833227 1.34312046995
+ 0.36038914177 1.33244641698
+ 0.37039995126 1.32165227563
+ 0.38041076075 1.31074763480
+ 0.39042157025 1.29974196964
+ 0.40043237974 1.28864464905
+ 0.41044318923 1.27746494296
+ 0.42045399873 1.26621202936
+ 0.43046480822 1.25489500038
+ 0.44047561771 1.24352286722
+ 0.45048642721 1.23210456360
+ 0.46049723670 1.22064894730
+ 0.47050804620 1.20916479960
+ 0.48051885569 1.19766082252
+ 0.49052966518 1.18614563362
+ 0.50054047468 1.17462775819
+ 0.51055128417 1.16311561896
+ 0.52056209366 1.15161752334
+ 0.53057290316 1.14014164812
+ 0.54058371265 1.12869602198
+ 0.55059452214 1.11728850594
+ 0.56060533164 1.10592677176
+ 0.57061614113 1.09461827923
+ 0.58062695062 1.08337025177
+ 0.59063776012 1.07218965161
+ 0.60064856961 1.06108315432
+ 0.61065937910 1.05005712345
+ 0.62067018860 1.03911758559
+ 0.63068099809 1.02827020618
+ 0.64069180758 1.01752026688
+ 0.65070261708 1.00687264443
+ 0.66071342657 0.99633179185
+ 0.67072423607 0.98590172198
+ 0.68073504556 0.97558599407
+ 0.69074585505 0.96538770341
+ 0.70075666455 0.95530947455
+ 0.71076747404 0.94535345800
+ 0.72077828353 0.93552133092
+ 0.73078909303 0.92581430161
+ 0.74079990252 0.91623311803
+ 0.75081071201 0.90677808017
+ 0.76082152151 0.89744905638
+ 0.77083233100 0.88824550330
+ 0.78084314049 0.87916648941
+ 0.79085394999 0.87021072173
+ 0.80086475948 0.86137657557
+ 0.81087556897 0.85266212680
+ 0.82088637847 0.84406518633
+ 0.83089718796 0.83558333644
+ 0.84090799745 0.82721396833
+ 0.85091880695 0.81895432052
+ 0.86092961644 0.81080151767
+ 0.87094042594 0.80275260911
+ 0.88095123543 0.79480460685
+ 0.89096204492 0.78695452231
+ 0.90097285442 0.77919940158
+ 0.91098366391 0.77153635846
+ 0.92099447340 0.76396260519
+ 0.93100528290 0.75647548019
+ 0.94101609239 0.74907247266
+ 0.95102690188 0.74175124377
+ 0.96103771138 0.73450964406
+ 0.97104852087 0.72734572700
+ 0.98105933036 0.72025775855
+ 0.99107013986 0.71324422257
+ 1.00108094935 0.70630382231
+ 1.01109175884 0.69943547975
+ 1.02110256834 0.69263830857
+ 1.03111337783 0.68591151436
+ 1.04112418733 0.67925431698
+ 1.05113499682 0.67266594246
+ 1.06114580631 0.66614562738
+ 1.07115661581 0.65969261707
+ 1.08116742530 0.65330616551
+ 1.09117823479 0.64698553538
+ 1.10118904429 0.64072999795
+ 1.11119985378 0.63453883298
+ 1.12121066327 0.62841132865
+ 1.13122147277 0.62234678148
+ 1.14123228226 0.61634449622
+ 1.15124309175 0.61040378579
+ 1.16125390125 0.60452397114
+ 1.17126471074 0.59870438124
+ 1.18127552023 0.59294435291
+ 1.19128632973 0.58724323082
+ 1.20129713922 0.58160036732
+ 1.21130794871 0.57601512241
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+ 6.70724236065 -0.14909300957
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+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+H 1.00 0 1 4 upf
+#
+# n l f energy (Ha)
+1 0 1.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.00000 -0.23860 4 7 8.50000
+1 0.70000 0.05000 4 7 11.00000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 0.70000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 1.00000
+1 1 1.00000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+0 0.00000 0.00000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+3.00 0.01
+
diff --git a/docs/conf.py b/docs/conf.py
index b5b0f6847..e139dcfd4 100644
--- a/docs/conf.py
+++ b/docs/conf.py
@@ -63,9 +63,9 @@
# built documents.
#
# The short X.Y version.
-version = u'1.3'
+version = u'1.4'
# The full version, including alpha/beta/rc tags.
-release = u'1.3'
+release = u'1.4'
# The language for content autogenerated by Sphinx. Refer to documentation
# for a list of supported languages.
diff --git a/docs/convergence.rst b/docs/convergence.rst
index e0448b71e..a1b3b01b9 100644
--- a/docs/convergence.rst
+++ b/docs/convergence.rst
@@ -36,7 +36,13 @@ cutoff is set with the parameter:
Grid.GridCutoff E
where ``E`` is an energy in Hartrees. The grid spacing can also be
-set manually, by specifying the number of grid points in each
+set manually (in Bohr radii):
+
+ ::
+
+ Grid.GridSpacing d
+
+Or it can be set by specifying the number of grid points in each
direction:
::
diff --git a/docs/groundstate.rst b/docs/groundstate.rst
index 6812e8469..faf796f26 100644
--- a/docs/groundstate.rst
+++ b/docs/groundstate.rst
@@ -101,6 +101,12 @@ arbitrary vector from the origin of the Brillouin zone, by specifying:
Diag.MPShiftY 0.0
Diag.MPShiftZ 0.0
+For the Monkhorst-Pack approach, instead of specifying the number of
+points in x, y and z explicitly, they can be set automatically by giving
+a spacing in reciprocal space: ``Diag.dk`` where units are inverse Bohr
+radii. The number of points will be chosen so that :math:`2\pi/(a\times dk)`
+is less than the value specified.
+
Alternatively, the points in reciprocal space can be specified
explicitly by giving a number of points and their locations and weights:
diff --git a/docs/input-output.rst b/docs/input-output.rst
index 68e2dbdd9..c8ea2427a 100644
--- a/docs/input-output.rst
+++ b/docs/input-output.rst
@@ -30,7 +30,7 @@ Full documentation can be found in :ref:`input_tags`.
* ``Diag.MPMesh`` T/F
* ``Diag.MPMeshX`` (and ``Y`` and ``Z``) N
* ``Diag.GammaCentred`` T/F
-* ``Grid.GridCutoff`` Energy in Ha (sets a grid spacing :math:`\delta x = \pi/\sqrt{2E}` for cutoff E in Ha)
+* ``Grid.GridCutoff`` Energy in Ha (sets a grid spacing :math:`\delta x = \pi/\sqrt{2E}` for cutoff E in Ha; this spacing can also be set manually using ``Grid.GridSpacing`` in Bohr)
* ``AtomMove.NumSteps`` N
* ``AtomMove.MaxForceTol`` in Ha/bohr
* ``AtomMove.OptCell`` T/F (optimises simulation cell size)
diff --git a/docs/input_tags.rst b/docs/input_tags.rst
index 7d4ab7344..b3180c33c 100644
--- a/docs/input_tags.rst
+++ b/docs/input_tags.rst
@@ -52,11 +52,16 @@ General.FunctionalType (*integer*)
GGA PBE + Zhang-Yang 98 (revPBE) 102 :cite:`e-Zhang:1998oq`
GGA PBE + Hammer-Hansen-Norskov 99 (RPBE) 103 :cite:`e-Hammer1999`
GGA WC 104 :cite:`e-Wu:2006cu`
+ hybrid PBE0 (25% of exact exchange) 201 :cite:`e-Perdew1996hyb`
========================================= ======= =======================
At the moment, only LSDA Perdew-Wang 92 and the three GGA
Perdew-Burke-Ernzerhof functional variants can be used in spin polarised calculations.
+ At the moment, only hybrid functionals with GGA PBE are allowed. Fraction of
+ exact exchange can be tuned. **Warning**: EXX contribution to forces are not
+ implemented yet.
+
Note that, if the code is compiled with LibXC, the full LibXC
set of functionals is available, selected with a negative six
digit number (-XXXCCC or -CCCXXX).
@@ -395,6 +400,12 @@ Grid.GridCutoff (*real*)
Default: 50 Ha.
+Grid.GridSpacing (*real*)
+ As an alternative, the grid spacing in Bohr radii can be set (the code will determine a number
+ of grid points that will be below this value)
+
+ Default: zero (value taken from Grid.GridCutoff above)
+
Go to :ref:`top `.
.. _input_minE:
@@ -662,7 +673,13 @@ Diag.GammaCentred (*boolean*)
Selects Monkhorst-Pack mesh centred on the Gamma point
*default*: F
-
+
+Diag.dk (*real*)
+ Sets the number of k-points in the Monkhorst-Pack method so that the spacing
+ in reciprocal space is less than the specified value.
+
+ *default*: 0.0
+
Diag.PaddingHmatrix (*boolean*)
Setting this flag allows the Hamiltonian and overlap matrices to be
made larger than their physical size, so that ScaLAPACK block sizes can
@@ -675,8 +692,11 @@ Diag.PaddingHmatrix (*boolean*)
Diag.BlockSizeR (*integer*)
Block size for rows (See next).
+ From v1.4, the default value is 32 when Diag.PaddingHmatrix is true.
+ It is recommended to check the efficiency (CPU time) on your platform by changing this value.
+ Usually 20-40 is appropriate.
- *default*: Determined automatically
+ *default*: 32 or Determined automatically (if Diag.PaddingHmatrix= true)
Diag.BlockSizeC (*integer*)
R ... rows, C ... columns
@@ -1334,6 +1354,42 @@ cDFT.AtomGroups (*block*)
Go to :ref:`top `.
+.. _input_exx:
+
+Exact exchange (EXX)
+--------------------
+
+EXX.Alpha (*real*)
+ Fraction of exact exchange for the density functional XC
+ functional. For example, a value of 1 yields to full EXX with
+ no GGA exchange.
+
+ *default*: 0.25
+
+EXX.Scheme (*integer*)
+ Select the algorithm to compute EXX matrix elements based on local
+ numerical Poisson solver. Either the contraction reduction
+ integral (CRI) method or full/screened computation
+ of the electron repulsion integrals (ERIs) at each SCF step. For
+ the latter, possibility of storing the integrals computed at the
+ first SCF step is available.
+
+ - 1 Direct SCF using the CRI algorithm
+ - 2 Direct SCF using explicit calculation of ERIs
+ - 3 Indirect SCF using explicit calculation of ERIs and storage
+
+ We recommand either 1 or 3.
+
+ *default*: 1
+
+EXX.Grid (*string*)
+ Grid accuracy for numerical solution of local the Poisson equation.
+ Choose either ``coarse``, ``standard`` or ``fine``.
+
+ *default*: ``standard``
+
+Go to :ref:`top `.
+
.. _input_vdw:
vdW-DF
diff --git a/docs/installing.rst b/docs/installing.rst
index 2c5ebc3e9..82cb3da92 100644
--- a/docs/installing.rst
+++ b/docs/installing.rst
@@ -86,6 +86,8 @@ Compiler flags to enable OpenMP are dependent on the vendor, but should be speci
On some systems, the default stack size for OpenMP is set to be rather small, and this can cause a segmentation fault when running with multiple threads. We recommend testing the effect of the environment variable ``OMP_STACKSIZE`` (and suggest setting it to 50M or larger as a first test).
+Most OpenMP multi-threading in CONQUEST uses the ``runtime`` schedule. This means the type of scheduling of work to threads can be set by the user by setting the ``OMP_SCHEDULE`` `variable`_. If the variable is unset, OpenMP will use a default implementation defined schedule.
+
Go to :ref:`top `
.. _install_spack:
@@ -112,5 +114,114 @@ The build can be customized by adding options to the
`Spack spec `_ ``conquest``.
The CONQUEST package includes variants for OpenMP support and different matrix multiplication kernels; more details can be found in the `Spack CONQUEST package `_.
+Installing on Ubuntu
+-----------
+
+CONQUEST can be compiled on Ubuntu after installing the required packages. The below instructions are given for Ubuntu 22.04 LTS and Ubuntu 24.04 LTS.
+The source files will be downloaded into the ``${USER}/local/src`` directory. The ${USER} variable will be automatically replaced by the current username.
+If compilation is successful, the executable file can be found in ``${USER}/local/src/conquest_master/bin``.
+
+Install needed packages
+~~~~~~~~~~~~~~~~
+
+.. code-block:: bash
+
+ sudo apt update
+ sudo apt upgrade
+
+ sudo apt install -y build-essential libtool # GCC and other tools for software development
+ sudo apt install -y openmpi-bin libopenmpi-dev # MPI
+ sudo apt install -y libfftw3-dev # FFT
+ sudo apt install -y libblas-dev liblapack-dev libscalapack-openmpi-dev # Linear algebra
+
+Install libxc
+~~~~~~~~~~~~~~~~~~~
+
+.. code-block:: bash
+
+ cd $HOME
+ mkdir -p ${HOME}/local/src
+ cd ${HOME}/local/src
+
+ wget https://gitlab.com/libxc/libxc/-/archive/6.2.2/libxc-6.2.2.tar.bz2 -O libxc.tar.bz2
+ tar -xf libxc.tar.bz2
+ cd libxc-6.2.2 && autoreconf -i && ./configure --prefix=$HOME/local
+ make
+ make check && make install
+
+Download CONQUEST
+~~~~~~~~~~~~~~~~~~
+
+.. code-block:: bash
+
+ cd ${HOME}/local/src
+ git clone https://github.com/OrderN/CONQUEST-release.git conquest_master
+ cd conquest_master/src
+
+Prepare makefile
+~~~~~~~~~~~~~~~~~~~
+
+.. code-block:: bash
+
+ # Prepare system.make file for Ubuntu.
+ cat > system/system.make << EOF
+
+ # Set compilers
+ FC=mpif90
+
+ # OpenMP flags
+ # Set this to "OMPFLAGS= " if compiling without openmp
+ # Set this to "OMPFLAGS= -fopenmp" if compiling with openmp
+ OMPFLAGS=
+ # Set this to "OMP_DUMMY = DUMMY" if compiling without openmp
+ # Set this to "OMP_DUMMY = " if compiling with openmp
+ OMP_DUMMY = DUMMY
+
+ # Set BLAS and LAPACK libraries
+ # MacOS X
+ # BLAS= -lvecLibFort
+ # Intel MKL use the Intel tool
+ # Generic
+ BLAS= -llapack -lblas
+ # Full scalapack library call; remove -lscalapack if using dummy diag module.
+ # If using OpenMPI, use -lscalapack-openmpi instead.
+ # If using Cray-libsci, use -llibsci_cray_mpi instead.
+ SCALAPACK = -lscalapack-openmpi
+
+ # LibXC compatibility
+ # Choose LibXC version: v4 (deprecated) or v5/6 (v5 and v6 have the same interface)
+ # XC_LIBRARY = LibXC_v4
+ XC_LIBRARY = LibXC_v5
+ XC_LIB = -lxcf90 -lxc
+ XC_COMPFLAGS = -I\${HOME}/local/include -I/usr/local/include
+
+ # Set FFT library
+ FFT_LIB=-lfftw3
+ FFT_OBJ=fft_fftw3.o
+
+ LIBS= \$(FFT_LIB) \$(XC_LIB) \$(SCALAPACK) \$(BLAS)
+
+ # Compilation flags
+ # NB for gcc10 you need to add -fallow-argument-mismatch
+ COMPFLAGS= -O3 \$(OMPFLAGS) \$(XC_COMPFLAGS) -fallow-argument-mismatch
+
+ # Linking flags
+ LINKFLAGS= -L\${HOME}/local/lib -L/usr/local/lib \$(OMPFLAGS)
+
+ # Matrix multiplication kernel type
+ MULT_KERN = default
+ # Use dummy DiagModule or not
+ DIAG_DUMMY =
+
+ EOF
+
+Compile CONQUEST
+~~~~~~~~~~~~~~~
+
+.. code-block:: bash
+
+
+ dos2unix ./makedeps # For Windows Subsystem for Linux (WSL), there may be some incompatibilities thus file conversion is recommended.
+ make # Or make -j`nproc` for parallel compilation using all available cores
Go to :ref:`top `
diff --git a/docs/references.bib b/docs/references.bib
index 9e84da2c0..31c99bee2 100644
--- a/docs/references.bib
+++ b/docs/references.bib
@@ -396,6 +396,18 @@ @article{Perdew1998
Year = {1998},
Bdsk-Url-1 = {https://doi.org/10.1103/PhysRevB.57.14999}}
+@article{Perdew1996hyb,
+ author = {Perdew, John P. and Ernzerhof, Matthias and Burke, Kieron},
+ title = {Rationale for mixing exact exchange with density functional approximations},
+ journal = {J. Chem. Phys.},
+ volume = {105},
+ number = {22},
+ pages = {9982},
+ year = {1996},
+ doi = {10.1063/1.472933},
+ Bdsk-Url-1 = {https://doi.org/10.1063/1.472933},
+}
+
@article{Hammer1999,
Author = {Hammer, B. and Hansen, L. B. and Nørskov, J. K.},
Doi = {10.1103/PhysRevB.59.7413},
diff --git a/pseudo-and-pao/GTH_LDA/Ag_q1/Ag.hgh b/pseudo-and-pao/GTH_LDA/Ag_q1/Ag.hgh
new file mode 100644
index 000000000..75e92b8e1
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ag_q1/Ag.hgh
@@ -0,0 +1,13 @@
+2 3
+Ag 1.00 0.650000 -2.376061 0.000000 0.000000 0.000000
+3
+ 1.012705 0.897931 0.289824 0.007267
+ -0.748323 -0.018764
+ 0.029787
+2
+ 1.235842 0.130081 0.117263
+ -0.277495
+1
+ 1.016159 -0.038842
+1
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ag_q1/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ag_q1/Conquest_ion_input
new file mode 100644
index 000000000..2fdfe0950
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ag_q1/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Ag
+%endblock
+
+%block Ag
+Atom.PseudopotentialFile Ag.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.003
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ag_q11/Ag.hgh b/pseudo-and-pao/GTH_LDA/Ag_q11/Ag.hgh
new file mode 100644
index 000000000..0a97b0a27
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ag_q11/Ag.hgh
@@ -0,0 +1,15 @@
+2 3
+Ag 11.00 0.570000 1.017053 0.000000 0.000000 0.000000
+3
+ 0.498900 2.990284 -1.515264 0.538172
+ 3.912395 -1.389553
+ 2.205847
+2
+ 0.630009 1.813968 -0.551231
+ 1.304450
+2
+ 0.387660 -3.420076 0.449755
+ -1.019949
+2
+4 2 10.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ag_q11/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ag_q11/Conquest_ion_input
new file mode 100644
index 000000000..13581c1fb
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ag_q11/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ag
+%endblock
+
+%block Ag
+Atom.PseudopotentialFile Ag.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.0048
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ag_q19/Ag.hgh b/pseudo-and-pao/GTH_LDA/Ag_q19/Ag.hgh
new file mode 100644
index 000000000..0fa43c7a7
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ag_q19/Ag.hgh
@@ -0,0 +1,16 @@
+2 3
+Ag 19.00 0.400000 26.102135 -5.217344 0.000000 0.000000
+2
+ 0.308145 1.556928 3.688114
+ -4.761335
+2
+ 0.421004 0.245508 -0.890601
+ 1.053773
+2
+ 0.447222 1.870119 -3.093688
+ 3.507912
+4
+4 0 2.0 1
+4 1 6.0 1
+4 2 10.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ag_q19/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ag_q19/Conquest_ion_input
new file mode 100644
index 000000000..5b8b046d5
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ag_q19/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ag
+%endblock
+
+%block Ag
+Atom.PseudopotentialFile Ag.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.03
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Al_q3/Al.hgh b/pseudo-and-pao/GTH_LDA/Al_q3/Al.hgh
new file mode 100644
index 000000000..4a2d98036
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Al_q3/Al.hgh
@@ -0,0 +1,10 @@
+1 3
+Al 3.00 0.450000 -8.491351 0.000000 0.000000 0.000000
+2
+ 0.460104 5.088340 -1.037843
+ 2.679700
+1
+ 0.536744 2.193438
+2
+3 0 2.0 0
+3 1 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Al_q3/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Al_q3/Conquest_ion_input
new file mode 100644
index 000000000..0a24eb318
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Al_q3/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Al
+%endblock
+
+%block Al
+Atom.PseudopotentialFile Al.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ar_q8/Ar.hgh b/pseudo-and-pao/GTH_LDA/Ar_q8/Ar.hgh
new file mode 100644
index 000000000..e8362e331
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ar_q8/Ar.hgh
@@ -0,0 +1,10 @@
+1 3
+Ar 8.00 0.400000 -7.100000 0.000000 0.000000 0.000000
+2
+ 0.317381 10.249487 -2.169845
+ 5.602516
+1
+ 0.351619 4.978801
+2
+3 0 2.0 0
+3 1 6.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ar_q8/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ar_q8/Conquest_ion_input
new file mode 100644
index 000000000..88b19ed48
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ar_q8/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ar
+%endblock
+
+%block Ar
+Atom.PseudopotentialFile Ar.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/As_q5/As.hgh b/pseudo-and-pao/GTH_LDA/As_q5/As.hgh
new file mode 100644
index 000000000..409ee3fcc
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/As_q5/As.hgh
@@ -0,0 +1,14 @@
+2 3
+As 5.00 0.520000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.456400 4.560761 -0.655459 -0.335174
+ 1.692389 0.865415
+ -1.373804
+2
+ 0.550562 1.812247 0.273292
+ -0.646727
+1
+ 0.685283 0.312373
+2
+4 0 2.0 0
+4 1 3.0 0
diff --git a/pseudo-and-pao/GTH_LDA/As_q5/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/As_q5/Conquest_ion_input
new file mode 100644
index 000000000..e481631ab
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/As_q5/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 As
+%endblock
+
+%block As
+Atom.PseudopotentialFile As.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.007
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Au_q1/Au.hgh b/pseudo-and-pao/GTH_LDA/Au_q1/Au.hgh
new file mode 100644
index 000000000..75c38d03f
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Au_q1/Au.hgh
@@ -0,0 +1,12 @@
+1 3
+Au 1.00 0.650000 -1.963712 -1.698123 0.000000 0.000000
+3
+ 0.919308 1.539599 0.181557 -0.193238
+ -0.468779 0.498938
+ -0.792039
+3
+ 1.140351 0.471229 0.210248 -0.062360
+ -0.497538 0.147570
+ -0.209758
+1
+6 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Au_q1/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Au_q1/Conquest_ion_input
new file mode 100644
index 000000000..db39aebe1
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Au_q1/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Au
+%endblock
+
+%block Au
+Atom.PseudopotentialFile Au.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.0018
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Au_q11/Au.hgh b/pseudo-and-pao/GTH_LDA/Au_q11/Au.hgh
new file mode 100644
index 000000000..bb6597a3f
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Au_q11/Au.hgh
@@ -0,0 +1,14 @@
+2 3
+Au 11.00 0.590000 11.604428 0.000000 0.000000 0.000000
+2
+ 0.521180 2.538614 -1.046137
+ 2.701113
+2
+ 0.630613 0.394853 -0.869592
+ 2.057831
+2
+ 0.440706 -4.719070 0.727771
+ -1.650429
+2
+5 2 10.0 0
+6 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Au_q11/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Au_q11/Conquest_ion_input
new file mode 100644
index 000000000..4d6064d83
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Au_q11/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Au
+%endblock
+
+%block Au
+Atom.PseudopotentialFile Au.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.005
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Au_q19/Au.hgh b/pseudo-and-pao/GTH_LDA/Au_q19/Au.hgh
new file mode 100644
index 000000000..df75c7cb6
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Au_q19/Au.hgh
@@ -0,0 +1,17 @@
+2 3
+Au 19.00 0.490000 9.073226 -0.340134 0.000000 0.000000
+3
+ 0.288038 -5.901820 26.425374 -15.508378
+ -59.339390 40.042459
+ -31.782717
+2
+ 0.355867 -7.088587 8.197964
+ -9.699962
+2
+ 0.333862 -8.825723 9.565353
+ -10.846091
+4
+5 0 2.0 1
+5 1 6.0 1
+5 2 10.0 0
+6 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Au_q19/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Au_q19/Conquest_ion_input
new file mode 100644
index 000000000..51dc1a244
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Au_q19/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Au
+%endblock
+
+%block Au
+Atom.PseudopotentialFile Au.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.04
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/B_q3/B.hgh b/pseudo-and-pao/GTH_LDA/B_q3/B.hgh
new file mode 100644
index 000000000..fb9965d33
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/B_q3/B.hgh
@@ -0,0 +1,9 @@
+1 3
+B 3.00 0.433930 -5.578642 0.804251 0.000000 0.000000
+1
+ 0.373843 6.233928
+0
+ 0.360393
+2
+2 0 2.0 0
+2 1 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/B_q3/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/B_q3/Conquest_ion_input
new file mode 100644
index 000000000..bd5b533fa
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/B_q3/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 B
+%endblock
+
+%block B
+Atom.PseudopotentialFile B.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ba_q10/Ba.hgh b/pseudo-and-pao/GTH_LDA/Ba_q10/Ba.hgh
new file mode 100644
index 000000000..e24d8f4ef
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ba_q10/Ba.hgh
@@ -0,0 +1,16 @@
+3 3
+Ba 10.00 0.540000 24.478653 -2.500850 0.000000 0.000000
+2
+ 0.514776 1.046729 0.378475
+ -0.977217
+2
+ 0.375190 -0.202439 -0.287492
+ 0.680331
+1
+ 0.665403 0.378418
+1
+ 0.304920 -18.795208
+3
+5 0 2.0 1
+5 1 6.0 1
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ba_q10/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ba_q10/Conquest_ion_input
new file mode 100644
index 000000000..a8635f5ff
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ba_q10/Conquest_ion_input
@@ -0,0 +1,32 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ba
+%endblock
+
+%block Ba
+Atom.PseudopotentialFile Ba.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.PAO_N_Shells 5
+Atom.BasisBlock BaBlock
+%endblock
+
+# Specify the number of PAOs for each n,l pair and then their radii
+# The radii below are based on default CONQUEST energies for the
+# valence shells
+%block BaBlock
+# n, l, number of zetas
+5 0 1
+5 1 1
+6 0 2
+6 1 1
+5 2 1
+# Radii for PAOs (bohr)
+6.8
+8.5
+11.6 6.2
+11.6
+11.6
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ba_q2/Ba.hgh b/pseudo-and-pao/GTH_LDA/Ba_q2/Ba.hgh
new file mode 100644
index 000000000..34db0de04
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ba_q2/Ba.hgh
@@ -0,0 +1,13 @@
+2 3
+Ba 2.00 1.200000 0.000000 0.000000 0.000000 0.000000
+3
+ 1.016187 0.922593 -0.295700 -0.081357
+ 0.763495 0.210063
+ -0.333465
+2
+ 1.249880 0.447168 -0.063843
+ 0.151081
+1
+ 0.937158 -0.718934
+1
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ba_q2/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ba_q2/Conquest_ion_input
new file mode 100644
index 000000000..31b4130e3
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ba_q2/Conquest_ion_input
@@ -0,0 +1,31 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.SolverStep 0.1
+General.SCFMixing 0.05
+
+%block SpeciesLabels
+1 Ba
+%endblock
+
+%block Ba
+Atom.PseudopotentialFile Ba.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.PAO_N_Shells 3
+Atom.BasisBlock BaBlock
+Atom.Cutoffs ra
+%endblock
+
+# Specify the number of PAOs for each n,l pair and then their radii
+# The radii below are based on default CONQUEST energies for the
+# valence shells
+%block BaBlock
+# n, l, number of zetas
+6 0 2
+6 1 1
+5 2 1
+# Radii for PAOs (bohr)
+12.0 7.6
+12.0
+12.0
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Be_q2/Be.hgh b/pseudo-and-pao/GTH_LDA/Be_q2/Be.hgh
new file mode 100644
index 000000000..53d91fcff
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Be_q2/Be.hgh
@@ -0,0 +1,8 @@
+1 3
+Be 2.00 0.739009 -2.592951 0.354839 0.000000 0.000000
+1
+ 0.528797 3.061666
+1
+ 0.658153 0.092462
+1
+2 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Be_q2/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Be_q2/Conquest_ion_input
new file mode 100644
index 000000000..2e9b10229
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Be_q2/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Be
+%endblock
+
+%block Be
+Atom.PseudopotentialFile Be.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.04
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Be_q4/Be.hgh b/pseudo-and-pao/GTH_LDA/Be_q4/Be.hgh
new file mode 100644
index 000000000..b79f44285
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Be_q4/Be.hgh
@@ -0,0 +1,9 @@
+1 3
+Be 4.00 0.325000 -24.015041 17.204014 -3.326390 0.165419
+0
+0.0 0.0
+0
+0.0 0.0
+2
+1 0 2.0 1
+2 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Be_q4/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Be_q4/Conquest_ion_input
new file mode 100644
index 000000000..e27362c2a
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Be_q4/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Be
+%endblock
+
+%block Be
+Atom.PseudopotentialFile Be.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Bi_q5/Bi.hgh b/pseudo-and-pao/GTH_LDA/Bi_q5/Bi.hgh
new file mode 100644
index 000000000..79231ca87
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Bi_q5/Bi.hgh
@@ -0,0 +1,14 @@
+2 3
+Bi 5.00 0.605000 6.679437 0.000000 0.000000 0.000000
+3
+ 0.678858 1.377634 0.198954 -0.114919
+ -0.513697 0.296720
+ -0.471028
+2
+ 0.798673 0.655578 0.170270
+ -0.402932
+1
+ 0.934683 0.378476
+2
+6 0 2.0 0
+6 1 3.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Bi_q5/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Bi_q5/Conquest_ion_input
new file mode 100644
index 000000000..d9c1a03b9
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Bi_q5/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Bi
+%endblock
+
+%block Bi
+Atom.PseudopotentialFile Bi.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.0020
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Br_q7/Br.hgh b/pseudo-and-pao/GTH_LDA/Br_q7/Br.hgh
new file mode 100644
index 000000000..c7b098b55
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Br_q7/Br.hgh
@@ -0,0 +1,14 @@
+2 3
+Br 7.00 0.500000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.428207 5.398837 -0.704996 -0.323017
+ 1.820292 0.834025
+ -1.323974
+2
+ 0.455323 3.108823 0.267154
+ -0.632202
+1
+ 0.557847 0.555903
+2
+4 0 2.0 0
+4 1 5.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Br_q7/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Br_q7/Conquest_ion_input
new file mode 100644
index 000000000..dce2dac94
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Br_q7/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Br
+%endblock
+
+%block Br
+Atom.PseudopotentialFile Br.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.010
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/C_q4/C.hgh b/pseudo-and-pao/GTH_LDA/C_q4/C.hgh
new file mode 100644
index 000000000..aa251c356
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/C_q4/C.hgh
@@ -0,0 +1,9 @@
+1 3
+C 4.00 0.348830 -8.513771 1.228432 0.000000 0.000000
+1
+ 0.304553 9.522842
+0
+ 0.232677
+2
+2 0 2.0 0
+2 1 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/C_q4/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/C_q4/Conquest_ion_input
new file mode 100644
index 000000000..802796558
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/C_q4/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 C
+%endblock
+
+%block C
+Atom.PseudopotentialFile C.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ca_q10/Ca.hgh b/pseudo-and-pao/GTH_LDA/Ca_q10/Ca.hgh
new file mode 100644
index 000000000..54b651ff1
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ca_q10/Ca.hgh
@@ -0,0 +1,14 @@
+2 3
+Ca 10.00 0.390000 -4.928146 -1.232854 0.000000 0.000000
+2
+ 0.281909 12.352340 -2.965720
+ 7.657455
+2
+ 0.310345 5.722423 -0.390289
+ 0.923591
+1
+ 0.904330 0.016806
+3
+3 0 2.0 1
+3 1 6.0 1
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ca_q10/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ca_q10/Conquest_ion_input
new file mode 100644
index 000000000..d27f08b93
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ca_q10/Conquest_ion_input
@@ -0,0 +1,15 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Ca
+%endblock
+
+%block Ca
+Atom.PseudopotentialFile Ca.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.0100
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ca_q2/Ca.hgh b/pseudo-and-pao/GTH_LDA/Ca_q2/Ca.hgh
new file mode 100644
index 000000000..078ddcb0a
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ca_q2/Ca.hgh
@@ -0,0 +1,13 @@
+2 3
+Ca 2.00 0.800000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.669737 1.645014 -0.590045 0.072216
+ 1.523491 -0.186460
+ 0.295996
+2
+ 0.946474 0.585479 -0.053384
+ 0.126329
+1
+ 0.526550 -3.032321
+1
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ca_q2/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ca_q2/Conquest_ion_input
new file mode 100644
index 000000000..4628a97a2
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ca_q2/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ca
+%endblock
+
+%block Ca
+Atom.PseudopotentialFile Ca.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.02
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Cd_q12/Cd.hgh b/pseudo-and-pao/GTH_LDA/Cd_q12/Cd.hgh
new file mode 100644
index 000000000..8930c49b0
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Cd_q12/Cd.hgh
@@ -0,0 +1,15 @@
+2 3
+Cd 12.00 0.550000 2.382713 0.000000 0.000000 0.000000
+3
+ 0.491505 3.207932 -1.603788 0.386514
+ 4.140963 -0.997974
+ 1.584234
+2
+ 0.598565 1.940150 -0.640581
+ 1.515892
+2
+ 0.377874 -4.190072 0.339607
+ -0.770156
+2
+4 2 10.0 0
+5 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Cd_q12/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Cd_q12/Conquest_ion_input
new file mode 100644
index 000000000..fc675dbe0
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Cd_q12/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Cd
+%endblock
+
+%block Cd
+Atom.PseudopotentialFile Cd.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.003
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Cd_q2/Cd.hgh b/pseudo-and-pao/GTH_LDA/Cd_q2/Cd.hgh
new file mode 100644
index 000000000..02d308661
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Cd_q2/Cd.hgh
@@ -0,0 +1,13 @@
+2 3
+Cd 2.00 0.625000 -1.796838 0.000000 0.000000 0.000000
+3
+ 0.828465 1.485292 0.164506 -0.099538
+ -0.424753 0.257007
+ -0.407986
+2
+ 0.972873 0.469208 0.189361
+ -0.448111
+1
+ 1.240949 0.065412
+1
+5 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Cd_q2/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Cd_q2/Conquest_ion_input
new file mode 100644
index 000000000..e2c3fa037
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Cd_q2/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Cd
+%endblock
+
+%block Cd
+Atom.PseudopotentialFile Cd.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.002
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Cl_q7/Cl.hgh b/pseudo-and-pao/GTH_LDA/Cl_q7/Cl.hgh
new file mode 100644
index 000000000..56e10e2d0
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Cl_q7/Cl.hgh
@@ -0,0 +1,10 @@
+1 3
+Cl 7.00 0.410000 -6.864754 0.000000 0.000000 0.000000
+2
+ 0.338208 9.062240 -1.961930
+ 5.065682
+1
+ 0.376137 4.465876
+2
+3 0 2.0 0
+3 1 5.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Cl_q7/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Cl_q7/Conquest_ion_input
new file mode 100644
index 000000000..bf41a5a07
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Cl_q7/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Cl
+%endblock
+
+%block Cl
+Atom.PseudopotentialFile Cl.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Co_q17/Co.hgh b/pseudo-and-pao/GTH_LDA/Co_q17/Co.hgh
new file mode 100644
index 000000000..00205045c
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Co_q17/Co.hgh
@@ -0,0 +1,15 @@
+2 3
+Co 17.00 0.355000 3.418391 0.482078 0.000000 0.000000
+2
+ 0.259140 11.195226 3.038675
+ -7.845825
+2
+ 0.251425 -0.551464 1.960436
+ -4.639237
+1
+ 0.221665 -12.075354
+4
+3 0 2.0 1
+3 1 6.0 1
+3 2 7.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Co_q17/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Co_q17/Conquest_ion_input
new file mode 100644
index 000000000..322899544
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Co_q17/Conquest_ion_input
@@ -0,0 +1,15 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.SolverStep 0.2
+
+%block SpeciesLabels
+1 Co
+%endblock
+
+%block Co
+Atom.PseudopotentialFile Co.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_large_radius_semicore_hgh 0.0001
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Co_q9/Co.hgh b/pseudo-and-pao/GTH_LDA/Co_q9/Co.hgh
new file mode 100644
index 000000000..87a86b6f4
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Co_q9/Co.hgh
@@ -0,0 +1,14 @@
+2 3
+Co 9.00 0.580000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.440457 3.334978 -1.112766 0.754134
+ 2.873150 -1.947165
+ 3.091028
+2
+ 0.610048 1.634005 -0.150473
+ 0.356083
+1
+ 0.291661 -10.358800
+2
+3 2 7.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Co_q9/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Co_q9/Conquest_ion_input
new file mode 100644
index 000000000..8d9cf9b5b
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Co_q9/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Co
+%endblock
+
+%block Co
+Atom.PseudopotentialFile Co.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.005
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Cr_q14/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Cr_q14/Conquest_ion_input
new file mode 100644
index 000000000..fb5589660
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Cr_q14/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Cr
+%endblock
+
+%block Cr
+Atom.PseudopotentialFile Cr.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_large_radius_semicore_hgh 0.0001
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Cr_q14/Cr.hgh b/pseudo-and-pao/GTH_LDA/Cr_q14/Cr.hgh
new file mode 100644
index 000000000..4c2cee889
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Cr_q14/Cr.hgh
@@ -0,0 +1,15 @@
+2 3
+Cr 14.00 0.370000 5.113362 -0.646819 0.000000 0.000000
+2
+ 0.306011 8.617835 1.602522
+ -4.137695
+2
+ 0.241090 3.161588 2.126791
+ -5.032906
+1
+ 0.219577 -11.157868
+4
+3 0 2.0 1
+3 1 6.0 1
+3 2 5.0 0
+4 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Cr_q6/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Cr_q6/Conquest_ion_input
new file mode 100644
index 000000000..ae757ace1
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Cr_q6/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Cr
+%endblock
+
+%block Cr
+Atom.PseudopotentialFile Cr.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.0055
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Cr_q6/Cr.hgh b/pseudo-and-pao/GTH_LDA/Cr_q6/Cr.hgh
new file mode 100644
index 000000000..0afbd5280
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Cr_q6/Cr.hgh
@@ -0,0 +1,14 @@
+2 3
+Cr 6.00 0.660000 0.000000 0.000000 0.000000 0.000000
+3
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diff --git a/pseudo-and-pao/GTH_LDA/Cs_q1/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Cs_q1/Conquest_ion_input
new file mode 100644
index 000000000..6704c6469
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Cs_q1/Conquest_ion_input
@@ -0,0 +1,16 @@
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diff --git a/pseudo-and-pao/GTH_LDA/Cs_q1/Cs.hgh b/pseudo-and-pao/GTH_LDA/Cs_q1/Cs.hgh
new file mode 100644
index 000000000..770090da6
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Cs_q1/Cs.hgh
@@ -0,0 +1,13 @@
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diff --git a/pseudo-and-pao/GTH_LDA/Cs_q9/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Cs_q9/Conquest_ion_input
new file mode 100644
index 000000000..52eca154f
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Cs_q9/Conquest_ion_input
@@ -0,0 +1,16 @@
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diff --git a/pseudo-and-pao/GTH_LDA/Cs_q9/Cs.hgh b/pseudo-and-pao/GTH_LDA/Cs_q9/Cs.hgh
new file mode 100644
index 000000000..59639e575
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Cs_q9/Cs.hgh
@@ -0,0 +1,16 @@
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diff --git a/pseudo-and-pao/GTH_LDA/Cu_q1/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Cu_q1/Conquest_ion_input
new file mode 100644
index 000000000..80ec1bd8c
--- /dev/null
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diff --git a/pseudo-and-pao/GTH_LDA/Cu_q1/Cu.hgh b/pseudo-and-pao/GTH_LDA/Cu_q1/Cu.hgh
new file mode 100644
index 000000000..cd7fad497
--- /dev/null
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diff --git a/pseudo-and-pao/GTH_LDA/Cu_q11/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Cu_q11/Conquest_ion_input
new file mode 100644
index 000000000..b2035b1d6
--- /dev/null
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diff --git a/pseudo-and-pao/GTH_LDA/Cu_q11/Cu.hgh b/pseudo-and-pao/GTH_LDA/Cu_q11/Cu.hgh
new file mode 100644
index 000000000..2e4ba1441
--- /dev/null
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diff --git a/pseudo-and-pao/GTH_LDA/Cu_q19/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Cu_q19/Conquest_ion_input
new file mode 100644
index 000000000..1bf7a499a
--- /dev/null
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diff --git a/pseudo-and-pao/GTH_LDA/Cu_q19/Cu.hgh b/pseudo-and-pao/GTH_LDA/Cu_q19/Cu.hgh
new file mode 100644
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--- /dev/null
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diff --git a/pseudo-and-pao/GTH_LDA/DO_NOT_USE_Ta_q5/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/DO_NOT_USE_Ta_q5/Conquest_ion_input
new file mode 100644
index 000000000..3b77451eb
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/DO_NOT_USE_Ta_q5/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ta
+%endblock
+
+%block Ta
+Atom.PseudopotentialFile Ta.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.02
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/DO_NOT_USE_Ta_q5/Ta.hgh b/pseudo-and-pao/GTH_LDA/DO_NOT_USE_Ta_q5/Ta.hgh
new file mode 100644
index 000000000..28c47a132
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/DO_NOT_USE_Ta_q5/Ta.hgh
@@ -0,0 +1,14 @@
+2 3
+Ta 5.00 0.744000 3.623116 0.000000 0.000000 0.000000
+2
+ 0.581801 2.005338 -1.172366
+ 3.027036
+2
+ 0.770646 0.518567 -0.500914
+ 1.185378
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+ 0.534370 -2.202200 0.734935
+ -1.666675
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diff --git a/pseudo-and-pao/GTH_LDA/F_q7/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/F_q7/Conquest_ion_input
new file mode 100644
index 000000000..f24856d74
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/F_q7/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
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+
+%block F
+Atom.PseudopotentialFile F.hgh
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diff --git a/pseudo-and-pao/GTH_LDA/F_q7/F.hgh b/pseudo-and-pao/GTH_LDA/F_q7/F.hgh
new file mode 100644
index 000000000..02306a720
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/F_q7/F.hgh
@@ -0,0 +1,9 @@
+1 3
+F 7.00 0.218525 -21.307361 3.072869 0.000000 0.000000
+1
+ 0.195567 23.584942
+0
+ 0.174268
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+2 0 2.0 0
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diff --git a/pseudo-and-pao/GTH_LDA/Fe_q16/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Fe_q16/Conquest_ion_input
new file mode 100644
index 000000000..d04b58980
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Fe_q16/Conquest_ion_input
@@ -0,0 +1,16 @@
+General.NumberOfSpecies 1
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+General.SolverStep 0.2
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+
+%block SpeciesLabels
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+
+%block Fe
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+Atom.ZetaForm com
+Atom.dE_small_radius 0.04
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Fe_q16/Fe.hgh b/pseudo-and-pao/GTH_LDA/Fe_q16/Fe.hgh
new file mode 100644
index 000000000..58c0b9c97
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Fe_q16/Fe.hgh
@@ -0,0 +1,15 @@
+2 3
+Fe 16.00 0.360000 5.392507 -0.030066 0.000000 0.000000
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+ 0.269268 10.193723 2.647177
+ -6.834982
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+ 0.247686 0.145613 2.212172
+ -5.234954
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diff --git a/pseudo-and-pao/GTH_LDA/Fe_q8/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Fe_q8/Conquest_ion_input
new file mode 100644
index 000000000..4784919d2
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Fe_q8/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
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+
+%block Fe
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+Atom.ZetaForm com
+Atom.dE_small_radius 0.004
+Atom.Cutoffs en
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diff --git a/pseudo-and-pao/GTH_LDA/Fe_q8/Fe.hgh b/pseudo-and-pao/GTH_LDA/Fe_q8/Fe.hgh
new file mode 100644
index 000000000..dae2f4fa4
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Fe_q8/Fe.hgh
@@ -0,0 +1,14 @@
+2 3
+Fe 8.00 0.610000 0.000000 0.000000 0.000000 0.000000
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+ 0.454482 3.016640 -1.000406 0.794782
+ 2.583038 -2.052117
+ 3.257635
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+ 0.638903 1.499642 -0.138129
+ 0.326874
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+ 0.308732 -9.145354
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diff --git a/pseudo-and-pao/GTH_LDA/Ga_q13/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ga_q13/Conquest_ion_input
new file mode 100644
index 000000000..a24dbe10f
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ga_q13/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ga
+%endblock
+
+%block Ga
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+Atom.ZetaForm com
+Atom.dE_small_radius 0.04
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+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ga_q13/Ga.hgh b/pseudo-and-pao/GTH_LDA/Ga_q13/Ga.hgh
new file mode 100644
index 000000000..16289eee1
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ga_q13/Ga.hgh
@@ -0,0 +1,15 @@
+2 3
+Ga 13.00 0.490000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.395302 12.457037 -7.085417 1.847127
+ 12.151587 -4.769262
+ 3.785485
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+ 0.580854 1.578986 0.328693
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diff --git a/pseudo-and-pao/GTH_LDA/Ga_q3/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ga_q3/Conquest_ion_input
new file mode 100644
index 000000000..317a4953f
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ga_q3/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
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+General.KBThresh 1e-6
+
+%block SpeciesLabels
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+
+%block Ga
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+Atom.ZetaForm com
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+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ga_q3/Ga.hgh b/pseudo-and-pao/GTH_LDA/Ga_q3/Ga.hgh
new file mode 100644
index 000000000..b6eb4213a
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ga_q3/Ga.hgh
@@ -0,0 +1,14 @@
+2 3
+Ga 3.00 0.560000 0.000000 0.000000 0.000000 0.000000
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+ 0.610791 2.369325 0.096443 -0.134625
+ -0.249015 0.347599
+ -0.551796
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+ 0.704596 0.746305 0.216838
+ -0.513132
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diff --git a/pseudo-and-pao/GTH_LDA/Ge_q4/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ge_q4/Conquest_ion_input
new file mode 100644
index 000000000..58cd86b31
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ge_q4/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
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+
+%block Ge
+Atom.PseudopotentialFile Ge.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.01
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+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ge_q4/Ge.hgh b/pseudo-and-pao/GTH_LDA/Ge_q4/Ge.hgh
new file mode 100644
index 000000000..971befde1
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ge_q4/Ge.hgh
@@ -0,0 +1,14 @@
+2 3
+Ge 4.00 0.540000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.493743 3.826891 -0.426118 -0.327956
+ 1.100231 0.846778
+ -1.344218
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+ 0.601064 1.362518 0.265112
+ -0.627370
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+ 0.788369 0.191205
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diff --git a/pseudo-and-pao/GTH_LDA/H_q1/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/H_q1/Conquest_ion_input
new file mode 100644
index 000000000..ca2dfc10f
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/H_q1/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
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+
+%block SpeciesLabels
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+%endblock
+
+%block H
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diff --git a/pseudo-and-pao/GTH_LDA/H_q1/H.hgh b/pseudo-and-pao/GTH_LDA/H_q1/H.hgh
new file mode 100644
index 000000000..1d98d338e
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/H_q1/H.hgh
@@ -0,0 +1,8 @@
+1 3
+H 1.00 0.200000 -4.180237 0.725075 0.000000 0.000000
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+0.0 0.0
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+1 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/He_q2/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/He_q2/Conquest_ion_input
new file mode 100644
index 000000000..46ecdf000
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/He_q2/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
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+
+%block SpeciesLabels
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+
+%block He
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diff --git a/pseudo-and-pao/GTH_LDA/He_q2/He.hgh b/pseudo-and-pao/GTH_LDA/He_q2/He.hgh
new file mode 100644
index 000000000..ad8651361
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/He_q2/He.hgh
@@ -0,0 +1,8 @@
+1 3
+He 2.00 0.200000 -9.112023 1.698368 0.000000 0.000000
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diff --git a/pseudo-and-pao/GTH_LDA/Hf_q12/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Hf_q12/Conquest_ion_input
new file mode 100644
index 000000000..fdbacaf54
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Hf_q12/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
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+
+%block SpeciesLabels
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+
+%block Hf
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+Atom.ZetaForm com
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+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Hf_q12/Hf.hgh b/pseudo-and-pao/GTH_LDA/Hf_q12/Hf.hgh
new file mode 100644
index 000000000..c5bad05c7
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Hf_q12/Hf.hgh
@@ -0,0 +1,17 @@
+2 3
+Hf 12.00 0.560000 5.134801 0.529191 0.000000 0.000000
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+ 0.422810 2.564442 2.329109 0.270754
+ -6.013732 -0.699083
+ 1.109760
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+ 0.472681 -1.025275 0.791296
+ -1.872548
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+ 0.426388 1.459363 2.329480
+ -5.282764
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diff --git a/pseudo-and-pao/GTH_LDA/Hg_q12/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Hg_q12/Conquest_ion_input
new file mode 100644
index 000000000..98a67a372
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Hg_q12/Conquest_ion_input
@@ -0,0 +1,16 @@
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+
+%block SpeciesLabels
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+
+%block Hg
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+Atom.ZetaForm com
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diff --git a/pseudo-and-pao/GTH_LDA/Hg_q12/Hg.hgh b/pseudo-and-pao/GTH_LDA/Hg_q12/Hg.hgh
new file mode 100644
index 000000000..f9198cf03
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Hg_q12/Hg.hgh
@@ -0,0 +1,14 @@
+2 3
+Hg 12.00 0.570000 2.134572 0.000000 0.000000 0.000000
+2
+ 0.521802 3.293920 -1.805198
+ 4.661001
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+ 0.621648 2.100960 -0.714150
+ 1.689988
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+ 0.401894 -1.669886 1.090607
+ -2.473265
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diff --git a/pseudo-and-pao/GTH_LDA/Hg_q2/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Hg_q2/Conquest_ion_input
new file mode 100644
index 000000000..ee9b0f319
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Hg_q2/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
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+General.KBThresh 1e-6
+
+%block SpeciesLabels
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+
+%block Hg
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+Atom.ZetaForm com
+Atom.dE_small_radius 0.003
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+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Hg_q2/Hg.hgh b/pseudo-and-pao/GTH_LDA/Hg_q2/Hg.hgh
new file mode 100644
index 000000000..9ef46de03
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Hg_q2/Hg.hgh
@@ -0,0 +1,13 @@
+2 3
+Hg 2.00 0.640000 -3.296329 0.000000 0.000000 0.000000
+3
+ 0.812108 1.765041 0.180530 -0.195166
+ -0.466127 0.503915
+ -0.799941
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+ 1.053714 0.474056 0.224733
+ -0.531816
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+ 1.100000 0.120638
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diff --git a/pseudo-and-pao/GTH_LDA/I_q7/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/I_q7/Conquest_ion_input
new file mode 100644
index 000000000..8b0a3ccd9
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/I_q7/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
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+General.KBThresh 1e-6
+
+%block SpeciesLabels
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+
+%block I
+Atom.PseudopotentialFile I.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.005
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/I_q7/I.hgh b/pseudo-and-pao/GTH_LDA/I_q7/I.hgh
new file mode 100644
index 000000000..0025d964c
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/I_q7/I.hgh
@@ -0,0 +1,14 @@
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+ 0.552830 1.338054 0.323336 -0.114043
+ -0.834851 0.294458
+ -0.467438
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+ 0.562251 0.674496 0.244159
+ -0.577787
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+ 0.794325 0.224345
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diff --git a/pseudo-and-pao/GTH_LDA/In_q13/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/In_q13/Conquest_ion_input
new file mode 100644
index 000000000..e4da97f1d
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/In_q13/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
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+
+%block SpeciesLabels
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+%endblock
+
+%block In
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+Atom.ZetaForm com
+Atom.dE_small_radius 0.03
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/In_q13/In.hgh b/pseudo-and-pao/GTH_LDA/In_q13/In.hgh
new file mode 100644
index 000000000..75be420d8
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/In_q13/In.hgh
@@ -0,0 +1,16 @@
+2 3
+In 13.00 0.530000 2.395404 0.000000 0.000000 0.000000
+3
+ 0.474081 3.554411 -1.841269 0.381831
+ 4.754135 -0.985883
+ 1.565040
+2
+ 0.559819 2.223664 -0.860062
+ 2.035278
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+ 0.360488 -4.566414 0.341207
+ -0.773785
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diff --git a/pseudo-and-pao/GTH_LDA/In_q3/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/In_q3/Conquest_ion_input
new file mode 100644
index 000000000..f76aa77f1
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/In_q3/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
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+General.KBThresh 1e-6
+
+%block SpeciesLabels
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+%endblock
+
+%block In
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+Atom.ZetaForm com
+Atom.dE_small_radius 0.003
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/In_q3/In.hgh b/pseudo-and-pao/GTH_LDA/In_q3/In.hgh
new file mode 100644
index 000000000..c7e520171
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/In_q3/In.hgh
@@ -0,0 +1,14 @@
+2 3
+In 3.00 0.610000 2.865777 0.000000 0.000000 0.000000
+3
+ 0.770602 1.256194 0.153856 -0.067905
+ -0.397255 0.175331
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+ -0.380789
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diff --git a/pseudo-and-pao/GTH_LDA/Ir_q17/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ir_q17/Conquest_ion_input
new file mode 100644
index 000000000..864d9d3c6
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ir_q17/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
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+
+%block SpeciesLabels
+1 Ir
+%endblock
+
+%block Ir
+Atom.PseudopotentialFile Ir.hgh
+Atom.ZetaForm com
+#Atom.dE_small_radius 0.04
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ir_q17/Ir.hgh b/pseudo-and-pao/GTH_LDA/Ir_q17/Ir.hgh
new file mode 100644
index 000000000..794eb07ce
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ir_q17/Ir.hgh
@@ -0,0 +1,17 @@
+2 3
+Ir 17.00 0.510000 4.904509 1.313786 0.000000 0.000000
+3
+ 0.404469 3.243278 2.833285 0.721429
+ -7.315509 -1.862721
+ 2.956978
+2
+ 0.411426 -0.380574 1.480880
+ -3.504403
+2
+ 0.376428 0.754315 2.590887
+ -5.875580
+4
+5 0 2.0 1
+5 1 6.0 1
+5 2 7.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ir_q9/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ir_q9/Conquest_ion_input
new file mode 100644
index 000000000..0665584ff
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ir_q9/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ir
+%endblock
+
+%block Ir
+Atom.PseudopotentialFile Ir.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.005
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ir_q9/Ir.hgh b/pseudo-and-pao/GTH_LDA/Ir_q9/Ir.hgh
new file mode 100644
index 000000000..fd4c85665
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ir_q9/Ir.hgh
@@ -0,0 +1,14 @@
+2 3
+Ir 9.00 0.641000 10.720016 0.000000 0.000000 0.000000
+2
+ 0.509960 2.445999 -1.088710
+ 2.811037
+2
+ 0.684971 0.461792 -0.551347
+ 1.304726
+2
+ 0.471745 -4.545484 0.721156
+ -1.635428
+2
+5 2 7.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/K_q1/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/K_q1/Conquest_ion_input
new file mode 100644
index 000000000..6490bbf61
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/K_q1/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 K
+%endblock
+
+%block K
+Atom.PseudopotentialFile K.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.02
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/K_q1/K.hgh b/pseudo-and-pao/GTH_LDA/K_q1/K.hgh
new file mode 100644
index 000000000..a6fd51450
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/K_q1/K.hgh
@@ -0,0 +1,13 @@
+2 3
+K 1.00 0.950000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.955364 0.914612 -0.111368 -0.073247
+ 0.287551 0.189123
+ -0.300224
+2
+ 1.086411 0.315462 -0.028817
+ 0.068194
+1
+ 0.720606 -1.529514
+1
+4 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/K_q9/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/K_q9/Conquest_ion_input
new file mode 100644
index 000000000..dd9d6aa27
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/K_q9/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 K
+%endblock
+
+%block K
+Atom.PseudopotentialFile K.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/K_q9/K.hgh b/pseudo-and-pao/GTH_LDA/K_q9/K.hgh
new file mode 100644
index 000000000..c15426aa5
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/K_q9/K.hgh
@@ -0,0 +1,12 @@
+1 3
+K 9.00 0.400000 -4.989348 -0.756048 0.000000 0.000000
+2
+ 0.294826 11.238705 -2.737339
+ 7.067779
+2
+ 0.322359 5.256702 -0.396777
+ 0.938947
+3
+3 0 2.0 0
+3 1 6.0 0
+4 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Kr_q8/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Kr_q8/Conquest_ion_input
new file mode 100644
index 000000000..77c92269d
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Kr_q8/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Kr
+%endblock
+
+%block Kr
+Atom.PseudopotentialFile Kr.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.015
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Kr_q8/Kr.hgh b/pseudo-and-pao/GTH_LDA/Kr_q8/Kr.hgh
new file mode 100644
index 000000000..a393aeae8
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Kr_q8/Kr.hgh
@@ -0,0 +1,14 @@
+2 3
+Kr 8.00 0.500000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.410759 5.911194 -0.761960 -0.355732
+ 1.967372 0.918497
+ -1.458069
+2
+ 0.430256 3.524357 0.292084
+ -0.691198
+1
+ 0.517120 0.629228
+2
+4 0 2.0 0
+4 1 6.0 0
diff --git a/pseudo-and-pao/GTH_LDA/La_q11/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/La_q11/Conquest_ion_input
new file mode 100644
index 000000000..d575f05d1
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/La_q11/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 La
+%endblock
+
+%block La
+Atom.PseudopotentialFile La.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.04
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/La_q11/La.hgh b/pseudo-and-pao/GTH_LDA/La_q11/La.hgh
new file mode 100644
index 000000000..97c9f3b8d
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/La_q11/La.hgh
@@ -0,0 +1,18 @@
+3 3
+La 11.00 0.535000 19.909308 -1.474830 0.000000 0.000000
+2
+ 0.551775 1.293272 0.434479
+ -1.121819
+3
+ 0.476308 1.172527 0.350236 0.008876
+ -0.828810 -0.021005
+ 0.029857
+1
+ 0.626672 0.328377
+1
+ 0.299310 -18.269439
+4
+5 0 2.0 1
+5 1 6.0 1
+5 2 1.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Li_q1/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Li_q1/Conquest_ion_input
new file mode 100644
index 000000000..9d9baf793
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Li_q1/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Li
+%endblock
+
+%block Li
+Atom.PseudopotentialFile Li.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.01
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Li_q1/Li.hgh b/pseudo-and-pao/GTH_LDA/Li_q1/Li.hgh
new file mode 100644
index 000000000..00973003a
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Li_q1/Li.hgh
@@ -0,0 +1,8 @@
+1 3
+Li 1.00 0.787553 -1.892612 0.286060 0.000000 0.000000
+1
+ 0.666375 1.858811
+1
+ 1.079306 -0.005895
+1
+2 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Li_q3/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Li_q3/Conquest_ion_input
new file mode 100644
index 000000000..0ce1aa72e
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Li_q3/Conquest_ion_input
@@ -0,0 +1,29 @@
+IO.PlotOutput T
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Li
+%endblock
+
+%block Li
+Atom.PseudopotentialFile Li.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs ra
+Atom.PAO_N_Shells 4
+Atom.BasisBlock LiBlock
+%endblock
+
+%block LiBlock
+# n, l, number of zetas
+1 0 1
+2 0 2
+2 1 1
+3 2 1
+# Radii for PAOs (bohr)
+3.0
+10.5 5.5
+10.5
+10.5
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Li_q3/Li.hgh b/pseudo-and-pao/GTH_LDA/Li_q3/Li.hgh
new file mode 100644
index 000000000..2b0101dcb
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Li_q3/Li.hgh
@@ -0,0 +1,11 @@
+2 3
+Li 3.00 0.400000 -14.034868 9.553476 -1.766488 0.084370
+0
+0.0 0.0
+0
+0.0 0.0
+0
+0.0 0.0
+2
+1 0 2.0 1
+2 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Mg_q10/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Mg_q10/Conquest_ion_input
new file mode 100644
index 000000000..a960840dc
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Mg_q10/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Mg
+%endblock
+
+%block Mg
+Atom.PseudopotentialFile Mg.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Mg_q10/Mg.hgh b/pseudo-and-pao/GTH_LDA/Mg_q10/Mg.hgh
new file mode 100644
index 000000000..0ecbf91cc
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Mg_q10/Mg.hgh
@@ -0,0 +1,10 @@
+1 3
+Mg 10.00 0.210950 -19.419008 2.871331 0.000000 0.000000
+1
+ 0.141547 40.316626
+1
+ 0.105469 -10.891113
+3
+2 0 2.0 1
+2 1 6.0 1
+3 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Mg_q2/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Mg_q2/Conquest_ion_input
new file mode 100644
index 000000000..cbcf77b5b
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Mg_q2/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Mg
+%endblock
+
+%block Mg
+Atom.PseudopotentialFile Mg.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Mg_q2/Mg.hgh b/pseudo-and-pao/GTH_LDA/Mg_q2/Mg.hgh
new file mode 100644
index 000000000..b5185d96f
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Mg_q2/Mg.hgh
@@ -0,0 +1,9 @@
+1 3
+Mg 2.00 0.651812 -2.864297 0.000000 0.000000 0.000000
+2
+ 0.556478 2.970957 -0.515084
+ 1.329941
+1
+ 0.677569 1.049881
+1
+3 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Mn_q15/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Mn_q15/Conquest_ion_input
new file mode 100644
index 000000000..a4d2b9bd2
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Mn_q15/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Mn
+%endblock
+
+%block Mn
+Atom.PseudopotentialFile Mn.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Mn_q15/Mn.hgh b/pseudo-and-pao/GTH_LDA/Mn_q15/Mn.hgh
new file mode 100644
index 000000000..ad1993550
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Mn_q15/Mn.hgh
@@ -0,0 +1,15 @@
+2 3
+Mn 15.00 0.365000 6.748683 -0.576569 0.000000 0.000000
+2
+ 0.280753 9.379532 2.159297
+ -5.575280
+2
+ 0.254536 0.371176 1.787103
+ -4.229057
+1
+ 0.221422 -12.115385
+4
+3 0 2.0 1
+3 1 6.0 1
+3 2 5.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Mn_q7/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Mn_q7/Conquest_ion_input
new file mode 100644
index 000000000..cfc360976
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Mn_q7/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Mn
+%endblock
+
+%block Mn
+Atom.PseudopotentialFile Mn.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.002
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Mn_q7/Mn.hgh b/pseudo-and-pao/GTH_LDA/Mn_q7/Mn.hgh
new file mode 100644
index 000000000..b2db4876f
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Mn_q7/Mn.hgh
@@ -0,0 +1,14 @@
+2 3
+Mn 7.00 0.640000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.481246 2.799031 -0.962863 0.625950
+ 2.486101 -1.616195
+ 2.565630
+2
+ 0.669304 1.368776 -0.133857
+ 0.316763
+1
+ 0.327763 -7.995418
+2
+3 2 5.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Mo_q14/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Mo_q14/Conquest_ion_input
new file mode 100644
index 000000000..f10869ac0
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Mo_q14/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Mo
+%endblock
+
+%block Mo
+Atom.PseudopotentialFile Mo.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.03
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Mo_q14/Mo.hgh b/pseudo-and-pao/GTH_LDA/Mo_q14/Mo.hgh
new file mode 100644
index 000000000..19aea8db3
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Mo_q14/Mo.hgh
@@ -0,0 +1,16 @@
+2 3
+Mo 14.00 0.430000 16.237452 1.496536 0.000000 0.000000
+2
+ 0.376255 3.362426 2.048528
+ -5.289276
+2
+ 0.361734 -0.379571 1.718923
+ -4.067713
+2
+ 0.525828 -1.543211 -0.473760
+ 1.074388
+4
+4 0 2.0 1
+4 1 6.0 1
+4 2 5.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Mo_q6/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Mo_q6/Conquest_ion_input
new file mode 100644
index 000000000..2e8d38277
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Mo_q6/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Mo
+%endblock
+
+%block Mo
+Atom.PseudopotentialFile Mo.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.005
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Mo_q6/Mo.hgh b/pseudo-and-pao/GTH_LDA/Mo_q6/Mo.hgh
new file mode 100644
index 000000000..1251c668f
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Mo_q6/Mo.hgh
@@ -0,0 +1,14 @@
+2 3
+Mo 6.00 0.699000 7.995868 0.000000 0.000000 0.000000
+2
+ 0.678126 1.289607 -0.386568
+ 0.998113
+2
+ 0.800771 0.301412 -0.313389
+ 0.741615
+2
+ 0.453384 -2.809708 3.007755
+ -6.820946
+2
+4 2 5.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/N_q5/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/N_q5/Conquest_ion_input
new file mode 100644
index 000000000..616da6124
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/N_q5/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 N
+%endblock
+
+%block N
+Atom.PseudopotentialFile N.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/N_q5/N.hgh b/pseudo-and-pao/GTH_LDA/N_q5/N.hgh
new file mode 100644
index 000000000..7d136e8a5
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/N_q5/N.hgh
@@ -0,0 +1,9 @@
+1 3
+N 5.00 0.289179 -12.234820 1.766407 0.000000 0.000000
+1
+ 0.256605 13.552243
+0
+ 0.270134
+2
+2 0 2.0 0
+2 1 3.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Na_q1/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Na_q1/Conquest_ion_input
new file mode 100644
index 000000000..b56e2ccc6
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Na_q1/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Na
+%endblock
+
+%block Na
+Atom.PseudopotentialFile Na.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.02
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Na_q1/Na.hgh b/pseudo-and-pao/GTH_LDA/Na_q1/Na.hgh
new file mode 100644
index 000000000..24246309a
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Na_q1/Na.hgh
@@ -0,0 +1,9 @@
+1 3
+Na 1.00 0.885509 -1.238867 0.000000 0.000000 0.000000
+2
+ 0.661104 1.847271 -0.225409
+ 0.582004
+1
+ 0.857119 0.471133
+1
+3 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Na_q9/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Na_q9/Conquest_ion_input
new file mode 100644
index 000000000..d7d520f79
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Na_q9/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Na
+%endblock
+
+%block Na
+Atom.PseudopotentialFile Na.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Na_q9/Na.hgh b/pseudo-and-pao/GTH_LDA/Na_q9/Na.hgh
new file mode 100644
index 000000000..c30a34cda
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Na_q9/Na.hgh
@@ -0,0 +1,10 @@
+1 3
+Na 9.00 0.246318 -7.545593 1.125997 0.000000 0.000000
+1
+ 0.141251 36.556987
+1
+ 0.139668 -10.392083
+3
+2 0 2.0 1
+2 1 6.0 1
+3 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Nb_q13/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Nb_q13/Conquest_ion_input
new file mode 100644
index 000000000..1df0a9bce
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Nb_q13/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Nb
+%endblock
+
+%block Nb
+Atom.PseudopotentialFile Nb.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.04
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Nb_q13/Nb.hgh b/pseudo-and-pao/GTH_LDA/Nb_q13/Nb.hgh
new file mode 100644
index 000000000..8fb516531
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Nb_q13/Nb.hgh
@@ -0,0 +1,16 @@
+2 3
+Nb 13.00 0.460000 13.505394 0.752434 0.000000 0.000000
+2
+ 0.393708 3.222025 1.781317
+ -4.599342
+2
+ 0.403626 -0.822037 0.949685
+ -2.247366
+2
+ 0.513644 -1.489848 -0.363269
+ 0.823817
+4
+4 0 2.0 1
+4 1 6.0 1
+4 2 4.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Nb_q5/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Nb_q5/Conquest_ion_input
new file mode 100644
index 000000000..7353dd130
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Nb_q5/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Nb
+%endblock
+
+%block Nb
+Atom.PseudopotentialFile Nb.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.005
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Nb_q5/Nb.hgh b/pseudo-and-pao/GTH_LDA/Nb_q5/Nb.hgh
new file mode 100644
index 000000000..df161fbfa
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Nb_q5/Nb.hgh
@@ -0,0 +1,14 @@
+2 3
+Nb 5.00 0.724000 4.021058 0.000000 0.000000 0.000000
+2
+ 0.699708 1.532651 -0.553164
+ 1.428264
+2
+ 0.846672 0.609675 -0.252189
+ 0.596788
+2
+ 0.516072 -2.696830 0.747410
+ -1.694967
+2
+4 2 4.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ne_q8/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ne_q8/Conquest_ion_input
new file mode 100644
index 000000000..470fd238f
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ne_q8/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ne
+%endblock
+
+%block Ne
+Atom.PseudopotentialFile Ne.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ne_q8/Ne.hgh b/pseudo-and-pao/GTH_LDA/Ne_q8/Ne.hgh
new file mode 100644
index 000000000..0806863df
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ne_q8/Ne.hgh
@@ -0,0 +1,10 @@
+1 3
+Ne 8.00 0.190000 -27.692852 4.005906 0.000000 0.000000
+2
+ 0.179488 28.506098 0.416828
+ -1.076245
+1
+ 0.214913 -0.000090
+2
+2 0 2.0 0
+2 1 6.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ni_q10/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ni_q10/Conquest_ion_input
new file mode 100644
index 000000000..4e71f140a
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ni_q10/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Ni
+%endblock
+
+%block Ni
+Atom.PseudopotentialFile Ni.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.005
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ni_q10/Ni.hgh b/pseudo-and-pao/GTH_LDA/Ni_q10/Ni.hgh
new file mode 100644
index 000000000..c12b87a44
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ni_q10/Ni.hgh
@@ -0,0 +1,14 @@
+2 3
+Ni 10.00 0.560000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.425399 3.619651 -1.196351 0.746222
+ 3.088965 -1.926736
+ 3.058598
+2
+ 0.584081 1.742220 -0.163259
+ 0.386341
+1
+ 0.278113 -11.608428
+2
+3 2 8.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ni_q18/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ni_q18/Conquest_ion_input
new file mode 100644
index 000000000..e98b8e360
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ni_q18/Conquest_ion_input
@@ -0,0 +1,15 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.SolverStep 0.2
+General.SCFMixing 0.2
+
+%block SpeciesLabels
+1 Ni
+%endblock
+
+%block Ni
+Atom.PseudopotentialFile Ni.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ni_q18/Ni.hgh b/pseudo-and-pao/GTH_LDA/Ni_q18/Ni.hgh
new file mode 100644
index 000000000..320ed444b
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ni_q18/Ni.hgh
@@ -0,0 +1,15 @@
+2 3
+Ni 18.00 0.350000 3.610311 0.449638 0.000000 0.000000
+2
+ 0.245105 12.161131 3.516254
+ -9.078929
+2
+ 0.234741 -0.820624 2.547747
+ -6.029071
+1
+ 0.214949 -13.395062
+4
+3 0 2.0 1
+3 1 6.0 1
+3 2 8.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/O_q6/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/O_q6/Conquest_ion_input
new file mode 100644
index 000000000..6ad0f4360
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/O_q6/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 O
+%endblock
+
+%block O
+Atom.PseudopotentialFile O.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/O_q6/O.hgh b/pseudo-and-pao/GTH_LDA/O_q6/O.hgh
new file mode 100644
index 000000000..721cecb14
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/O_q6/O.hgh
@@ -0,0 +1,9 @@
+1 3
+O 6.00 0.247621 -16.580318 2.395701 0.000000 0.000000
+1
+ 0.221786 18.266917
+0
+ 0.256829
+2
+2 0 2.0 0
+2 1 4.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Os_q16/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Os_q16/Conquest_ion_input
new file mode 100644
index 000000000..d4f527317
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Os_q16/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Os
+%endblock
+
+%block Os
+Atom.PseudopotentialFile Os.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Os_q16/Os.hgh b/pseudo-and-pao/GTH_LDA/Os_q16/Os.hgh
new file mode 100644
index 000000000..347e80266
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Os_q16/Os.hgh
@@ -0,0 +1,17 @@
+2 3
+Os 16.00 0.520000 5.613073 0.921955 0.000000 0.000000
+3
+ 0.410578 2.785758 2.591851 0.548220
+ -6.692130 -1.415499
+ 2.247034
+2
+ 0.422395 -0.590005 1.275474
+ -3.018323
+2
+ 0.380252 0.880133 2.527968
+ -5.732892
+4
+5 0 2.0 1
+5 1 6.0 1
+5 2 6.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Os_q8/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Os_q8/Conquest_ion_input
new file mode 100644
index 000000000..1ef9ad2ae
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Os_q8/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Os
+%endblock
+
+%block Os
+Atom.PseudopotentialFile Os.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.008
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Os_q8/Os.hgh b/pseudo-and-pao/GTH_LDA/Os_q8/Os.hgh
new file mode 100644
index 000000000..1addcf54f
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Os_q8/Os.hgh
@@ -0,0 +1,14 @@
+2 3
+Os 8.00 0.667000 9.440459 0.000000 0.000000 0.000000
+2
+ 0.510307 2.402367 -1.179984
+ 3.046706
+2
+ 0.717553 0.499523 -0.445094
+ 1.053284
+2
+ 0.487586 -4.142035 0.734681
+ -1.666100
+2
+5 2 6.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/P_q5/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/P_q5/Conquest_ion_input
new file mode 100644
index 000000000..0ba3f5455
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/P_q5/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 P
+%endblock
+
+%block P
+Atom.PseudopotentialFile P.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/P_q5/P.hgh b/pseudo-and-pao/GTH_LDA/P_q5/P.hgh
new file mode 100644
index 000000000..2b5a60a82
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/P_q5/P.hgh
@@ -0,0 +1,10 @@
+1 3
+P 5.00 0.430000 -6.654220 0.000000 0.000000 0.000000
+2
+ 0.389803 6.842136 -1.493691
+ 3.856693
+1
+ 0.440796 3.282606
+2
+3 0 2.0 0
+3 1 3.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Pb_q4/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Pb_q4/Conquest_ion_input
new file mode 100644
index 000000000..07bb552cb
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Pb_q4/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Pb
+%endblock
+
+%block Pb
+Atom.PseudopotentialFile Pb.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.003
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Pb_q4/Pb.hgh b/pseudo-and-pao/GTH_LDA/Pb_q4/Pb.hgh
new file mode 100644
index 000000000..e1bdee132
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Pb_q4/Pb.hgh
@@ -0,0 +1,14 @@
+2 3
+Pb 4.00 0.617500 0.753143 0.000000 0.000000 0.000000
+3
+ 0.705259 1.979927 0.063889 -0.196659
+ -0.164960 0.507770
+ -0.806060
+2
+ 0.846641 0.864420 0.228601
+ -0.540969
+1
+ 0.971939 0.374967
+2
+6 0 2.0 0
+6 1 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Pd_q10/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Pd_q10/Conquest_ion_input
new file mode 100644
index 000000000..32eade18f
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Pd_q10/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Pd
+%endblock
+
+%block Pd
+Atom.PseudopotentialFile Pd.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.005
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Pd_q10/Pd.hgh b/pseudo-and-pao/GTH_LDA/Pd_q10/Pd.hgh
new file mode 100644
index 000000000..8c23eef16
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Pd_q10/Pd.hgh
@@ -0,0 +1,14 @@
+2 3
+Pd 10.00 0.596000 5.209665 0.000000 0.000000 0.000000
+2
+ 0.582204 2.411076 -0.898114
+ 2.318920
+2
+ 0.688787 1.227253 -0.320322
+ 0.758021
+2
+ 0.442835 -4.377131 -0.182235
+ 0.413271
+2
+4 2 9.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Pd_q18/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Pd_q18/Conquest_ion_input
new file mode 100644
index 000000000..b6fa43000
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Pd_q18/Conquest_ion_input
@@ -0,0 +1,15 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Pd
+%endblock
+
+%block Pd
+Atom.PseudopotentialFile Pd.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.02
+Atom.dE_large_radius_semicore_hgh 0.00003
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Pd_q18/Pd.hgh b/pseudo-and-pao/GTH_LDA/Pd_q18/Pd.hgh
new file mode 100644
index 000000000..db7198403
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Pd_q18/Pd.hgh
@@ -0,0 +1,16 @@
+2 3
+Pd 18.00 0.410000 15.720259 0.140765 0.000000 0.000000
+2
+ 0.342151 5.177686 2.266787
+ -5.852819
+2
+ 0.343111 -0.372561 1.377064
+ -3.258728
+2
+ 0.494916 -1.608273 -0.637895
+ 1.446609
+4
+4 0 2.0 1
+4 1 6.0 1
+4 2 9.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Po_q6/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Po_q6/Conquest_ion_input
new file mode 100644
index 000000000..2fef66405
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Po_q6/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Po
+%endblock
+
+%block Po
+Atom.PseudopotentialFile Po.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.002
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Po_q6/Po.hgh b/pseudo-and-pao/GTH_LDA/Po_q6/Po.hgh
new file mode 100644
index 000000000..2a4ab72cd
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Po_q6/Po.hgh
@@ -0,0 +1,14 @@
+2 3
+Po 6.00 0.592500 10.411731 0.000000 0.000000 0.000000
+3
+ 0.647950 1.144203 0.284994 -0.082802
+ -0.735851 0.213793
+ -0.339386
+2
+ 0.748947 0.594562 0.149421
+ -0.353595
+1
+ 0.880468 0.433232
+2
+6 0 2.0 0
+6 1 4.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Pt_q10/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Pt_q10/Conquest_ion_input
new file mode 100644
index 000000000..39de9a64e
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Pt_q10/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Pt
+%endblock
+
+%block Pt
+Atom.PseudopotentialFile Pt.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.015
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Pt_q10/Pt.hgh b/pseudo-and-pao/GTH_LDA/Pt_q10/Pt.hgh
new file mode 100644
index 000000000..2eac89b29
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Pt_q10/Pt.hgh
@@ -0,0 +1,14 @@
+2 3
+Pt 10.00 0.616000 11.027417 0.000000 0.000000 0.000000
+2
+ 0.520132 2.447430 -1.022607
+ 2.640360
+2
+ 0.658976 0.408453 -0.696287
+ 1.647716
+2
+ 0.451243 -4.552295 0.927069
+ -2.102396
+2
+5 2 9.0 0
+6 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Pt_q18/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Pt_q18/Conquest_ion_input
new file mode 100644
index 000000000..273308265
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Pt_q18/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Pt
+%endblock
+
+%block Pt
+Atom.PseudopotentialFile Pt.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Pt_q18/Pt.hgh b/pseudo-and-pao/GTH_LDA/Pt_q18/Pt.hgh
new file mode 100644
index 000000000..7998d3a7c
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Pt_q18/Pt.hgh
@@ -0,0 +1,17 @@
+2 3
+Pt 18.00 0.500000 5.445832 1.156382 0.000000 0.000000
+3
+ 0.409942 2.994366 2.884897 1.035209
+ -7.448772 -2.672899
+ 4.243095
+2
+ 0.398652 -0.225181 1.596063
+ -3.776974
+2
+ 0.367964 0.632067 2.537907
+ -5.755431
+4
+5 0 2.0 1
+5 1 6.0 1
+5 2 9.0 0
+6 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/README.md b/pseudo-and-pao/GTH_LDA/README.md
new file mode 100644
index 000000000..94092fc36
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/README.md
@@ -0,0 +1,9 @@
+This directory contains GTH/HGH pseudopotentials for the LDA XC functional
+based on the data distributed with CP2K (which in turn tabulates the results in
+Phys. Rev. B 54, 1703 (1996), Phys. Rev. B 58, 3641 (1998) and Theor. Chem. Acc. 114, 145 (2005)
+
+Note that these are not tested by the CONQUEST developers, and should be treated
+with care. In particular, PAO generation is at present in beta phase.
+
+Please note that at present you should not use the Ba_q2 or Ta_q5 directories
+(the PAO solver does not converge for these two configurations).
diff --git a/pseudo-and-pao/GTH_LDA/Rb_q1/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Rb_q1/Conquest_ion_input
new file mode 100644
index 000000000..4ffc175d5
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Rb_q1/Conquest_ion_input
@@ -0,0 +1,32 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.SolverStep 0.02
+
+%block SpeciesLabels
+1 Rb
+%endblock
+
+# NB It is important that the atom cutoffs are based on radii not
+# energies to fit with the specification block
+%block Rb
+Atom.PseudopotentialFile Rb.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.PAO_N_Shells 3
+Atom.BasisBlock RbBlock
+Atom.Cutoffs ra
+%endblock
+
+# Specify the number of PAOs for each n,l pair and then their radii
+# The radii below are based on default CONQUEST energies for the
+# valence shells
+%block RbBlock
+# n, l, number of zetas
+5 0 2
+5 1 1
+4 2 1
+# Radii for PAOs (bohr)
+12.7 8.2
+12.7
+12.7
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Rb_q1/Rb.hgh b/pseudo-and-pao/GTH_LDA/Rb_q1/Rb.hgh
new file mode 100644
index 000000000..61387ca8f
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Rb_q1/Rb.hgh
@@ -0,0 +1,13 @@
+2 3
+Rb 1.00 1.096207 0.847333 -0.748120 0.000000 0.000000
+3
+ 0.955699 0.887460 -0.349765 -0.001647
+ 0.903088 0.004252
+ -0.006750
+2
+ 1.156681 0.461734 -0.142034
+ 0.336113
+1
+ 0.664323 -1.362938
+1
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Rb_q9/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Rb_q9/Conquest_ion_input
new file mode 100644
index 000000000..bfe7ed339
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Rb_q9/Conquest_ion_input
@@ -0,0 +1,36 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+IO.PlotOutput T
+
+%block SpeciesLabels
+1 Rb
+%endblock
+
+# NB It is important that the atom cutoffs are based on radii not
+# energies to fit with the specification block
+%block Rb
+Atom.PseudopotentialFile Rb.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.PAO_N_Shells 5
+Atom.BasisBlock RbBlock
+Atom.Cutoffs ra
+%endblock
+
+# Specify the number of PAOs for each n,l pair and then their radii
+# The radii below are based on default CONQUEST energies for the
+# valence shells
+%block RbBlock
+# n, l, number of zetas
+4 0 1
+4 1 1
+5 0 2
+5 1 1
+4 2 1
+# Radii for PAOs (bohr)
+6.7
+8.6
+12.7 6.4
+12.7
+12.7
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Rb_q9/Rb.hgh b/pseudo-and-pao/GTH_LDA/Rb_q9/Rb.hgh
new file mode 100644
index 000000000..da4256253
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Rb_q9/Rb.hgh
@@ -0,0 +1,14 @@
+2 3
+Rb 9.00 0.490000 4.504151 -0.741018 0.000000 0.000000
+2
+ 0.282301 9.536329 -3.674157
+ 9.486634
+2
+ 0.301886 2.209592 -2.313715
+ 5.475249
+1
+ 0.514895 0.449376
+3
+4 0 2.0 1
+4 1 6.0 1
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Re_q15/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Re_q15/Conquest_ion_input
new file mode 100644
index 000000000..0e27da9e8
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Re_q15/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Re
+%endblock
+
+%block Re
+Atom.PseudopotentialFile Re.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Re_q15/Re.hgh b/pseudo-and-pao/GTH_LDA/Re_q15/Re.hgh
new file mode 100644
index 000000000..ab2b5e9fe
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Re_q15/Re.hgh
@@ -0,0 +1,17 @@
+2 3
+Re 15.00 0.530000 5.592660 0.943957 0.000000 0.000000
+3
+ 0.403252 2.760720 2.477321 0.211949
+ -6.396415 -0.547249
+ 0.868732
+2
+ 0.440951 -0.900546 1.061180
+ -2.511211
+2
+ 0.390395 0.875251 2.501356
+ -5.672543
+4
+5 0 2.0 1
+5 1 6.0 1
+5 2 5.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Re_q7/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Re_q7/Conquest_ion_input
new file mode 100644
index 000000000..4e481945f
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Re_q7/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Re
+%endblock
+
+%block Re
+Atom.PseudopotentialFile Re.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.005
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Re_q7/Re.hgh b/pseudo-and-pao/GTH_LDA/Re_q7/Re.hgh
new file mode 100644
index 000000000..b98ad4408
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Re_q7/Re.hgh
@@ -0,0 +1,14 @@
+2 3
+Re 7.00 0.693000 8.180816 0.000000 0.000000 0.000000
+2
+ 0.509816 2.269379 -1.366594
+ 3.528529
+2
+ 0.745839 0.496693 -0.391234
+ 0.925829
+2
+ 0.500954 -3.689630 0.835441
+ -1.894601
+2
+5 2 5.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Rh_q17/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Rh_q17/Conquest_ion_input
new file mode 100644
index 000000000..9507f9a83
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Rh_q17/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Rh
+%endblock
+
+%block Rh
+Atom.PseudopotentialFile Rh.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.03
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Rh_q17/Rh.hgh b/pseudo-and-pao/GTH_LDA/Rh_q17/Rh.hgh
new file mode 100644
index 000000000..80658fe42
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Rh_q17/Rh.hgh
@@ -0,0 +1,16 @@
+2 3
+Rh 17.00 0.420000 15.225012 0.415911 0.000000 0.000000
+2
+ 0.350052 4.715292 2.248470
+ -5.805525
+2
+ 0.350253 -0.504694 1.425369
+ -3.373040
+2
+ 0.496950 -1.685594 -0.611921
+ 1.387707
+4
+4 0 2.0 1
+4 1 6.0 1
+4 2 8.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Rh_q9/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Rh_q9/Conquest_ion_input
new file mode 100644
index 000000000..990fea004
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Rh_q9/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Rh
+%endblock
+
+%block Rh
+Atom.PseudopotentialFile Rh.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.004
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Rh_q9/Rh.hgh b/pseudo-and-pao/GTH_LDA/Rh_q9/Rh.hgh
new file mode 100644
index 000000000..52a2857bd
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Rh_q9/Rh.hgh
@@ -0,0 +1,14 @@
+2 3
+Rh 9.00 0.621429 5.397962 0.000000 0.000000 0.000000
+2
+ 0.598079 2.242111 -0.833310
+ 2.151597
+2
+ 0.709586 1.155278 -0.297852
+ 0.704846
+2
+ 0.369207 -1.053058 4.817013
+ -10.923960
+2
+4 2 8.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Rn_q8/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Rn_q8/Conquest_ion_input
new file mode 100644
index 000000000..23868d5f6
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Rn_q8/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Rn
+%endblock
+
+%block Rn
+Atom.PseudopotentialFile Rn.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.003
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Rn_q8/Rn.hgh b/pseudo-and-pao/GTH_LDA/Rn_q8/Rn.hgh
new file mode 100644
index 000000000..cf2102490
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Rn_q8/Rn.hgh
@@ -0,0 +1,14 @@
+2 3
+Rn 8.00 0.57000000 14.62918461 0.00000000 0.00000000 0.00000000
+ 3
+ 0.61518195 0.98183224 0.40238854 -0.02938821
+ -1.03896274 0.07588004
+ -0.12045584
+ 2
+ 0.67669721 0.61227859 0.14541822
+ -0.34412231
+ 1
+ 0.78833715 0.55774596
+2
+6 0 2.0 0
+6 1 6.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ru_q16/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ru_q16/Conquest_ion_input
new file mode 100644
index 000000000..7e0603276
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ru_q16/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ru
+%endblock
+
+%block Ru
+Atom.PseudopotentialFile Ru.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.03
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ru_q16/Ru.hgh b/pseudo-and-pao/GTH_LDA/Ru_q16/Ru.hgh
new file mode 100644
index 000000000..ca335fa6c
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ru_q16/Ru.hgh
@@ -0,0 +1,16 @@
+2 3
+Ru 16.00 0.430000 13.582571 0.596227 0.000000 0.000000
+2
+ 0.364084 4.480632 2.040551
+ -5.268679
+2
+ 0.364053 -0.320372 1.292965
+ -3.059714
+2
+ 0.495850 -1.597870 -0.513935
+ 1.165495
+4
+4 0 2.0 1
+4 1 6.0 1
+4 2 7.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ru_q8/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ru_q8/Conquest_ion_input
new file mode 100644
index 000000000..4d4e43bc4
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ru_q8/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ru
+%endblock
+
+%block Ru
+Atom.PseudopotentialFile Ru.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.004
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ru_q8/Ru.hgh b/pseudo-and-pao/GTH_LDA/Ru_q8/Ru.hgh
new file mode 100644
index 000000000..ee7b1501c
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ru_q8/Ru.hgh
@@ -0,0 +1,14 @@
+2 3
+Ru 8.00 0.647214 8.687723 0.000000 0.000000 0.000000
+2
+ 0.625656 1.637866 -0.514849
+ 1.329335
+2
+ 0.746425 0.639012 -0.274834
+ 0.650376
+2
+ 0.440358 -4.883365 1.350985
+ -3.063746
+2
+4 2 7.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/S_q6/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/S_q6/Conquest_ion_input
new file mode 100644
index 000000000..dd5eb751d
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/S_q6/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 S
+%endblock
+
+%block S
+Atom.PseudopotentialFile S.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/S_q6/S.hgh b/pseudo-and-pao/GTH_LDA/S_q6/S.hgh
new file mode 100644
index 000000000..bef8c7bca
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/S_q6/S.hgh
@@ -0,0 +1,10 @@
+1 3
+S 6.00 0.420000 -6.554492 0.000000 0.000000 0.000000
+2
+ 0.361757 7.905303 -1.731881
+ 4.471698
+1
+ 0.405285 3.866579
+2
+3 0 2.0 0
+3 1 4.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Sb_q5/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Sb_q5/Conquest_ion_input
new file mode 100644
index 000000000..931f592d2
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Sb_q5/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Sb
+%endblock
+
+%block Sb
+Atom.PseudopotentialFile Sb.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.005
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Sb_q5/Sb.hgh b/pseudo-and-pao/GTH_LDA/Sb_q5/Sb.hgh
new file mode 100644
index 000000000..9c587c23a
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Sb_q5/Sb.hgh
@@ -0,0 +1,14 @@
+2 3
+Sb 5.00 0.590000 6.680228 0.000000 0.000000 0.000000
+3
+ 0.597684 1.951477 -0.014538 -0.191918
+ 0.037537 0.495531
+ -0.786631
+2
+ 0.672122 0.970313 0.197230
+ -0.466731
+1
+ 0.856557 0.300103
+2
+5 0 2.0 0
+5 1 3.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Sc_q11/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Sc_q11/Conquest_ion_input
new file mode 100644
index 000000000..45d0d4e87
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Sc_q11/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Sc
+%endblock
+
+%block Sc
+Atom.PseudopotentialFile Sc.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Sc_q11/Sc.hgh b/pseudo-and-pao/GTH_LDA/Sc_q11/Sc.hgh
new file mode 100644
index 000000000..1966b709e
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Sc_q11/Sc.hgh
@@ -0,0 +1,15 @@
+2 3
+Sc 11.00 0.385000 7.425036 -0.489852 0.000000 0.000000
+2
+ 0.359707 6.119585 0.992821
+ -2.563453
+2
+ 0.243234 6.376618 2.542399
+ -6.016415
+1
+ 0.252945 -8.020892
+4
+3 0 2.0 1
+3 1 6.0 1
+3 2 1.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Sc_q3/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Sc_q3/Conquest_ion_input
new file mode 100644
index 000000000..d00a1df4c
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Sc_q3/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Sc
+%endblock
+
+%block Sc
+Atom.PseudopotentialFile Sc.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.006
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Sc_q3/Sc.hgh b/pseudo-and-pao/GTH_LDA/Sc_q3/Sc.hgh
new file mode 100644
index 000000000..34ad86dca
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Sc_q3/Sc.hgh
@@ -0,0 +1,14 @@
+2 3
+Sc 3.00 0.750000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.597079 1.835768 -0.671695 0.346074
+ 1.734309 -0.893560
+ 1.418483
+2
+ 0.847994 0.784127 -0.104264
+ 0.246733
+1
+ 0.454653 -3.859241
+2
+3 2 1.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Se_q6/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Se_q6/Conquest_ion_input
new file mode 100644
index 000000000..41170aad9
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Se_q6/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Se
+%endblock
+
+%block Se
+Atom.PseudopotentialFile Se.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.01
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Se_q6/Se.hgh b/pseudo-and-pao/GTH_LDA/Se_q6/Se.hgh
new file mode 100644
index 000000000..250fe56b5
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Se_q6/Se.hgh
@@ -0,0 +1,14 @@
+2 3
+Se 6.00 0.510000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.432531 5.145131 -0.794740 -0.334051
+ 2.052009 0.862517
+ -1.369203
+2
+ 0.472473 2.858806 0.249604
+ -0.590670
+1
+ 0.613420 0.434829
+2
+4 0 2.0 0
+4 1 4.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Si_q4/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Si_q4/Conquest_ion_input
new file mode 100644
index 000000000..35912ade0
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Si_q4/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Si
+%endblock
+
+%block Si
+Atom.PseudopotentialFile Si.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Si_q4/Si.hgh b/pseudo-and-pao/GTH_LDA/Si_q4/Si.hgh
new file mode 100644
index 000000000..dd53a990d
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Si_q4/Si.hgh
@@ -0,0 +1,10 @@
+1 3
+Si 4.00 0.440000 -7.336103 0.000000 0.000000 0.000000
+2
+ 0.422738 5.906928 -1.261894
+ 3.258196
+1
+ 0.484278 2.727013
+2
+3 0 2.0 0
+3 1 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Sn_q4/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Sn_q4/Conquest_ion_input
new file mode 100644
index 000000000..30d7696a2
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Sn_q4/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Sn
+%endblock
+
+%block Sn
+Atom.PseudopotentialFile Sn.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.005
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Sn_q4/Sn.hgh b/pseudo-and-pao/GTH_LDA/Sn_q4/Sn.hgh
new file mode 100644
index 000000000..0bfac7ad4
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Sn_q4/Sn.hgh
@@ -0,0 +1,14 @@
+2 3
+Sn 4.00 0.605000 4.610912 0.000000 0.000000 0.000000
+3
+ 0.663544 1.648791 0.054986 -0.140663
+ -0.141974 0.363190
+ -0.576546
+2
+ 0.745865 0.769355 0.188077
+ -0.445070
+1
+ 0.944459 0.225115
+2
+5 0 2.0 0
+5 1 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Sr_q10/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Sr_q10/Conquest_ion_input
new file mode 100644
index 000000000..936b38ca6
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Sr_q10/Conquest_ion_input
@@ -0,0 +1,35 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Sr
+%endblock
+
+# NB It is important that the atom cutoffs are based on radii not
+# energies to fit with the specification block
+%block Sr
+Atom.PseudopotentialFile Sr.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.PAO_N_Shells 5
+Atom.BasisBlock SrBlock
+Atom.Cutoffs ra
+%endblock
+
+# Specify the number of PAOs for each n,l pair and then their radii
+# The radii below are based on default CONQUEST energies for the
+# valence shells
+%block SrBlock
+# n, l, number of zetas
+4 0 1
+4 1 1
+5 0 2
+5 1 1
+4 2 1
+# Radii for PAOs (bohr)
+6.1
+7.3
+10.8 5.8
+10.8
+10.8
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Sr_q10/Sr.hgh b/pseudo-and-pao/GTH_LDA/Sr_q10/Sr.hgh
new file mode 100644
index 000000000..880b5f337
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Sr_q10/Sr.hgh
@@ -0,0 +1,14 @@
+2 3
+Sr 10.00 0.480000 5.571455 -1.079963 0.000000 0.000000
+2
+ 0.275441 9.995135 -3.616080
+ 9.336679
+2
+ 0.302243 3.169126 -1.711113
+ 4.049231
+1
+ 0.502045 0.438728
+3
+4 0 2.0 1
+4 1 6.0 1
+5 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Sr_q2/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Sr_q2/Conquest_ion_input
new file mode 100644
index 000000000..d33cd63fd
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Sr_q2/Conquest_ion_input
@@ -0,0 +1,32 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Sr
+%endblock
+
+# NB It is important that the atom cutoffs are based on radii not
+# energies to fit with the specification block
+%block Sr
+Atom.PseudopotentialFile Sr.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.PAO_N_Shells 3
+Atom.BasisBlock SrBlock
+Atom.Cutoffs ra
+%endblock
+
+# Specify the number of PAOs for each n,l pair and then their radii
+# The radii below are based on default CONQUEST energies for the
+# valence shells
+%block SrBlock
+# n, l, number of zetas
+5 0 2
+5 1 1
+4 2 1
+# Radii for PAOs (bohr)
+10.9 7.5
+10.9
+10.9
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Sr_q2/Sr.hgh b/pseudo-and-pao/GTH_LDA/Sr_q2/Sr.hgh
new file mode 100644
index 000000000..2a10d0af7
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Sr_q2/Sr.hgh
@@ -0,0 +1,13 @@
+2 3
+Sr 2.00 1.010000 0.684749 -0.062125 0.000000 0.000000
+3
+ 0.837564 1.200395 -0.358900 -0.077061
+ 0.926675 0.198972
+ -0.315858
+2
+ 1.174178 0.439983 -0.007719
+ 0.018267
+1
+ 0.743175 -1.386990
+1
+5 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ta_q13/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ta_q13/Conquest_ion_input
new file mode 100644
index 000000000..a27a767fb
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ta_q13/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ta
+%endblock
+
+%block Ta
+Atom.PseudopotentialFile Ta.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ta_q13/Ta.hgh b/pseudo-and-pao/GTH_LDA/Ta_q13/Ta.hgh
new file mode 100644
index 000000000..9aad991f6
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ta_q13/Ta.hgh
@@ -0,0 +1,17 @@
+2 3
+Ta 13.00 0.550000 4.546236 0.779422 0.000000 0.000000
+3
+ 0.421853 2.708136 2.242829 0.231206
+ -5.790959 -0.596972
+ 0.947663
+2
+ 0.461345 -0.724853 0.936098
+ -2.215211
+2
+ 0.410994 1.348495 2.375420
+ -5.386947
+4
+5 0 2.0 1
+5 1 6.0 1
+5 2 3.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Tc_q15/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Tc_q15/Conquest_ion_input
new file mode 100644
index 000000000..993d11c55
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Tc_q15/Conquest_ion_input
@@ -0,0 +1,15 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Tc
+%endblock
+
+%block Tc
+Atom.PseudopotentialFile Tc.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.04
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Tc_q15/Tc.hgh b/pseudo-and-pao/GTH_LDA/Tc_q15/Tc.hgh
new file mode 100644
index 000000000..5b7926cc1
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Tc_q15/Tc.hgh
@@ -0,0 +1,16 @@
+2 3
+Tc 15.00 0.430000 14.910011 1.046381 0.000000 0.000000
+2
+ 0.369721 3.917408 2.040442
+ -5.268399
+2
+ 0.357772 -0.270000 1.579497
+ -3.737771
+2
+ 0.510487 -1.586709 -0.499301
+ 1.132307
+4
+4 0 2.0 1
+4 1 6.0 1
+4 2 5.0 0
+5 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Tc_q7/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Tc_q7/Conquest_ion_input
new file mode 100644
index 000000000..136303a48
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Tc_q7/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Tc
+%endblock
+
+%block Tc
+Atom.PseudopotentialFile Tc.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.005
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Tc_q7/Tc.hgh b/pseudo-and-pao/GTH_LDA/Tc_q7/Tc.hgh
new file mode 100644
index 000000000..a4fc70b1c
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Tc_q7/Tc.hgh
@@ -0,0 +1,14 @@
+2 3
+Tc 7.00 0.673000 13.315381 0.000000 0.000000 0.000000
+2
+ 0.677612 0.819218 -0.134958
+ 0.348460
+2
+ 0.784275 0.028673 -0.278209
+ 0.658363
+2
+ 0.519890 -5.984224 -0.318294
+ 0.721822
+2
+4 2 5.0 0
+5 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Te_q6/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Te_q6/Conquest_ion_input
new file mode 100644
index 000000000..f4d8c8b5c
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Te_q6/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Te
+%endblock
+
+%block Te
+Atom.PseudopotentialFile Te.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.006
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Te_q6/Te.hgh b/pseudo-and-pao/GTH_LDA/Te_q6/Te.hgh
new file mode 100644
index 000000000..ba719658a
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Te_q6/Te.hgh
@@ -0,0 +1,14 @@
+2 3
+Te 6.00 0.575000 9.387085 0.000000 0.000000 0.000000
+3
+ 0.556456 2.046890 0.011360 -0.214971
+ -0.029333 0.555053
+ -0.881119
+2
+ 0.615262 1.033478 0.203332
+ -0.481172
+1
+ 0.805101 0.317411
+2
+5 0 2.0 0
+5 1 4.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ti_q12/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ti_q12/Conquest_ion_input
new file mode 100644
index 000000000..1acd772e5
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ti_q12/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ti
+%endblock
+
+%block Ti
+Atom.PseudopotentialFile Ti.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ti_q12/Ti.hgh b/pseudo-and-pao/GTH_LDA/Ti_q12/Ti.hgh
new file mode 100644
index 000000000..13bb970b7
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ti_q12/Ti.hgh
@@ -0,0 +1,15 @@
+2 3
+Ti 12.00 0.380000 7.548789 -0.588377 0.000000 0.000000
+2
+ 0.334235 6.925740 1.216893
+ -3.142005
+2
+ 0.242416 5.079086 2.655593
+ -6.284281
+1
+ 0.242948 -9.125896
+4
+3 0 2.0 1
+3 1 6.0 1
+3 2 2.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Ti_q4/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Ti_q4/Conquest_ion_input
new file mode 100644
index 000000000..212de993a
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ti_q4/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Ti
+%endblock
+
+%block Ti
+Atom.PseudopotentialFile Ti.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.005
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Ti_q4/Ti.hgh b/pseudo-and-pao/GTH_LDA/Ti_q4/Ti.hgh
new file mode 100644
index 000000000..a88eaf7f9
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Ti_q4/Ti.hgh
@@ -0,0 +1,14 @@
+2 3
+Ti 4.00 0.720000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.528411 1.866613 -0.557800 0.892503
+ 1.440233 -2.304432
+ 3.658172
+2
+ 0.791146 0.967916 -0.110160
+ 0.260687
+1
+ 0.408712 -4.826456
+2
+3 2 2.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Tl_q13/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Tl_q13/Conquest_ion_input
new file mode 100644
index 000000000..02d7d9dd9
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Tl_q13/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Tl
+%endblock
+
+%block Tl
+Atom.PseudopotentialFile Tl.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Tl_q13/Tl.hgh b/pseudo-and-pao/GTH_LDA/Tl_q13/Tl.hgh
new file mode 100644
index 000000000..6c6192e09
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Tl_q13/Tl.hgh
@@ -0,0 +1,15 @@
+2 3
+Tl 13.00 0.550000 7.301886 0.000000 0.000000 0.000000
+2
+ 0.502423 3.326560 -1.681413
+ 4.341390
+2
+ 0.572016 1.272807 -1.264438
+ 2.992206
+2
+ 0.393185 -3.200652 1.326534
+ -3.008296
+3
+5 2 10.0 1
+6 0 2.0 0
+6 1 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Tl_q3/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Tl_q3/Conquest_ion_input
new file mode 100644
index 000000000..24f410d5d
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Tl_q3/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Tl
+%endblock
+
+%block Tl
+Atom.PseudopotentialFile Tl.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.0025
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Tl_q3/Tl.hgh b/pseudo-and-pao/GTH_LDA/Tl_q3/Tl.hgh
new file mode 100644
index 000000000..6e44e843c
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Tl_q3/Tl.hgh
@@ -0,0 +1,14 @@
+2 3
+Tl 3.00 0.630000 -1.235846 0.000000 0.000000 0.000000
+3
+ 0.754005 1.875766 0.117615 -0.190627
+ -0.303680 0.492196
+ -0.781337
+2
+ 0.903742 0.759668 0.247935
+ -0.586721
+1
+ 1.063512 0.247614
+2
+6 0 2.0 0
+6 1 1.0 0
diff --git a/pseudo-and-pao/GTH_LDA/V_q13/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/V_q13/Conquest_ion_input
new file mode 100644
index 000000000..8dbdf49f4
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/V_q13/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 V
+%endblock
+
+%block V
+Atom.PseudopotentialFile V.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/V_q13/V.hgh b/pseudo-and-pao/GTH_LDA/V_q13/V.hgh
new file mode 100644
index 000000000..861ea4d6d
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/V_q13/V.hgh
@@ -0,0 +1,15 @@
+2 3
+V 13.00 0.375000 4.941291 -0.096443 0.000000 0.000000
+2
+ 0.326651 7.659390 1.507454
+ -3.892229
+2
+ 0.246407 4.256230 2.510620
+ -5.941212
+1
+ 0.240791 -8.828518
+4
+3 0 2.0 1
+3 1 6.0 1
+3 2 3.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/V_q5/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/V_q5/Conquest_ion_input
new file mode 100644
index 000000000..2c7ed7dfa
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/V_q5/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 V
+%endblock
+
+%block V
+Atom.PseudopotentialFile V.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.004
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/V_q5/V.hgh b/pseudo-and-pao/GTH_LDA/V_q5/V.hgh
new file mode 100644
index 000000000..d3a8ebe4b
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/V_q5/V.hgh
@@ -0,0 +1,14 @@
+2 3
+V 5.00 0.690000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.514704 2.208670 -0.734613 0.750559
+ 1.896763 -1.937936
+ 3.076377
+2
+ 0.743504 1.115751 -0.121131
+ 0.286649
+1
+ 0.374890 -5.841633
+2
+3 2 3.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/W_q14/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/W_q14/Conquest_ion_input
new file mode 100644
index 000000000..2df46a986
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/W_q14/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 W
+%endblock
+
+%block W
+Atom.PseudopotentialFile W.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/W_q14/W.hgh b/pseudo-and-pao/GTH_LDA/W_q14/W.hgh
new file mode 100644
index 000000000..ae18e8a49
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/W_q14/W.hgh
@@ -0,0 +1,17 @@
+2 3
+W 14.00 0.540000 4.800251 0.901544 0.000000 0.000000
+3
+ 0.418570 2.692204 2.332557 0.297239
+ -6.022638 -0.767467
+ 1.218316
+2
+ 0.449555 -0.702084 1.036024
+ -2.451680
+2
+ 0.399602 1.177436 2.448917
+ -5.553621
+4
+5 0 2.0 1
+5 1 6.0 1
+5 2 4.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/W_q6/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/W_q6/Conquest_ion_input
new file mode 100644
index 000000000..be3c29cf5
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/W_q6/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 W
+%endblock
+
+%block W
+Atom.PseudopotentialFile W.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.012
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/W_q6/W.hgh b/pseudo-and-pao/GTH_LDA/W_q6/W.hgh
new file mode 100644
index 000000000..640e6b21f
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/W_q6/W.hgh
@@ -0,0 +1,14 @@
+2 3
+W 6.00 0.719000 4.058450 0.000000 0.000000 0.000000
+2
+ 0.582463 2.161166 -1.061778
+ 2.741500
+2
+ 0.742307 0.600973 -0.549326
+ 1.299943
+2
+ 0.534959 -2.517063 0.347977
+ -0.789137
+2
+5 2 4.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Xe_q8/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Xe_q8/Conquest_ion_input
new file mode 100644
index 000000000..4350d750b
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Xe_q8/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Xe
+%endblock
+
+%block Xe
+Atom.PseudopotentialFile Xe.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.006
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Xe_q8/Xe.hgh b/pseudo-and-pao/GTH_LDA/Xe_q8/Xe.hgh
new file mode 100644
index 000000000..8f8563b04
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Xe_q8/Xe.hgh
@@ -0,0 +1,14 @@
+2 3
+Xe 8.00 0.560000 12.734280 0.000000 0.000000 0.000000
+3
+ 0.507371 2.236451 0.156295 -0.276303
+ -0.403551 0.713412
+ -1.132507
+2
+ 0.541024 1.130043 0.318101
+ -0.752764
+1
+ 0.729821 0.280131
+2
+5 0 2.0 0
+5 1 6.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Y_q11/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Y_q11/Conquest_ion_input
new file mode 100644
index 000000000..a5b5923c7
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Y_q11/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Y
+%endblock
+
+%block Y
+Atom.PseudopotentialFile Y.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Y_q11/Y.hgh b/pseudo-and-pao/GTH_LDA/Y_q11/Y.hgh
new file mode 100644
index 000000000..80c535ea5
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Y_q11/Y.hgh
@@ -0,0 +1,16 @@
+2 3
+Y 11.00 0.475000 6.892621 -1.448411 0.000000 0.000000
+2
+ 0.259296 11.068494 -4.058746
+ 10.479636
+2
+ 0.288511 3.019075 -1.809679
+ 4.282482
+2
+ 0.503642 0.339919 -0.007956
+ 0.018043
+4
+4 0 2.0 1
+4 1 6.0 1
+4 2 1.0 0
+5 0 2.0 0
diff --git a/pseudo-and-pao/GTH_LDA/Y_q3/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Y_q3/Conquest_ion_input
new file mode 100644
index 000000000..060229515
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Y_q3/Conquest_ion_input
@@ -0,0 +1,16 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.SCFMixing 0.25
+General.SolverStep 0.02
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Y
+%endblock
+
+%block Y
+Atom.PseudopotentialFile Y.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.010
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_LDA/Y_q3/Y.hgh b/pseudo-and-pao/GTH_LDA/Y_q3/Y.hgh
new file mode 100644
index 000000000..304c058a9
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Y_q3/Y.hgh
@@ -0,0 +1,15 @@
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diff --git a/pseudo-and-pao/GTH_LDA/Zn_q12/Conquest_ion_input b/pseudo-and-pao/GTH_LDA/Zn_q12/Conquest_ion_input
new file mode 100644
index 000000000..37cd33199
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Zn_q12/Conquest_ion_input
@@ -0,0 +1,14 @@
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diff --git a/pseudo-and-pao/GTH_LDA/Zn_q12/Zn.hgh b/pseudo-and-pao/GTH_LDA/Zn_q12/Zn.hgh
new file mode 100644
index 000000000..3ebb613ce
--- /dev/null
+++ b/pseudo-and-pao/GTH_LDA/Zn_q12/Zn.hgh
@@ -0,0 +1,14 @@
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new file mode 100644
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--- /dev/null
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diff --git a/pseudo-and-pao/GTH_LDA/Zn_q2/Zn.hgh b/pseudo-and-pao/GTH_LDA/Zn_q2/Zn.hgh
new file mode 100644
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--- /dev/null
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new file mode 100644
index 000000000..2bf94a613
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index 000000000..a8b89d753
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ag_q19/Conquest_ion_input
@@ -0,0 +1,15 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.SolverMaxIters 300
+
+%block SpeciesLabels
+1 Ag
+%endblock
+
+%block Ag
+Atom.PseudopotentialFile Ag.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.02
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Al_q3/Al.hgh b/pseudo-and-pao/GTH_PBE/Al_q3/Al.hgh
new file mode 100644
index 000000000..10f0e59a7
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Al_q3/Al.hgh
@@ -0,0 +1,10 @@
+1 4
+Al 3.00 0.450000 -7.554761 0.000000 0.000000 0.000000
+2
+ 0.487435 6.959938 -1.888836
+ 2.438477
+1
+ 0.562189 1.865299
+2
+3 0 2.0 0
+3 1 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Al_q3/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Al_q3/Conquest_ion_input
new file mode 100644
index 000000000..0a24eb318
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Al_q3/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Al
+%endblock
+
+%block Al
+Atom.PseudopotentialFile Al.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Ar_q8/Ar.hgh b/pseudo-and-pao/GTH_PBE/Ar_q8/Ar.hgh
new file mode 100644
index 000000000..20e016996
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ar_q8/Ar.hgh
@@ -0,0 +1,10 @@
+1 4
+Ar 8.00 0.400000 -7.100000 0.000000 0.000000 0.000000
+2
+ 0.318815 17.252038 -5.585488
+ 7.210834
+1
+ 0.353370 4.974216
+2
+3 0 2.0 0
+3 1 6.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Ar_q8/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Ar_q8/Conquest_ion_input
new file mode 100644
index 000000000..88b19ed48
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ar_q8/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ar
+%endblock
+
+%block Ar
+Atom.PseudopotentialFile Ar.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/As_q5/As.hgh b/pseudo-and-pao/GTH_PBE/As_q5/As.hgh
new file mode 100644
index 000000000..ef83fad0e
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/As_q5/As.hgh
@@ -0,0 +1,14 @@
+2 4
+As 5.00 0.520000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.455550 5.520673 0.035122 -1.061082
+ -1.771193 2.739703
+ -2.174572
+2
+ 0.554606 1.021792 0.629208
+ -0.744489
+1
+ 0.703689 0.314795
+2
+4 0 2.0 0
+4 1 3.0 0
diff --git a/pseudo-and-pao/GTH_PBE/As_q5/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/As_q5/Conquest_ion_input
new file mode 100644
index 000000000..cbd5f53e7
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/As_q5/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 As
+%endblock
+
+%block As
+Atom.PseudopotentialFile As.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.015
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Au_q11/Au.hgh b/pseudo-and-pao/GTH_PBE/Au_q11/Au.hgh
new file mode 100644
index 000000000..40736e9d0
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Au_q11/Au.hgh
@@ -0,0 +1,14 @@
+2 4
+Au 11.00 0.590000 10.517179 0.000000 0.000000 0.000000
+2
+ 0.543847 5.786811 -2.250680
+ 2.905615
+2
+ 0.609173 4.284049 -4.071285
+ 4.817210
+2
+ 0.437309 -7.403281 3.010193
+ -3.413238
+2
+5 2 10.0 0
+6 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Au_q11/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Au_q11/Conquest_ion_input
new file mode 100644
index 000000000..1db89df72
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Au_q11/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Au
+%endblock
+
+%block Au
+Atom.PseudopotentialFile Au.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.010
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Au_q19/Au.hgh b/pseudo-and-pao/GTH_PBE/Au_q19/Au.hgh
new file mode 100644
index 000000000..648c34ab1
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Au_q19/Au.hgh
@@ -0,0 +1,18 @@
+2 4
+Au 19.00 0.490000 8.369459 0.000000 0.000000 0.000000
+3
+ 0.290084 -5.988690 26.105021 -15.176219
+ -58.385560 39.184830
+ -31.101995
+3
+ 0.361506 -5.876953 4.731446 2.927105
+ -0.725139 -6.926795
+ 4.922910
+2
+ 0.340373 -8.804584 9.491915
+ -10.762820
+4
+5 0 2.0 1
+5 1 6.0 1
+5 2 10.0 0
+6 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Au_q19/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Au_q19/Conquest_ion_input
new file mode 100644
index 000000000..cc5be8b0e
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Au_q19/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Au
+%endblock
+
+%block Au
+Atom.PseudopotentialFile Au.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/B_q3/B.hgh b/pseudo-and-pao/GTH_PBE/B_q3/B.hgh
new file mode 100644
index 000000000..bca0bbf29
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/B_q3/B.hgh
@@ -0,0 +1,9 @@
+1 4
+B 3.00 0.418991 -5.859462 0.903756 0.000000 0.000000
+1
+ 0.371320 6.297280
+0
+ 0.364563
+2
+2 0 2.0 0
+2 1 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/B_q3/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/B_q3/Conquest_ion_input
new file mode 100644
index 000000000..bd5b533fa
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/B_q3/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 B
+%endblock
+
+%block B
+Atom.PseudopotentialFile B.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Ba_q10/Ba.hgh b/pseudo-and-pao/GTH_PBE/Ba_q10/Ba.hgh
new file mode 100644
index 000000000..b6673e5d0
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ba_q10/Ba.hgh
@@ -0,0 +1,16 @@
+3 4
+Ba 10.00 0.540000 24.526781 -2.468670 0.000000 0.000000
+2
+ 0.492068 0.095151 1.169318
+ -1.509584
+2
+ 0.391489 0.800183 -1.616839
+ 1.913070
+1
+ 0.672173 0.388531
+1
+ 0.300498 -19.653795
+3
+5 0 2.0 1
+5 1 6.0 1
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Ba_q10/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Ba_q10/Conquest_ion_input
new file mode 100644
index 000000000..9bb681422
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ba_q10/Conquest_ion_input
@@ -0,0 +1,33 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ba
+%endblock
+
+%block Ba
+Atom.PseudopotentialFile Ba.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.PAO_N_Shells 5
+Atom.BasisBlock BaBlock
+Atom.Cutoffs ra
+%endblock
+
+# Specify the number of PAOs for each n,l pair and then their radii
+# The radii below are based on default CONQUEST energies for the
+# valence shells
+%block BaBlock
+# n, l, number of zetas
+5 0 1
+5 1 1
+6 0 2
+6 1 1
+5 2 1
+# Radii for PAOs (bohr)
+6.8
+8.5
+11.7 6.2
+11.7
+11.7
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Be_q4/Be.hgh b/pseudo-and-pao/GTH_PBE/Be_q4/Be.hgh
new file mode 100644
index 000000000..ef94ee069
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Be_q4/Be.hgh
@@ -0,0 +1,9 @@
+1 4
+Be 4.00 0.325000 -24.067467 17.279022 -3.339106 0.165549
+0
+0.0 0.0
+0
+0.0 0.0
+2
+1 0 2.0 1
+2 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Be_q4/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Be_q4/Conquest_ion_input
new file mode 100644
index 000000000..e27362c2a
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Be_q4/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Be
+%endblock
+
+%block Be
+Atom.PseudopotentialFile Be.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Bi_q15/Bi.hgh b/pseudo-and-pao/GTH_PBE/Bi_q15/Bi.hgh
new file mode 100644
index 000000000..eaecf3a86
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Bi_q15/Bi.hgh
@@ -0,0 +1,15 @@
+2 4
+Bi 15.00 0.510000 13.396222 0.000000 0.000000 0.000000
+2
+ 0.481204 9.545481 -3.945114
+ 5.093121
+2
+ 0.548946 5.633594 -3.177138
+ 3.759240
+2
+ 0.397303 -6.037537 0.925236
+ -1.049118
+3
+5 2 10.0 1
+6 0 2.0 0
+6 1 3.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Bi_q15/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Bi_q15/Conquest_ion_input
new file mode 100644
index 000000000..e24690cd2
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Bi_q15/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Bi
+%endblock
+
+%block Bi
+Atom.PseudopotentialFile Bi.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Bi_q5/Bi.hgh b/pseudo-and-pao/GTH_PBE/Bi_q5/Bi.hgh
new file mode 100644
index 000000000..74bf99648
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Bi_q5/Bi.hgh
@@ -0,0 +1,14 @@
+2 4
+Bi 5.00 0.605000 7.945757 0.000000 0.000000 0.000000
+3
+ 0.582232 0.643735 2.247616 -1.440601
+ -5.244797 3.719615
+ -2.952353
+2
+ 0.766394 0.212533 0.379834
+ -0.449426
+1
+ 0.965655 0.347298
+2
+6 0 2.0 0
+6 1 3.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Bi_q5/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Bi_q5/Conquest_ion_input
new file mode 100644
index 000000000..092496798
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Bi_q5/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-5
+
+%block SpeciesLabels
+1 Bi
+%endblock
+
+%block Bi
+Atom.PseudopotentialFile Bi.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.004
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Br_q7/Br.hgh b/pseudo-and-pao/GTH_PBE/Br_q7/Br.hgh
new file mode 100644
index 000000000..d0dac2c9c
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Br_q7/Br.hgh
@@ -0,0 +1,14 @@
+2 4
+Br 7.00 0.500000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.438039 6.078556 0.330498 -1.238382
+ -2.440900 3.197489
+ -2.537928
+2
+ 0.453136 2.459304 0.522753
+ -0.618530
+1
+ 0.567714 0.559266
+2
+4 0 2.0 0
+4 1 5.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Br_q7/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Br_q7/Conquest_ion_input
new file mode 100644
index 000000000..0bb3987c6
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Br_q7/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Br
+%endblock
+
+%block Br
+Atom.PseudopotentialFile Br.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.020
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/C_q4/C.hgh b/pseudo-and-pao/GTH_PBE/C_q4/C.hgh
new file mode 100644
index 000000000..747ff5740
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/C_q4/C.hgh
@@ -0,0 +1,9 @@
+1 4
+C 4.00 0.338471 -8.803674 1.339211 0.000000 0.000000
+1
+ 0.302576 9.622487
+0
+ 0.291507
+2
+2 0 2.0 0
+2 1 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/C_q4/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/C_q4/Conquest_ion_input
new file mode 100644
index 000000000..802796558
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/C_q4/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 C
+%endblock
+
+%block C
+Atom.PseudopotentialFile C.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Ca_q10/Ca.hgh b/pseudo-and-pao/GTH_PBE/Ca_q10/Ca.hgh
new file mode 100644
index 000000000..385f2de7d
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ca_q10/Ca.hgh
@@ -0,0 +1,14 @@
+2 4
+Ca 10.00 0.390000 -4.167072 -1.583798 0.000000 0.000000
+2
+ 0.289356 20.531876 -7.129786
+ 9.204514
+2
+ 0.327882 5.805605 -0.428753
+ 0.507308
+1
+ 0.679617 0.058068
+3
+3 0 2.0 1
+3 1 6.0 1
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Ca_q10/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Ca_q10/Conquest_ion_input
new file mode 100644
index 000000000..a8d377cdf
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ca_q10/Conquest_ion_input
@@ -0,0 +1,33 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ca
+%endblock
+
+%block Ca
+Atom.PseudopotentialFile Ca.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.PAO_N_Shells 5
+Atom.BasisBlock CaBlock
+Atom.Cutoffs ra
+%endblock
+
+# Specify the number of PAOs for each n,l pair and then their radii
+# The radii below are based on default CONQUEST energies for the
+# valence shells
+%block CaBlock
+# n, l, number of zetas
+3 0 1
+3 1 1
+4 0 2
+4 1 1
+4 2 1
+# Radii for PAOs (bohr)
+5.57
+6.70
+10.49 5.53
+10.49
+10.49
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Cd_q12/Cd.hgh b/pseudo-and-pao/GTH_PBE/Cd_q12/Cd.hgh
new file mode 100644
index 000000000..695a16ca8
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Cd_q12/Cd.hgh
@@ -0,0 +1,15 @@
+2 4
+Cd 12.00 0.550000 3.633959 0.000000 0.000000 0.000000
+3
+ 0.491279 10.111382 -6.506954 1.804577
+ 11.335586 -4.659397
+ 3.698282
+2
+ 0.599710 4.001487 -1.883936
+ 2.229103
+2
+ 0.377873 -6.137032 1.535711
+ -1.741332
+2
+4 2 10.0 0
+5 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Cd_q12/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Cd_q12/Conquest_ion_input
new file mode 100644
index 000000000..6c94232a6
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Cd_q12/Conquest_ion_input
@@ -0,0 +1,18 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Cd
+%endblock
+
+# We have made the equal energy shift cutoff radius approach
+# the default here, as the equal radius approach leaves the
+# d orbitals almost entirely identical
+%block Cd
+Atom.PseudopotentialFile Cd.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.007
+Atom.Cutoffs en
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Cl_q7/Cl.hgh b/pseudo-and-pao/GTH_PBE/Cl_q7/Cl.hgh
new file mode 100644
index 000000000..1abc4c84c
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Cl_q7/Cl.hgh
@@ -0,0 +1,10 @@
+1 4
+Cl 7.00 0.410000 -6.392082 0.000000 0.000000 0.000000
+2
+ 0.339539 15.218990 -4.934523
+ 6.370442
+1
+ 0.378474 4.338775
+2
+3 0 2.0 0
+3 1 5.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Cl_q7/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Cl_q7/Conquest_ion_input
new file mode 100644
index 000000000..bf41a5a07
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Cl_q7/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Cl
+%endblock
+
+%block Cl
+Atom.PseudopotentialFile Cl.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Co_q17/Co.hgh b/pseudo-and-pao/GTH_PBE/Co_q17/Co.hgh
new file mode 100644
index 000000000..7e5e0f443
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Co_q17/Co.hgh
@@ -0,0 +1,15 @@
+2 4
+Co 17.00 0.355000 4.828197 0.368143 0.000000 0.000000
+2
+ 0.276801 -0.584496 9.286293
+ -11.988552
+2
+ 0.268158 -6.851953 5.680133
+ -6.720824
+1
+ 0.222584 -12.333150
+4
+3 0 2.0 1
+3 1 6.0 1
+3 2 7.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Co_q17/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Co_q17/Conquest_ion_input
new file mode 100644
index 000000000..22316c3a8
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Co_q17/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.SolverStep 0.2
+
+%block SpeciesLabels
+1 Co
+%endblock
+
+%block Co
+Atom.PseudopotentialFile Co.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Cr_q14/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Cr_q14/Conquest_ion_input
new file mode 100644
index 000000000..fbf366013
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Cr_q14/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Cr
+%endblock
+
+%block Cr
+Atom.PseudopotentialFile Cr.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Cr_q14/Cr.hgh b/pseudo-and-pao/GTH_PBE/Cr_q14/Cr.hgh
new file mode 100644
index 000000000..f98870c12
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Cr_q14/Cr.hgh
@@ -0,0 +1,15 @@
+2 4
+Cr 14.00 0.370000 5.699658 -0.695486 0.000000 0.000000
+2
+ 0.313934 2.869955 4.974456
+ -6.421996
+2
+ 0.240866 -4.476209 7.331414
+ -8.674646
+1
+ 0.220286 -11.197116
+4
+3 0 2.0 1
+3 1 6.0 1
+3 2 5.0 0
+4 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Cs_q9/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Cs_q9/Conquest_ion_input
new file mode 100644
index 000000000..bbb0c8f2b
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Cs_q9/Conquest_ion_input
@@ -0,0 +1,39 @@
+# The basis set created by this file should be fairly reliable,
+# and we recommend using it, or adapting it to make larger basis
+# sets by changing the number of zeta functions and their radii
+# in the BasisBlock below. At present it is a DZP size basis
+# (though there are two types of polarisation orbital, l=1 and l=2)
+
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Cs
+%endblock
+
+%block Cs
+Atom.PseudopotentialFile Cs.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.PAO_N_Shells 5
+Atom.BasisBlock CsBlock
+Atom.Cutoffs ra
+%endblock
+
+# Specify the number of PAOs for each n,l pair and then their radii
+# The radii below are based on default CONQUEST energies for the
+# valence shells
+%block CsBlock
+# n, l, number of zetas
+5 0 1
+5 1 1
+6 0 2
+6 1 1
+5 2 1
+# Radii for PAOs (bohr)
+7.4
+9.6
+13.7 6.8
+13.7
+13.7
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Cs_q9/Cs.hgh b/pseudo-and-pao/GTH_PBE/Cs_q9/Cs.hgh
new file mode 100644
index 000000000..4d65e0e9b
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Cs_q9/Cs.hgh
@@ -0,0 +1,16 @@
+3 4
+Cs 9.00 0.540000 33.313317 -2.921217 0.000000 0.000000
+2
+ 0.461896 -3.322927 2.455653
+ -3.170235
+2
+ 0.366359 -4.950764 0.840390
+ -0.994363
+1
+ 0.761502 0.198407
+1
+ 0.597015 -1.550567
+3
+5 0 2.0 1
+5 1 6.0 1
+6 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Cu_q11/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Cu_q11/Conquest_ion_input
new file mode 100644
index 000000000..6ba6f90d3
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Cu_q11/Conquest_ion_input
@@ -0,0 +1,17 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Cu
+%endblock
+
+# We have made the equal energy shift cutoff radius approach
+# the default here, as the equal radius approach leaves the
+# d orbitals almost entirely identical
+%block Cu
+Atom.PseudopotentialFile Cu.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.010
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Cu_q11/Cu.hgh b/pseudo-and-pao/GTH_PBE/Cu_q11/Cu.hgh
new file mode 100644
index 000000000..d057fed0f
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Cu_q11/Cu.hgh
@@ -0,0 +1,14 @@
+2 4
+Cu 11.00 0.530000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.431355 9.693805 -6.470165 1.935952
+ 11.501774 -4.998607
+ 3.967521
+2
+ 0.561392 2.545473 -0.784636
+ 0.928394
+1
+ 0.264555 -12.828614
+2
+3 2 10.0 0
+4 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Cu_q19/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Cu_q19/Conquest_ion_input
new file mode 100644
index 000000000..1bf7a499a
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Cu_q19/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.SCFMixing 0.2
+
+%block SpeciesLabels
+1 Cu
+%endblock
+
+%block Cu
+Atom.PseudopotentialFile Cu.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Cu_q19/Cu.hgh b/pseudo-and-pao/GTH_PBE/Cu_q19/Cu.hgh
new file mode 100644
index 000000000..e276ca153
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Cu_q19/Cu.hgh
@@ -0,0 +1,15 @@
+2 4
+Cu 19.00 0.345000 0.051970 1.249043 0.000000 0.000000
+2
+ 0.250028 0.750193 10.735821
+ -13.859886
+2
+ 0.222025 -13.059599 14.747638
+ -17.449641
+1
+ 0.215568 -12.456724
+4
+3 0 2.0 1
+3 1 6.0 1
+3 2 10.0 0
+4 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Cu_q19/charge.dat b/pseudo-and-pao/GTH_PBE/Cu_q19/charge.dat
new file mode 100644
index 000000000..e7784210c
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Cu_q19/charge.dat
@@ -0,0 +1,1238 @@
+ 1.7241379310344828E-005 8.3520545899004678E-002
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diff --git a/pseudo-and-pao/GTH_PBE/F_q7/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/F_q7/Conquest_ion_input
new file mode 100644
index 000000000..f24856d74
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/F_q7/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 F
+%endblock
+
+%block F
+Atom.PseudopotentialFile F.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/F_q7/F.hgh b/pseudo-and-pao/GTH_PBE/F_q7/F.hgh
new file mode 100644
index 000000000..65e8ebce1
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/F_q7/F.hgh
@@ -0,0 +1,9 @@
+1 4
+F 7.00 0.214930 -21.573028 3.199776 0.000000 0.000000
+1
+ 0.194684 23.743540
+0
+ 0.186156
+2
+2 0 2.0 0
+2 1 5.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Fe_q16/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Fe_q16/Conquest_ion_input
new file mode 100644
index 000000000..d04b58980
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Fe_q16/Conquest_ion_input
@@ -0,0 +1,16 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.SolverStep 0.2
+General.SCFMixing 0.2
+
+%block SpeciesLabels
+1 Fe
+%endblock
+
+%block Fe
+Atom.PseudopotentialFile Fe.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.04
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Fe_q16/Fe.hgh b/pseudo-and-pao/GTH_PBE/Fe_q16/Fe.hgh
new file mode 100644
index 000000000..91e346dcd
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Fe_q16/Fe.hgh
@@ -0,0 +1,15 @@
+2 4
+Fe 16.00 0.360000 6.756789 -0.228833 0.000000 0.000000
+2
+ 0.278263 0.629506 7.913132
+ -10.215810
+2
+ 0.251383 -7.932133 7.697079
+ -9.107307
+1
+ 0.222856 -12.385799
+4
+3 0 2.0 1
+3 1 6.0 1
+3 2 6.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Ga_q13/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Ga_q13/Conquest_ion_input
new file mode 100644
index 000000000..f88f6a1c1
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ga_q13/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ga
+%endblock
+
+%block Ga
+Atom.PseudopotentialFile Ga.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.06
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Ga_q13/Ga.hgh b/pseudo-and-pao/GTH_PBE/Ga_q13/Ga.hgh
new file mode 100644
index 000000000..d94181b77
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ga_q13/Ga.hgh
@@ -0,0 +1,15 @@
+2 4
+Ga 13.00 0.490000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.416777 10.475690 -4.921768 0.870706
+ 7.770178 -2.248152
+ 1.784415
+2
+ 0.569627 1.777985 0.195860
+ -0.231744
+1
+ 0.238126 -16.248680
+3
+3 2 10.0 1
+4 0 2.0 0
+4 1 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Ga_q3/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Ga_q3/Conquest_ion_input
new file mode 100644
index 000000000..197d1c155
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ga_q3/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Ga
+%endblock
+
+%block Ga
+Atom.PseudopotentialFile Ga.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.0035
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Ga_q3/Ga.hgh b/pseudo-and-pao/GTH_PBE/Ga_q3/Ga.hgh
new file mode 100644
index 000000000..01313e28b
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ga_q3/Ga.hgh
@@ -0,0 +1,14 @@
+2 4
+Ga 3.00 0.560000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.565866 2.215751 1.032448 -0.760629
+ -2.570048 1.963937
+ -1.558827
+2
+ 0.646716 0.311224 0.613416
+ -0.725804
+1
+ 0.999425 0.089520
+2
+4 0 2.0 0
+4 1 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Ge_q4/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Ge_q4/Conquest_ion_input
new file mode 100644
index 000000000..41696a86b
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ge_q4/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Ge
+%endblock
+
+%block Ge
+Atom.PseudopotentialFile Ge.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.006
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Ge_q4/Ge.hgh b/pseudo-and-pao/GTH_PBE/Ge_q4/Ge.hgh
new file mode 100644
index 000000000..3dad23419
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ge_q4/Ge.hgh
@@ -0,0 +1,14 @@
+2 4
+Ge 4.00 0.540000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.421865 7.510241 -0.588108 -1.447976
+ -1.595888 3.738657
+ -2.967467
+2
+ 0.567529 0.913860 0.546875
+ -0.647072
+1
+ 0.813914 0.197177
+2
+4 0 2.0 0
+4 1 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/H_q1/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/H_q1/Conquest_ion_input
new file mode 100644
index 000000000..152fede07
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/H_q1/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 H
+%endblock
+
+%block H
+Atom.PseudopotentialFile H.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/H_q1/H.hgh b/pseudo-and-pao/GTH_PBE/H_q1/H.hgh
new file mode 100644
index 000000000..5824993c6
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/H_q1/H.hgh
@@ -0,0 +1,8 @@
+1 4
+H 1.00 0.200000 -4.178900 0.724463 0.000000 0.000000
+0
+0.0 0.0
+0
+0.0 0.0
+1
+1 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/He_q2/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/He_q2/Conquest_ion_input
new file mode 100644
index 000000000..46ecdf000
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/He_q2/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 He
+%endblock
+
+%block He
+Atom.PseudopotentialFile He.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/He_q2/He.hgh b/pseudo-and-pao/GTH_PBE/He_q2/He.hgh
new file mode 100644
index 000000000..2fa5adc68
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/He_q2/He.hgh
@@ -0,0 +1,8 @@
+1 4
+He 2.00 0.200000 -9.122144 1.702708 0.000000 0.000000
+0
+0.0 0.0
+0
+0.0 0.0
+1
+1 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Hf_q12/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Hf_q12/Conquest_ion_input
new file mode 100644
index 000000000..fdbacaf54
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Hf_q12/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Hf
+%endblock
+
+%block Hf
+Atom.PseudopotentialFile Hf.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Hf_q12/Hf.hgh b/pseudo-and-pao/GTH_PBE/Hf_q12/Hf.hgh
new file mode 100644
index 000000000..502cd9da7
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Hf_q12/Hf.hgh
@@ -0,0 +1,17 @@
+2 4
+Hf 12.00 0.560000 15.522366 -2.433567 0.000000 0.000000
+3
+ 0.311828 -10.910131 27.372646 -14.961570
+ -59.672929 38.630607
+ -30.662094
+2
+ 0.361967 -9.651700 9.223297
+ -10.913153
+2
+ 0.415791 -2.748915 0.481333
+ -0.545781
+4
+5 0 2.0 1
+5 1 6.0 1
+5 2 2.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Hg_q12/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Hg_q12/Conquest_ion_input
new file mode 100644
index 000000000..7c86ab7ce
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Hg_q12/Conquest_ion_input
@@ -0,0 +1,16 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.SolverStep 0.05
+General.SCFMixing 0.2
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Hg
+%endblock
+
+%block Hg
+Atom.PseudopotentialFile Hg.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.009
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Hg_q12/Hg.hgh b/pseudo-and-pao/GTH_PBE/Hg_q12/Hg.hgh
new file mode 100644
index 000000000..8532e55c1
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Hg_q12/Hg.hgh
@@ -0,0 +1,14 @@
+2 4
+Hg 12.00 0.570000 8.467847 0.000000 0.000000 0.000000
+2
+ 0.529787 7.371243 -2.969944
+ 3.834181
+2
+ 0.635166 3.551161 -1.722909
+ 2.038574
+2
+ 0.407985 -8.613980 5.007561
+ -5.678041
+2
+5 2 10.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/I_q7/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/I_q7/Conquest_ion_input
new file mode 100644
index 000000000..cd437d7d9
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/I_q7/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 I
+%endblock
+
+%block I
+Atom.PseudopotentialFile I.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.01
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/I_q7/I.hgh b/pseudo-and-pao/GTH_PBE/I_q7/I.hgh
new file mode 100644
index 000000000..a2f07c222
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/I_q7/I.hgh
@@ -0,0 +1,14 @@
+2 4
+I 7.00 0.560000 8.207102 0.000000 0.000000 0.000000
+3
+ 0.531928 2.308146 1.003909 -0.959156
+ -2.856109 2.476530
+ -1.965685
+2
+ 0.589182 0.906482 0.425071
+ -0.502950
+1
+ 0.739721 0.479195
+2
+5 0 2.0 0
+5 1 5.0 0
diff --git a/pseudo-and-pao/GTH_PBE/In_q13/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/In_q13/Conquest_ion_input
new file mode 100644
index 000000000..e4da97f1d
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/In_q13/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 In
+%endblock
+
+%block In
+Atom.PseudopotentialFile In.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.03
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/In_q13/In.hgh b/pseudo-and-pao/GTH_PBE/In_q13/In.hgh
new file mode 100644
index 000000000..98e6d2da7
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/In_q13/In.hgh
@@ -0,0 +1,16 @@
+2 4
+In 13.00 0.530000 3.324785 0.000000 0.000000 0.000000
+3
+ 0.479495 11.117160 -6.573507 1.506863
+ 10.937275 -3.890704
+ 3.088151
+2
+ 0.569933 4.700614 -2.217064
+ 2.623266
+2
+ 0.377069 -4.002288 -0.840128
+ 0.952616
+3
+4 2 10.0 1
+5 0 2.0 0
+5 1 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/In_q3/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/In_q3/Conquest_ion_input
new file mode 100644
index 000000000..0e1d5437e
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/In_q3/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-5
+
+%block SpeciesLabels
+1 In
+%endblock
+
+%block In
+Atom.PseudopotentialFile In.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.004
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/In_q3/In.hgh b/pseudo-and-pao/GTH_PBE/In_q3/In.hgh
new file mode 100644
index 000000000..8a101a685
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/In_q3/In.hgh
@@ -0,0 +1,14 @@
+2 4
+In 3.00 0.610000 5.086228 0.000000 0.000000 0.000000
+3
+ 0.688883 0.562284 0.999004 -0.480938
+ -2.071955 1.241777
+ -0.985630
+2
+ 0.763710 0.108923 0.423278
+ -0.500830
+1
+ 1.143912 0.116839
+2
+5 0 2.0 0
+5 1 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Ir_q17/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Ir_q17/Conquest_ion_input
new file mode 100644
index 000000000..f36f7a0dc
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ir_q17/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ir
+%endblock
+
+%block Ir
+Atom.PseudopotentialFile Ir.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.05
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Ir_q17/Ir.hgh b/pseudo-and-pao/GTH_PBE/Ir_q17/Ir.hgh
new file mode 100644
index 000000000..05c85e7e8
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ir_q17/Ir.hgh
@@ -0,0 +1,17 @@
+2 4
+Ir 17.00 0.510000 13.410806 -2.341948 0.000000 0.000000
+3
+ 0.387264 -2.516285 1.055190 4.675056
+ 6.241735 -12.070943
+ 9.581014
+2
+ 0.346083 -6.526151 7.353184
+ -8.700405
+2
+ 0.378813 -0.855953 -1.175351
+ 1.332723
+4
+5 0 2.0 1
+5 1 6.0 1
+5 2 7.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Ir_q9/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Ir_q9/Conquest_ion_input
new file mode 100644
index 000000000..41d1efc22
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ir_q9/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Ir
+%endblock
+
+%block Ir
+Atom.PseudopotentialFile Ir.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.013
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Ir_q9/Ir.hgh b/pseudo-and-pao/GTH_PBE/Ir_q9/Ir.hgh
new file mode 100644
index 000000000..0fe277acd
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ir_q9/Ir.hgh
@@ -0,0 +1,14 @@
+2 4
+Ir 9.00 0.641000 14.581814 0.000000 0.000000 0.000000
+2
+ 0.510105 3.715250 -1.262637
+ 1.630058
+2
+ 0.684892 1.919102 -1.896195
+ 2.243608
+2
+ 0.471735 -8.856031 3.170253
+ -3.594729
+2
+5 2 7.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/K_q9/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/K_q9/Conquest_ion_input
new file mode 100644
index 000000000..bdc48244e
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/K_q9/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 K
+%endblock
+
+%block K
+Atom.PseudopotentialFile K.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.04
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/K_q9/K.hgh b/pseudo-and-pao/GTH_PBE/K_q9/K.hgh
new file mode 100644
index 000000000..db985d8dc
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/K_q9/K.hgh
@@ -0,0 +1,12 @@
+1 4
+K 9.00 0.400000 -3.363552 -1.086530 0.000000 0.000000
+2
+ 0.305318 17.850623 -5.622649
+ 7.258808
+2
+ 0.316484 7.333780 -2.460945
+ 2.911829
+3
+3 0 2.0 1
+3 1 6.0 1
+4 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Kr_q8/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Kr_q8/Conquest_ion_input
new file mode 100644
index 000000000..77c92269d
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Kr_q8/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Kr
+%endblock
+
+%block Kr
+Atom.PseudopotentialFile Kr.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.015
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Kr_q8/Kr.hgh b/pseudo-and-pao/GTH_PBE/Kr_q8/Kr.hgh
new file mode 100644
index 000000000..c497f8374
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Kr_q8/Kr.hgh
@@ -0,0 +1,14 @@
+2 4
+Kr 8.00 0.500000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.421657 6.465304 0.538660 -1.502601
+ -3.139389 3.879700
+ -3.079416
+2
+ 0.433744 2.601165 0.705110
+ -0.834297
+1
+ 0.524691 0.635595
+2
+4 0 2.0 0
+4 1 6.0 0
diff --git a/pseudo-and-pao/GTH_PBE/La_q11/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/La_q11/Conquest_ion_input
new file mode 100644
index 000000000..ed8b57476
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/La_q11/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 La
+%endblock
+
+%block La
+Atom.PseudopotentialFile La.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.02
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/La_q11/La.hgh b/pseudo-and-pao/GTH_PBE/La_q11/La.hgh
new file mode 100644
index 000000000..a4a369e9f
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/La_q11/La.hgh
@@ -0,0 +1,17 @@
+3 4
+La 11.00 0.535000 20.689805 -1.703270 0.000000 0.000000
+2
+ 0.561447 -0.028240 1.078598
+ -1.392464
+2
+ 0.475173 0.268023 0.673285
+ -0.796642
+1
+ 0.629084 0.380227
+1
+ 0.299117 -18.443549
+4
+5 0 2.0 1
+5 1 6.0 1
+5 2 1.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Li_q3/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Li_q3/Conquest_ion_input
new file mode 100644
index 000000000..6cb5cb3e4
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Li_q3/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Li
+%endblock
+
+%block Li
+Atom.PseudopotentialFile Li.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Li_q3/Li.hgh b/pseudo-and-pao/GTH_PBE/Li_q3/Li.hgh
new file mode 100644
index 000000000..a441713a8
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Li_q3/Li.hgh
@@ -0,0 +1,9 @@
+1 4
+Li 3.00 0.400000 -14.081155 9.626220 -1.783616 0.085152
+0
+0.0 0.0
+0
+0.0 0.0
+2
+1 0 2.0 1
+2 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Mg_q10/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Mg_q10/Conquest_ion_input
new file mode 100644
index 000000000..990db35a4
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Mg_q10/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Mg
+%endblock
+
+%block Mg
+Atom.PseudopotentialFile Mg.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.02
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Mg_q10/Mg.hgh b/pseudo-and-pao/GTH_PBE/Mg_q10/Mg.hgh
new file mode 100644
index 000000000..2cae2af43
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Mg_q10/Mg.hgh
@@ -0,0 +1,10 @@
+1 4
+Mg 10.00 0.192758 -20.575391 3.040167 0.000000 0.000000
+1
+ 0.141407 41.047292
+1
+ 0.102932 -9.985626
+3
+2 0 2.0 1
+2 1 6.0 1
+3 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Mg_q2/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Mg_q2/Conquest_ion_input
new file mode 100644
index 000000000..32eb2d8d3
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Mg_q2/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Mg
+%endblock
+
+%block Mg
+Atom.PseudopotentialFile Mg.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.03
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Mg_q2/Mg.hgh b/pseudo-and-pao/GTH_PBE/Mg_q2/Mg.hgh
new file mode 100644
index 000000000..fd37bae02
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Mg_q2/Mg.hgh
@@ -0,0 +1,9 @@
+1 4
+Mg 2.00 0.576960 -2.690407 0.000000 0.000000 0.000000
+2
+ 0.593924 3.503211 -0.716772
+ 0.925348
+1
+ 0.707157 0.831158
+1
+3 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Mn_q15/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Mn_q15/Conquest_ion_input
new file mode 100644
index 000000000..259b53844
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Mn_q15/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Mn
+%endblock
+
+%block Mn
+Atom.PseudopotentialFile Mn.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.02
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Mn_q15/Mn.hgh b/pseudo-and-pao/GTH_PBE/Mn_q15/Mn.hgh
new file mode 100644
index 000000000..e764a3bd0
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Mn_q15/Mn.hgh
@@ -0,0 +1,15 @@
+2 4
+Mn 15.00 0.365000 6.093046 -0.446469 0.000000 0.000000
+2
+ 0.295686 1.887120 6.356837
+ -8.206641
+2
+ 0.245613 -6.570025 7.983360
+ -9.446039
+1
+ 0.222523 -11.612051
+4
+3 0 2.0 1
+3 1 6.0 1
+3 2 5.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Mo_q14/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Mo_q14/Conquest_ion_input
new file mode 100644
index 000000000..e514f9633
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Mo_q14/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Mo
+%endblock
+
+%block Mo
+Atom.PseudopotentialFile Mo.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.02
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Mo_q14/Mo.hgh b/pseudo-and-pao/GTH_PBE/Mo_q14/Mo.hgh
new file mode 100644
index 000000000..15e9eb7c5
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Mo_q14/Mo.hgh
@@ -0,0 +1,16 @@
+2 4
+Mo 14.00 0.430000 28.609368 -4.721803 0.000000 0.000000
+2
+ 0.345216 0.146303 2.762005
+ -3.565733
+2
+ 0.416888 -0.190785 -0.728744
+ 0.862262
+2
+ 0.420508 1.216814 -2.686463
+ 3.046162
+4
+4 0 2.0 1
+4 1 6.0 1
+4 2 5.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/N_q5/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/N_q5/Conquest_ion_input
new file mode 100644
index 000000000..616da6124
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/N_q5/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 N
+%endblock
+
+%block N
+Atom.PseudopotentialFile N.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/N_q5/N.hgh b/pseudo-and-pao/GTH_PBE/N_q5/N.hgh
new file mode 100644
index 000000000..b1396dc87
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/N_q5/N.hgh
@@ -0,0 +1,9 @@
+1 4
+N 5.00 0.283791 -12.415226 1.868096 0.000000 0.000000
+1
+ 0.255405 13.630263
+0
+ 0.245495
+2
+2 0 2.0 0
+2 1 3.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Na_q1/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Na_q1/Conquest_ion_input
new file mode 100644
index 000000000..b56e2ccc6
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Na_q1/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Na
+%endblock
+
+%block Na
+Atom.PseudopotentialFile Na.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.02
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Na_q1/Na.hgh b/pseudo-and-pao/GTH_PBE/Na_q1/Na.hgh
new file mode 100644
index 000000000..ee31a994f
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Na_q1/Na.hgh
@@ -0,0 +1,9 @@
+1 4
+Na 1.00 0.713926 -3.151645 0.000000 0.000000 0.000000
+2
+ 0.760129 1.912609 -0.167203
+ 0.215859
+1
+ 0.888469 0.509299
+1
+3 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Na_q9/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Na_q9/Conquest_ion_input
new file mode 100644
index 000000000..599182790
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Na_q9/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Na
+%endblock
+
+%block Na
+Atom.PseudopotentialFile Na.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.01
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Na_q9/Na.hgh b/pseudo-and-pao/GTH_PBE/Na_q9/Na.hgh
new file mode 100644
index 000000000..b50baef73
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Na_q9/Na.hgh
@@ -0,0 +1,10 @@
+1 4
+Na 9.00 0.236523 0.295105 -0.913885 0.000000 0.000000
+1
+ 0.143560 34.601492
+1
+ 0.129932 -14.277462
+3
+2 0 2.0 1
+2 1 6.0 1
+3 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Nb_q13/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Nb_q13/Conquest_ion_input
new file mode 100644
index 000000000..73dd7037b
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Nb_q13/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Nb
+%endblock
+
+%block Nb
+Atom.PseudopotentialFile Nb.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.02
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Nb_q13/Nb.hgh b/pseudo-and-pao/GTH_PBE/Nb_q13/Nb.hgh
new file mode 100644
index 000000000..a130c8631
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Nb_q13/Nb.hgh
@@ -0,0 +1,16 @@
+2 4
+Nb 13.00 0.460000 26.275263 -4.578031 0.000000 0.000000
+2
+ 0.351169 -1.043719 3.277904
+ -4.231756
+2
+ 0.405460 -0.662466 -0.907829
+ 1.074157
+2
+ 0.422122 1.494093 -3.430040
+ 3.889299
+4
+4 0 2.0 1
+4 1 6.0 1
+4 2 4.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Ne_q8/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Ne_q8/Conquest_ion_input
new file mode 100644
index 000000000..470fd238f
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ne_q8/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ne
+%endblock
+
+%block Ne
+Atom.PseudopotentialFile Ne.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Ne_q8/Ne.hgh b/pseudo-and-pao/GTH_PBE/Ne_q8/Ne.hgh
new file mode 100644
index 000000000..ba270a289
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ne_q8/Ne.hgh
@@ -0,0 +1,10 @@
+1 4
+Ne 8.00 0.190000 -27.120160 4.360450 0.000000 0.000000
+2
+ 0.176059 28.177371 0.833656
+ -1.076245
+1
+ 0.195475 -0.236294
+2
+2 0 2.0 0
+2 1 6.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Ni_q18/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Ni_q18/Conquest_ion_input
new file mode 100644
index 000000000..69ee65b12
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ni_q18/Conquest_ion_input
@@ -0,0 +1,16 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.SolverStep 0.2
+General.SCFMixing 0.2
+
+%block SpeciesLabels
+1 Ni
+%endblock
+
+%block Ni
+Atom.PseudopotentialFile Ni.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.02
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Ni_q18/Ni.hgh b/pseudo-and-pao/GTH_PBE/Ni_q18/Ni.hgh
new file mode 100644
index 000000000..1ae288fa3
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ni_q18/Ni.hgh
@@ -0,0 +1,15 @@
+2 4
+Ni 18.00 0.350000 2.102166 0.648484 0.000000 0.000000
+2
+ 0.261295 0.622658 9.970227
+ -12.871507
+2
+ 0.224253 -11.142708 12.429566
+ -14.706861
+1
+ 0.215348 -12.628146
+4
+3 0 2.0 1
+3 1 6.0 1
+3 2 8.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/O_q6/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/O_q6/Conquest_ion_input
new file mode 100644
index 000000000..6ad0f4360
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/O_q6/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 O
+%endblock
+
+%block O
+Atom.PseudopotentialFile O.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/O_q6/O.hgh b/pseudo-and-pao/GTH_PBE/O_q6/O.hgh
new file mode 100644
index 000000000..449d64c47
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/O_q6/O.hgh
@@ -0,0 +1,9 @@
+1 4
+O 6.00 0.244554 -16.667215 2.487311 0.000000 0.000000
+1
+ 0.220956 18.337458
+0
+ 0.211332
+2
+2 0 2.0 0
+2 1 4.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Os_q16/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Os_q16/Conquest_ion_input
new file mode 100644
index 000000000..12d267936
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Os_q16/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Os
+%endblock
+
+%block Os
+Atom.PseudopotentialFile Os.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.02
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Os_q16/Os.hgh b/pseudo-and-pao/GTH_PBE/Os_q16/Os.hgh
new file mode 100644
index 000000000..dc6ac301a
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Os_q16/Os.hgh
@@ -0,0 +1,17 @@
+2 4
+Os 16.00 0.520000 13.463030 -2.241170 0.000000 0.000000
+3
+ 0.390122 -3.274168 2.360031 3.611019
+ 2.826535 -9.323610
+ 7.400386
+2
+ 0.349450 -6.899282 7.529319
+ -8.908810
+2
+ 0.392842 -0.942683 -1.081570
+ 1.226386
+4
+5 0 2.0 1
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+5 2 6.0 0
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diff --git a/pseudo-and-pao/GTH_PBE/Os_q8/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Os_q8/Conquest_ion_input
new file mode 100644
index 000000000..e4570c011
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Os_q8/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Os
+%endblock
+
+%block Os
+Atom.PseudopotentialFile Os.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.009
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Os_q8/Os.hgh b/pseudo-and-pao/GTH_PBE/Os_q8/Os.hgh
new file mode 100644
index 000000000..8e794df9b
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Os_q8/Os.hgh
@@ -0,0 +1,14 @@
+2 4
+Os 8.00 0.667000 13.079049 0.000000 0.000000 0.000000
+2
+ 0.495760 4.350339 -1.496803
+ 1.932364
+2
+ 0.701161 1.816696 -1.998159
+ 2.364254
+2
+ 0.471173 -10.995987 5.979181
+ -6.779754
+2
+5 2 6.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/P_q5/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/P_q5/Conquest_ion_input
new file mode 100644
index 000000000..0ba3f5455
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/P_q5/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 P
+%endblock
+
+%block P
+Atom.PseudopotentialFile P.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/P_q5/P.hgh b/pseudo-and-pao/GTH_PBE/P_q5/P.hgh
new file mode 100644
index 000000000..f0839b498
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/P_q5/P.hgh
@@ -0,0 +1,10 @@
+1 4
+P 5.00 0.430000 -5.875943 0.000000 0.000000 0.000000
+2
+ 0.396377 11.008862 -3.470356
+ 4.480210
+1
+ 0.448298 3.056064
+2
+3 0 2.0 0
+3 1 3.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Pb_q14/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Pb_q14/Conquest_ion_input
new file mode 100644
index 000000000..a2241942d
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Pb_q14/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Pb
+%endblock
+
+%block Pb
+Atom.PseudopotentialFile Pb.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+Atom.Perturbative_Polarised F
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Pb_q14/Pb.hgh b/pseudo-and-pao/GTH_PBE/Pb_q14/Pb.hgh
new file mode 100644
index 000000000..8d3334af3
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Pb_q14/Pb.hgh
@@ -0,0 +1,15 @@
+2 4
+Pb 14.00 0.530000 12.572143 0.000000 0.000000 0.000000
+2
+ 0.495549 8.429807 -3.440056
+ 4.441093
+2
+ 0.569348 4.981506 -2.896399
+ 3.427066
+2
+ 0.404224 -6.814913 1.837827
+ -2.083900
+3
+5 2 10.0 1
+6 0 2.0 0
+6 1 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Pb_q4/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Pb_q4/Conquest_ion_input
new file mode 100644
index 000000000..dbe0bd2dc
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Pb_q4/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-5
+
+%block SpeciesLabels
+1 Pb
+%endblock
+
+%block Pb
+Atom.PseudopotentialFile Pb.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.0038
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Pb_q4/Pb.hgh b/pseudo-and-pao/GTH_PBE/Pb_q4/Pb.hgh
new file mode 100644
index 000000000..d06a04155
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Pb_q4/Pb.hgh
@@ -0,0 +1,14 @@
+2 4
+Pb 4.00 0.617500 4.672384 0.000000 0.000000 0.000000
+3
+ 0.622359 0.879918 2.081148 -1.431257
+ -5.014690 3.695490
+ -2.933204
+2
+ 0.812002 0.153457 0.478898
+ -0.566640
+1
+ 1.025015 0.301702
+2
+6 0 2.0 0
+6 1 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Pd_q10/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Pd_q10/Conquest_ion_input
new file mode 100644
index 000000000..c9e2e5c22
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Pd_q10/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Pd
+%endblock
+
+%block Pd
+Atom.PseudopotentialFile Pd.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.009
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Pd_q10/Pd.hgh b/pseudo-and-pao/GTH_PBE/Pd_q10/Pd.hgh
new file mode 100644
index 000000000..d704fef4a
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Pd_q10/Pd.hgh
@@ -0,0 +1,14 @@
+2 4
+Pd 10.00 0.596000 5.299874 0.000000 0.000000 0.000000
+2
+ 0.591950 5.308195 -2.062379
+ 2.662520
+2
+ 0.666285 2.734584 -1.466970
+ 1.735742
+2
+ 0.438518 -3.719788 -0.807388
+ 0.915492
+2
+4 2 9.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Pd_q18/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Pd_q18/Conquest_ion_input
new file mode 100644
index 000000000..165e9dadf
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Pd_q18/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Pd
+%endblock
+
+%block Pd
+Atom.PseudopotentialFile Pd.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.04
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Pd_q18/Pd.hgh b/pseudo-and-pao/GTH_PBE/Pd_q18/Pd.hgh
new file mode 100644
index 000000000..3e3ed32b8
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Pd_q18/Pd.hgh
@@ -0,0 +1,16 @@
+2 4
+Pd 18.00 0.410000 26.783659 -4.931306 0.000000 0.000000
+2
+ 0.337971 -0.718729 4.384867
+ -5.660838
+2
+ 0.415196 -0.046244 -1.077952
+ 1.275450
+2
+ 0.440270 1.639164 -3.093688
+ 3.507912
+4
+4 0 2.0 1
+4 1 6.0 1
+4 2 9.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Po_q6/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Po_q6/Conquest_ion_input
new file mode 100644
index 000000000..a1fcf0024
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Po_q6/Conquest_ion_input
@@ -0,0 +1,15 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Po
+%endblock
+
+%block Po
+Atom.PseudopotentialFile Po.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.002
+Atom.dE_large_radius_semicore_hgh 1e-5
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Po_q6/Po.hgh b/pseudo-and-pao/GTH_PBE/Po_q6/Po.hgh
new file mode 100644
index 000000000..12f963597
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Po_q6/Po.hgh
@@ -0,0 +1,14 @@
+2 4
+Po 6.00 0.592500 8.134326 0.000000 0.000000 0.000000
+3
+ 0.804224 0.326334 0.105400 0.528094
+ 0.722875 -1.363533
+ 1.082271
+2
+ 0.817037 0.158015 0.375302
+ -0.444064
+1
+ 0.890149 0.462532
+2
+6 0 2.0 0
+6 1 4.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Pt_q10/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Pt_q10/Conquest_ion_input
new file mode 100644
index 000000000..479e18031
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Pt_q10/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Pt
+%endblock
+
+%block Pt
+Atom.PseudopotentialFile Pt.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.008
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Pt_q10/Pt.hgh b/pseudo-and-pao/GTH_PBE/Pt_q10/Pt.hgh
new file mode 100644
index 000000000..8b753ec83
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Pt_q10/Pt.hgh
@@ -0,0 +1,14 @@
+2 4
+Pt 10.00 0.616000 11.313635 0.000000 0.000000 0.000000
+2
+ 0.550904 4.733491 -1.784594
+ 2.303901
+2
+ 0.674138 2.534798 -1.778066
+ 2.103836
+2
+ 0.457392 -7.264011 2.558665
+ -2.901253
+2
+5 2 9.0 0
+6 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Pt_q18/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Pt_q18/Conquest_ion_input
new file mode 100644
index 000000000..b386fb4e5
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Pt_q18/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Pt
+%endblock
+
+%block Pt
+Atom.PseudopotentialFile Pt.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.02
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Pt_q18/Pt.hgh b/pseudo-and-pao/GTH_PBE/Pt_q18/Pt.hgh
new file mode 100644
index 000000000..a3fa76e8a
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Pt_q18/Pt.hgh
@@ -0,0 +1,18 @@
+2 4
+Pt 18.00 0.500000 8.814323 -0.292509 0.000000 0.000000
+3
+ 0.298002 -5.968385 24.212900 -13.789679
+ -53.687634 35.604799
+ -28.260433
+3
+ 0.360172 -6.668659 7.170659 0.766904
+ -7.207661 -1.814825
+ 1.289806
+2
+ 0.340532 -8.589905 9.410122
+ -10.670075
+4
+5 0 2.0 1
+5 1 6.0 1
+5 2 9.0 0
+6 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/README.md b/pseudo-and-pao/GTH_PBE/README.md
new file mode 100644
index 000000000..6556cf51b
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/README.md
@@ -0,0 +1,6 @@
+This directory contains GTH/HGH pseudopotentials for the PBE XC functional
+based on the data distributed with CP2K (which in turn tabulates the results in
+Phys. Rev. B 54, 1703 (1996), Phys. Rev. B 58, 3641 (1998) and Theor. Chem. Acc. 114, 145 (2005)).
+
+Note that these are not tested by the CONQUEST developers, and should be treated
+with care. In particular, PAO generation is at present in beta phase.
diff --git a/pseudo-and-pao/GTH_PBE/Rb_q9/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Rb_q9/Conquest_ion_input
new file mode 100644
index 000000000..8c9afec74
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Rb_q9/Conquest_ion_input
@@ -0,0 +1,33 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Rb
+%endblock
+
+%block Rb
+Atom.PseudopotentialFile Rb.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.PAO_N_Shells 5
+Atom.BasisBlock RbBlock
+Atom.Cutoffs ra
+%endblock
+
+# Specify the number of PAOs for each n,l pair and then their radii
+# The radii below are based on default CONQUEST energies for the
+# valence shells
+%block RbBlock
+# n, l, number of zetas
+4 0 1
+4 1 1
+5 0 2
+5 1 1
+4 2 1
+# Radii for PAOs (bohr)
+6.6
+8.6
+13.0 8.3
+13.0
+13.0
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Rb_q9/Rb.hgh b/pseudo-and-pao/GTH_PBE/Rb_q9/Rb.hgh
new file mode 100644
index 000000000..9ee9d1012
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Rb_q9/Rb.hgh
@@ -0,0 +1,14 @@
+2 4
+Rb 9.00 0.490000 5.669086 -0.811627 0.000000 0.000000
+2
+ 0.281803 21.390732 -8.078667
+ 10.429514
+2
+ 0.285708 12.256349 -12.198541
+ 14.433508
+1
+ 0.541797 0.345666
+3
+4 0 2.0 1
+4 1 6.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Re_q15/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Re_q15/Conquest_ion_input
new file mode 100644
index 000000000..4813e6e98
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Re_q15/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Re
+%endblock
+
+%block Re
+Atom.PseudopotentialFile Re.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.03
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Re_q15/Re.hgh b/pseudo-and-pao/GTH_PBE/Re_q15/Re.hgh
new file mode 100644
index 000000000..dd84ddd2a
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Re_q15/Re.hgh
@@ -0,0 +1,17 @@
+2 4
+Re 15.00 0.530000 13.462631 -2.234922 0.000000 0.000000
+3
+ 0.393801 -3.717481 3.154779 2.855935
+ 0.572376 -7.373992
+ 5.852925
+2
+ 0.352533 -7.053404 7.566758
+ -8.953109
+2
+ 0.401868 -0.900024 -1.149171
+ 1.303037
+4
+5 0 2.0 1
+5 1 6.0 1
+5 2 5.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Re_q7/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Re_q7/Conquest_ion_input
new file mode 100644
index 000000000..3070f23b9
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Re_q7/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Re
+%endblock
+
+%block Re
+Atom.PseudopotentialFile Re.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.008
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Re_q7/Re.hgh b/pseudo-and-pao/GTH_PBE/Re_q7/Re.hgh
new file mode 100644
index 000000000..bf44dff97
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Re_q7/Re.hgh
@@ -0,0 +1,14 @@
+2 4
+Re 7.00 0.693000 11.961942 0.000000 0.000000 0.000000
+2
+ 0.463315 6.087009 -2.191380
+ 2.829059
+2
+ 0.709648 1.815062 -2.354122
+ 2.785435
+2
+ 0.476065 -12.393710 8.006297
+ -9.078287
+2
+5 2 5.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Rh_q17/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Rh_q17/Conquest_ion_input
new file mode 100644
index 000000000..4837871b6
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Rh_q17/Conquest_ion_input
@@ -0,0 +1,15 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Rh
+%endblock
+
+%block Rh
+Atom.PseudopotentialFile Rh.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.02
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Rh_q17/Rh.hgh b/pseudo-and-pao/GTH_PBE/Rh_q17/Rh.hgh
new file mode 100644
index 000000000..c0c8ffb6a
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Rh_q17/Rh.hgh
@@ -0,0 +1,16 @@
+2 4
+Rh 17.00 0.420000 26.206793 -4.937383 0.000000 0.000000
+2
+ 0.345446 -0.452482 3.892804
+ -5.025589
+2
+ 0.378380 -0.941112 -0.005699
+ 0.006744
+2
+ 0.433747 1.574236 -3.012172
+ 3.415482
+4
+4 0 2.0 1
+4 1 6.0 1
+4 2 8.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Rh_q9/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Rh_q9/Conquest_ion_input
new file mode 100644
index 000000000..dd17b9147
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Rh_q9/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Rh
+%endblock
+
+%block Rh
+Atom.PseudopotentialFile Rh.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.009
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Rh_q9/Rh.hgh b/pseudo-and-pao/GTH_PBE/Rh_q9/Rh.hgh
new file mode 100644
index 000000000..27e1721ee
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Rh_q9/Rh.hgh
@@ -0,0 +1,14 @@
+2 4
+Rh 9.00 0.619009 4.704544 0.000000 0.000000 0.000000
+2
+ 0.613327 4.993205 -1.929782
+ 2.491338
+2
+ 0.693650 2.532375 -1.280860
+ 1.515534
+2
+ 0.370038 -16.882604 14.718217
+ -16.688889
+2
+4 2 8.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Ru_q16/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Ru_q16/Conquest_ion_input
new file mode 100644
index 000000000..f17bdb090
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ru_q16/Conquest_ion_input
@@ -0,0 +1,15 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Ru
+%endblock
+
+%block Ru
+Atom.PseudopotentialFile Ru.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.03
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Ru_q16/Ru.hgh b/pseudo-and-pao/GTH_PBE/Ru_q16/Ru.hgh
new file mode 100644
index 000000000..0b5000c23
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ru_q16/Ru.hgh
@@ -0,0 +1,16 @@
+2 4
+Ru 16.00 0.430000 26.832391 -5.050497 0.000000 0.000000
+2
+ 0.341355 -0.555041 3.715490
+ -4.796677
+2
+ 0.428271 0.106775 -1.277572
+ 1.511643
+2
+ 0.438148 1.509217 -2.943054
+ 3.337110
+4
+4 0 2.0 1
+4 1 6.0 1
+4 2 7.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Ru_q8/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Ru_q8/Conquest_ion_input
new file mode 100644
index 000000000..75c1e1c64
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ru_q8/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Ru
+%endblock
+
+%block Ru
+Atom.PseudopotentialFile Ru.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.015
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Ru_q8/Ru.hgh b/pseudo-and-pao/GTH_PBE/Ru_q8/Ru.hgh
new file mode 100644
index 000000000..d3d0800c7
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ru_q8/Ru.hgh
@@ -0,0 +1,14 @@
+2 4
+Ru 8.00 0.612113 5.044893 0.000000 0.000000 0.000000
+2
+ 0.642150 4.625564 -1.803349
+ 2.328114
+2
+ 0.679367 3.233952 -2.421011
+ 2.864578
+2
+ 0.380597 -15.531655 13.580451
+ -15.398783
+2
+4 2 7.0 0
+5 0 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/S_q6/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/S_q6/Conquest_ion_input
new file mode 100644
index 000000000..dd5eb751d
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/S_q6/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 S
+%endblock
+
+%block S
+Atom.PseudopotentialFile S.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/S_q6/S.hgh b/pseudo-and-pao/GTH_PBE/S_q6/S.hgh
new file mode 100644
index 000000000..545d6e6c4
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/S_q6/S.hgh
@@ -0,0 +1,10 @@
+1 4
+S 6.00 0.420000 -5.986260 0.000000 0.000000 0.000000
+2
+ 0.364820 13.143544 -4.241830
+ 5.476180
+1
+ 0.409480 3.700891
+2
+3 0 2.0 0
+3 1 4.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Sb_q5/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Sb_q5/Conquest_ion_input
new file mode 100644
index 000000000..322d23954
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Sb_q5/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-5
+
+%block SpeciesLabels
+1 Sb
+%endblock
+
+%block Sb
+Atom.PseudopotentialFile Sb.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.008
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Sb_q5/Sb.hgh b/pseudo-and-pao/GTH_PBE/Sb_q5/Sb.hgh
new file mode 100644
index 000000000..6b151bcc1
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Sb_q5/Sb.hgh
@@ -0,0 +1,14 @@
+2 4
+Sb 5.00 0.590000 7.928521 0.000000 0.000000 0.000000
+3
+ 0.556136 1.430478 1.261426 -0.923234
+ -3.130133 2.383779
+ -1.892066
+2
+ 0.622755 0.561472 0.304845
+ -0.360698
+1
+ 0.889486 0.270869
+2
+5 0 2.0 0
+5 1 3.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Sc_q11/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Sc_q11/Conquest_ion_input
new file mode 100644
index 000000000..e12f3107f
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Sc_q11/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Sc
+%endblock
+
+%block Sc
+Atom.PseudopotentialFile Sc.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.02
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Sc_q11/Sc.hgh b/pseudo-and-pao/GTH_PBE/Sc_q11/Sc.hgh
new file mode 100644
index 000000000..15360e434
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Sc_q11/Sc.hgh
@@ -0,0 +1,15 @@
+2 4
+Sc 11.00 0.385000 8.214900 -0.557059 0.000000 0.000000
+2
+ 0.363611 2.646533 3.021084
+ -3.900203
+2
+ 0.243898 -2.634823 7.992137
+ -9.456424
+1
+ 0.253206 -8.165948
+4
+3 0 2.0 1
+3 1 6.0 1
+3 2 1.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Se_q6/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Se_q6/Conquest_ion_input
new file mode 100644
index 000000000..cb7b81c50
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Se_q6/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Se
+%endblock
+
+%block Se
+Atom.PseudopotentialFile Se.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.015
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Se_q6/Se.hgh b/pseudo-and-pao/GTH_PBE/Se_q6/Se.hgh
new file mode 100644
index 000000000..909ebd995
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Se_q6/Se.hgh
@@ -0,0 +1,14 @@
+2 4
+Se 6.00 0.510000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.432460 6.518110 -0.222716 -1.196129
+ -1.657978 3.088392
+ -2.451335
+2
+ 0.470492 2.281262 0.365335
+ -0.432271
+1
+ 0.625600 0.439799
+2
+4 0 2.0 0
+4 1 4.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Si_q4/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Si_q4/Conquest_ion_input
new file mode 100644
index 000000000..35912ade0
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Si_q4/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Si
+%endblock
+
+%block Si
+Atom.PseudopotentialFile Si.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Si_q4/Si.hgh b/pseudo-and-pao/GTH_PBE/Si_q4/Si.hgh
new file mode 100644
index 000000000..7846f7b53
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Si_q4/Si.hgh
@@ -0,0 +1,10 @@
+1 4
+Si 4.00 0.440000 -6.269288 0.000000 0.000000 0.000000
+2
+ 0.435634 8.951742 -2.706271
+ 3.493781
+1
+ 0.497942 2.431277
+2
+3 0 2.0 0
+3 1 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Sn_q4/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Sn_q4/Conquest_ion_input
new file mode 100644
index 000000000..7f5442a77
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Sn_q4/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-5
+
+%block SpeciesLabels
+1 Sn
+%endblock
+
+%block Sn
+Atom.PseudopotentialFile Sn.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.007
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Sn_q4/Sn.hgh b/pseudo-and-pao/GTH_PBE/Sn_q4/Sn.hgh
new file mode 100644
index 000000000..e02a81a4e
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Sn_q4/Sn.hgh
@@ -0,0 +1,14 @@
+2 4
+Sn 4.00 0.605000 6.266782 0.000000 0.000000 0.000000
+3
+ 0.566437 1.571181 1.470041 -1.178577
+ -3.814770 3.043072
+ -2.415363
+2
+ 0.641850 0.526898 0.403258
+ -0.477141
+1
+ 0.990873 0.198766
+2
+5 0 2.0 0
+5 1 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Sr_q10/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Sr_q10/Conquest_ion_input
new file mode 100644
index 000000000..7ac48569e
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Sr_q10/Conquest_ion_input
@@ -0,0 +1,33 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Sr
+%endblock
+
+%block Sr
+Atom.PseudopotentialFile Sr.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.PAO_N_Shells 5
+Atom.BasisBlock SrBlock
+Atom.Cutoffs ra
+%endblock
+
+# Specify the number of PAOs for each n,l pair and then their radii
+# The radii below are based on default CONQUEST energies for the
+# valence shells
+%block SrBlock
+# n, l, number of zetas
+4 0 1
+4 1 1
+5 0 2
+5 1 1
+4 2 1
+# Radii for PAOs (bohr)
+6.1
+7.5
+10.97 5.8
+10.97
+10.97
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Sr_q10/Sr.hgh b/pseudo-and-pao/GTH_PBE/Sr_q10/Sr.hgh
new file mode 100644
index 000000000..0bf089a3c
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Sr_q10/Sr.hgh
@@ -0,0 +1,14 @@
+2 4
+Sr 10.00 0.480000 6.810950 -1.196110 0.000000 0.000000
+2
+ 0.275886 21.289719 -7.899034
+ 10.197609
+2
+ 0.281741 11.709051 -10.965777
+ 12.974882
+1
+ 0.521089 0.360539
+3
+4 0 2.0 1
+4 1 6.0 1
+5 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Ta_q13/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Ta_q13/Conquest_ion_input
new file mode 100644
index 000000000..60816c171
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ta_q13/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ta
+%endblock
+
+%block Ta
+Atom.PseudopotentialFile Ta.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.02
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Ta_q13/Ta.hgh b/pseudo-and-pao/GTH_PBE/Ta_q13/Ta.hgh
new file mode 100644
index 000000000..12a31f3a5
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ta_q13/Ta.hgh
@@ -0,0 +1,17 @@
+2 4
+Ta 13.00 0.550000 13.385202 -2.253920 0.000000 0.000000
+3
+ 0.400883 -4.436709 4.176489 1.875608
+ -2.341148 -4.842799
+ 3.843852
+2
+ 0.356549 -7.624428 8.178955
+ -9.677470
+2
+ 0.418229 -1.113561 -0.875331
+ 0.992532
+4
+5 0 2.0 1
+5 1 6.0 1
+5 2 3.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Ta_q5/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Ta_q5/Conquest_ion_input
new file mode 100644
index 000000000..89d570ece
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ta_q5/Conquest_ion_input
@@ -0,0 +1,13 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ta
+%endblock
+
+%block Ta
+Atom.PseudopotentialFile Ta.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.008
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Ta_q5/Ta.hgh b/pseudo-and-pao/GTH_PBE/Ta_q5/Ta.hgh
new file mode 100644
index 000000000..8d3aa2bae
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ta_q5/Ta.hgh
@@ -0,0 +1,14 @@
+2 4
+Ta 5.00 0.744000 9.839343 0.000000 0.000000 0.000000
+2
+ 0.452397 6.123381 -2.168903
+ 2.800042
+2
+ 0.751644 1.649701 -2.514810
+ 2.975564
+2
+ 0.501142 -12.423345 9.014734
+ -10.221747
+2
+5 2 3.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Tc_q15/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Tc_q15/Conquest_ion_input
new file mode 100644
index 000000000..1bd1fd4e8
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Tc_q15/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Tc
+%endblock
+
+%block Tc
+Atom.PseudopotentialFile Tc.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.03
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Tc_q15/Tc.hgh b/pseudo-and-pao/GTH_PBE/Tc_q15/Tc.hgh
new file mode 100644
index 000000000..7426f7ff2
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Tc_q15/Tc.hgh
@@ -0,0 +1,16 @@
+2 4
+Tc 15.00 0.430000 27.301999 -4.647157 0.000000 0.000000
+2
+ 0.346175 -0.379219 3.340566
+ -4.312652
+2
+ 0.423468 -0.241516 -0.822150
+ 0.972781
+2
+ 0.431865 1.218785 -2.674010
+ 3.032042
+4
+4 0 2.0 1
+4 1 6.0 1
+4 2 5.0 0
+5 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Te_q6/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Te_q6/Conquest_ion_input
new file mode 100644
index 000000000..f4b8861a2
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Te_q6/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-5
+
+%block SpeciesLabels
+1 Te
+%endblock
+
+%block Te
+Atom.PseudopotentialFile Te.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.013
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Te_q6/Te.hgh b/pseudo-and-pao/GTH_PBE/Te_q6/Te.hgh
new file mode 100644
index 000000000..097621b13
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Te_q6/Te.hgh
@@ -0,0 +1,14 @@
+2 4
+Te 6.00 0.575000 8.713649 0.000000 0.000000 0.000000
+3
+ 0.574922 1.401813 0.978780 -0.486306
+ -2.054576 1.255637
+ -0.996631
+2
+ 0.589891 0.764789 0.323986
+ -0.383346
+1
+ 0.813389 0.344858
+2
+5 0 2.0 0
+5 1 4.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Ti_q12/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Ti_q12/Conquest_ion_input
new file mode 100644
index 000000000..8208f2136
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ti_q12/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Ti
+%endblock
+
+%block Ti
+Atom.PseudopotentialFile Ti.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.03
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Ti_q12/Ti.hgh b/pseudo-and-pao/GTH_PBE/Ti_q12/Ti.hgh
new file mode 100644
index 000000000..f632fea07
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Ti_q12/Ti.hgh
@@ -0,0 +1,15 @@
+2 4
+Ti 12.00 0.380000 8.711442 -0.700287 0.000000 0.000000
+2
+ 0.337771 2.575264 3.692971
+ -4.767605
+2
+ 0.242531 -4.630541 8.870875
+ -10.496161
+1
+ 0.243317 -9.406653
+4
+3 0 2.0 1
+3 1 6.0 1
+3 2 2.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Tl_q13/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Tl_q13/Conquest_ion_input
new file mode 100644
index 000000000..daf5115d6
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Tl_q13/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Tl
+%endblock
+
+%block Tl
+Atom.PseudopotentialFile Tl.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Tl_q13/Tl.hgh b/pseudo-and-pao/GTH_PBE/Tl_q13/Tl.hgh
new file mode 100644
index 000000000..5aae9a6b7
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Tl_q13/Tl.hgh
@@ -0,0 +1,15 @@
+2 4
+Tl 13.00 0.550000 12.290585 0.000000 0.000000 0.000000
+2
+ 0.512803 7.190170 -2.863011
+ 3.696131
+2
+ 0.577115 4.760946 -3.673325
+ 4.346337
+2
+ 0.393230 -11.012687 6.421592
+ -7.281401
+3
+5 2 10.0 1
+6 0 2.0 0
+6 1 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Tl_q3/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Tl_q3/Conquest_ion_input
new file mode 100644
index 000000000..06450212b
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Tl_q3/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-5
+
+%block SpeciesLabels
+1 Tl
+%endblock
+
+%block Tl
+Atom.PseudopotentialFile Tl.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.004
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Tl_q3/Tl.hgh b/pseudo-and-pao/GTH_PBE/Tl_q3/Tl.hgh
new file mode 100644
index 000000000..3a00de30c
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Tl_q3/Tl.hgh
@@ -0,0 +1,14 @@
+2 4
+Tl 3.00 0.630000 1.452721 0.000000 0.000000 0.000000
+3
+ 0.780768 0.379730 1.209128 -0.458568
+ -2.306838 1.184017
+ -0.939785
+2
+ 0.897050 -0.024236 0.582356
+ -0.689053
+1
+ 1.093792 0.227642
+2
+6 0 2.0 0
+6 1 1.0 0
diff --git a/pseudo-and-pao/GTH_PBE/V_q13/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/V_q13/Conquest_ion_input
new file mode 100644
index 000000000..a55e64174
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/V_q13/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 V
+%endblock
+
+%block V
+Atom.PseudopotentialFile V.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.03
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/V_q13/V.hgh b/pseudo-and-pao/GTH_PBE/V_q13/V.hgh
new file mode 100644
index 000000000..a49dfc89a
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/V_q13/V.hgh
@@ -0,0 +1,15 @@
+2 4
+V 13.00 0.375000 7.474704 -0.370264 0.000000 0.000000
+2
+ 0.327795 1.940878 4.725688
+ -6.100837
+2
+ 0.244766 -5.978167 9.358639
+ -11.073291
+1
+ 0.241739 -9.499891
+4
+3 0 2.0 1
+3 1 6.0 1
+3 2 3.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/W_q14/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/W_q14/Conquest_ion_input
new file mode 100644
index 000000000..2ca57fb1a
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/W_q14/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 W
+%endblock
+
+%block W
+Atom.PseudopotentialFile W.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.03
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/W_q14/W.hgh b/pseudo-and-pao/GTH_PBE/W_q14/W.hgh
new file mode 100644
index 000000000..7bca9117c
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/W_q14/W.hgh
@@ -0,0 +1,17 @@
+2 4
+W 14.00 0.540000 13.414811 -2.213456 0.000000 0.000000
+3
+ 0.397028 -4.141211 3.835423 2.233179
+ -1.319244 -5.766044
+ 4.576656
+2
+ 0.353531 -7.456236 8.112326
+ -9.598634
+2
+ 0.412107 -0.954661 -1.067446
+ 1.210370
+4
+5 0 2.0 1
+5 1 6.0 1
+5 2 4.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/W_q6/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/W_q6/Conquest_ion_input
new file mode 100644
index 000000000..5a5050b2e
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/W_q6/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 W
+%endblock
+
+%block W
+Atom.PseudopotentialFile W.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.014
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/W_q6/W.hgh b/pseudo-and-pao/GTH_PBE/W_q6/W.hgh
new file mode 100644
index 000000000..5fd3093ea
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/W_q6/W.hgh
@@ -0,0 +1,14 @@
+2 4
+W 6.00 0.719000 10.699890 0.000000 0.000000 0.000000
+2
+ 0.467554 5.803503 -2.070633
+ 2.673175
+2
+ 0.726665 1.788719 -2.554158
+ 3.022121
+2
+ 0.499291 -10.598326 6.447893
+ -7.311224
+2
+5 2 4.0 0
+6 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Xe_q8/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Xe_q8/Conquest_ion_input
new file mode 100644
index 000000000..e406cf592
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Xe_q8/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Xe
+%endblock
+
+%block Xe
+Atom.PseudopotentialFile Xe.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.010
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Xe_q8/Xe.hgh b/pseudo-and-pao/GTH_PBE/Xe_q8/Xe.hgh
new file mode 100644
index 000000000..4a2b6a3ea
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Xe_q8/Xe.hgh
@@ -0,0 +1,14 @@
+2 4
+Xe 8.00 0.560000 8.036363 0.000000 0.000000 0.000000
+3
+ 0.530494 2.232021 1.200358 -0.998498
+ -3.173713 2.578111
+ -2.046312
+2
+ 0.581775 0.796982 0.591233
+ -0.699556
+1
+ 0.685545 0.560189
+2
+5 0 2.0 0
+5 1 6.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Y_q11/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Y_q11/Conquest_ion_input
new file mode 100644
index 000000000..0d484d08c
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Y_q11/Conquest_ion_input
@@ -0,0 +1,15 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-7
+
+%block SpeciesLabels
+1 Y
+%endblock
+
+%block Y
+Atom.PseudopotentialFile Y.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.04
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Y_q11/Y.hgh b/pseudo-and-pao/GTH_PBE/Y_q11/Y.hgh
new file mode 100644
index 000000000..670f9e558
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Y_q11/Y.hgh
@@ -0,0 +1,16 @@
+2 4
+Y 11.00 0.475000 12.167769 -2.328551 0.000000 0.000000
+2
+ 0.246741 23.450272 -8.325357
+ 10.747990
+2
+ 0.296564 5.978634 -5.852350
+ 6.924593
+2
+ 0.450456 1.187490 -1.318673
+ 1.495235
+4
+4 0 2.0 1
+4 1 6.0 1
+4 2 1.0 0
+5 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Zn_q12/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Zn_q12/Conquest_ion_input
new file mode 100644
index 000000000..70e3e5b2c
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Zn_q12/Conquest_ion_input
@@ -0,0 +1,17 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+General.KBThresh 1e-6
+
+%block SpeciesLabels
+1 Zn
+%endblock
+
+# We have made the equal energy shift cutoff radius approach
+# the default here, as the equal radius approach leaves the
+# d orbitals almost entirely identical
+%block Zn
+Atom.PseudopotentialFile Zn.hgh
+Atom.ZetaForm com
+Atom.dE_small_radius 0.006
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Zn_q12/Zn.hgh b/pseudo-and-pao/GTH_PBE/Zn_q12/Zn.hgh
new file mode 100644
index 000000000..6c292b3a3
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Zn_q12/Zn.hgh
@@ -0,0 +1,14 @@
+2 4
+Zn 12.00 0.510000 0.000000 0.000000 0.000000 0.000000
+3
+ 0.400316 11.530041 -8.791898 3.145086
+ 16.465775 -8.120578
+ 6.445509
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+ 0.543182 2.597195 -0.594263
+ 0.703141
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+ 0.250959 -14.466958
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diff --git a/pseudo-and-pao/GTH_PBE/Zn_q20/Conquest_ion_input b/pseudo-and-pao/GTH_PBE/Zn_q20/Conquest_ion_input
new file mode 100644
index 000000000..ccea41b4b
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Zn_q20/Conquest_ion_input
@@ -0,0 +1,14 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Zn
+%endblock
+
+%block Zn
+Atom.PseudopotentialFile Zn.hgh
+Atom.ZetaForm com
+Atom.Perturbative_Polarised F
+Atom.dE_small_radius 0.04
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE/Zn_q20/Zn.hgh b/pseudo-and-pao/GTH_PBE/Zn_q20/Zn.hgh
new file mode 100644
index 000000000..7a3bd71ae
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Zn_q20/Zn.hgh
@@ -0,0 +1,15 @@
+2 4
+Zn 20.00 0.340000 0.551885 1.243944 0.000000 0.000000
+2
+ 0.243949 -1.347627 12.793131
+ -16.515861
+2
+ 0.239754 -9.721458 8.071144
+ -9.549906
+1
+ 0.208552 -14.193809
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+3 0 2.0 1
+3 1 6.0 1
+3 2 10.0 0
+4 0 2.0 0
diff --git a/pseudo-and-pao/GTH_PBE/Zn_q20/charge.dat b/pseudo-and-pao/GTH_PBE/Zn_q20/charge.dat
new file mode 100644
index 000000000..93cc1e562
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE/Zn_q20/charge.dat
@@ -0,0 +1,1241 @@
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+%endblock
+
+%block Cl
+Atom.PseudopotentialFile Cl.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE_PCC/F_q7/Conquest_ion_input b/pseudo-and-pao/GTH_PBE_PCC/F_q7/Conquest_ion_input
new file mode 100644
index 000000000..f24856d74
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE_PCC/F_q7/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 F
+%endblock
+
+%block F
+Atom.PseudopotentialFile F.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE_PCC/F_q7/F.hgh b/pseudo-and-pao/GTH_PBE_PCC/F_q7/F.hgh
new file mode 100644
index 000000000..98f0059e5
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE_PCC/F_q7/F.hgh
@@ -0,0 +1,10 @@
+1 4
+F 7.00 0.206103 -19.867165 2.793089 0.000000 0.000000
+1
+ 0.195181 23.470473
+0
+ 0.300000
+2
+2 0 2.0 0
+2 1 5.0 0
+ 0.171543 1 193.635582
diff --git a/pseudo-and-pao/GTH_PBE_PCC/N_q5/Conquest_ion_input b/pseudo-and-pao/GTH_PBE_PCC/N_q5/Conquest_ion_input
new file mode 100644
index 000000000..616da6124
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE_PCC/N_q5/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 N
+%endblock
+
+%block N
+Atom.PseudopotentialFile N.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE_PCC/N_q5/N.hgh b/pseudo-and-pao/GTH_PBE_PCC/N_q5/N.hgh
new file mode 100644
index 000000000..73bb0c72a
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE_PCC/N_q5/N.hgh
@@ -0,0 +1,10 @@
+1 4
+N 5.00 0.241796 -10.043285 1.397190 0.000000 0.000000
+1
+ 0.256966 12.968017
+1
+ 0.156855 -0.734530
+2
+2 0 2.0 0
+2 1 3.0 0
+ 0.246115 1 70.686838
diff --git a/pseudo-and-pao/GTH_PBE_PCC/O_q6/Conquest_ion_input b/pseudo-and-pao/GTH_PBE_PCC/O_q6/Conquest_ion_input
new file mode 100644
index 000000000..6ad0f4360
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE_PCC/O_q6/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 O
+%endblock
+
+%block O
+Atom.PseudopotentialFile O.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE_PCC/O_q6/O.hgh b/pseudo-and-pao/GTH_PBE_PCC/O_q6/O.hgh
new file mode 100644
index 000000000..ba2d7e237
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE_PCC/O_q6/O.hgh
@@ -0,0 +1,10 @@
+1 4
+O 6.00 0.260999 -14.151806 1.978295 0.000000 0.000000
+1
+ 0.223083 18.371814
+1
+ 0.268441 0.100036
+2
+2 0 2.0 0
+2 1 4.0 0
+ 0.252338 1 44.010987
diff --git a/pseudo-and-pao/GTH_PBE_PCC/P_q5/Conquest_ion_input b/pseudo-and-pao/GTH_PBE_PCC/P_q5/Conquest_ion_input
new file mode 100644
index 000000000..0ba3f5455
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE_PCC/P_q5/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 P
+%endblock
+
+%block P
+Atom.PseudopotentialFile P.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE_PCC/P_q5/P.hgh b/pseudo-and-pao/GTH_PBE_PCC/P_q5/P.hgh
new file mode 100644
index 000000000..43963ecf3
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE_PCC/P_q5/P.hgh
@@ -0,0 +1,11 @@
+1 4
+P 5.00 0.340000 -1.622583 -0.724121 0.000000 0.000000
+2
+ 0.382089 3.477535 -0.012666
+ 3.474614
+1
+ 0.434110 3.378593
+2
+3 0 2.0 0
+3 1 3.0 0
+ 0.398676 1 57.502259
diff --git a/pseudo-and-pao/GTH_PBE_PCC/README.md b/pseudo-and-pao/GTH_PBE_PCC/README.md
new file mode 100644
index 000000000..bea7b9ca9
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE_PCC/README.md
@@ -0,0 +1,8 @@
+This directory contains GTH/HGH pseudopotentials for the PBE XC functional
+with partial core corrections (also known as non-linear core corrections)
+based on the data distributed with CP2K (which in turn tabulates the results
+in Phys. Rev. B 54, 1703 (1996), Phys. Rev. B 58, 3641 (1998), Theor. Chem.
+Acc. 114, 145 (2005) and J. Chem. Phys. 138, 104109 (2013)).
+
+Note that these are not tested by the CONQUEST developers, and should be treated
+with care. In particular, PAO generation is at present in beta phase.
diff --git a/pseudo-and-pao/GTH_PBE_PCC/S_q6/Conquest_ion_input b/pseudo-and-pao/GTH_PBE_PCC/S_q6/Conquest_ion_input
new file mode 100644
index 000000000..dd5eb751d
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE_PCC/S_q6/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 S
+%endblock
+
+%block S
+Atom.PseudopotentialFile S.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE_PCC/S_q6/S.hgh b/pseudo-and-pao/GTH_PBE_PCC/S_q6/S.hgh
new file mode 100644
index 000000000..34a75398f
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE_PCC/S_q6/S.hgh
@@ -0,0 +1,11 @@
+1 4
+S 6.00 0.330000 1.490428 -0.733139 0.000000 0.000000
+2
+ 0.370457 6.186048 0.000000
+ 2.577608
+1
+ 0.397724 3.891133
+2
+3 0 2.0 0
+3 1 4.0 0
+ 0.386218 1 79.635998
diff --git a/pseudo-and-pao/GTH_PBE_PCC/Si_q4/Conquest_ion_input b/pseudo-and-pao/GTH_PBE_PCC/Si_q4/Conquest_ion_input
new file mode 100644
index 000000000..35912ade0
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE_PCC/Si_q4/Conquest_ion_input
@@ -0,0 +1,12 @@
+General.NumberOfSpecies 1
+General.PSFormat hgh
+
+%block SpeciesLabels
+1 Si
+%endblock
+
+%block Si
+Atom.PseudopotentialFile Si.hgh
+Atom.ZetaForm com
+Atom.Cutoffs en
+%endblock
diff --git a/pseudo-and-pao/GTH_PBE_PCC/Si_q4/Si.hgh b/pseudo-and-pao/GTH_PBE_PCC/Si_q4/Si.hgh
new file mode 100644
index 000000000..348a0e54c
--- /dev/null
+++ b/pseudo-and-pao/GTH_PBE_PCC/Si_q4/Si.hgh
@@ -0,0 +1,11 @@
+1 4
+Si 4.00 0.330000 -0.078460 -0.793782 0.000000 0.000000
+2
+ 0.421795 2.873922 0.025588
+ 2.594581
+1
+ 0.488003 2.479628
+2
+3 0 2.0 0
+3 1 2.0 0
+ 0.442792 1 38.177656
diff --git a/pseudo-and-pao/README.md b/pseudo-and-pao/README.md
index 6dd7768f2..60a007a2d 100644
--- a/pseudo-and-pao/README.md
+++ b/pseudo-and-pao/README.md
@@ -1,10 +1,17 @@
This directory contains sample pseudopotentials and pseudo-atomic
orbital (PAO) basis sets for elements in the [PseudoDojo
-database](http://www.pseudo-dojo.org) (roughly speaking up to 86Rn).
+database](http://www.pseudo-dojo.org) (roughly speaking up to 86Rn)
+in the directories LDA, PBE and PBEsol. It also contains GTH/HGH
+pseudopotentials from the CP2K project in the directories GTH_LDA
+and GTH_PBE.
It also includes the input files you will need for generating basis
sets of your own using the CONQUEST basis generation code. More
-details are found in the documentation directory.
+details are found in the documentation directory. Please note that
+the implementation of the GTH/HGH potentials, and the PAOs associated
+with them, is still at a relatively early stage and has not been
+tested. If you find any issues with these, please report them to the
+developers.
The potentials are available for LDA, PBE and PBEsol
exchange-correlation functionals.
diff --git a/src/H_matrix_module.f90 b/src/H_matrix_module.f90
index 26262c1d9..2b8d8964e 100644
--- a/src/H_matrix_module.f90
+++ b/src/H_matrix_module.f90
@@ -182,8 +182,11 @@ module H_matrix_module
!! Changed matS, matKE, matNL and matNA to be spin_SF dependent
!! 2019/01/31 16:00 nakata
!! Moved dump_matrix(NSmatrix) to sub:get_S_matrix
+ !! 2020/14/11 16:00 LAT
+ !! Add matK, matX dump
!! 2021/07/19 15:46 dave
!! Removed writing out of charge density
+
!! SOURCE
!!
subroutine get_H_matrix(rebuild_KE_NL, fixed_potential, electrons, &
@@ -192,7 +195,7 @@ subroutine get_H_matrix(rebuild_KE_NL, fixed_potential, electrons, &
use datatypes
use numbers
use matrix_data, only: Hrange, Srange
- use mult_module, only: matNL, matKE, matH, &
+ use mult_module, only: matNL, matKE, matH, matK, &
matrix_scale, matrix_sum, &
matrix_product, &
matS, matX, matNAatomf, matNA, &
@@ -217,7 +220,8 @@ subroutine get_H_matrix(rebuild_KE_NL, fixed_potential, electrons, &
area_ops, nspin, nspin_SF, &
spin_factor, blips, &
flag_analytic_blip_int, &
- flag_neutral_atom, min_layer
+ flag_neutral_atom, min_layer,&
+ flag_self_consistent
use functions_on_grid, only: atomfns, H_on_atomfns, &
gridfunctions
use io_module, only: dump_matrix, dump_blips, &
@@ -237,7 +241,7 @@ subroutine get_H_matrix(rebuild_KE_NL, fixed_potential, electrons, &
use global_module, only: flag_exx, exx_niter, exx_siter, exx_alpha
use exx_kernel_default, only: get_X_matrix
use exx_module, only: get_X_params
- use exx_types, only: exx_hgrid, exx_psolver, exx_radius
+ use exx_types, only: exx_hgrid, exx_psolver, exx_radius, exx_store_eris, exx_scheme
use exx_io, only: exx_global_write
!****lat>$
use energy, only: local_ps_energy
@@ -265,6 +269,7 @@ subroutine get_H_matrix(rebuild_KE_NL, fixed_potential, electrons, &
character(len=9), dimension(2) :: print_exxspin
logical :: flag_build_Hatomf, flag_do_SFtransform
+
print_exxspin(1) = 'spin up '
print_exxspin(2) = 'spin down'
@@ -358,37 +363,63 @@ subroutine get_H_matrix(rebuild_KE_NL, fixed_potential, electrons, &
!
!
!****lat<$
- if (flag_exx) then
+ if (flag_exx .and. flag_self_consistent ) then
+ !
+ exx_store_eris = .false.
+ !
! Ugly stuff but for now that's ok. Purpose is to adapt EXX accuracy to
! the SCF covergence: closer to convergence finest is the grid
!
!if (inode==ionode) print*, 'exx_pulay_r0 = ', exx_pulay_r0
- if ( exx_niter < exx_siter ) then
- ! For first H building use pure DFT. To be improved for Hartree-Fock
+ !
+ !
+ if ( exx_niter == 1 .and. exx_scheme /= 3 ) then
+ !
if (inode == ionode .and. iprint_exx > 3) &
- write (io_lun, *) 'EXX: first guess from DFT'
+ write (io_lun, *) 'EXX: get_X_params'
+ !
+ call get_X_params(backtrace_level)
!
- else
+ ! For first H building use pure DFT since we need K to get X
+ ! (X is the exchange matrix)
!
if (inode == ionode .and. iprint_exx > 3) &
- write (io_lun, *) 'EXX: setting get_X_matrix'
+ write (io_lun, *) 'EXX: first guess from DFT'
+ !
+ else if ( exx_niter == 1 .and. exx_scheme == 3 ) then
+ ! ! exx_scheme = 3 is for computing and storing ERIs
+ ! (faster than all the other methods but requires storage)
+ !
call get_X_params(backtrace_level)
-
- call exx_global_write()
!
- !if (inode == ionode .and. iprint_exx > 3) &
- !write (io_lun, *) 'EXX: doing get_X_matrix'
+ exx_store_eris = .true.
+ !
+ ! first call to compute and store ERIs (no need K here)
do spin = 1, nspin
if (inode == ionode .and. iprint_exx > 3) &
- write (io_lun, *) 'EXX: doing get_X_matrix: ', print_exxspin(spin)
- call get_X_matrix(spin,backtrace_level)
+ write (io_lun, *) 'EXX: compute and store ERIs ', print_exxspin(spin)
+ call get_X_matrix(spin, exx_scheme, exx_store_eris, exx_niter, exx_siter, backtrace_level)
+ end do
+ !
+ else if ( exx_niter > exx_siter ) then
+ !
+ if (inode == ionode .and. iprint_exx > 2) &
+ write (io_lun, *) 'EXX: get_X_matrix'
+ !call get_X_params(backtrace_level)
+ !
+ !call exx_global_write()
+ !
+ do spin = 1, nspin
+ !if (inode == ionode .and. iprint_exx > 3) &
+ !write (io_lun, *) 'EXX: doing get_X_matrix: ', print_exxspin(spin)
+ call get_X_matrix(spin, exx_scheme, exx_store_eris, exx_niter, exx_siter, backtrace_level)
end do
!
!if (inode == ionode .and. iprint_exx > 3) &
!write (io_lun, *) 'EXX: done get_X_matrix'
do spin = 1, nspin
- if (inode == ionode .and. iprint_exx > 3) &
- write (io_lun, *) 'EXX: done get_X_matrix: ', print_exxspin(spin)
+ !if (inode == ionode .and. iprint_exx > 3) &
+ !write (io_lun, *) 'EXX: done get_X_matrix: ', print_exxspin(spin)
call matrix_sum(one, matHatomf(spin),-exx_alpha*half, matXatomf(spin))
end do
!
@@ -396,6 +427,10 @@ subroutine get_H_matrix(rebuild_KE_NL, fixed_potential, electrons, &
!
exx_niter = exx_niter + 1
!
+ !if ( exx_niter > 2 ) then
+ ! stop
+ !end if
+ !
end if
!****lat>$
endif ! flag_build_Hatomf
@@ -429,6 +464,8 @@ subroutine get_H_matrix(rebuild_KE_NL, fixed_potential, electrons, &
if (iprint_ops > 3) then
if (nspin == 1) then
call dump_matrix("NH", matH(1), inode)
+ call dump_matrix("NK", matK(1), inode)
+ call dump_matrix("NX", matX(1), inode)
else
call dump_matrix("NH_up", matH(1), inode)
call dump_matrix("NH_dn", matH(2), inode)
diff --git a/src/Makefile b/src/Makefile
index 6f3509b23..88e75b5b8 100644
--- a/src/Makefile
+++ b/src/Makefile
@@ -102,7 +102,7 @@ initial_read_module.o:initial_read_module.f90 datestamp.o
# for GCC13, possibly only on Mac. It doesn't need any other
# compiler flags (libraries or communications) so should be OK like this
pseudo_tm_info.o:pseudo_tm_info.f90
- $(FC) -c $<
+ $(FC) $(XC_COMPFLAGS) -c $<
#datestamp.f90: $(COMMENT)
# $(ECHOSTR) "module datestamp\n" > datestamp.f90
diff --git a/src/PAO_grid_transform_module.f90 b/src/PAO_grid_transform_module.f90
index 813aa6f5b..0d95148cc 100644
--- a/src/PAO_grid_transform_module.f90
+++ b/src/PAO_grid_transform_module.f90
@@ -96,6 +96,8 @@ module PAO_grid_transform_module
!! 2023/08/23 11:20 tkoskela
!! Added OMP threading, merged single_PAO_to_grad and single_PAO_to_grid into
!! single subroutine PAO_or_gradPAO_to_grid
+!! 2023/11/15 11:20 lionel
+!! Added optional argument sys to evaluate_pao interface
!! SOURCE
!!
subroutine PAO_or_gradPAO_to_grid(pao_fns, evaluate, direction)
@@ -143,11 +145,12 @@ subroutine PAO_or_gradPAO_to_grid(pao_fns, evaluate, direction)
! Interface to return a value val given arguments
! direction,species,l,acz,m,x,y,z. Implemented by
! evaluate_pao() and pao_elem_derivative_2().
- subroutine evaluate(direction,species,l,acz,m,x,y,z,val)
+ subroutine evaluate(direction,species,l,acz,m,x,y,z,val,sys)
use datatypes, only: double
integer, intent(in) :: species,l,acz,m
integer, intent(in) :: direction
real(kind=double), intent(in) :: x,y,z
+ logical, intent(in), optional :: sys
real(kind=double), intent(out) :: val
end subroutine evaluate
end interface
@@ -183,7 +186,7 @@ end subroutine evaluate
! loop arround grid points in the domain, and for each
! point, get the PAO values
-
+ !
! Note: Using OpenMP in this loop requires some redesign because there is a loop
! carrier dependency in next_offset_position.
blocks_loop: do iblock = 1, domain%groups_on_node ! primary set of blocks
diff --git a/src/ScalapackFormat.f90 b/src/ScalapackFormat.f90
index 620716c4e..0ecfe9407 100644
--- a/src/ScalapackFormat.f90
+++ b/src/ScalapackFormat.f90
@@ -283,8 +283,6 @@ subroutine allocate_arrays (nkp)
blocks_c = ceiling((real(matrix_size,double)-RD_ERR)/block_size_c)
if(blocks_r .ne. blocks_c) call cq_abort("ScalapackFormat: blocks_r /= blocks_c")
matrix_size_padH = blocks_r * block_size_r
- call check_block_parameters(flag_err)
- if(flag_err) call cq_abort("ScalapacFormat: check_block_parameter ",blocks_c, proc_cols)
else
blocks_r = (matrix_size/block_size_r)
blocks_c = (matrix_size/block_size_c)
@@ -321,17 +319,6 @@ subroutine allocate_arrays (nkp)
call stop_timer(tmr_std_allocation)
return
1 format(10x,'AllocArr: block sizes are: ',2i5)
- contains
- subroutine check_block_parameters(flag_err)
- implicit none
- logical, intent(out):: flag_err
- flag_err=.false.
- if(blocks_c < blocks_r) flag_err = .true.
- if(blocks_c < proc_cols) flag_err = .true.
- !the next one should not be necessary
- if(blocks_r < proc_rows) flag_err = .true.
- return
- end subroutine check_block_parameters
end subroutine allocate_arrays
!!***
diff --git a/src/SelfCon_module.f90 b/src/SelfCon_module.f90
index ca9bfbbda..f78558a19 100644
--- a/src/SelfCon_module.f90
+++ b/src/SelfCon_module.f90
@@ -1764,6 +1764,10 @@ end subroutine get_new_rho
!! - Introduced spin-up/down atomic charge
!! 2019/11/21 10:51 dave
!! - Tweak to use gsum for 2D array for charge
+ !! 2024/09/03 18:00 nakata
+ !! - changed matS and matK to matSatomf and MatKatomf for MSSFs
+ !! (so Srange is changed to aSa_range),
+ !! then spin_SF is no longer used, because matSatomf is not spin-dependent
subroutine get_atomic_charge()
use datatypes
@@ -1771,8 +1775,8 @@ subroutine get_atomic_charge()
use global_module, only: ni_in_cell, area_SC, nspin, spin_factor, &
flag_SpinDependentSF
use primary_module, only: bundle
- use matrix_data, only: Srange
- use mult_module, only: matK, matS, atom_trace, matrix_sum, &
+ use matrix_data, only: aSa_range
+ use mult_module, only: matKatomf, matSatomf, atom_trace, matrix_sum, &
allocate_temp_matrix, free_temp_matrix
use atoms, only: atoms_on_node
use GenComms, only: gsum, inode, ionode, cq_abort
@@ -1782,7 +1786,7 @@ subroutine get_atomic_charge()
implicit none
! Local variables
- integer :: chun, stat, n,l, glob_ind, spin, spin_SF
+ integer :: chun, stat, n,l, glob_ind, spin
integer, dimension(nspin) :: temp_mat
real(double), dimension(:,:), allocatable :: charge, node_charge
@@ -1803,12 +1807,10 @@ subroutine get_atomic_charge()
! automatically called on each node
node_charge = zero
charge = zero
- spin_SF = 1
do spin = 1, nspin
- if (flag_SpinDependentSF) spin_SF = spin
- temp_mat(spin) = allocate_temp_matrix(Srange, 0)
- call matrix_sum(zero, temp_mat(spin), one, matK(spin))
- call atom_trace(temp_mat(spin), matS(spin_SF), l, node_charge(:,spin))
+ temp_mat(spin) = allocate_temp_matrix(aSa_range, 0)
+ call matrix_sum(zero, temp_mat(spin), one, matKatomf(spin))
+ call atom_trace(temp_mat(spin), matSatomf, l, node_charge(:,spin))
! sum from the node_charge into the total charge array
do n = 1, l
glob_ind = atoms_on_node(n, inode)
diff --git a/src/XC_LibXC_v4_module.f90 b/src/XC_LibXC_v4_module.f90
index c5c6db2d1..88040ea5f 100644
--- a/src/XC_LibXC_v4_module.f90
+++ b/src/XC_LibXC_v4_module.f90
@@ -437,7 +437,7 @@ subroutine get_xc_potential(density, xc_potential, xc_epsilon, &
!
case (functional_hyb_pbe0)
!
- if ( exx_niter < exx_siter ) then
+ if ( exx_niter <= exx_siter ) then
exx_tmp = one
else
exx_tmp = one - exx_alpha
@@ -455,7 +455,7 @@ subroutine get_xc_potential(density, xc_potential, xc_epsilon, &
case (functional_hartree_fock)
! ****
! not optimal but experimental
- if (exx_niter < exx_siter) then
+ if (exx_niter <= exx_siter) then
! for the first call of get_H_matrix using Hartree-Fock method
! to get something not to much stupid ; use pure exchange functional
! in near futur such as Xalpha
@@ -2670,7 +2670,7 @@ subroutine get_xc_energy(density, xc_energy, size)
!
case (functional_hyb_pbe0)
!
- if ( exx_niter < exx_siter ) then
+ if ( exx_niter <= exx_siter ) then
exx_tmp = one
else
exx_tmp = one - exx_alpha
@@ -2682,7 +2682,7 @@ subroutine get_xc_energy(density, xc_energy, size)
case (functional_hartree_fock)
! ****
! not optimal but experimental
- if (exx_niter < exx_siter) then
+ if (exx_niter <= exx_siter) then
! for the first call of get_H_matrix using Hartree-Fock method
! to get something not to much stupid ; use pure exchange functional
! in near futur such as Xalpha
diff --git a/src/XC_LibXC_v5_module.f90 b/src/XC_LibXC_v5_module.f90
index d2a6ce59a..ec61a5553 100644
--- a/src/XC_LibXC_v5_module.f90
+++ b/src/XC_LibXC_v5_module.f90
@@ -441,7 +441,7 @@ subroutine get_xc_potential(density, xc_potential, xc_epsilon, &
!
case (functional_hyb_pbe0)
!
- if ( exx_niter < exx_siter ) then
+ if ( exx_niter <= exx_siter ) then
exx_tmp = one
else
exx_tmp = one - exx_alpha
@@ -459,7 +459,7 @@ subroutine get_xc_potential(density, xc_potential, xc_epsilon, &
case (functional_hartree_fock)
! ****
! not optimal but experimental
- if (exx_niter < exx_siter) then
+ if (exx_niter <= exx_siter) then
! for the first call of get_H_matrix using Hartree-Fock method
! to get something not to much stupid ; use pure exchange functional
! in near futur such as Xalpha
@@ -2680,7 +2680,7 @@ subroutine get_xc_energy(density, xc_energy, size)
!
case (functional_hyb_pbe0)
!
- if ( exx_niter < exx_siter ) then
+ if ( exx_niter <= exx_siter ) then
exx_tmp = one
else
exx_tmp = one - exx_alpha
@@ -2692,7 +2692,7 @@ subroutine get_xc_energy(density, xc_energy, size)
case (functional_hartree_fock)
! ****
! not optimal but experimental
- if (exx_niter < exx_siter) then
+ if (exx_niter <= exx_siter) then
! for the first call of get_H_matrix using Hartree-Fock method
! to get something not to much stupid ; use pure exchange functional
! in near futur such as Xalpha
diff --git a/src/build_PAO_matrices.module.f90 b/src/build_PAO_matrices.module.f90
index a888c9f05..593ea7943 100644
--- a/src/build_PAO_matrices.module.f90
+++ b/src/build_PAO_matrices.module.f90
@@ -457,6 +457,7 @@ subroutine assemble_deriv_2(direction,range,matA,flag)
!use angular_coeff_routines, ONLY: numerical_ol_gradient
use matrix_data, ONLY: mat, halo
use mult_module, ONLY: matrix_scale, store_matrix_value_pos, matrix_pos
+ use pseudo_tm_info, ONLY: pseudo
implicit none
@@ -501,6 +502,8 @@ subroutine assemble_deriv_2(direction,range,matA,flag)
neigh_global_part = BCS_parts%lab_cell(mat(part,range)%i_part(ist))
neigh_global_num = id_glob(parts%icell_beg(neigh_global_part)+mat(part,range)%i_seq(ist)-1)
neigh_species = species_glob(neigh_global_num)
+ ! This avoids a problem when using only a local potential
+ if(flag==3.and.pseudo(neigh_species)%n_pjnl==0) cycle
! Where to put the result - this will become matrix_pos
wheremat = matrix_pos(matA,iprim,halo(range)%i_halo(gcspart))
! Now loop over support functions and PAOs and call routine
diff --git a/src/control.f90 b/src/control.f90
index 505d0b5d0..36fbd69af 100644
--- a/src/control.f90
+++ b/src/control.f90
@@ -139,6 +139,8 @@ module control
!! coordinates.
!! 2022/09/16 16:51 dave
!! Added SQNM options for ion/cell optimisation (only partly complete)
+!! 2024/11/04 Augustin Lu
+!! Added stress to write_extxyz call
!! SOURCE
!!
subroutine control_run(fixed_potential, vary_mu, total_energy)
@@ -147,7 +149,7 @@ subroutine control_run(fixed_potential, vary_mu, total_energy)
use dimens, only: r_core_squared, r_h
use GenComms, only: my_barrier, cq_abort, cq_warn
use pseudopotential_data, only: set_pseudopotential
- use force_module, only: tot_force
+ use force_module, only: tot_force, stress
use minimise, only: get_E_and_F
use global_module, only: runtype, flag_self_consistent, &
flag_out_wf, flag_write_DOS, wf_self_con, &
@@ -188,7 +190,7 @@ subroutine control_run(fixed_potential, vary_mu, total_energy)
endif
call get_E_and_F(fixed_potential, vary_mu, total_energy,&
flag_ff, flag_wf, level=backtrace_level)
- if (flag_write_extxyz) call write_extxyz('trajectory.xyz', total_energy, tot_force)
+ if (flag_write_extxyz) call write_extxyz('trajectory.xyz', total_energy, tot_force,stress)
!
else if ( leqi(runtype, 'cg') ) then
if (flag_opt_cell) then
@@ -320,7 +322,7 @@ subroutine cg_run(fixed_potential, vary_mu, total_energy)
safemin2, cg_line_min, safe, adapt_backtrack, backtrack
use GenComms, only: gsum, myid, inode, ionode
use GenBlas, only: dot
- use force_module, only: tot_force
+ use force_module, only: tot_force, stress
use io_module, only: write_atomic_positions, pdb_template, &
check_stop, write_xsf, write_extxyz, &
print_atomic_positions, return_prefix
@@ -496,7 +498,7 @@ subroutine cg_run(fixed_potential, vary_mu, total_energy)
end if
call write_atomic_positions("UpdatedAtoms.dat", trim(pdb_template))
if (flag_write_xsf) call write_xsf('trajectory.xsf', iter)
- if (flag_write_extxyz .and. mod(iter,XYZfreq) == 0) call write_extxyz('trajectory.xyz', energy1, tot_force)
+ if (flag_write_extxyz .and. mod(iter,XYZfreq) == 0) call write_extxyz('trajectory.xyz', energy1, tot_force, stress)
! Analyse forces
g0 = dot(length, tot_force, 1, tot_force, 1)
call get_maxf(max)
@@ -1558,7 +1560,7 @@ subroutine lbfgs(fixed_potential, vary_mu, total_energy)
use move_atoms, only: updateL, updateLorK, updateSFcoeff
use GenComms, only: gsum, myid, inode, ionode, gcopy, my_barrier
use GenBlas, only: dot
- use force_module, only: tot_force
+ use force_module, only: tot_force, stress
use io_module, only: write_atomic_positions, pdb_template, &
check_stop, write_xsf, write_extxyz
use memory_module, only: reg_alloc_mem, reg_dealloc_mem, type_dbl
@@ -1718,7 +1720,7 @@ subroutine lbfgs(fixed_potential, vary_mu, total_energy)
! Add call to write_atomic_positions and write_xsf (2020/01/17: smujahed)
call write_atomic_positions("UpdatedAtoms.dat", trim(pdb_template))
if (flag_write_xsf) call write_xsf('trajectory.xsf', iter)
- if (flag_write_extxyz .and. mod(iter,XYZfreq) == 0) call write_extxyz('trajectory.xyz', energy1, tot_force)
+ if (flag_write_extxyz .and. mod(iter,XYZfreq) == 0) call write_extxyz('trajectory.xyz', energy1, tot_force, stress)
! Build q
do i=iter, iter_low, -1
! Indexing
@@ -1848,7 +1850,7 @@ subroutine sqnm(fixed_potential, vary_mu, total_energy)
use move_atoms, only: single_step, backtrack_linemin
use GenComms, only: myid, inode, ionode
use GenBlas, only: dot, syev
- use force_module, only: tot_force
+ use force_module, only: tot_force, stress
use io_module, only: write_atomic_positions, pdb_template, write_extxyz, &
check_stop, write_xsf, print_atomic_positions, return_prefix
use memory_module, only: reg_alloc_mem, reg_dealloc_mem, type_dbl
@@ -2028,7 +2030,7 @@ subroutine sqnm(fixed_potential, vary_mu, total_energy)
! Add call to write_atomic_positions and write_xsf (2020/01/17: smujahed)
call write_atomic_positions("UpdatedAtoms.dat", trim(pdb_template))
if (flag_write_xsf) call write_xsf('trajectory.xsf', iter)
- if (flag_write_extxyz .and. mod(iter,XYZfreq) == 0) call write_extxyz('trajectory.xyz', energy1, tot_force)
+ if (flag_write_extxyz .and. mod(iter,XYZfreq) == 0) call write_extxyz('trajectory.xyz', energy1, tot_force, stress)
! Build significant subspace
Sij = zero
omega = zero
@@ -2438,7 +2440,7 @@ subroutine cell_sqnm(fixed_potential, vary_mu, total_energy)
! Add call to write_atomic_positions and write_xsf (2020/01/17: smujahed)
call write_atomic_positions("UpdatedAtoms.dat", trim(pdb_template))
if (flag_write_xsf) call write_xsf('trajectory.xsf', iter)
- if (flag_write_extxyz .and. mod(iter,XYZfreq) == 0) call write_extxyz('trajectory.xyz', energy1, tot_force)
+ if (flag_write_extxyz .and. mod(iter,XYZfreq) == 0) call write_extxyz('trajectory.xyz', energy1, tot_force, stress)
! Build significant subspace
Sij = zero
omega = zero
@@ -2888,7 +2890,7 @@ subroutine full_sqnm(fixed_potential, vary_mu, total_energy)
! Add call to write_atomic_positions and write_xsf (2020/01/17: smujahed)
call write_atomic_positions("UpdatedAtoms.dat", trim(pdb_template))
if (flag_write_xsf) call write_xsf('trajectory.xsf', iter)
- if (flag_write_extxyz .and. mod(iter,XYZfreq) == 0) call write_extxyz('trajectory.xyz', energy1, tot_force)
+ if (flag_write_extxyz .and. mod(iter,XYZfreq) == 0) call write_extxyz('trajectory.xyz', energy1, tot_force, stress)
! Build significant subspace
Sij = zero
omega = zero
@@ -3288,7 +3290,7 @@ subroutine cell_cg_run(fixed_potential, vary_mu, total_energy)
rcellx, d_units(dist_units), rcelly, d_units(dist_units), rcellz, d_units(dist_units)
end if
call write_atomic_positions("UpdatedAtoms.dat", trim(pdb_template))
- if (flag_write_extxyz .and. mod(iter,XYZfreq) == 0) call write_extxyz('trajectory.xyz', energy1, tot_force)
+ if (flag_write_extxyz .and. mod(iter,XYZfreq) == 0) call write_extxyz('trajectory.xyz', energy1, tot_force, stress)
! Analyse Stresses and energies
dH = enthalpy1 - enthalpy0
volume = rcellx*rcelly*rcellz
@@ -4356,7 +4358,7 @@ subroutine full_cg_run_single_vector(fixed_potential, vary_mu, total_energy)
end if
call write_atomic_positions("UpdatedAtoms.dat", trim(pdb_template))
if (flag_write_xsf) call write_xsf('trajectory.xsf', iter)
- if (flag_write_extxyz .and. mod(iter,XYZfreq) == 0) call write_extxyz('trajectory.xyz', energy1, tot_force)
+ if (flag_write_extxyz .and. mod(iter,XYZfreq) == 0) call write_extxyz('trajectory.xyz', energy1, tot_force, stress)
! Analyse forces and stress
g0 = dot(length-3, tot_force, 1, tot_force, 1)
diff --git a/src/dimens_module.f90 b/src/dimens_module.f90
index 80b161a72..467488d91 100644
--- a/src/dimens_module.f90
+++ b/src/dimens_module.f90
@@ -55,7 +55,7 @@ module dimens
real(double) :: r_super_x, r_super_y, r_super_z, volume
real(double) :: r_super_x_squared, r_super_y_squared, r_super_z_squared
- real(double) :: r_s, r_h, r_c, r_nl, r_core_squared, r_dft_d2, r_exx
+ real(double) :: r_s, r_h, r_c, r_nl, r_core_squared, r_dft_d2, r_exx, r_exxs
real(double) :: r_s_atomf, r_h_atomf, r_MS, r_LD
real(double) :: grid_point_volume, one_over_grid_point_volume
real(double) :: support_grid_volume
@@ -161,6 +161,8 @@ module dimens
!! flag_MDold was removed.
!! 2019/12/02 15:17 dave
!! Added checks to round RadiusAtomf and RadiusSupport to safe value (including grid points)
+!! 2024/07/18 14:18 lionel
+!! Check consistency of Xrange wrt r_exx read from input
!! SOURCE
!!
subroutine set_dimensions(inode, ionode,HNL_fac,non_local, n_species, non_local_species, core_radius)
@@ -275,8 +277,8 @@ subroutine set_dimensions(inode, ionode,HNL_fac,non_local, n_species, non_local_
end do
if(non_local.and.(inode==ionode).and.iprint_init>0) then
write(io_lun,2) r_core
-2 format(8x,'This calculation includes non-local pseudopotentials,'/&
- 9x,'with a maximum core radius of ',f15.8)
+2 format(/4x,'This calculation includes non-local pseudopotentials,'/&
+ 4x,'with a maximum core radius of ',f15.8)
end if
if (r_core-r_h>1e-4_double) then
call cq_abort('set_dimens: r_core > r_support',r_core,r_h)
@@ -311,24 +313,25 @@ subroutine set_dimensions(inode, ionode,HNL_fac,non_local, n_species, non_local_
! **< lat >** don't touch
if(flag_exx) then
- if( rcut(Xrange) > rcut(Hrange) ) then
- rcut(Hrange) = rcut(Xrange)
- rcut(SXrange) = rcut(Hrange)
- !
- else if ( rcut(Xrange) <= zero ) then
+ if ( r_exx <= zero ) then
rcut(Xrange) = rcut(Hrange)
- rcut(SXrange) = rcut(Hrange)
- !
+ !rcut(SXrange) = rcut(Hrange)
+ r_exx = rcut(Xrange)/2_double
else
rcut(Xrange) = two*r_exx
- rcut(SXrange) = two*r_exx
- !
- endif
+ end if
+ if ( r_exxs <= zero ) then
+ !rcut(Xrange) = rcut(Hrange)
+ rcut(SXrange) = rcut(Hrange)
+ r_exxs = rcut(SXrange)/2_double
+ else
+ rcut(SXrange) = two*r_exxs
+ end if
else
rcut(Xrange) = two
rcut(SXrange) = two
end if
-
+
! New 16:25, 2014/08/29 **< lat >**
!rcut(Hrange) = (two*(r_h + r_nl))
!rcut(Hrange) = (two*(r_h+HNL_fac*r_core))
diff --git a/src/exx.obj b/src/exx.obj
index 253e8e365..c95e6b21b 100644
--- a/src/exx.obj
+++ b/src/exx.obj
@@ -25,6 +25,13 @@ EXX_OBJS= exx_module.o \
exx_types.o \
exx_memory.o \
exx_io.o \
- exx_evalpao.o
+ exx_evalpao.o \
+ exx_poisson.o \
+ exx_evalgto.o \
+ exx_erigto.o \
+ gto_format.o \
+ read_gto_info.o
+# libint_module.o \
+# libint_f.o
# fft_fftw3.o
-
+# libint_f.o \
diff --git a/src/exx_erigto.f90 b/src/exx_erigto.f90
new file mode 100644
index 000000000..0386420b4
--- /dev/null
+++ b/src/exx_erigto.f90
@@ -0,0 +1,852 @@
+module exx_erigto
+
+ use datatypes
+ use numbers, ONLY: pi,zero,one,two,four,half,three_halves
+
+
+ USE ISO_C_BINDING, ONLY: C_DOUBLE, C_F_POINTER, C_F_PROCPOINTER, C_NULL_PTR
+ !use libint_f, only: libint_t, libint2_static_init, libint2_static_cleanup,&
+ ! libint2_build, libint2_max_am_eri, libint2_cleanup_eri, &
+ ! compute_eri_f, libint2_init_eri, print_eri
+
+
+ implicit none
+
+ !TYPE(libint_t), DIMENSION(1) :: erieval
+
+ !INTEGER, PARAMETER :: dp = C_DOUBLE
+
+
+ ! The equations herein are based upon
+ ! 'Gaussian Expansion Methods for Molecular Orbitals' H. Taketa,
+ ! S. Huzinaga, and K. O-ohata. H. Phys. Soc. Japan, 21, 2313, 1966.
+ !
+contains
+ ! Functions in this module:
+ ! eri_gto: Compute the coulomb repulsion between four primitive gaussian functions
+ ! overlap_gto: Compute the overlap between two primitive gaussians
+ !
+ function eri_gto_hoh( &
+ xa, ya, za, norma, la, ma, na, alphaa, &
+ xb, yb, zb, normb, lb, mb, nb, alphab, &
+ xc, yc, zc, normc, lc, mc, nc, alphac, &
+ xd, yd, zd, normd, ld, md, nd, alphad)
+ ! use functions: dist2, product_center_1D, Fgamma
+ ! use subroutines: B_array
+ implicit none
+ ! Funtion
+ real(double) :: eri_gto_hoh
+
+ ! Parameters
+ integer, parameter :: MAXLEN=25
+
+ ! Arguments
+ real(double), intent(in) :: xa,ya,za,norma,alphaa,xb,yb,zb,normb,alphab
+ real(double), intent(in) :: xc,yc,zc,normc,alphac,xd,yd,zd,normd,alphad
+ integer, intent(in) :: la,ma,na,lb,mb,nb,lc,mc,nc,ld,md,nd
+
+ ! Local variables
+ real(double) :: rab2,rcd2,rpq2
+ real(double) :: xp,yp,zp,xq,yq,zq
+ real(double) :: gamma1,gamma2,delta,sum,xval
+
+ real(double) :: Bx(0:MAXLEN-1), By(0:MAXLEN-1), Bz(0:MAXLEN-1)
+ integer :: i,j,k
+
+
+ Bx = zero ; By = zero ; Bz = zero
+
+ rab2 = dist2(xa,ya,za,xb,yb,zb)
+ rcd2 = dist2(xc,yc,zc,xd,yd,zd)
+
+ xp = product_center_1D(alphaa,xa,alphab,xb)
+ yp = product_center_1D(alphaa,ya,alphab,yb)
+ zp = product_center_1D(alphaa,za,alphab,zb)
+ xq = product_center_1D(alphac,xc,alphad,xd)
+ yq = product_center_1D(alphac,yc,alphad,yd)
+ zq = product_center_1D(alphac,zc,alphad,zd)
+
+ rpq2 = dist2(xp,yp,zp,xq,yq,zq)
+
+ gamma1 = alphaa+alphab
+ gamma2 = alphac+alphad
+
+ delta = (one/gamma1+one/gamma2)/four
+
+ call B_array(la+lb+lc+ld+1,Bx, &
+ la,lb,lc,ld,xp,xa,xb,xq,xc,xd,gamma1,gamma2,delta)
+ call B_array(ma+mb+mc+md+1,By, &
+ ma,mb,mc,md,yp,ya,yb,yq,yc,yd,gamma1,gamma2,delta)
+ call B_array(na+nb+nc+nd+1,Bz, &
+ na,nb,nc,nd,zp,za,zb,zq,zc,zd,gamma1,gamma2,delta)
+
+ sum = zero
+ do i = 0,la+lb+lc+ld
+ do j = 0, ma+mb+mc+md
+ do k = 0, na+nb+nc+nd
+ xval = float(i+j+k) ! cast to double
+ sum = sum + &
+ Bx(i)*By(j)*Bz(k) &
+ *Fgamma(xval,0.25d0*rpq2/delta)
+ !print*, Bx(i), By(j), Bz(k),Fgamma(xval,0.25d0*rpq2/delta)
+ enddo
+ enddo
+ enddo
+
+ !print*, 'sum =', sum
+
+ eri_gto_hoh = two*pi**2.5d0 &
+ /(gamma1*gamma2*sqrt(gamma1+gamma2)) &
+ *exp(-alphaa*alphab*rab2/gamma1) &
+ *exp(-alphac*alphad*rcd2/gamma2) &
+ *sum*norma*normb*normc*normd
+
+ return
+ end function eri_gto_hoh
+ !
+ function overlap_gto(alpha1,l1,m1,n1,x1,y1,z1, &
+ alpha2,l2,m2,n2,x2,y2,z2)
+ ! Note: this function does multiply by the normalization constant
+ ! Use functions: product_center_1D,dist2,overlap1D
+ implicit none
+ ! Function
+ real(double) :: overlap_gto
+ ! Arguments
+ real(double), intent(in) :: alpha1,x1,y1,z1,alpha2,x2,y2,z2
+ integer, intent(in) :: l1,m1,n1,l2,m2,n2
+ ! Local variables
+ real(double) :: rab2,gamma,xp,yp,zp,factor,wx,wy,wz
+
+ rab2 = dist2(x1,y1,z1,x2,y2,z2)
+
+ gamma = alpha1+alpha2
+ xp = product_center_1D(alpha1,x1,alpha2,x2)
+ yp = product_center_1D(alpha1,y1,alpha2,y2)
+ zp = product_center_1D(alpha1,z1,alpha2,z2)
+
+ factor = ((pi/gamma)**1.5d0)*exp(-alpha1*alpha2*rab2/gamma)
+
+ wx = overlap1D(l1,l2,xp-x1,xp-x2,gamma)
+ wy = overlap1D(m1,m2,yp-y1,yp-y2,gamma)
+ wz = overlap1D(n1,n2,zp-z1,zp-z2,gamma)
+ overlap_gto = factor*wx*wy*wz;
+ return
+ end function overlap_gto
+ !
+ function norm_gto(alpha,l,m,n)
+ ! Compute the norm of any Cartesian Gaussian function
+ implicit none
+ ! Function
+ real(double) :: norm_gto
+ ! Arguments
+ real(double), intent(in) :: alpha
+ integer, intent(in) :: l,m,n
+ ! Local variables
+ real(double) :: numo,deno
+
+ numo = two**(two*(l+m+n)+1.5d0) &
+ *alpha**((l+m+n)+1.5d0)
+ deno = fact2(2*l-1) &
+ *fact2(2*m-1) &
+ *fact2(2*n-1) &
+ *pi**1.5d0
+ norm_gto = sqrt(numo/deno)
+ return
+ end function norm_gto
+ !
+ function overlap1D(l1,l2,xap,xbp,gamma)
+ ! Use functions: binomial_prefactor,fact2
+ implicit none
+ ! Function
+ real(double) :: overlap1D
+ ! Arguments
+ integer, intent(in) :: l1,l2
+ real(double), intent(in) :: xap,xbp,gamma
+ ! Local variables
+ integer :: i
+ real(double) :: sum
+ sum = zero
+
+ do i=0, int(half*(l1+l2))
+ sum = sum + &
+ binomial_prefactor(2*i,l1,l2,xap,xbp)* &
+ fact2(2*i-1)/((2*gamma)**i)
+ enddo
+ overlap1D = sum
+ return
+ end function overlap1D
+ !
+ function dist2(xa,ya,za,xb,yb,zb)
+
+ implicit none
+ ! Function
+ real(double) :: dist2
+ ! Arguments
+ real(double), intent(in) :: xa,ya,za,xb,yb,zb
+ ! Local variables
+ real(double) :: dx,dy,dz
+
+ dx = xa-xb
+ dy = ya-yb
+ dz = za-zb
+ dist2 = dx*dx+dy*dy+dz*dz
+ return
+ end function dist2
+ !
+ function product_center_1D(alphaa,xa,alphab,xb)
+
+ implicit none
+ real(double) :: product_center_1D
+ real(double), intent(in) :: alphaa,xa,alphab,xb
+
+ product_center_1D = (alphaa*xa+alphab*xb)/(alphaa+alphab)
+ return
+ end function product_center_1D
+ !
+ function Fgamma(a,x)
+ ! use function: gammap
+ implicit none
+ real(double) :: a,x
+ real(double) :: Fgamma,val
+
+ if (x .lt. 0.00001d0) x = 0.000001d0
+ val = gammp(a+half,x)
+ Fgamma = half*(x**(-a-half))*val
+ return
+ end function Fgamma
+ !
+ subroutine B_array(n,barry,l1,l2,l3,l4, &
+ p,a,b,q,c,d,g1,g2,delta)
+ ! use functions: barry, b_term
+ implicit none
+ ! Arguments
+ integer, intent(in) :: n,l1,l2,l3,l4
+ real(double), intent(in) :: p,a,b,q,c,d,g1,g2,delta
+ real(double), intent(inout) :: barry(0:n-1)
+ ! Local variables
+ integer ::i,i1,i2,j1,j2,k,index
+
+ barry = zero
+ !do i = 0, n-1
+ ! barry(i) = zero
+ !enddo
+
+ do i1=0, l1+l2
+ do i2=0, l3+l4
+ do j1=0, i1/2
+ do j2=0, i2/2
+ do k=0, (i1+i2)/2-j1-j2
+ index = i1+i2-2*(j1+j2)-k
+ barry(index) = barry(index) &
+ + b_term(i1,i2,j1,j2,k,l1,l2,l3,l4, &
+ p,a,b,q,c,d,g1,g2,delta)
+ enddo
+ enddo
+ enddo
+ enddo
+ enddo
+ return
+ end subroutine B_array
+ !
+ function b_term(i1,i2,j1,j2,k,l1,l2,l3,l4, &
+ p,a,b,q,c,d,g1,g2,delta)
+ ! use functions: fB, fact_ratio2
+ implicit none
+ ! Function
+ real(double) :: b_term
+ ! Arguments
+ integer, intent(in) :: i1,i2,j1,j2,k,l1,l2,l3,l4
+ real(double), intent(in) :: p,a,b,q,c,d,g1,g2,delta
+
+ !real*8 fB
+ !integer fact_ratio2
+
+ b_term = fB(i1,l1,l2,p,a,b,j1,g1) &
+ *((-1)**i2)*fB(i2,l3,l4,q,c,d,j2,g2) &
+ *((-1)**k)*fact_ratio2(i1+i2-2*(j1+j2),k) &
+ *(q-p)**(i1+i2-2*(j1+j2)-2*k) &
+ /(delta)**(i1+i2-2*(j1+j2)-k)
+
+ return
+ end function b_term
+ !
+ function fB(i,l1,l2,px,ax,bx,ir,g)
+ ! use functions: binomial_prefactor, Bfunc
+ implicit none
+ real(double) :: fB
+ real(double), intent(in) :: px,ax,bx,g
+ integer, intent(in) :: i,l1,l2,ir
+
+ fB = binomial_prefactor(i,l1,l2,px-ax,px-bx)*Bfunc(i,ir,g)
+ return
+ end function fB
+ !
+ function Bfunc(i,ir,g)
+ ! use function: fact_ratio2
+ implicit none
+ real(double) :: Bfunc
+ real(double) :: g
+ integer :: i,ir
+
+ Bfunc = fact_ratio2(i,ir)*((4*g)**(ir-i))
+ return
+ end function Bfunc
+ !
+ function binomial_prefactor(s,ia,ib,xpa,xpb)
+ ! use functions: binomial
+ implicit none
+ ! Function
+ real(double) :: binomial_prefactor
+ ! Arguments
+ integer, intent(in) :: s,ia,ib
+ real(double), intent(in) :: xpa,xpb
+ ! Local variables
+ integer :: j
+ real(double) :: sum
+
+ sum = zero
+ do j=0,s
+ if ((s-ia .le. j) .and. (j .le. ib)) &
+ sum = sum + binomial(ia,s-j)*binomial(ib,j) &
+ *(xpa**(ia-s+j))*(xpb**(ib-j))
+ enddo
+ binomial_prefactor = sum
+ return
+ end function binomial_prefactor
+ !
+ function binomial(i,j)
+ ! use function: fact
+ implicit none
+ integer :: binomial
+ integer, intent(in) :: i,j
+
+ binomial = fact(i)/fact(j)/fact(i-j)
+
+ return
+ end function binomial
+ !
+ function fact(n)
+
+ implicit none
+ integer :: i,n,fact
+
+ fact=1
+ if (n .le. 1) return
+ do i=1,n
+ fact = fact*i
+ enddo
+ return
+ end function fact
+ !
+ function fact2(n)
+ ! Compute double factorial n!!
+ implicit none
+ integer :: fact2,i,n
+
+ fact2=1
+ if (n .le. 1) return
+ do i = 1,n,2
+ fact2 = fact2*i
+ enddo
+ return
+ end function fact2
+ !
+ function fact_ratio2(i,j)
+ ! use function: fact
+ implicit none
+ integer, intent(in) :: i,j
+ integer :: fact_ratio2
+
+ fact_ratio2 = fact(i)/fact(j)/fact(i-2*j)
+ return
+ end function fact_ratio2
+ !
+ ! The following are from Numerical Recipes
+ ! gammp is hacked a bit to return exp(gln)*gamma
+ function gammp(a,x)
+ ! use subroutines: gcf, gser
+ implicit none
+ real(double), intent(in) :: a,x
+ real(double) :: gammp
+ real(double) :: gammcf,gamser,gln
+
+ if(x.lt.0..or.a.le.0.) stop 'exx_erigto: error, bad arguments in gammp'
+ if(x.lt.a+one)then
+ call gser(gamser,a,x,gln)
+ gammp=exp(gln)*gamser
+ else
+ call gcf(gammcf,a,x,gln)
+ gammp=exp(gln)*(one-gammcf)
+ endif
+ return
+ end function gammp
+ !
+ subroutine gser(gamser,a,x,gln)
+
+ implicit none
+ ! Arguments
+ real(double), intent(in) :: a,x
+ real(double), intent(out) :: gamser,gln
+ ! Local parameters
+ real(double),parameter :: EPS=3.e-9
+ integer, parameter :: ITMAX=100
+ ! Local variables
+ integer :: n
+ real(double) :: sum,del,ap
+
+ gln=gammln(a)
+ if(x.le.0.)then
+ if(x.lt.0.) stop 'exx_erigto: error, x < 0 in gser'
+ gamser=zero
+ return
+ endif
+ ap =a
+ sum=one/a
+ del=sum
+ do 11 n=1,ITMAX
+ ap =ap+one
+ del=del*x/ap
+ sum=sum+del
+ if(abs(del).lt.abs(sum)*EPS) goto 1
+11 end do
+ stop 'exx_erigto: error, a too large, ITMAX too small in gser'
+1 gamser=sum*exp(-x+a*log(x)-gln)
+ return
+ end subroutine gser
+ !
+ function gammln(xx)
+
+ implicit none
+ ! Function
+ real(double) :: gammln
+ ! Arguments
+ real(double), intent(in) :: xx
+ ! Local variables
+ integer :: j
+ real(double) :: ser,stp,tmp,x,y,cof(6)
+ SAVE cof,stp
+ DATA cof,stp/76.18009172947146d0,-86.50532032941677d0, &
+ 24.01409824083091d0,-1.231739572450155d0,.1208650973866179d-2, &
+ -.5395239384953d-5,2.5066282746310005d0/
+
+ x=xx
+ y=x
+ tmp=x+5.5d0
+ tmp=(x+0.5d0)*log(tmp)-tmp
+ ser=1.000000000190015d0
+ do 11 j=1,6
+ y=y+one
+ ser=ser+cof(j)/y
+11 end do
+ gammln=tmp+log(stp*ser/x)
+ return
+ end function gammln
+ !
+ subroutine gcf(gammcf,a,x,gln)
+ ! use function gammln
+ implicit none
+ ! Arguments
+ real(double), intent(in) :: a,x
+ real(double), intent(out) :: gln,gammcf
+ ! Local parameters
+ real(double),parameter :: EPS=3.e-9
+ real(double),parameter :: FPMIN=1.e-30
+ integer, parameter :: ITMAX=100
+
+ ! Local variables
+ integer :: i
+ real(double) :: an,b,c,d,del,h
+
+ gln=gammln(a)
+ !gln=dlgamma(a)
+ b=x+one-a
+ c=one/FPMIN
+ d=one/b
+ h=d
+ do 11 i=1,ITMAX
+ an=-i*(i-a)
+ b=b+two
+ d=an*d+b
+ if(abs(d).lt.FPMIN)d=FPMIN
+ c=b+an/c
+ if(abs(c).lt.FPMIN)c=FPMIN
+ d=one/d
+ del=d*c
+ h=h*del
+ if(abs(del-one).lt.EPS) goto 1
+11 end do
+ stop 'exx_erigto: error, a too large, ITMAX too small in gcf'
+1 gammcf=exp(-x+a*log(x)-gln)*h
+ return
+ end subroutine gcf
+ !
+ function dlgamma(x)
+ implicit real(double) (a - h, o - z)
+ dimension a(0 : 21), b(0 : 97), c(0 : 64), d(0 : 6)
+ integer :: i, k
+ data (a(i), i = 0, 10) / &
+ 0.00009967270908702825d0, -0.00019831672170162227d0, &
+ -0.00117085315349625822d0, 0.00722012810948319552d0, &
+ -0.00962213009367802970d0, -0.04219772092994235254d0, &
+ 0.16653861065243609743d0, -0.04200263501129018037d0, &
+ -0.65587807152061930091d0, 0.57721566490153514421d0, &
+ 0.99999999999999999764d0 /
+ data (a(i), i = 11, 21) / &
+ 0.00004672097259011420d0, -0.00006812300803992063d0, &
+ -0.00132531159076610073d0, 0.00733521178107202770d0, &
+ -0.00968095666383935949d0, -0.04217642811873540280d0, &
+ 0.16653313644244428256d0, -0.04200165481709274859d0, &
+ -0.65587818792782740945d0, 0.57721567315209190522d0, &
+ 0.99999999973565236061d0 /
+ data (b(i), i = 0, 13) / &
+ -0.00000000004587497028d0, 0.00000000019023633960d0, &
+ 0.00000000086377323367d0, 0.00000001155136788610d0, &
+ -0.00000002556403058605d0, -0.00000015236723372486d0,&
+ -0.00000316805106385740d0, 0.00000122903704923381d0, &
+ 0.00002334372474572637d0, 0.00111544038088797696d0, &
+ 0.00344717051723468982d0, 0.03198287045148788384d0, &
+ -0.32705333652955399526d0, 0.40120442440953927615d0 /
+ data (b(i), i = 14, 27) / &
+ & -0.00000000005184290387d0, -0.00000000083355121068d0, &
+ & -0.00000000256167239813d0, 0.00000001455875381397d0, &
+ & 0.00000013512178394703d0, 0.00000029898826810905d0, &
+ & -0.00000358107254612779d0, -0.00002445260816156224d0,&
+ & -0.00004417127762011821d0, 0.00112859455189416567d0, &
+ & 0.00804694454346728197d0, 0.04919775747126691372d0, &
+ & -0.24818372840948854178d0, 0.11071780856646862561d0 /
+ data (b(i), i = 28, 41) / &
+ & 0.00000000030279161576d0, 0.00000000160742167357d0, &
+ & -0.00000000405596009522d0, -0.00000005089259920266d0,&
+ & -0.00000002029496209743d0, 0.00000135130272477793d0, &
+ & 0.00000391430041115376d0, -0.00002871505678061895d0, &
+ & -0.00023052137536922035d0, 0.00045534656385400747d0, &
+ & 0.01153444585593040046d0, 0.07924014651650476036d0, &
+ & -0.12152192626936502982d0, -0.07916438300260539592d0 /
+ data (b(i), i = 42, 55) / &
+ & -0.00000000050919149580d0, -0.00000000115274986907d0,&
+ & 0.00000001237873512188d0, 0.00000002937383549209d0, &
+ & -0.00000030621450667958d0, -0.00000077409414949954d0,&
+ & 0.00000816753874325579d0, 0.00002412433382517375d0, &
+ & -0.00026061217606063700d0, -0.00091000087658659231d0,&
+ & 0.01068093850598380797d0, 0.11395654404408482305d0, &
+ & 0.07209569059984075595d0, -0.10971041451764266684d0 /
+ data (b(i), i = 56, 69) / &
+ & 0.00000000040119897187d0, -0.00000000013224526679d0, &
+ & -0.00000001002723190355d0, 0.00000002569249716518d0, &
+ & 0.00000020336011868466d0, -0.00000118097682726060d0, &
+ & -0.00000300660303810663d0, 0.00004402212897757763d0, &
+ & -0.00001462405876235375d0, -0.00164873795596001280d0, &
+ & 0.00513927520866443706d0, 0.13843580753590579416d0, &
+ & 0.32730190978254056722d0, 0.08588339725978624973d0 /
+ data (b(i), i = 70, 83) / &
+ & -0.00000000015413428348d0, 0.00000000064905779353d0, &
+ & 0.00000000160702811151d0, -0.00000002655645793815d0, &
+ & 0.00000007619544277956d0, 0.00000047604380765353d0, &
+ & -0.00000490748870866195d0, 0.00000821513040821212d0, &
+ & 0.00014804944070262948d0, -0.00122152255762163238d0, &
+ & -0.00087425289205498532d0, 0.14438703699657968310d0, &
+ & 0.61315889733595543766d0, 0.55513708159976477557d0 /
+ data (b(i), i = 84, 97) / &
+ & 0.00000000001049740243d0, -0.00000000025832017855d0, &
+ & 0.00000000139591845075d0, -0.00000000021177278325d0, &
+ & -0.00000005082950464905d0, 0.00000037801785193343d0, &
+ & -0.00000073982266659145d0, -0.00001088918441519888d0, &
+ & 0.00012491810452478905d0, -0.00049171790705139895d0, &
+ & -0.00425707089448266460d0, 0.13595080378472757216d0, &
+ & 0.89518356003149514744d0, 1.31073912535196238583d0 /
+ data (c(i), i = 0, 12) / &
+ & 0.0000000116333640008d0, -0.0000000833156123568d0, &
+ & 0.0000003832869977018d0, -0.0000015814047847688d0, &
+ & 0.0000065010672324100d0, -0.0000274514060128677d0, &
+ & 0.0001209015360925566d0, -0.0005666333178228163d0, &
+ & 0.0029294103665559733d0, -0.0180340086069185819d0, &
+ & 0.1651788780501166204d0, 1.1031566406452431944d0, &
+ & 1.2009736023470742248d0 /
+ data (c(i), i = 13, 25) / &
+ & 0.0000000013842760642d0, -0.0000000069417501176d0, &
+ & 0.0000000342976459827d0, -0.0000001785317236779d0, &
+ & 0.0000009525947257118d0, -0.0000052483007560905d0, &
+ & 0.0000302364659535708d0, -0.0001858396115473822d0, &
+ & 0.0012634378559425382d0, -0.0102594702201954322d0, &
+ & 0.1243625515195050218d0, 1.3888709263595291174d0, &
+ & 2.4537365708424422209d0 /
+ data (c(i), i = 26, 38) / &
+ & 0.0000000001298977078d0, -0.0000000008029574890d0, &
+ & 0.0000000049454846150d0, -0.0000000317563534834d0, &
+ & 0.0000002092136698089d0, -0.0000014252023958462d0, &
+ & 0.0000101652510114008d0, -0.0000774550502862323d0, &
+ & 0.0006537746948291078d0, -0.0066014912535521830d0, &
+ & 0.0996711934948138193d0, 1.6110931485817511402d0, &
+ & 3.9578139676187162939d0 /
+ data (c(i), i = 39, 51) / &
+ & 0.0000000000183995642d0, -0.0000000001353537034d0, &
+ & 0.0000000009984676809d0, -0.0000000076346363974d0, &
+ & 0.0000000599311464148d0, -0.0000004868554120177d0, &
+ & 0.0000041441957716669d0, -0.0000377160856623282d0, &
+ & 0.0003805693126824884d0, -0.0045979851178130194d0, &
+ & 0.0831422678749791178d0, 1.7929113303999329439d0, &
+ & 5.6625620598571415285d0 /
+ data (c(i), i = 52, 64) / &
+ & 0.0000000000034858778d0, -0.0000000000297587783d0, &
+ & 0.0000000002557677575d0, -0.0000000022705728282d0, &
+ & 0.0000000207024992450d0, -0.0000001954426390917d0, &
+ & 0.0000019343161886722d0, -0.0000204790249102570d0, &
+ & 0.0002405181940241215d0, -0.0033842087561074799d0, &
+ & 0.0713079483483518997d0, 1.9467574842460867884d0, &
+ & 7.5343642367587329552d0 /
+ data (d(i), i = 0, 6) / &
+ & -0.00163312359200500807d0, 0.00083644533703385956d0, &
+ & -0.00059518947575728181d0, 0.00079365057505415415d0, &
+ & -0.00277777777735463043d0, 0.08333333333333309869d0, &
+ & 0.91893853320467274178d0 /
+ w = x
+ if (x .lt. 0) w = 1 - x
+ if (w .lt. 0.5d0) then
+ k = 0
+ if (w .ge. 0.25d0) k = 11
+ y = ((((((((((a(k) * w + a(k + 1)) * w + &
+ a(k + 2)) * w + a(k + 3)) * w + a(k + 4)) * w + &
+ a(k + 5)) * w + a(k + 6)) * w + a(k + 7)) * w + &
+ a(k + 8)) * w + a(k + 9)) * w + a(k + 10)) * w
+ y = -log(y)
+ else if (w .lt. 3.5d0) then
+ t = w - 4.5d0 / (w + 0.5d0)
+ k = int(t + 4)
+ t = t - (k - 3.5d0)
+ k = k * 14
+ y = ((((((((((((b(k) * t + b(k + 1)) * t + &
+ b(k + 2)) * t + b(k + 3)) * t + b(k + 4)) * t + &
+ b(k + 5)) * t + b(k + 6)) * t + b(k + 7)) * t + &
+ b(k + 8)) * t + b(k + 9)) * t + b(k + 10)) * t + &
+ b(k + 11)) * t + b(k + 12)) * t + b(k + 13)
+ else if (w .lt. 8) then
+ k = (int(w)) - 3
+ t = w - (k + 3.5d0)
+ k = k * 13
+ y = (((((((((((c(k) * t + c(k + 1)) * t + &
+ c(k + 2)) * t + c(k + 3)) * t + c(k + 4)) * t + &
+ c(k + 5)) * t + c(k + 6)) * t + c(k + 7)) * t + &
+ c(k + 8)) * t + c(k + 9)) * t + c(k + 10)) * t + &
+ c(k + 11)) * t + c(k + 12)
+ else
+ v = 1 / w
+ t = v * v
+ y = (((((d(0) * t + d(1)) * t + d(2)) * t + &
+ d(3)) * t + d(4)) * t + d(5)) * v + d(6)
+ y = y + ((w - 0.5d0) * log(w) - w)
+ end if
+ if (x .lt. 0) y = log(pi / sin(pi * x)) - y
+ dlgamma = y
+ end function dlgamma
+ !
+ !
+ !
+ subroutine compute_eri_hoh(i,j,k,l,i_nsp,j_nsp,k_nsp,l_nsp,i_xyz,j_xyz,k_xyz,l_xyz,&
+ i_nt, j_nt, k_nt, l_nt, eri_gto)
+
+ use gto_format_new, only: gto
+
+ implicit none
+
+ integer, intent(in) :: i,j,k,l
+ integer, intent(in) :: i_nsp,j_nsp,k_nsp,l_nsp
+ real(double), intent(in) :: i_xyz(3),j_xyz(3),k_xyz(3),l_xyz(3)
+ real(double), intent(out) :: eri_gto
+ character(len=8), intent(out) :: i_nt, j_nt, k_nt, l_nt
+
+ integer :: i_nx, j_nx, k_nx, l_nx
+ integer :: i_ny, j_ny, k_ny, l_ny
+ integer :: i_nz, j_nz, k_nz, l_nz
+ integer :: i_n, j_n, k_n, l_n
+
+ integer :: ia_gto, jb_gto, kg_gto, ld_gto
+ real(double) :: ai, aj, ak, al, di, dj, dk, dl
+ real(double) :: i_norm, j_norm, k_norm, l_norm
+ real(double) :: ci, cj, ck, cl
+
+ real(double), dimension(5) :: F
+
+ i_nt = trim(gto( i_nsp )%sf( i )%nt)
+ j_nt = trim(gto( j_nsp )%sf( j )%nt)
+ k_nt = trim(gto( k_nsp )%sf( k )%nt)
+ l_nt = trim(gto( l_nsp )%sf( l )%nt)
+
+ spherical_ia: do i_n = 1, gto( i_nsp )%sf( i )%sph_size
+ spherical_jb: do j_n = 1, gto( j_nsp )%sf( j )%sph_size
+ spherical_kg: do k_n = 1, gto( k_nsp )%sf( k )%sph_size
+ spherical_ld: do l_n = 1, gto( l_nsp )%sf( l )%sph_size
+
+ i_nx = gto( i_nsp )%sf( i )%sph_nx( i_n )
+ i_ny = gto( i_nsp )%sf( i )%sph_ny( i_n )
+ i_nz = gto( i_nsp )%sf( i )%sph_nz( i_n )
+ ci = gto( i_nsp )%sf( i )%sph_c ( i_n )
+
+
+ j_nx = gto( j_nsp )%sf( j )%sph_nx( j_n )
+ j_ny = gto( j_nsp )%sf( j )%sph_ny( j_n )
+ j_nz = gto( j_nsp )%sf( j )%sph_nz( j_n )
+ cj = gto( j_nsp )%sf( j )%sph_c ( j_n )
+
+ k_nx = gto( k_nsp )%sf( k )%sph_nx( k_n )
+ k_ny = gto( k_nsp )%sf( k )%sph_ny( k_n )
+ k_nz = gto( k_nsp )%sf( k )%sph_nz( k_n )
+ ck = gto( k_nsp )%sf( k )%sph_c ( k_n )
+
+ l_nx = gto( l_nsp )%sf( l )%sph_nx( l_n )
+ l_ny = gto( l_nsp )%sf( l )%sph_ny( l_n )
+ l_nz = gto( l_nsp )%sf( l )%sph_nz( l_n )
+ cl = gto( l_nsp )%sf( l )%sph_c ( l_n )
+
+ prim_ld: do ld_gto = 1, gto( l_nsp )%sf( l )%ngto
+ prim_kg: do kg_gto = 1, gto( k_nsp )%sf( k )%ngto
+ prim_jb: do jb_gto = 1, gto( j_nsp )%sf( j )%ngto
+ prim_ia: do ia_gto = 1, gto( i_nsp )%sf( i )%ngto
+
+ ai = gto( i_nsp )%sf( i )%a( ia_gto )
+ aj = gto( j_nsp )%sf( j )%a( jb_gto )
+ ak = gto( k_nsp )%sf( k )%a( kg_gto )
+ al = gto( l_nsp )%sf( l )%a( ld_gto )
+
+ di = gto( i_nsp )%sf( i )%d( ia_gto )
+ dj = gto( j_nsp )%sf( j )%d( jb_gto )
+ dk = gto( k_nsp )%sf( k )%d( kg_gto )
+ dl = gto( l_nsp )%sf( l )%d( ld_gto )
+
+ i_norm = gto( i_nsp )%sf( i )%norm
+ j_norm = gto( j_nsp )%sf( j )%norm
+ k_norm = gto( k_nsp )%sf( k )%norm
+ l_norm = gto( l_nsp )%sf( l )%norm
+
+ !i_norm = 1.0d0
+ !j_norm = 1.0d0
+ !k_norm = 1.0d0
+ !l_norm = 1.0d0
+
+ eri_gto = eri_gto + (ci*cj*ck*cl) * (di*dj*dk*dl) * &
+ eri_gto_hoh( &
+ i_xyz(1), i_xyz(2), i_xyz(3), i_norm, i_nx, i_ny, i_nz, ai, &
+ k_xyz(1), k_xyz(2), k_xyz(3), k_norm, k_nx, k_ny, k_nz, ak, &
+ l_xyz(1), l_xyz(2), l_xyz(3), l_norm, l_nx, l_ny, l_nz, al, &
+ j_xyz(1), j_xyz(2), j_xyz(3), j_norm, j_nx, j_ny, j_nz, aj)
+
+
+ !call compute_eri(1, ai, ia%xyz_ip, &
+ ! 1, aj, jb%xyz_cv, &
+ ! 1, ak, kg%xyz_cv, &
+ ! 1, al, ld%xyz_cv)
+
+ !F = [0.41608906765397796d0, 0.044889937015574935d0, &
+ ! 0.013706554295511562d0, 0.0063780699489852013d0, &
+ ! 0.39523364424416996d0]
+
+ !F(1) = 1.0d0
+
+
+ !print*, eri_gto_hoh( &
+ ! i_xyz(1), i_xyz(2), i_xyz(3), 1.0d0, i_nx, i_ny, i_nz, ai, &
+ ! k_xyz(1), k_xyz(2), k_xyz(3), 1.0d0, k_nx, k_ny, k_nz, ak, &
+ ! l_xyz(1), l_xyz(2), l_xyz(3), 1.0d0, l_nx, l_ny, l_nz, al, &
+ ! j_xyz(1), j_xyz(2), j_xyz(3), 1.0d0, j_nx, j_ny, j_nz, aj)
+
+
+ !CALL libint2_static_init()
+ !CALL libint2_init_eri(erieval, 0, C_NULL_PTR)
+ !CALL compute_eri_f(1, 0, &
+ ! 0, [1.0d0], [ai], i_xyz, &
+ ! 0, [1.0d0], [ak], k_xyz, &
+ ! 0, [1.0d0], [al], l_xyz, &
+ ! 0, [1.0d0], [aj], j_xyz, &
+ ! F, erieval)
+ !CALL print_eri(0, 0, 0, 0, 0, erieval)
+ !print*, erieval
+ !CALL libint2_cleanup_eri(erieval)
+
+!!$ allocate(phi_on_grid_ia(2*extent+1,2*extent+1,2*extent+1))
+!!$ phi_on_grid_ia = zero
+!!$ allocate(phi_on_grid_jb(2*extent+1,2*extent+1,2*extent+1))
+!!$ phi_on_grid_jb = zero
+!!$ allocate(phi_on_grid_kg(2*extent+1,2*extent+1,2*extent+1))
+!!$ phi_on_grid_kg = zero
+!!$ allocate(phi_on_grid_ld(2*extent+1,2*extent+1,2*extent+1))
+!!$ phi_on_grid_ld = zero
+!!$ allocate(work_out_3d_(2*extent+1,2*extent+1,2*extent+1))
+!!$ work_out_3d_ = zero
+!!$ allocate(work_in_3d_(2*extent+1,2*extent+1,2*extent+1))
+!!$ work_in_3d_ = zero
+!!$
+!!$
+!!$ call exx_gto_on_grid_prim(inode,ia%ip, &
+!!$ i_nsp, &
+!!$ extent, ia%xyz, &
+!!$ phi_on_grid_ia,r_int,xyz_zero,i_nx,i_ny,i_nz,ai)
+!!$
+!!$ call exx_gto_on_grid_prim(inode,jb%global_num,&
+!!$ j_nsp, &
+!!$ extent, jb%xyz,&
+!!$ phi_on_grid_jb,r_int,xyz_zero,j_nx,j_ny,j_nz,aj)
+!!$
+!!$ call exx_gto_on_grid_prim(inode,kg%global_num,&
+!!$ k_nsp,&
+!!$ extent,kg%xyz,&
+!!$ phi_on_grid_kg,r_int,xyz_zero,k_nx,k_ny,k_nz,ak)
+!!$
+!!$ call exx_gto_on_grid_prim(inode,ld%global_num,&
+!!$ l_nsp,&
+!!$ extent,ld%xyz,&
+!!$ phi_on_grid_ld,r_int,xyz_zero,l_nx,l_ny,l_nz,al)
+!!$
+!!$
+!!$ work_in_3d_(:,:,:) = phi_on_grid_ld(:,:,:) * &
+!!$ phi_on_grid_jb(:,:,:)
+!!$
+!!$ !call hf_v_on_grid(inode,extent,work_in_3d,&
+!!$ ! work_out_3d,r_int, &
+!!$ ! exx_psolver,p_scheme,pulay_radius,p_omega,&
+!!$ ! p_ngauss,p_gauss, &
+!!$ ! w_gauss)
+!!$
+!!$ call exx_v_on_grid(inode,extent,work_in_3d_,work_out_3d_,&
+!!$ r_int, &
+!!$ exx_psolver,exx_pscheme,pulay_radius,p_omega,&
+!!$ p_ngauss,p_gauss,&
+!!$ w_gauss,fftwrho3d,reckernel_3d)
+!!$
+!!$ work_in_3d_ = phi_on_grid_ia(:,:,:) * phi_on_grid_kg(:,:,:)
+!!$
+!!$ !eri_pao = zero
+!!$ do ii = 1, 2*extent + 1
+!!$ do jj = 1, 2*extent + 1
+!!$ do kk = 1, 2*extent + 1
+!!$ eri_pao = eri_pao + &
+!!$ work_in_3d_ (ii,jj,kk) * &
+!!$ work_out_3d_(ii,jj,kk) * dv
+!!$ !i_norm * j_norm * k_norm * l_norm
+!!$ end do
+!!$ end do
+!!$ end do
+!!$
+!!$ !eri_pao = eri_pao
+!!$
+!!$ deallocate(phi_on_grid_ia)
+!!$ deallocate(phi_on_grid_jb)
+!!$ deallocate(phi_on_grid_kg)
+!!$ deallocate(phi_on_grid_ld)
+!!$ deallocate(work_out_3d_)
+!!$ deallocate(work_in_3d_)
+
+
+
+ end do prim_ia
+ end do prim_jb
+ end do prim_kg
+ end do prim_ld
+ !
+
+ end do spherical_ld
+ end do spherical_kg
+ end do spherical_jb
+ end do spherical_ia
+
+ end subroutine compute_eri_hoh
+ !
+end module exx_erigto
diff --git a/src/exx_evalgto.f90 b/src/exx_evalgto.f90
new file mode 100644
index 000000000..a022b94f0
--- /dev/null
+++ b/src/exx_evalgto.f90
@@ -0,0 +1,707 @@
+module exx_evalgto
+
+ use datatypes
+ use numbers, ONLY: zero, one, two, three, four, five, six, fifteen, sixteen
+ use numbers, ONLY: half, quarter, very_small, pi, twopi, fourpi
+ implicit none
+
+contains
+
+
+ subroutine exx_gto_on_grid_new_new(inode,atom,spec,extent,xyz,nsuppfuncs,phi_on_grid,r_int,rst)
+
+ use timer_module, ONLY: start_timer, stop_timer
+ use exx_types, ONLY: unit_matrix_write, tmr_std_exx_evalgto
+ use exx_types, ONLY: exx_overlap, exx_cartesian, exx_gto
+ use GenComms, ONLY: cq_abort
+
+ use angular_coeff_routines, ONLY: evaluate_pao, re_cart_norm
+ use dimens, ONLY: r_h
+ use gto_format_new, ONLY: gto
+
+ implicit none
+
+ ! << Passed variables >>
+ integer, intent(in) :: extent ! number of grid points [for 1 dimension]
+ integer, intent(in) :: inode
+ integer, intent(in) :: atom
+ integer, intent(in) :: spec
+ integer, intent(in) :: nsuppfuncs
+
+ real(double), intent(in) :: xyz(3)
+ real(double), intent(in) :: rst(3)
+ real(double), intent(in) :: r_int
+
+ real(double), dimension(2*extent+1,2*extent+1,2*extent+1,nsuppfuncs), &
+ intent(inout) :: phi_on_grid
+
+ real(double), parameter :: a1g_norm = sqrt(one/(four*pi))
+ real(double), parameter :: t1u_norm = sqrt(three/(four*pi))
+
+ ! << Local variables >>
+ !real(double), dimension(nsuppfuncs) :: sfsum
+ integer :: nx, ny, nz
+ integer :: mx, my, mz
+ integer :: px, py, pz
+ integer :: ex, ey, ez
+
+ real(double) :: grid_spacing
+ real(double) :: x, y, z, r
+ real(double) :: int, n, rest
+ real(double) :: xyz_delta(3)
+
+ integer :: count1, ierr, stat
+ integer :: i, j, p, l1, m1, acz1, ngrid
+ integer :: ijk_delta(3), ijk(3), kji(3), njk(3), nji(3)
+
+ real(double) :: gto_rad, gto_cart, gto_val
+ real(double) :: a, d, factor
+
+ ngrid = 2*extent+1
+ grid_spacing = r_int/real(extent,double)
+ phi_on_grid = zero
+
+ mx = -extent ; px = extent
+ my = mx ; py = px
+ mz = my ; pz = py
+
+ call start_timer(tmr_std_exx_evalgto)
+ ! Define the overlap box
+ overlap_box: if (exx_overlap) then
+ do i = 1, 3
+ n = xyz(i)/grid_spacing
+ rest = n - real(aint(n))
+
+ if (abs(rest) >= half) then
+ int = ceiling(abs(n))
+ int = sign(int,n)
+ xyz_delta(i) = int - n
+
+ else if (abs(rest) < half) then
+ int = floor(abs(n))
+ int = sign(int,n)
+ xyz_delta(i) = int - n
+
+ else if ((rest == zero)) then
+ int = n
+ xyz_delta(i) = zero
+
+ end if
+
+ ijk_delta(i) = int
+ xyz_delta(i) = xyz_delta(i)*grid_spacing
+ end do
+
+ do i = 1, 3
+ if (ijk_delta(i) > 0) then
+ ijk(i) = ijk_delta(i) + 1
+ njk(i) = ngrid
+ kji(i) = 1
+ nji(i) = ngrid - ijk_delta(i)
+
+ else if (ijk_delta(i) < 0) then
+ ijk(i) = 1
+ njk(i) = ngrid + ijk_delta(i)
+ kji(i) = -ijk_delta(i) + 1
+ nji(i) = ngrid
+
+ else
+ ijk(i) = 1
+ njk(i) = ngrid
+ kji(i) = 1
+ nji(i) = ngrid
+
+ end if
+ end do
+ mx = mx +kji(1)-1
+ my = my +kji(2)-1
+ mz = mz +kji(3)-1
+ px = px -ijk(1)+1
+ py = py -ijk(2)+1
+ pz = pz -ijk(3)+1
+ end if overlap_box
+
+ do i = 1, gto( spec )%nsf_gto_tot
+
+ ex = gto( spec )%sf( i )%nx
+ ey = gto( spec )%sf( i )%ny
+ ez = gto( spec )%sf( i )%nz
+
+ factor = re_cart_norm( l1,m1-l1-1 ) !call re_cart_norm(l1,m1-l1-1,factor)
+
+ grid_x_loop: do nx = mx, px
+ x = xyz(1) + real(nx,double)*grid_spacing + rst(1)
+
+ grid_y_loop: do ny = my, py
+ y = xyz(2) + real(ny,double)*grid_spacing + rst(2)
+
+ grid_z_loop: do nz = mz, pz
+ z = xyz(3) + real(nz,double)*grid_spacing + rst(3)
+
+ r = sqrt(x*x+y*y+z*z)
+
+ gto_cart = (x**real(ex))*(y**real(ey))*(z**real(ez))
+
+ gto_rad = zero
+ primitive: do p = 1, gto( spec )%sf( i )%ngto
+
+ a = gto( spec )%sf( i )%a( p )
+
+ !gto_rad = gto_rad + exp(-a*r**2)
+ gto_rad = gto_rad + d*exp(-a*r**2)
+
+ end do primitive
+
+ gto_val = gto_rad * gto_cart !* factor
+ phi_on_grid(nx+extent+1,ny+extent+1,nz+extent+1,i) = gto_val
+
+ end do grid_z_loop
+ end do grid_y_loop
+ end do grid_x_loop
+
+ end do
+ call stop_timer(tmr_std_exx_evalgto,.true.)
+
+ return
+ end subroutine exx_gto_on_grid_new_new
+
+
+
+ subroutine exx_gto_on_grid_new(inode,atom,spec,extent,xyz,nsuppfuncs,phi_on_grid,r_int,rst)
+
+ use timer_module, ONLY: start_timer, stop_timer
+ use exx_types, ONLY: unit_matrix_write, tmr_std_exx_evalgto
+ use exx_types, ONLY: exx_overlap, exx_cartesian, exx_gto
+ use GenComms, ONLY: cq_abort
+
+ use angular_coeff_routines, ONLY: evaluate_pao, re_cart_norm
+ use dimens, ONLY: r_h
+ use gto_format_new, ONLY: gto
+
+ implicit none
+
+ ! << Passed variables >>
+ integer, intent(in) :: extent ! number of grid points [for 1 dimension]
+ integer, intent(in) :: inode
+ integer, intent(in) :: atom
+ integer, intent(in) :: spec
+ integer, intent(in) :: nsuppfuncs
+
+ real(double), intent(in) :: xyz(3)
+ real(double), intent(in) :: rst(3)
+ real(double), intent(in) :: r_int
+
+ real(double), dimension(2*extent+1,2*extent+1,2*extent+1,nsuppfuncs), &
+ intent(inout) :: phi_on_grid
+
+ real(double), parameter :: a1g_norm = sqrt(one/(four*pi))
+ real(double), parameter :: t1u_norm = sqrt(three/(four*pi))
+
+ ! << Local variables >>
+ !real(double), dimension(nsuppfuncs) :: sfsum
+ integer :: nx, ny, nz
+ integer :: mx, my, mz
+ integer :: px, py, pz
+ integer :: ex, ey, ez
+
+ real(double) :: grid_spacing
+ real(double) :: x, y, z, r
+ real(double) :: int, n, rest
+ real(double) :: xyz_delta(3)
+
+ integer :: count1, ierr, stat
+ integer :: i, j, p, l1, m1, acz1, n1, ngrid
+ integer :: ijk_delta(3), ijk(3), kji(3), njk(3), nji(3)
+
+ real(double) :: gto_rad, gto_cart, gto_val
+ real(double) :: a, d, factor, c
+
+ ngrid = 2*extent+1
+ grid_spacing = r_int/real(extent,double)
+ phi_on_grid = zero
+
+ mx = -extent ; px = extent
+ my = mx ; py = px
+ mz = my ; pz = py
+
+ call start_timer(tmr_std_exx_evalgto)
+ ! Define the overlap box
+ overlap_box: if (exx_overlap) then
+ do i = 1, 3
+ n = xyz(i)/grid_spacing
+ rest = n - real(aint(n))
+
+ if (abs(rest) >= half) then
+ int = ceiling(abs(n))
+ int = sign(int,n)
+ xyz_delta(i) = int - n
+
+ else if (abs(rest) < half) then
+ int = floor(abs(n))
+ int = sign(int,n)
+ xyz_delta(i) = int - n
+
+ else if ((rest == zero)) then
+ int = n
+ xyz_delta(i) = zero
+
+ end if
+
+ ijk_delta(i) = int
+ xyz_delta(i) = xyz_delta(i)*grid_spacing
+ end do
+
+ do i = 1, 3
+ if (ijk_delta(i) > 0) then
+ ijk(i) = ijk_delta(i) + 1
+ njk(i) = ngrid
+ kji(i) = 1
+ nji(i) = ngrid - ijk_delta(i)
+
+ else if (ijk_delta(i) < 0) then
+ ijk(i) = 1
+ njk(i) = ngrid + ijk_delta(i)
+ kji(i) = -ijk_delta(i) + 1
+ nji(i) = ngrid
+
+ else
+ ijk(i) = 1
+ njk(i) = ngrid
+ kji(i) = 1
+ nji(i) = ngrid
+
+ end if
+ end do
+ mx = mx +kji(1)-1
+ my = my +kji(2)-1
+ mz = mz +kji(3)-1
+ px = px -ijk(1)+1
+ py = py -ijk(2)+1
+ pz = pz -ijk(3)+1
+ end if overlap_box
+
+ count1 = 1
+ angu_loop: do l1 = 0, gto(spec)%greatest_angmom
+
+ !if (l1 == 0) factor = a1g_norm
+ !if (l1 == 1) factor = t1u_norm
+
+ zeta_loop: do acz1 = 1, gto(spec)%angmom(l1)%n_zeta_in_angmom
+
+ !magn_loop: do m1 = 1, gto(spec)%angmom(l1)%nf_gto
+
+ magn_loop: do m1 = -l1, +l1
+
+ factor = re_cart_norm(l1,m1)! call re_cart_norm(l1,m1-l1-1,factor)
+
+ !sph_loop: do n1 = 1, gto(nsp)%angmom(l1)%transform_sph(m1)%size
+
+ !ex = gto(spec)%angmom(l1)%nx(m1)
+ !ey = gto(spec)%angmom(l1)%ny(m1)
+ !ez = gto(spec)%angmom(l1)%nz(m1)
+
+ !factor = re_cart_norm(l1,m1)! call re_cart_norm(l1,m1-l1-1,factor)
+
+ grid_x_loop: do nx = mx, px
+ x = xyz(1) + real(nx,double)*grid_spacing + rst(1)
+
+ grid_y_loop: do ny = my, py
+ y = xyz(2) + real(ny,double)*grid_spacing + rst(2)
+
+ grid_z_loop: do nz = mz, pz
+ z = xyz(3) + real(nz,double)*grid_spacing + rst(3)
+
+ r = sqrt(x*x+y*y+z*z)
+
+ gto_cart = zero
+ sph_loop: do n1 = 1, gto(spec)%angmom(l1)%transform_sph(m1)%size
+
+ ex = gto(spec)%angmom(l1)%transform_sph(m1)%nx(n1)
+ ey = gto(spec)%angmom(l1)%transform_sph(m1)%ny(n1)
+ ez = gto(spec)%angmom(l1)%transform_sph(m1)%nz(n1)
+ c = gto(spec)%angmom(l1)%transform_sph(m1)%c( n1)
+
+ gto_cart = gto_cart + c * x**real(ex) * y**real(ey) * z**real(ez)
+
+ end do sph_loop
+ !
+ gto_rad = zero
+ primitive: do p = 1, gto(spec)%angmom(l1)%zeta(acz1)%ngto
+
+ a = gto(spec)%angmom(l1)%zeta(acz1)%a(p)
+ d = gto(spec)%angmom(l1)%zeta(acz1)%d(p)
+
+ gto_rad = gto_rad + d*exp(-a*r**2)
+
+ end do primitive
+
+ gto_val = gto_rad * gto_cart * factor
+ phi_on_grid(nx+extent+1,ny+extent+1,nz+extent+1,count1) = gto_val
+
+ end do grid_z_loop
+ end do grid_y_loop
+ end do grid_x_loop
+
+ count1 = count1 + 1
+ end do magn_loop
+ end do zeta_loop
+ end do angu_loop
+
+ call stop_timer(tmr_std_exx_evalgto,.true.)
+
+ return
+ end subroutine exx_gto_on_grid_new
+
+
+ subroutine exx_gto_on_grid(inode,atom,spec,extent,xyz,nsuppfuncs,phi_on_grid,r_int,rst)
+
+ use timer_module, ONLY: start_timer, stop_timer
+ use exx_types, ONLY: unit_matrix_write, tmr_std_exx_evalgto
+ use exx_types, ONLY: exx_overlap, exx_cartesian, exx_gto
+ use GenComms, ONLY: cq_abort
+
+ use angular_coeff_routines, ONLY: evaluate_pao
+ use dimens, ONLY: r_h
+ use gto_format, ONLY: gto
+
+ implicit none
+
+ ! << Passed variables >>
+ integer, intent(in) :: extent ! number of grid points [for 1 dimension]
+ integer, intent(in) :: inode
+ integer, intent(in) :: atom
+ integer, intent(in) :: spec
+ integer, intent(in) :: nsuppfuncs
+
+ real(double), intent(in) :: xyz(3)
+ real(double), intent(in) :: rst(3)
+ real(double), intent(in) :: r_int
+
+ real(double), dimension(nsuppfuncs,2*extent+1,2*extent+1,2*extent+1), &
+ intent(inout) :: phi_on_grid
+
+ ! << Local variables >>
+ !real(double), dimension(nsuppfuncs) :: sfsum
+ integer :: nx, ny, nz
+ integer :: mx, my, mz
+ integer :: px, py, pz
+ integer :: ex, ey, ez
+
+ real(double) :: grid_spacing
+ real(double) :: x, y, z, r
+ real(double) :: int, n, rest
+ real(double) :: xyz_delta(3)
+
+ integer :: count1, nsf1
+ integer :: ierr, stat
+ integer :: i, j, k, kk, ngrid
+ integer :: ijk_delta(3), ijk(3), kji(3), njk(3), nji(3)
+
+ integer :: gto_lmn, index
+ real(double) :: gto_val, gto_sph, gto_rad, gto_cart
+ real(double) :: ak, dk, Nk
+ character(len=16) :: nt
+
+ ngrid = 2*extent+1
+ grid_spacing = r_int/real(extent,double)
+ phi_on_grid = zero
+
+ mx = -extent ; px = extent
+ my = mx ; py = px
+ mz = my ; pz = py
+
+ call start_timer(tmr_std_exx_evalgto)
+ ! Define the overlap box
+ overlap_box: if (exx_overlap) then
+ do i = 1, 3
+ n = xyz(i)/grid_spacing
+ rest = n - real(aint(n))
+
+ if (abs(rest) >= half) then
+ int = ceiling(abs(n))
+ int = sign(int,n)
+ xyz_delta(i) = int - n
+
+ else if (abs(rest) < half) then
+ int = floor(abs(n))
+ int = sign(int,n)
+ xyz_delta(i) = int - n
+
+ else if ((rest == zero)) then
+ int = n
+ xyz_delta(i) = zero
+
+ end if
+
+ ijk_delta(i) = int
+ xyz_delta(i) = xyz_delta(i)*grid_spacing
+ end do
+
+ do i = 1, 3
+ if (ijk_delta(i) > 0) then
+ ijk(i) = ijk_delta(i) + 1
+ njk(i) = ngrid
+ kji(i) = 1
+ nji(i) = ngrid - ijk_delta(i)
+
+ else if (ijk_delta(i) < 0) then
+ ijk(i) = 1
+ njk(i) = ngrid + ijk_delta(i)
+ kji(i) = -ijk_delta(i) + 1
+ nji(i) = ngrid
+
+ else
+ ijk(i) = 1
+ njk(i) = ngrid
+ kji(i) = 1
+ nji(i) = ngrid
+
+ end if
+ end do
+ mx = mx +kji(1)-1
+ my = my +kji(2)-1
+ mz = mz +kji(3)-1
+ px = px -ijk(1)+1
+ py = py -ijk(2)+1
+ pz = pz -ijk(3)+1
+ end if overlap_box
+!!$
+ count1 = 1
+ !print*,
+ shell_loop: do nsf1 = 1, gto( spec )%nshell
+
+ do index = 1, gto( spec )%shell( nsf1 )%nf
+
+ ex = gto( spec )%shell( nsf1 )%nx( index )
+ ey = gto( spec )%shell( nsf1 )%ny( index )
+ ez = gto( spec )%shell( nsf1 )%nz( index )
+ nt = gto( spec )%shell( nsf1 )%nt( index )
+
+ !print*, gto( spec )%label, 'ex ey ez', ex, ey, ez, trim(nt), &
+ ! (gto( spec )%shell( nsf1 )%ak( k ), k = 1, gto( spec )%shell( nsf1 )%n)
+ !
+ grid_x_loop: do nx = mx, px
+ x = xyz(1) + real(nx,double)*grid_spacing + rst(1)
+
+ grid_y_loop: do ny = my, py
+ y = xyz(2) + real(ny,double)*grid_spacing + rst(2)
+
+ grid_z_loop: do nz = mz, pz
+ z = xyz(3) + real(nz,double)*grid_spacing + rst(3)
+
+ r = sqrt(x*x+y*y+z*z)
+
+ gto_cart = (x**real(ex))*(y**real(ey))*(z**real(ez))
+
+ gto_rad = zero
+ do k = 1, gto( spec )%shell( nsf1 )%n
+ ak = gto( spec )%shell( nsf1 )%ak( k )
+ dk = gto( spec )%shell( nsf1 )%dk( k )
+ Nk = gto( spec )%shell( nsf1 )%Nk( k, index )
+
+ gto_rad = gto_rad + exp(-ak*r**2)!*Nk
+
+ end do
+
+
+ gto_val = gto_rad * gto_cart ! / ( sqrt(4*pi) )
+
+ phi_on_grid(count1,&
+ nx+extent+1, &
+ ny+extent+1, &
+ nz+extent+1) = gto_val
+
+ end do grid_z_loop
+ end do grid_y_loop
+ end do grid_x_loop
+
+ count1 = count1 + 1
+ end do
+ end do shell_loop
+
+ call stop_timer(tmr_std_exx_evalgto,.true.)
+
+ return
+ end subroutine exx_gto_on_grid
+ !
+ subroutine exx_gto_on_grid_prim(inode,atom,spec,extent,xyz,phi_on_grid,r_int,rst,ex,ey,ez,ak)
+
+ use timer_module, ONLY: start_timer, stop_timer
+ use exx_types, ONLY: unit_matrix_write, tmr_std_exx_evalgto
+ use exx_types, ONLY: exx_overlap, exx_cartesian, exx_gto
+ use GenComms, ONLY: cq_abort
+
+ use angular_coeff_routines, ONLY: evaluate_pao
+ use dimens, ONLY: r_h
+ use gto_format, ONLY: gto
+
+ implicit none
+
+ ! << Passed variables >>
+ integer, intent(in) :: extent ! number of grid points [for 1 dimension]
+ integer, intent(in) :: inode
+ integer, intent(in) :: atom
+ integer, intent(in) :: spec
+ !integer, intent(in) :: nsuppfuncs
+
+ real(double), intent(in) :: xyz(3)
+ real(double), intent(in) :: rst(3)
+ real(double), intent(in) :: r_int
+
+ real(double), dimension(2*extent+1,2*extent+1,2*extent+1), &
+ intent(inout) :: phi_on_grid
+
+ ! << Local variables >>
+ !real(double), dimension(nsuppfuncs) :: sfsum
+ integer :: nx, ny, nz
+ integer :: mx, my, mz
+ integer :: px, py, pz
+ integer :: ex, ey, ez
+
+ real(double) :: grid_spacing
+ real(double) :: x, y, z, r
+ real(double) :: int, n, rest
+ real(double) :: xyz_delta(3)
+
+ integer :: count1, nsf1
+ integer :: ierr, stat
+ integer :: i, j, k, kk, ngrid
+ integer :: ijk_delta(3), ijk(3), kji(3), njk(3), nji(3)
+
+ integer :: gto_lmn, index, l1
+ real(double) :: gto_val, gto_sph, gto_rad, gto_cart
+ real(double) :: ak, dk, Nk, factor
+
+ real(double), parameter :: a1g_norm = sqrt(one/(four*pi))
+ real(double), parameter :: t1u_norm = sqrt(three/(four*pi))
+
+
+ ngrid = 2*extent+1
+ grid_spacing = r_int/real(extent,double)
+ phi_on_grid = zero
+
+ mx = -extent ; px = extent
+ my = mx ; py = px
+ mz = my ; pz = py
+
+ call start_timer(tmr_std_exx_evalgto)
+ !
+ factor = 1.0d0
+ !l1 = nx + ny + nz
+ !if (l1 == 0) factor = a1g_norm
+ !if (l1 == 1) factor = t1u_norm
+ !
+ grid_x_loop: do nx = mx, px
+ x = xyz(1) + real(nx,double)*grid_spacing + rst(1)
+
+ grid_y_loop: do ny = my, py
+ y = xyz(2) + real(ny,double)*grid_spacing + rst(2)
+
+ grid_z_loop: do nz = mz, pz
+ z = xyz(3) + real(nz,double)*grid_spacing + rst(3)
+
+ r = sqrt(x*x+y*y+z*z)
+
+ gto_cart = (x**real(ex))*(y**real(ey))*(z**real(ez))
+
+ gto_rad = exp(-ak*r**2)
+
+ gto_val = gto_rad * gto_cart
+
+ phi_on_grid(&
+ nx+extent+1, &
+ ny+extent+1, &
+ nz+extent+1) = gto_val * factor
+
+ end do grid_z_loop
+ end do grid_y_loop
+ end do grid_x_loop
+
+ call stop_timer(tmr_std_exx_evalgto,.true.)
+
+ return
+ end subroutine exx_gto_on_grid_prim
+ !
+!!$ subroutine re_cart_norm(l,m,norm)
+!!$
+!!$ use datatypes
+!!$ use numbers
+!!$ use GenComms,ONLY: cq_abort
+!!$
+!!$ implicit none
+!!$ !
+!!$ !
+!!$ integer, intent(in) :: l, m
+!!$ real(double), intent(out):: norm
+!!$ !
+!!$ real(double), parameter :: a1g_norm = sqrt(one/(four*pi))
+!!$ real(double), parameter :: t1u_norm = sqrt(three/(four*pi))
+!!$ real(double), parameter :: t2g_norm = sqrt(fifteen/(four*pi))
+!!$ real(double), parameter :: eg_a_norm = sqrt(fifteen/(sixteen*pi))
+!!$ real(double), parameter :: eg_b_norm = sqrt(five/(sixteen*pi))
+!!$ !
+!!$ real(double), parameter :: f0_norm = sqrt(seven/(sixteen*pi))
+!!$ real(double), parameter :: f1_norm = sqrt( 21.0_double/(sixteen*two*pi))
+!!$ real(double), parameter :: f2_norm = sqrt(105.0_double/(sixteen*pi))
+!!$ real(double), parameter :: f3_norm = sqrt( 35.0_double/(sixteen*two*pi))
+!!$ !
+!!$ integer :: i
+!!$ !
+!!$ if(l == 0) then !s-type function
+!!$ !
+!!$ norm = a1g_norm
+!!$ !
+!!$ else if(l == 1) then !p-type function
+!!$ !
+!!$ norm = t1u_norm
+!!$ !
+!!$ else if(l == 2) then !d-type function
+!!$ !
+!!$ select case( m )
+!!$
+!!$ case( 3 ) ! d_{x2-y2}
+!!$ norm = 1.0d0
+!!$ case( 2 ) ! d_{x2-y2}
+!!$ norm = eg_a_norm !(x*x-y*y)
+!!$ case( 1 ) ! d_{xz}
+!!$ norm = t2g_norm !(x*z)
+!!$ case( 0 ) ! d_{z2}
+!!$ norm = eg_b_norm!(3*z*z-r*r)
+!!$ case(-1 ) ! d_{yz}
+!!$ norm = t2g_norm !(y*z)
+!!$ case(-2 ) ! d_{xy}
+!!$ norm =-t2g_norm !(x*y) ! take care phase factor
+!!$ case default
+!!$ call cq_abort('re_cart_norm/problem with (l,m) =',l,m)
+!!$ end select
+!!$ !
+!!$ else if(l == 3) then !f-type function
+!!$ !
+!!$ select case( m )
+!!$ case( 3 ) ! f_{x3-xy2}
+!!$ norm = f3_norm !*(x*x - 3*y*y)*x
+!!$ case( 2 ) ! f_{zx2-zy2}
+!!$ norm = f2_norm !*(x*x - y*y)*z
+!!$ case( 1 ) ! f_{xz2}
+!!$ norm = f1_norm !*(5*z*z - r*r)*x
+!!$ case( 0 ) ! f_{z3}
+!!$ norm = f0_norm !*(5*z*z - 3*r*r)*z
+!!$ case(-1 ) ! f_{yz2}
+!!$ norm = f1_norm !(5*z*z - r*r)*y
+!!$ case(-2 ) ! f_{xyz}
+!!$ norm = f2_norm !x*y*z
+!!$ case(-3 ) ! f_{3yx2-y3}
+!!$ norm = f3_norm !(3*x*x - y*y)*y
+!!$ case default
+!!$ call cq_abort('re_cart_norm/problem with (l,m) =',l,m)
+!!$ end select
+!!$ !
+!!$ else if( l > 3) then
+!!$ call cq_abort('re_cart_norm/not implemented for l > 3')
+!!$ else
+!!$ call cq_abort('re_cart_norm/problem with l =',l)
+!!$ end if
+!!$
+!!$ end subroutine re_cart_norm
+
+end module exx_evalgto
diff --git a/src/exx_evalpao.f90 b/src/exx_evalpao.f90
index e0d0ec395..a54627ea2 100644
--- a/src/exx_evalpao.f90
+++ b/src/exx_evalpao.f90
@@ -15,12 +15,21 @@ module exx_evalpao
!! 2016/12/29 21:30 nakata
!! Used pao information instead of blips_on_atom, and
!! removed support_spec_format (blips_on_atom), which is no longer needed
+!! 2019/01/23 11:20 lionel
+!! pao on grid are now evaluated from evaluate_pao in ol_ang_coeff_subs.f90
+!! Cartesian system is preferred in this case (faster) cf. exx_cartesian = T/F
+!! 2023/15/23 14:03 lionel
+!! Added dummy argument to evaluate_pao
+!! 2024/02/28 11:00 Connor
+!! Added OpenMP thread parallelisation around xyz loops
+!!
subroutine exx_phi_on_grid(inode,atom,spec,extent,xyz,nsuppfuncs,phi_on_grid,r_int,rst)
use numbers, only: zero, one, two, three, four, five, six, fifteen, sixteen
use numbers, only: half, quarter, very_small, pi, twopi, fourpi
use exx_types, only: unit_matrix_write, tmr_std_exx_evalpao
- use exx_types, only: exx_overlap, exx_cartesian
+ use exx_types, only: exx_overlap, exx_cartesian, exx_gto, exx_gto_poisson
+ use exx_evalgto, only: exx_gto_on_grid_new
use angular_coeff_routines, only: evaluate_pao
use dimens, only: r_h
@@ -43,7 +52,7 @@ subroutine exx_phi_on_grid(inode,atom,spec,extent,xyz,nsuppfuncs,phi_on_grid,r_i
intent(inout) :: phi_on_grid
! << Local variables >>
- real(double), dimension(nsuppfuncs) :: sfsum
+ !real(double), dimension(nsuppfuncs) :: sfsum
integer :: nx, ny, nz
integer :: mx, my, mz
@@ -53,7 +62,7 @@ subroutine exx_phi_on_grid(inode,atom,spec,extent,xyz,nsuppfuncs,phi_on_grid,r_i
real(double) :: grid_spacing
real(double) :: x, y, z, r
real(double) :: int, n, rest
- real(double) :: xyz_delta(3)
+ real(double) :: xyz_delta(3), xyz_offset(3)
integer :: count1, nsf1
integer :: ierr, stat
@@ -63,7 +72,8 @@ subroutine exx_phi_on_grid(inode,atom,spec,extent,xyz,nsuppfuncs,phi_on_grid,r_i
real(double) :: xj1, xj2, a, b, c, d, del_r, alpha
real(double) :: a_table, b_table, c_table, d_table
-
+ integer :: i_dummy = 0
+
! << Called subroutine variables >>
real(double) :: pao_val, y_val
@@ -73,191 +83,115 @@ subroutine exx_phi_on_grid(inode,atom,spec,extent,xyz,nsuppfuncs,phi_on_grid,r_i
real(double), parameter :: eg_a_norm = sqrt(fifteen/(sixteen*pi))
real(double), parameter :: eg_b_norm = sqrt(five/(sixteen*pi))
- ngrid = 2*extent+1
- grid_spacing = r_int/real(extent,double)
- phi_on_grid = zero
- sfsum = zero
-
- mx = -extent ; px = extent
- my = mx ; py = px
- mz = my ; pz = py
-
- call start_timer(tmr_std_exx_evalpao)
-
- !Define the overlap box
- overlap_box: if (exx_overlap) then
- do i = 1, 3
- n = xyz(i)/ grid_spacing
- rest = n - real(aint(n))
-
- if (abs(rest) >= half) then
- int = ceiling(abs(n))
- int = sign(int,n)
- xyz_delta(i) = int - n
-
- else if (abs(rest) < half) then
- int = floor(abs(n))
- int = sign(int,n)
- xyz_delta(i) = int - n
-
- else if ((rest == zero)) then
- int = n
- xyz_delta(i) = zero
-
- end if
-
- ijk_delta(i) = int
- xyz_delta(i) = xyz_delta(i)*grid_spacing
- end do
-
- do i = 1, 3
- if (ijk_delta(i) > 0) then
- ijk(i) = ijk_delta(i) + 1
- njk(i) = ngrid
- kji(i) = 1
- nji(i) = ngrid - ijk_delta(i)
-
- else if (ijk_delta(i) < 0) then
- ijk(i) = 1
- njk(i) = ngrid + ijk_delta(i)
- kji(i) = -ijk_delta(i) + 1
- nji(i) = ngrid
-
- else
- ijk(i) = 1
- njk(i) = ngrid
- kji(i) = 1
- nji(i) = ngrid
-
- end if
- !write(*,'(5F12.6,4I6)') xyz(i), n, int, rest, &
- ! xyz_delta(i), ijk(i), njk(i), kji(i), nji(i)
- !write(*,'(4I6)') ijk(i), njk(i), kji(i), nji(i)
-
- end do
- mx = mx +kji(1)-1
- my = my +kji(2)-1
- mz = mz +kji(3)-1
- px = px -ijk(1)+1
- py = py -ijk(2)+1
- pz = pz -ijk(3)+1
- end if overlap_box
-
- grid_x_loop: do nx = mx, px
- x = xyz(1) + real(nx,double)*grid_spacing + rst(1)
-
- grid_y_loop: do ny = my, py
- y = xyz(2) + real(ny,double)*grid_spacing + rst(2)
-
- grid_z_loop: do nz = mz, pz
- z = xyz(3) + real(nz,double)*grid_spacing + rst(3)
-
- !norm = sqrt((x-xyz(1))**2+(y-xyz(2))**2+(z-xyz(3))**2)
- !if (norm <= r_h) then
-
- r = sqrt(x*x+y*y+z*z)
- !if(r < very_small) then
- ! r = zero
- !end if
-
- !print*, '1 cycle start'
-
- count1 = 1
- sfsum = zero
- angu_loop: do l1 = 0, pao(spec)%greatest_angmom
-
- zeta_loop: do acz = 1, pao(spec)%angmom(l1)%n_zeta_in_angmom
-
- magn_loop: do m1 = -l1, l1
-
- pao_val = zero
- y_val = zero
- rec_ylm: if (.not.exx_cartesian) then
- call evaluate_pao(0,spec,l1,acz,m1,x,y,z,pao_val)
- else
- npts = pao(spec)%angmom(l1)%zeta(acz)%length
- del_r = (pao(spec)%angmom(l1)%zeta(acz)%cutoff/&
- (pao(spec)%angmom(l1)%zeta(acz)%length-1))
-
- n1 = floor(r/del_r)
- n2 = n1 + 1
-
- if(n2 > npts-1) then
- pao_val = 0.0_double
-
- else
- xj1 = n1 * del_r
- xj2 = xj1 + del_r
-
- a = (xj2 - r)/del_r
- b = 1.0_double - a
- c = a*(a*a - 1.0_double)*del_r*del_r/6.0_double
- d = b*(b*b - 1.0_double)*del_r*del_r/6.0_double
-
- a_table = pao(spec)%angmom(l1)%zeta(acz)%table(n1+1)
- b_table = pao(spec)%angmom(l1)%zeta(acz)%table(n2+1)
- c_table = pao(spec)%angmom(l1)%zeta(acz)%table2(n1+1)
- d_table = pao(spec)%angmom(l1)%zeta(acz)%table2(n2+1)
-
- pao_val = a*a_table + b*b_table + c*c_table + d*d_table
-
- if (l1 == 0) then !s-type function
- y_val = a1g_norm
-
- else if(l1 == 1) then !p-type function
- r_p: if (r > zero) then
- select case(m1)
- case( 1) !p_x
- y_val = t1u_norm*x
- case( 0) !p_z
- y_val = t1u_norm*z
- case(-1) !p_y
- y_val = t1u_norm*y
- case default
- call cq_abort('exx_phi_on_grid/Unrecognized magn. m ',m1)
- end select
- else
- y_val = zero
- end if r_p
- else if(l1 == 2) then !d-type function
- r_d: if (r > zero) then
- select case(m1)
- case( 2) ! d_{x2-y2}
- y_val = eg_a_norm*(x*x-y*y)
- case( 1) ! d_{xz}
- y_val = t2g_norm*(x*z)
- case( 0) ! d_{z2}
- y_val = eg_b_norm*(3.0d0*z*z-r*r)
- case(-1) ! d_{yz}
- y_val = t2g_norm*(y*z)
- case(-2) ! d_{yz}
- y_val = -t2g_norm*(x*y) ! Take care phase factor
- case default
- call cq_abort('exx_phi_on_grid/Unrecognized mag. m ',m1)
- end select
- else
- y_val = zero
- end if r_d
- else
- call cq_abort('exx_phi_on_grid/Unrecognized angul. l ',l1)
- end if
-
- pao_val = pao_val*y_val
- end if
- end if rec_ylm
-
- ! Put pao_val directly into phi_on_grid
- ! (only for primitive PAOs and not for blips)
- phi_on_grid(nx+extent+1,ny+extent+1,nz+extent+1,count1) = pao_val
-
- count1 = count1 + 1
- end do magn_loop
- end do zeta_loop
- end do angu_loop
-
- end do grid_z_loop
- end do grid_y_loop
- end do grid_x_loop
+ if (exx_gto_poisson) then
+ call exx_gto_on_grid_new(inode,atom,spec,extent,xyz,nsuppfuncs,phi_on_grid,r_int,rst)
+ else
+
+ ngrid = 2*extent+1
+ grid_spacing = r_int/real(extent,double)
+ phi_on_grid = zero
+ !sfsum = zero
+
+ mx = -extent ; px = extent
+ my = mx ; py = px
+ mz = my ; pz = py
+
+ call start_timer(tmr_std_exx_evalpao)
+
+ !Define the overlap box
+ overlap_box: if (exx_overlap) then
+ do i = 1, 3
+ n = xyz(i)/ grid_spacing
+ rest = n - real(aint(n))
+
+ if (abs(rest) >= half) then
+ int = ceiling(abs(n))
+ int = sign(int,n)
+ xyz_delta(i) = int - n
+
+ else if (abs(rest) < half) then
+ int = floor(abs(n))
+ int = sign(int,n)
+ xyz_delta(i) = int - n
+
+ else if ((rest == zero)) then
+ int = n
+ xyz_delta(i) = zero
+
+ end if
+
+ ijk_delta(i) = int
+ xyz_delta(i) = xyz_delta(i)*grid_spacing
+ end do
+
+ do i = 1, 3
+ if (ijk_delta(i) > 0) then
+ ijk(i) = ijk_delta(i) + 1
+ njk(i) = ngrid
+ kji(i) = 1
+ nji(i) = ngrid - ijk_delta(i)
+
+ else if (ijk_delta(i) < 0) then
+ ijk(i) = 1
+ njk(i) = ngrid + ijk_delta(i)
+ kji(i) = -ijk_delta(i) + 1
+ nji(i) = ngrid
+
+ else
+ ijk(i) = 1
+ njk(i) = ngrid
+ kji(i) = 1
+ nji(i) = ngrid
+
+ end if
+ !write(*,'(5F12.6,4I6)') xyz(i), n, int, rest, &
+ ! xyz_delta(i), ijk(i), njk(i), kji(i), nji(i)
+ !write(*,'(4I6)') ijk(i), njk(i), kji(i), nji(i)
+
+ end do
+ mx = mx +kji(1)-1
+ my = my +kji(2)-1
+ mz = mz +kji(3)-1
+ px = px -ijk(1)+1
+ py = py -ijk(2)+1
+ pz = pz -ijk(3)+1
+ end if overlap_box
+ xyz_offset = xyz + rst
+
+ !$omp parallel do collapse(3) schedule(runtime) default(none) &
+ !$omp shared(mx,my,mz,px,py,pz,grid_spacing,xyz_offset,pao, &
+ !$omp spec,phi_on_grid,i_dummy,exx_cartesian,extent) &
+ !$omp private(nx,ny,nz,x,y,z,count1,l1,acz,m1,pao_val)
+ grid_x_loop: do nx = mx, px
+ grid_y_loop: do ny = my, py
+ grid_z_loop: do nz = mz, pz
+ x = nx*grid_spacing + xyz_offset(1)
+ y = ny*grid_spacing + xyz_offset(2)
+ z = nz*grid_spacing + xyz_offset(3)
+
+ count1 = 1
+ angu_loop: do l1 = 0, pao(spec)%greatest_angmom
+
+ zeta_loop: do acz = 1, pao(spec)%angmom(l1)%n_zeta_in_angmom
+
+ magn_loop: do m1 = -l1, l1
+
+ call evaluate_pao(i_dummy,spec,l1,acz,m1,x,y,z,pao_val,exx_cartesian)
+
+ ! Put pao_val directly into phi_on_grid
+ ! (only for primitive PAOs and not for blips)
+ phi_on_grid(nx+extent+1,ny+extent+1,nz+extent+1,count1) = pao_val
+ count1 = count1 + 1
+ end do magn_loop
+ end do zeta_loop
+ end do angu_loop
+
+ end do grid_z_loop
+ end do grid_y_loop
+ end do grid_x_loop
+ !$omp end parallel do
+
+ end if
call stop_timer(tmr_std_exx_evalpao,.true.)
diff --git a/src/exx_kernel_default.f90 b/src/exx_kernel_default.f90
index c5bed2b8c..425d5f8aa 100644
--- a/src/exx_kernel_default.f90
+++ b/src/exx_kernel_default.f90
@@ -12,7 +12,7 @@
!! exx_kernel_default
!!
!! PURPOSE
-!! Holds the routines to compute exact exchange matrix (matX)
+!! Holds the routines to compute exact exchange matrix (matXatomf)
!! Parallelized version deriving from multiply_kernel_default
!!
!! AUTHOR
@@ -47,11 +47,11 @@ module exx_kernel_default
use timer_module, only: start_timer, stop_timer, print_timer, lun_tmr
use timer_module, only: start_backtrace, stop_backtrace, cq_timer
use timer_stdclocks_module, only: tmr_std_exx
-
- !**** ISF Poisson solver Will be available in the forthcoming version
+ use global_module, only: exx_cutoff
+ !use dimens, only: r_exx
!use Poisson_Solver, only: PSolver, createKernel, gequad
-
- use exx_types, only: reckernel_3d, fftwrho3d, exx_debug
+
+ use exx_types, only: reckernel_3d, exx_debug
use exx_io
implicit none
@@ -59,10 +59,10 @@ module exx_kernel_default
! Area identification
integer, parameter, private :: area = 13
-!!***
-
+ !!***
+
contains
-
+
!!****f* exx_kernel_default/get_X_matrix *
!!
!! NAME
@@ -86,9 +86,13 @@ module exx_kernel_default
!! tags)
!! 2018/11/13 18:00 nakata
!! Removed matS which was passed but not used
+ !! 2020/12/06 16:26 Lionel
+ !! added calculation of ERIs with storage
+ !! 2020/28/12 17:40 Lionel
+ !! added numerical ERI filtering (usefull for debugg)
!! SOURCE
!!
- subroutine get_X_matrix( exxspin, level )
+ subroutine get_X_matrix( exxspin, scheme, backup_eris, niter, siter, level )
use numbers
use global_module
@@ -100,53 +104,55 @@ subroutine get_X_matrix( exxspin, level )
use GenComms, only: my_barrier, cq_abort, mtime
use multiply_module, only: prefetch
!
- use energy, only: exx_energy
- !
- use primary_module, only: bundle
- use cover_module, only: BCS_parts
- use matrix_data, only: mat, Hrange, Srange, Xrange, SXrange, halo, rcut
+ use matrix_data, only: Hrange, Srange, Xrange, SXrange
use mult_module, only: S_X_SX, mat_p, mult
- use mult_module, only: matX, matK, matrix_scale, matrix_trace
+ use mult_module, only: matXatomf, matK, matrix_scale, matrix_trace
use mult_module, only: matrix_product_trace, matrix_product_trace_length
- use mult_module, only: return_matrix_value, matrix_pos
+ use mult_module, only: return_matrix_value, matrix_pos, matrix_sum
use mult_module, only: store_matrix_value, store_matrix_value_pos
- use memory_module, only: write_mem_use
+ use mult_module, only: matrix_transpose, allocate_temp_matrix, free_temp_matrix, matX, S_trans
+ use memory_module, only: write_mem_use, reg_alloc_mem, reg_dealloc_mem, type_dbl, type_int
use species_module, only: nsf_species
!
use exx_memory, only: exx_mem_alloc
!
- use exx_types, only: prim_atomic_data, neigh_atomic_data, &
- tmr_std_exx_evalpao, &
- tmr_std_exx_setup, tmr_std_exx_fetch_K, &
+ use fft_interface_module, only: fft3_init_wrapper
+ !
+ use exx_types, only: prim_atomic_data, neigh_atomic_data, store_eris, &
+ tmr_std_exx_evalpao, tmr_std_exx_nsup, &
+ tmr_std_exx_setup, tmr_std_exx_barrier, &
tmr_std_exx_fetch, tmr_std_exx_accumul, &
tmr_std_exx_matmult, tmr_std_exx_poisson, &
tmr_std_exx_allocat, tmr_std_exx_dealloc, &
- tmr_std_exx_fetch, tmr_std_exx_kernel, &
- unit_matrix_write, unit_output_write, &
- unit_timers_write, unit_screen_write, &
- unit_memory_write
+ tmr_std_exx_comms, tmr_std_exx_kernel, &
+ unit_timers_write, unit_memory_write, &
+ unit_exx_debug, unit_eri_debug, &
+ unit_eri_filter_debug, &
+ file_exx_timers, file_exx_memory, &
+ file_exx_debug, file_eri_debug, &
+ file_eri_filter_debug
- use exx_types, only: grid_spacing, r_int, extent, &
- ewald_alpha, ewald_charge, ewald_rho, ewald_pot, &
+ use exx_types, only: exx_alloc, r_int, extent, &
+ ewald_alpha, ewald_rho, ewald_pot, &
pulay_radius, p_omega, p_ngauss, p_gauss, w_gauss, &
- exx_psolver,p_scheme, isf_order, ngrid, kernel, &
- exx_alloc, exx_mem, exx_phil, exx_screen_pao, &
- exx_total_time
+ exx_psolver,exx_pscheme, kernel, &
+ exx_total_time, eris, exx_filter, exx_gto
!
- use exx_module,only: exx_scal_rho_3d, exx_ewald_rho, exx_ewald_pot
+ use exx_poisson, only: exx_scal_rho_3d, exx_ewald_rho, exx_ewald_pot
!
- !**** ISF Poisson solver Will be available in the forthcoming version
- !use Poisson_Solver, only: createBeylkin
+ use input_module, only: fdf_boolean
!
implicit none
- integer, optional :: level
+ integer, intent(in), optional :: level
+ integer, intent(in) :: exxspin, scheme
+ logical, intent(in) :: backup_eris
+
+ integer, intent(in) :: niter, siter
! Local variables
- integer :: exxspin
- integer :: lab_const
- integer :: invdir,ierr,kpart,ind_part,ncover_yz,n_which,ipart,nnode
- integer :: icall,n_cont,kpart_next,ind_partN,k_off
+ integer :: invdir,ierr,kpart,ind_part,ncover_yz,ipart,nnode
+ integer :: icall,n_cont,k_off
integer :: icall2,stat,ilen2,lenb_rem
! Remote variables to be allocated
integer(integ),allocatable :: ibpart_rem(:)
@@ -161,12 +167,8 @@ subroutine get_X_matrix( exxspin, level )
integer(integ),pointer :: ibndimj_rem(:)
! Arrays for remote variables to point to
-
-
-
integer, target :: part_array(3*mult(S_X_SX)%parts%mx_mem_grp+ &
- 5*mult(S_X_SX)%parts%mx_mem_grp*mult(S_X_SX)%bmat( exxspin )%mx_abs)
-
+ 5*mult(S_X_SX)%parts%mx_mem_grp*mult(S_X_SX)%bmat(1)%mx_abs)
integer, allocatable, dimension(:) :: recv_part
@@ -174,158 +176,160 @@ subroutine get_X_matrix( exxspin, level )
integer, dimension(MPI_STATUS_SIZE) :: mpi_stat
integer :: offset,sends,i,j
- logical :: flag,call_flag
+ logical :: get_exx
real(double) :: t0,t1
-
- integer :: iprim, np, nsf1, nsf2, gcspart
- integer :: maxsuppfuncs
-
- type(prim_atomic_data) :: ia !i_alpha
- type(neigh_atomic_data) :: jb !j_beta
- type(neigh_atomic_data) :: kg !k_gamma
- type(neigh_atomic_data) :: ld !l_delta
- !
- real(double) :: xyz_ghost(3), r_ghost, tmp
- integer :: wheremat
- !
- integer :: unit1, unit2, unit3, unit4, unit5
- character(len=20) :: filename1, filename2, filename3, filename4, filename5, filename6, filename7
+ integer :: maxsuppfuncs, nb_eris
type(cq_timer) :: backtrace_timer
- integer :: backtrace_level
+ integer :: backtrace_level, mattmp
!
!==============================================================================================================
-!****lat<$
+ !****lat<$
if ( present(level) ) backtrace_level = level+1
if ( .not. present(level) ) backtrace_level = -10
call start_backtrace(t=backtrace_timer,who='get_X_matrix',&
where=area,level=backtrace_level,echo=.true.)
-!****lat>$
-
+ !****lat>$
+
call start_timer(tmr_std_exx)
call start_timer(tmr_std_exx_setup)
!
if ( iprint_exx > 3 ) then
- !call io_assign(unit_matrix_write)
- !unit1 = unit_matrix_write
- !unit1 = 100001
- !unit_matrix_write = unit1
- !call get_file_name('exx_matrix.debug',numprocs,inode,filename1)
- !open(unit1,file=filename1)
-
- !call io_assign(unit_output_write)
- !unit2 = unit_output_write
- !unit2 = 100002
- !unit_output_write = unit2
- !call get_file_name('exx_output.debug',numprocs,inode,filename2)
- !open(unit2,file=filename2)
-
- call io_assign(unit_timers_write)
- call get_file_name('exx_timers',numprocs,inode,filename3)
- open(unit_timers_write,file=filename3)
!
+ if (fdf_boolean('IO.WriteOutToFile',.true.)) then
+ if ( (niter == 1 .and. scheme == 3) .or. (niter == siter + 1 .and. (scheme == 1 .or. scheme == 2 ) )) then
+ call io_assign(unit_timers_write)
+ call get_file_name('exx_timers',numprocs,inode,file_exx_timers)
+ open(unit_timers_write,file=file_exx_timers)
+ !
+ call io_assign(unit_memory_write)
+ call get_file_name('exx_memory',numprocs,inode,file_exx_memory)
+ open(unit_memory_write,file=file_exx_memory)
+ !
+ else
+
+ open(unit_timers_write,file=file_exx_timers,status='old', position='append')
+ open(unit_memory_write,file=file_exx_memory,status='old', position='append')
+ end if
+ else
+ unit_timers_write = 6
+ unit_memory_write = 6
+ end if
!
- call io_assign(unit_memory_write)
- call get_file_name('exx_memory',numprocs,inode,filename4)
- open(unit_memory_write,file=filename4)
-
- !call io_assign(unit_screen_write)
- !unit5 = unit_screen_write
- !unit5 = 100005
- !unit_screen_write = unit5
- !call get_file_name('exx_screen.debug',numprocs,inode,filename5)
- !open(unit5,file=filename5)
-
- !call io_assign(unit_exx_debug)
- !call get_file_name('Exx_debug.debug',numprocs,inode,filename6)
- !open(unit_exx_debug,file=filename6)
- !call exx_write_head(unit_exx_debug,inode,bundle%groups_on_node)
- !
- !call exx_global_write()
+ end if
+
+ if ( exx_debug ) then
+
+ if ( (niter == 1 .and. scheme == 3) .or. (niter == siter + 1 .and. (scheme == 1 .or. scheme == 2 ) )) then
+ call io_assign(unit_exx_debug)
+ call get_file_name('exx_debug',numprocs,inode,file_exx_debug)
+ open(unit_exx_debug,file=file_exx_debug)
+ !
+ call io_assign(unit_eri_debug)
+ call get_file_name('eri_debug',numprocs,inode,file_eri_debug)
+ open(unit_eri_debug,file=file_eri_debug)
+ !
+ call io_assign(unit_eri_filter_debug)
+ call get_file_name('eri_filter_debug',numprocs,inode,file_eri_filter_debug)
+ open(unit_eri_filter_debug,file=file_eri_filter_debug)
+ !
+ else
+ open(unit_exx_debug,file=file_exx_debug,status='old', position='append')
+ open(unit_eri_debug,file=file_eri_debug,status='old', position='append')
+ open(unit_eri_filter_debug,file=file_eri_filter_debug,status='old', position='append')
+ !
+ end if
!
end if
!
maxsuppfuncs = maxval(nsf_species)
!
- call exx_mem_alloc(extent,0,0,'work_3d' ,'alloc')
+ if ( scheme > 0 ) then
+ call exx_mem_alloc(extent,0,0,'work_3d' ,'alloc')
+ end if
!
!DRB! This appears to set up the different Poisson solvers
if (exx_psolver == 'fftw') then
call exx_mem_alloc(extent,0,0,'fftw_3d','alloc')
call exx_mem_alloc(extent,0,0,'reckernel_3d','alloc')
- poisson_fftw: select case(p_scheme)
+ poisson_fftw: select case(exx_pscheme)
case('default')
- call exx_scal_rho_3d(inode,extent,r_int,p_scheme,pulay_radius, &
- p_omega,p_ngauss,p_gauss,w_gauss)
+ call exx_scal_rho_3d(inode,extent,r_int,exx_pscheme,pulay_radius, &
+ p_omega,p_ngauss,p_gauss,w_gauss,reckernel_3d)
case('ewald')
call exx_mem_alloc(extent,0,0,'ewald_3d','alloc')
call exx_ewald_rho(ewald_rho,extent,ewald_alpha,r_int)
call exx_ewald_pot(ewald_pot,extent,ewald_alpha,r_int)
- call exx_scal_rho_3d(inode,extent,r_int,p_scheme,pulay_radius, &
- p_omega,p_ngauss,p_gauss,w_gauss)
-
+ call exx_scal_rho_3d(inode,extent,r_int,exx_pscheme,pulay_radius, &
+ p_omega,p_ngauss,p_gauss,w_gauss,reckernel_3d)
+
case('pulay')
- call exx_scal_rho_3d(inode,extent,r_int,p_scheme,pulay_radius, &
- p_omega,p_ngauss,p_gauss,w_gauss)
+ call exx_scal_rho_3d(inode,extent,r_int,exx_pscheme,pulay_radius, &
+ p_omega,p_ngauss,p_gauss,w_gauss,reckernel_3d)
case('yukawa')
- call exx_scal_rho_3d(inode,extent,r_int,p_scheme,pulay_radius, &
- p_omega,p_ngauss,p_gauss,w_gauss)
+ call exx_scal_rho_3d(inode,extent,r_int,exx_pscheme,pulay_radius, &
+ p_omega,p_ngauss,p_gauss,w_gauss,reckernel_3d)
case('gauss')
- call cq_abort('EXX: Gaussian representation if 1/r for solving &
- &the Poisson equation &
- &is currently under testing...')
- !call createBeylkin(p_gauss,w_gauss,r_int)
- !call exx_scal_rho_3d(inode,extent,r_int,p_scheme,pulay_radius, &
- ! p_omega,p_ngauss,p_gauss,w_gauss)
+ call cq_abort('EXX Gaussian representation if 1/r for solving &
+ &the Poisson equation &
+ &is currently under testing...')
case default
- call exx_scal_rho_3d(inode,extent,r_int,p_scheme,pulay_radius, &
- p_omega,p_ngauss,p_gauss,w_gauss)
+ call exx_scal_rho_3d(inode,extent,r_int,exx_pscheme,pulay_radius, &
+ p_omega,p_ngauss,p_gauss,w_gauss,reckernel_3d)
end select poisson_fftw
else if (exx_psolver == 'isf') then
- call cq_abort('EXX: ISF Poisson solver is not available yet ; &
- &under optimisation...')
- !call exx_mem_alloc(extent,0,0,'isf_rho','alloc')
- !call createKernel('F',ngrid,ngrid,ngrid,grid_spacing,grid_spacing,grid_spacing,isf_order,&
- ! 0,1,kernel)
-
+ call cq_abort('EXX with ISF Poisson solver disabled')
+ !
end if
call stop_timer(tmr_std_exx_setup,.true.)
!
- !DRB! Zero matrix - spin polarised possible - fix this later ?
- !DRB! Where is matX allocated ? immi
- !call matrix_scale(zero, matX(1))
- !
- !
- call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_i','alloc')
- call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_j','alloc')
- call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_k','alloc')
- call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_l','alloc')
- !
- call exx_mem_alloc(extent,maxsuppfuncs,0,'Phy_k','alloc')
- call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'Ome_kj','alloc')
- call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'rho_kj','alloc')
- call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'vhf_kj','alloc')
+ if ( .not. exx_alloc ) then
+ !
+ if ( scheme > 0 ) then
+ call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_i','alloc')
+ call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_j','alloc')
+ call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_k','alloc')
+ call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_l','alloc')
+ !
+ if ( scheme == 1 ) then
+ call exx_mem_alloc(extent,maxsuppfuncs,0,'Phy_k','alloc')
+ call exx_mem_alloc(extent,0,0,'Ome_kj_1d_buffer','alloc')
+ !
+ end if
+ !
+ end if
+ !
+ end if
!
+ if ( scheme == 3 ) then
+ !
+ if ( niter == 1 .and. exxspin==1) then
+ allocate( eris( mult(S_X_SX)%ahalo%np_in_halo ), STAT=stat)
+ if(stat/=0) call cq_abort('Error allocating memory to eris/exx !',stat)
+ end if
+ !
+ end if
!
+ !
!==============================================================================================================
!
- call matrix_scale(zero,matX( exxspin ))
+ call matrix_scale(zero,matXatomf( exxspin ))
!
call start_timer(tmr_std_exx_kernel)
!
call start_timer(tmr_std_exx_allocat)
if(iprint_mat>3.AND.myid==0) t0 = mtime()
! Allocate memory for the elements
- allocate(ibpart_rem(mult(S_X_SX)%parts%mx_mem_grp*mult(S_X_SX)%bmat( exxspin )%mx_abs),STAT=stat)
+ allocate(ibpart_rem(mult(S_X_SX)%parts%mx_mem_grp*mult(S_X_SX)%bmat(1)%mx_abs),STAT=stat)
if(stat/=0) call cq_abort('mat_mult: error allocating ibpart_rem')
call stop_timer(tmr_std_exx_allocat,.true.)
!
@@ -341,49 +345,26 @@ subroutine get_X_matrix( exxspin, level )
call start_timer(tmr_std_exx_allocat)
allocate(nreqs(sends*2),STAT=stat)
if(stat/=0) call cq_abort("mat_mult: Error allocating nreqs",sends,stat)
- call stop_timer(tmr_std_exx_allocat,.true.)
allocate(recv_part(0:mult(S_X_SX)%comms%inode),STAT=stat)
if(stat/=0) call cq_abort('mat_mult: error allocating recv_part')
+ call stop_timer(tmr_std_exx_allocat,.true.)
+ !
recv_part = zero
!
sends = 0
invdir = 0
- call Mquest_start_send(mult(S_X_SX),mat_p(matK( exxspin ))%matrix,nreqs,myid,mult(S_X_SX)%prim%mx_ngonn,sends)
- !ncover_yz=mult(S_X_SX)%gcs%ncovery*mult(S_X_SX)%gcs%ncoverz
- ncover_yz=mult(S_X_SX)%gcs%ncovery*mult(S_X_SX)%gcs%ncoverz
!
- ! #ifdef OMP_M
- ! !$omp parallel default(none) &
- ! !$omp shared(a, b, c, a_b_c, myid, lena, lenc, tmr_std_allocation, &
- ! !$omp ncover_yz, ibpart_rem, atrans, usegemm) &
- ! !$omp private(kpart, icall, ind_part, ipart, nnode, b_rem, &
- ! !$omp lenb_rem, n_cont, part_array, ilen2, offset, &
- ! !$omp nbnab_rem, ibind_rem, ib_nd_acc_rem, ibseq_rem, &
- ! !$omp npxyz_rem, ibndimj_rem, k_off, icall2)
- ! !$omp do
- ! #end if
- !
- if ( exx_debug ) then
- call hf_write_info(unit1,inode,10,mult(S_X_SX)%ahalo%np_in_halo,0,0,0,0, &
- 0,0,'XX',xyz_ghost,r_ghost,0,0,0,zero,zero,0)
- end if
+ call start_timer(tmr_std_exx_comms)
+ call Mquest_start_send(mult(S_X_SX),mat_p(matK( exxspin ))%matrix,nreqs,myid,mult(S_X_SX)%prim%mx_ngonn,sends)
+ call stop_timer(tmr_std_exx_comms,.true.)
!
+ ncover_yz=mult(S_X_SX)%gcs%ncovery*mult(S_X_SX)%gcs%ncoverz
!
- !call hf_write_info(unit1,inode,10,bundle%groups_on_node,0,0,0,0, &
- ! 0,0,'XX',xyz_ghost,r_ghost,0,0,0,zero,zero,0)
!
- xyz_ghost = zero
- r_ghost = zero
do kpart = 1,mult(S_X_SX)%ahalo%np_in_halo ! Main loop
icall=1
ind_part = mult(S_X_SX)%ahalo%lab_hcell(kpart)
!
- !print*, 'inode', inode,'kpart', kpart, ind_part
- if ( exx_debug ) then
- call hf_write_info(unit1,inode,20,0,kpart,mult(S_X_SX)%ahalo%np_in_halo,0,0, &
- 0,0,'XX',xyz_ghost,r_ghost,0,0,0,zero,zero,0)
- end if
- !
if(kpart>1) then ! Is it a periodic image of the previous partition ?
if(ind_part.eq.mult(S_X_SX)%ahalo%lab_hcell(kpart-1)) then
icall=0
@@ -392,19 +373,26 @@ subroutine get_X_matrix( exxspin, level )
nnode = mult(S_X_SX)%comms%neigh_node_list(kpart)
recv_part(nnode) = recv_part(nnode)+1
!
+ call start_timer(tmr_std_exx_dealloc)
if(allocated(b_rem)) deallocate(b_rem)
+ call stop_timer(tmr_std_exx_dealloc,.true.)
+ !
if(mult(S_X_SX)%parts%i_cc2node(ind_part)==myid+1) then
lenb_rem = mult(S_X_SX)%bmat(ipart)%part_nd_nabs
else
lenb_rem = mult(S_X_SX)%comms%ilen3rec(ipart,nnode)
end if
!
+ call start_timer(tmr_std_exx_allocat)
allocate(b_rem(lenb_rem))
+ call stop_timer(tmr_std_exx_allocat,.true.)
!
+ call start_timer(tmr_std_exx_comms)
call prefetch(kpart,mult(S_X_SX)%ahalo,mult(S_X_SX)%comms,mult(S_X_SX)%bmat,icall, &
n_cont,part_array,mult(S_X_SX)%bindex,b_rem,lenb_rem,mat_p(matK( exxspin ))%matrix, &
myid,ilen2,mx_msg_per_part,mult(S_X_SX)%parts,mult(S_X_SX)%prim,mult(S_X_SX)%gcs,&
(recv_part(nnode)-1)*2)
+ call stop_timer(tmr_std_exx_comms,.true.)
!
offset = 0
nbnab_rem => part_array(offset+1:offset+n_cont)
@@ -420,12 +408,15 @@ subroutine get_X_matrix( exxspin, level )
ibndimj_rem => part_array(offset+1:offset+ilen2)
!
if(offset+ilen2>3*mult(S_X_SX)%parts%mx_mem_grp+ &
- 5*mult(S_X_SX)%parts%mx_mem_grp*mult(S_X_SX)%bmat( exxspin )%mx_abs) then
+ 5*mult(S_X_SX)%parts%mx_mem_grp*mult(S_X_SX)%bmat(1)%mx_abs) then
call cq_abort('mat_mult: error pointing to part_array ',kpart)
end if
- ! Create ibpart_rem
+
+ call start_timer(tmr_std_exx_comms)
call end_part_comms(myid,n_cont,nbnab_rem,ibind_rem,npxyz_rem,&
ibpart_rem,ncover_yz,mult(S_X_SX)%gcs%ncoverz)
+ call stop_timer(tmr_std_exx_comms,.true.)
+ !
end if
else ! Get the data
ipart = mult(S_X_SX)%parts%i_cc2seq(ind_part)
@@ -433,7 +424,10 @@ subroutine get_X_matrix( exxspin, level )
recv_part(nnode) = recv_part(nnode)+1
!
!
+ call start_timer(tmr_std_exx_dealloc)
if(allocated(b_rem)) deallocate(b_rem)
+ call stop_timer(tmr_std_exx_dealloc,.true.)
+ !
if(mult(S_X_SX)%parts%i_cc2node(ind_part)==myid+1) then
lenb_rem = mult(S_X_SX)%bmat(ipart)%part_nd_nabs
else
@@ -446,11 +440,12 @@ subroutine get_X_matrix( exxspin, level )
allocate(b_rem(lenb_rem))
call stop_timer(tmr_std_exx_allocat,.true.)
!
- !
+ call start_timer(tmr_std_exx_comms)
call prefetch(kpart,mult(S_X_SX)%ahalo,mult(S_X_SX)%comms,mult(S_X_SX)%bmat,icall, &
n_cont,part_array,mult(S_X_SX)%bindex,b_rem,lenb_rem,mat_p(matK( exxspin ))%matrix, &
myid,ilen2,mx_msg_per_part,mult(S_X_SX)%parts,mult(S_X_SX)%prim,mult(S_X_SX)%gcs,&
(recv_part(nnode)-1)*2)
+ call stop_timer(tmr_std_exx_comms,.true.)
!
lenb_rem = size(b_rem)
!
@@ -463,47 +458,179 @@ subroutine get_X_matrix( exxspin, level )
offset = offset+3*ilen2 ; ibndimj_rem => part_array(offset+1:offset+ilen2)
!
if(offset+ilen2>3*mult(S_X_SX)%parts%mx_mem_grp+ &
- 5*mult(S_X_SX)%parts%mx_mem_grp*mult(S_X_SX)%bmat( exxspin )%mx_abs) then
+ 5*mult(S_X_SX)%parts%mx_mem_grp*mult(S_X_SX)%bmat(1)%mx_abs) then
call cq_abort('Error pointing to part_array !',kpart)
end if
- !
+ !
+ call start_timer(tmr_std_exx_comms)
call end_part_comms(myid,n_cont,nbnab_rem,ibind_rem,npxyz_rem,&
ibpart_rem,ncover_yz,mult(S_X_SX)%gcs%ncoverz)
+ call stop_timer(tmr_std_exx_comms,.true.)
!
end if ! End of the "if this isn't the first partition" loop
k_off = mult(S_X_SX)%ahalo%lab_hcover(kpart) ! --- offset for pbcs
icall2 = 1
!
- call m_kern_exx( k_off,kpart,ib_nd_acc_rem,ibind_rem,nbnab_rem,&
- ibpart_rem,ibseq_rem,ibndimj_rem, &
- !atrans, &
- b_rem, &
- mat_p(matX( exxspin ))%matrix, &
- mult(S_X_SX)%ahalo,mult(S_X_SX)%chalo,mult(S_X_SX)%ltrans, &
- mult(S_X_SX)%bmat( exxspin )%mx_abs,mult(S_X_SX)%parts%mx_mem_grp, &
- mult(S_X_SX)%prim%mx_iprim, &
- !lena, &
- lenb_rem, &
- mat_p(matX( exxspin ))%length)
+ if ( scheme == 1 ) then
+
+ if (iprint_exx > 5) write(io_lun,*) 'Proc :', myid, &
+ 'EXX: performing CRI calculation on kpart =', kpart
+
+ call m_kern_exx_cri( k_off,kpart,ib_nd_acc_rem,ibind_rem,nbnab_rem,&
+ ibpart_rem,ibseq_rem,ibndimj_rem, &
+ b_rem, &
+ mat_p(matXatomf( exxspin ))%matrix, &
+ mult(S_X_SX)%ahalo,mult(S_X_SX)%chalo,mult(S_X_SX)%ltrans, &
+ mult(S_X_SX)%bmat(1)%mx_abs,mult(S_X_SX)%parts%mx_mem_grp, &
+ lenb_rem, &
+ mat_p(matXatomf( exxspin ))%length)
+
+ else if ( scheme == 2 ) then
+
+ if (iprint_exx > 5) write(io_lun,*) 'Proc :', myid, &
+ 'EXX: performing on-the-fly ERI calculation on kpart =', kpart
+ call m_kern_exx_eri( k_off,kpart,ib_nd_acc_rem,ibind_rem,nbnab_rem,&
+ ibpart_rem,ibseq_rem, &
+ b_rem, &
+ mat_p(matXatomf( exxspin ))%matrix, &
+ mult(S_X_SX)%ahalo,mult(S_X_SX)%chalo,mult(S_X_SX)%ltrans, &
+ mult(S_X_SX)%bmat(1)%mx_abs,mult(S_X_SX)%parts%mx_mem_grp, &
+ lenb_rem, &
+ mat_p(matXatomf( exxspin ))%length, backup_eris)
+
+ else if (scheme == 3 ) then
+
+ if ( niter == 1 .and. exxspin==1) then
+ !
+ get_exx = .false.
+ !
+ if (iprint_exx > 5) write(io_lun,*) 'Proc :', myid, &
+ 'EXX: preparing store ERI calculation on kpart =', kpart
+ !
+ ! First dummy call to get the number of ERIs on each proc
+ !
+ call m_kern_exx_dummy( k_off,kpart,ib_nd_acc_rem,ibind_rem,nbnab_rem,&
+ ibpart_rem,ibseq_rem, &
+ b_rem, &
+ mat_p(matXatomf( exxspin ))%matrix, &
+ mult(S_X_SX)%ahalo,mult(S_X_SX)%chalo,mult(S_X_SX)%ltrans, &
+ mult(S_X_SX)%bmat(1)%mx_abs,mult(S_X_SX)%parts%mx_mem_grp, &
+ lenb_rem, &
+ mat_p(matXatomf( exxspin ))%length, nb_eris, get_exx, .false. )
+
+
+ if (iprint_exx > 5) write(io_lun,*) 'Proc :', myid, &
+ 'EXX: allocate ERIs on kpart =', kpart
+
+ !
+ ! Allocate ERI arrays
+ !
+ call start_timer(tmr_std_exx_allocat)
+ allocate(eris(kpart)%store_eris( nb_eris ), STAT=stat)
+ call stop_timer(tmr_std_exx_allocat,.true.)
+ if(stat/=0) call cq_abort('Error allocating memory toeris/exx !',stat)
+ eris(kpart)%store_eris = 0.0d0
+ !
+ call start_timer(tmr_std_exx_allocat)
+ allocate(eris(kpart)%filter_eris( nb_eris ), STAT=stat)
+ call stop_timer(tmr_std_exx_allocat,.true.)
+ if(stat/=0) call cq_abort('Error allocating memory toeris/exx !',stat)
+ call reg_alloc_mem(area_exx, nb_eris, type_int,'eris',unit_memory_write)
+ eris(kpart)%filter_eris = .true.
+
+ !
+ ! Second dummy call for poor-man filtering of ERIs
+ !
+ if ( exx_filter ) then
+ !
+ if (iprint_exx > 5) write(io_lun,*) 'Proc :', myid, &
+ 'EXX: setup filtering on kpart =', kpart
+ !
+ call m_kern_exx_dummy( k_off,kpart,ib_nd_acc_rem,ibind_rem,nbnab_rem,&
+ ibpart_rem,ibseq_rem, &
+ b_rem, &
+ mat_p(matXatomf( exxspin ))%matrix, &
+ mult(S_X_SX)%ahalo,mult(S_X_SX)%chalo,mult(S_X_SX)%ltrans, &
+ mult(S_X_SX)%bmat(1)%mx_abs,mult(S_X_SX)%parts%mx_mem_grp, &
+ lenb_rem, &
+ mat_p(matXatomf( exxspin ))%length, nb_eris, get_exx, exx_filter )
+ end if
+ !
+ !call my_barrier()
+ !
+ if (iprint_exx > 5) write(io_lun,*) 'Proc :', myid, &
+ 'EXX: compute and store ERIs on kpart =', kpart
+ !
+ ! Third call to compute and store ERIs
+ !
+ call m_kern_exx_eri( k_off,kpart,ib_nd_acc_rem,ibind_rem,nbnab_rem,&
+ ibpart_rem,ibseq_rem, &
+ b_rem, &
+ mat_p(matXatomf( exxspin ))%matrix, &
+ mult(S_X_SX)%ahalo,mult(S_X_SX)%chalo,mult(S_X_SX)%ltrans, &
+ mult(S_X_SX)%bmat(1)%mx_abs,mult(S_X_SX)%parts%mx_mem_grp, &
+ lenb_rem, &
+ mat_p(matXatomf( exxspin ))%length, backup_eris)
+
+ else
+ !
+ get_exx = .true.
+
+ if (iprint_exx > 5) write(io_lun,*) 'Proc :', myid, &
+ 'EXX: use stored ERIs to get X on kpart =', kpart
+
+ call m_kern_exx_dummy( k_off,kpart,ib_nd_acc_rem,ibind_rem,nbnab_rem,&
+ ibpart_rem,ibseq_rem, &
+ b_rem, &
+ mat_p(matXatomf( exxspin ))%matrix, &
+ mult(S_X_SX)%ahalo,mult(S_X_SX)%chalo,mult(S_X_SX)%ltrans, &
+ mult(S_X_SX)%bmat(1)%mx_abs,mult(S_X_SX)%parts%mx_mem_grp, &
+ lenb_rem, &
+ mat_p(matXatomf( exxspin ))%length, nb_eris, get_exx, .false. )
+ end if
+
+ else if ( scheme == -1 ) then
+
+ get_exx = .false.
+
+ if (iprint_exx > 5) write(io_lun,*) 'Proc :', myid, &
+ 'EXX: dummy calculation on kpart =', kpart
+
+ call m_kern_exx_dummy( k_off,kpart,ib_nd_acc_rem,ibind_rem,nbnab_rem,&
+ ibpart_rem,ibseq_rem, &
+ b_rem, &
+ mat_p(matXatomf( exxspin ))%matrix, &
+ mult(S_X_SX)%ahalo,mult(S_X_SX)%chalo,mult(S_X_SX)%ltrans, &
+ mult(S_X_SX)%bmat(1)%mx_abs,mult(S_X_SX)%parts%mx_mem_grp, &
+ lenb_rem, &
+ mat_p(matXatomf( exxspin ))%length, nb_eris, get_exx, .false. )
+
+ end if
+
end do ! End of the kpart=1,ahalo%np_in_halo loop !
+ ! Symmetrise the matrix: note that this needs to be made compatiable with MSSF
+ mattmp = allocate_temp_matrix(Srange,S_trans)
+ call matrix_transpose(matX(exxspin),mattmp)
+ call matrix_sum(half,matXatomf(exxspin),half,mattmp)
+ call free_temp_matrix(mattmp)
!
- ! #ifdef OMP_M
- ! !$omp end do
- ! !$omp end parallel
- ! #end if
!
call start_timer(tmr_std_exx_dealloc)
if(allocated(b_rem)) deallocate(b_rem)
call stop_timer(tmr_std_exx_dealloc,.true.)
!
+ call start_timer(tmr_std_exx_comms)
if(sends>0) then
do i=1,sends
call MPI_Wait(nreqs(i),mpi_stat,ierr)
if(ierr/=0) call cq_abort("Error waiting for send to finish",i)
end do
end if
+ call stop_timer(tmr_std_exx_comms,.true.)
!
+ call start_timer(tmr_std_exx_barrier)
call my_barrier
+ call stop_timer(tmr_std_exx_barrier,.true.)
!
call start_timer(tmr_std_exx_dealloc)
deallocate(nreqs,STAT=stat)
@@ -512,15 +639,11 @@ subroutine get_X_matrix( exxspin, level )
if(stat/=0) call cq_abort('mat_mult: error deallocating ibpart_rem')
call stop_timer(tmr_std_exx_dealloc,.true.)
!
- call my_barrier
- !
call start_timer(tmr_std_exx_dealloc)
deallocate(ibpart_rem,STAT=stat)
if(stat/=0) call cq_abort('mat_mult: error deallocating recv_part')
call stop_timer(tmr_std_exx_dealloc,.true.)
!
- call my_barrier
- !
if(iprint_mat>3.AND.myid==0) then
t1 = mtime()
write(io_lun,*) 'mult time: ',t1-t0
@@ -528,33 +651,33 @@ subroutine get_X_matrix( exxspin, level )
!
call stop_timer(tmr_std_exx_kernel,.true.)
!
- !exx = matrix_product_trace(matX(1),matK(1))
- !if (inode == ionode) then
- ! print*, 'exx energy'
- !end if
- !
- if ( exx_debug ) then
- !call exx_write_tail(unit1,inode)
+ if ( scheme > 0 ) then
+ call exx_mem_alloc(extent,0,0,'work_3d' ,'dealloc')
end if
!
- !
- call exx_mem_alloc(extent,0,0,'work_3d' ,'dealloc')
- !
- call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_i','dealloc')
- call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_j','dealloc')
- call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_k','dealloc')
- call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_l','dealloc')
- !
- call exx_mem_alloc(extent,maxsuppfuncs,0,'Phy_k','dealloc')
- call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'Ome_kj','dealloc')
- call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'rho_kj','dealloc')
- call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'vhf_kj','dealloc')
- !
+ if ( .not. exx_alloc ) then
+ !
+ if ( scheme > 0 ) then
+ !
+ call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_i','dealloc')
+ call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_j','dealloc')
+ call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_k','dealloc')
+ call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_l','dealloc')
+ !
+ if ( scheme == 1 ) then
+ call exx_mem_alloc(extent,maxsuppfuncs,0,'Phy_k','dealloc')
+ call exx_mem_alloc(extent,0,0,'Ome_kj_1d_buffer','dealloc')
+ !
+ end if
+ !
+ end if
+ !
+ end if
!
if (exx_psolver == 'fftw') then
call exx_mem_alloc(extent,0,0,'fftw_3d', 'dealloc')
call exx_mem_alloc(extent,0,0,'reckernel_3d','dealloc')
- select case(p_scheme)
+ select case(exx_pscheme)
case('default')
case('gauss')
case('pulay')
@@ -562,17 +685,14 @@ subroutine get_X_matrix( exxspin, level )
call exx_mem_alloc(extent,0,0,'ewald_3d','dealloc')
case default
end select
-
else if (exx_psolver == 'isf') then
call exx_mem_alloc(extent,0,0,'isf_rho','dealloc')
deallocate(kernel)
end if
!
- if (inode == ionode) then
- !call write_mem_use(unit_memory_write,area_exx)
- end if
+ if ( iprint_exx > 3 ) call write_mem_use(unit_memory_write,area_exx)
!
- call my_barrier()
+ call stop_timer(tmr_std_exx,.true.)
!
! Timers and elapse time
exx_total_time = &
@@ -580,54 +700,224 @@ subroutine get_X_matrix( exxspin, level )
tmr_std_exx_poisson%t_tot + &
tmr_std_exx_matmult%t_tot + &
tmr_std_exx_accumul%t_tot + &
+ tmr_std_exx_nsup%t_tot + &
tmr_std_exx_allocat%t_tot + &
tmr_std_exx_dealloc%t_tot + &
tmr_std_exx_setup%t_tot + &
tmr_std_exx_write%t_tot + &
- tmr_std_exx_fetch%t_tot
- !tmr_std_exx_fetch_K%t_tot
-
- call stop_timer(tmr_std_exx,.true.)
+ tmr_std_exx_barrier%t_tot + &
+ tmr_std_exx_fetch%t_tot + &
+ tmr_std_exx_comms%t_tot
if ( iprint_exx > 3 ) then
+
call print_timer(tmr_std_exx_setup, "exx_setup time:", unit_timers_write)
- call print_timer(tmr_std_exx_write, "exx_write time:", unit_timers_write)
- call print_timer(tmr_std_exx_kernel, "exx_kernel time:", unit_timers_write)
+ call print_timer(tmr_std_exx_write, "exx_write time:", unit_timers_write)
call print_timer(tmr_std_exx_fetch, "exx_fetch time:", unit_timers_write)
- !call print_timer(tmr_std_exx_fetch_K,"exx_fetch_K time:", unit_timers_write)
-
call print_timer(tmr_std_exx_evalpao,"exx_evalpao time:", unit_timers_write)
call print_timer(tmr_std_exx_poisson,"exx_poisson time:", unit_timers_write)
call print_timer(tmr_std_exx_matmult,"exx_matmult time:", unit_timers_write)
- call print_timer(tmr_std_exx_accumul,"exx_accumul time:", unit_timers_write)
+ call print_timer(tmr_std_exx_accumul,"exx_accumul time:", unit_timers_write)
+ call print_timer(tmr_std_exx_nsup, "exx_nsup time:", unit_timers_write)
call print_timer(tmr_std_exx_allocat,"exx_allocat time:", unit_timers_write)
call print_timer(tmr_std_exx_dealloc,"exx_dealloc time:", unit_timers_write)
+ call print_timer(tmr_std_exx_barrier,"exx_barrier time:", unit_timers_write)
+ call print_timer(tmr_std_exx_comms, "exx_comms time:", unit_timers_write)
+ call print_timer(tmr_std_exx_kernel, "exx_kernel time:", unit_timers_write)
call print_timer(tmr_std_exx, "exx_total time:", unit_timers_write)
-
write(unit=unit_timers_write,fmt='("Timing: Proc ",i6,": Time spent in ", a50, " = ", &
- &f12.5," s")') inode, 'get_X_matrix', tmr_std_exx%t_tot
-
+ &f12.5," s")') inode, 'get_X_matrix', tmr_std_exx%t_tot
write(unit=unit_timers_write,fmt='("Timing: Proc ",i6,": Time spent in ", a50, " = ", &
- &f12.5," s")') inode, 'timer calls', tmr_std_exx%t_tot-exx_total_time
-
- !call io_close(unit_matrix_write)
- !call io_close(unit_output_write)
- !call io_close(unit_screen_write)
- call io_close(unit_memory_write)
- call io_close(unit_timers_write)
+ &f12.5," s")') inode, 'timer calls', tmr_std_exx%t_tot-exx_total_time
+ write(unit_timers_write,*)
+ !
+ if (fdf_boolean('IO.WriteOutToFile',.true.)) then
+ call io_close(unit_memory_write)
+ call io_close(unit_timers_write)
+ end if
!
!
end if
-!****lat<$
+ if ( exx_debug ) then
+ call io_close(unit_eri_debug)
+ call io_close(unit_exx_debug)
+ call io_close(unit_eri_filter_debug)
+ end if
+
+ !****lat<$
call stop_backtrace(t=backtrace_timer,who='get_X_matrix',echo=.true.)
-!****lat>$
+ !****lat>$
return
end subroutine get_X_matrix
- !!***
+ !
+ !!****f* exx_kernel_default/cri_eri_inner_calculation *
+ !!
+ !! NAME
+ !! cri_eri_inner_calculation
+ !!
+ !! PURPOSE
+ !! Deduplicate the inner calculations of m_kern_exx_cri and m_kern_exx_eri.
+ !!
+ !! INPUTS
+ !! To ensure thread safety, variables which are altered must be passed in
+ !! as parameters rather than imported.
+ !!
+ !! AUTHOR
+ !! Connor Aird
+ !!
+ !! CREATION DATE
+ !! 2024/05/21
+ !!
+ !! MODIFICATION HISTORY
+ !!
+ !! SOURCE
+ !!
+ subroutine cri_eri_inner_calculation(nsf1_array, phi_i, Ome_kj, nsf1, nsf_jb, nsf_kg, dv, &
+ multiplier, ncaddr, ia_nsup, ewald_charge, work_out_3d, work_in_3d, &
+ c, backup_eris, store_eris_ptr)
+
+ use exx_poisson, only: exx_v_on_grid, exx_ewald_charge
+
+ use exx_types, only: phi_j, phi_k, ewald_rho, p_gauss, w_gauss, reckernel_3d, ewald_pot, &
+ pulay_radius, p_ngauss, r_int, p_omega, exx_psolver, exx_pscheme, extent, store_eris
+
+ use GenBlas, only: dot
+
+ use numbers, only: zero
+
+ implicit none
+
+ real(double), pointer, intent(in) :: Ome_kj(:,:,:), phi_i(:,:,:,:)
+ integer, intent(in) :: nsf1, nsf_jb, nsf_kg ! The indices of the loops from which this function is called
+ integer, intent(in) :: ncaddr, ia_nsup
+ real(double), intent(in) :: nsf1_array(:,:,:,:), dv, multiplier
+ real(double), intent(out) :: ewald_charge, work_out_3d(:,:,:), work_in_3d(:,:,:)
+ real(double), intent(inout) :: c(:)
+ ! Backup eris parameters. Optional as they are only needed by eri function
+ logical, intent(in) :: backup_eris
+ real(double), pointer, intent(inout), OPTIONAL :: store_eris_ptr(:,:)
+ integer :: nsf3
+ real(double) :: exx_mat_elem
+
+ work_out_3d = zero
+ !
+ work_in_3d = nsf1_array(:,:,:,nsf1) * phi_j(:,:,:,nsf_jb)
+ !
+ if (exx_psolver=='fftw' .and. exx_pscheme=='ewald') then
+ call exx_ewald_charge(work_in_3d,extent,dv,ewald_charge)
+ work_in_3d = work_in_3d - ewald_rho*ewald_charge
+ end if
+ !
+ call exx_v_on_grid(inode,extent,work_in_3d,work_out_3d,r_int, &
+ exx_psolver,exx_pscheme,pulay_radius,p_omega,p_ngauss,p_gauss,&
+ w_gauss,reckernel_3d)
+
+ if (exx_psolver=='fftw' .and. exx_pscheme=='ewald') then
+ work_out_3d = work_out_3d + ewald_pot*ewald_charge
+ end if
+ !
+ Ome_kj = work_out_3d * phi_k(:,:,:,nsf_kg)
+ !
+ do nsf3 = 1, ia_nsup
+ !
+ ! Can we instead always store directly into store_eris_ptr(nsf2, nsf3)?
+ exx_mat_elem = dot((2*extent+1)**3, phi_i(:,:,:,nsf3), 1, Ome_kj, 1) * dv * multiplier
+ !
+ if ( backup_eris ) then
+ !
+ ! eris(kpart)%store_eris( count ) = exx_mat_elem
+ store_eris_ptr(nsf3, nsf_jb) = exx_mat_elem
+ !
+ else
+ !
+ c(ncaddr + nsf3 - 1) = c(ncaddr + nsf3 - 1) + exx_mat_elem
+ !
+ end if
+ !
+ end do ! nsf3 = 1, ia%nsup
+ end subroutine cri_eri_inner_calculation
+ !
+ !!****f* exx_kernel_default/eri_gto_inner_calculation *
+ !!
+ !! NAME
+ !! eri_gto_inner_calculation
+ !!
+ !! PURPOSE
+ !! simplify m_kern_exx_eri to allow a simple subroutine call inside the threaded region.
+ !!
+ !! INPUTS
+ !! To ensure thread safety, variables which are altered must be passed in
+ !! as parameters rather than imported.
+ !!
+ !! AUTHOR
+ !! Connor Aird
+ !!
+ !! CREATION DATE
+ !! 2024/05/24
+ !!
+ !! MODIFICATION HISTORY
+ !!
+ !! SOURCE
+ !!
+ subroutine eri_gto_inner_calculation(ld, kg, jb, ia, nsf_ld, nsf_kg, nsf_jb, &
+ ncaddr, c, i_nt, j_nt, k_nt, l_nt, backup_eris, store_eris_ptr, &
+ filter_eris_ptr, should_compute_eri_hoh)
+
+ use exx_poisson, only: exx_v_on_grid, exx_ewald_charge
+
+ use exx_types, only: prim_atomic_data, neigh_atomic_data, p_ngauss, store_eris
- !!****f* exx_kernel_default/m_kern_exx *
+ use GenBlas, only: dot
+
+ use numbers, only: zero
+
+ use exx_erigto, only: compute_eri_hoh
+
+ implicit none
+
+ type(neigh_atomic_data), intent(in) :: ld, kg, jb
+ type(prim_atomic_data), intent(in) :: ia
+ integer, intent(in) :: nsf_ld, nsf_jb, nsf_kg
+ integer, intent(in) :: ncaddr
+ real(double), intent(inout) :: c(:)
+ character(len=8), intent(inout) :: i_nt, j_nt, k_nt, l_nt
+ logical, intent(in) :: backup_eris, should_compute_eri_hoh
+ real(double), pointer, intent(inout) :: store_eris_ptr(:,:)
+ logical, pointer, intent(inout) :: filter_eris_ptr(:,:)
+ integer :: nsf_ia
+ real(double) :: exx_mat_elem
+ !
+ do nsf_ia = 1, ia%nsup
+ !
+ exx_mat_elem = zero
+ !
+ if ( should_compute_eri_hoh .and. filter_eris_ptr( nsf_ia, nsf_jb ) ) then
+ !
+ !print*, 'toto'
+ call compute_eri_hoh( nsf_ia, nsf_jb, nsf_kg, nsf_ld, &
+ ia%spec, jb%spec, kg%spec, ld%spec, &
+ ia%xyz_ip, jb%xyz_cv, kg%xyz_cv, ld%xyz_cv,&
+ i_nt, j_nt, k_nt, l_nt,&
+ exx_mat_elem )
+ !
+ end if
+ !
+ if ( backup_eris ) then
+ !
+ store_eris_ptr(nsf_ia, nsf_jb) = exx_mat_elem
+ !
+ else
+ !
+ c(ncaddr + nsf_ia - 1) = c(ncaddr + nsf_ia - 1) + exx_mat_elem
+ !
+ end if
+ !
+ end do ! nsf_ia = 1, ia%nsup
+ end subroutine eri_gto_inner_calculation
+ !
+ !!****f* exx_kernel_default/m_kern_exx_cri *
!!
!! NAME
!! m_kern_exx
@@ -643,115 +933,90 @@ end subroutine get_X_matrix
!! 2014/05/29
!!
!! MODIFICATION HISTORY
+ !! 2024/02/28 Connor
+ !! Combined three instances of nsup loops into one and added omp threading
+ !! 2024/05/24 Connor
+ !! Extract inner calculation into cri_eri_inner_calculation to de-duplicate code
!!
!! SOURCE
!!
- subroutine m_kern_exx(k_off, kpart, ib_nd_acc, ibaddr, nbnab, &
- ibpart, ibseq, bndim2, b, c, ahalo, chalo, &
- at, mx_absb, mx_part, &
- mx_iprim, lenb, lenc,debug)
+ subroutine m_kern_exx_cri(k_off, kpart, ib_nd_acc, ibaddr, nbnab, &
+ ibpart, ibseq, bndim2, b, c, ahalo, chalo, at, mx_absb, mx_part, &
+ lenb, lenc )
use numbers, only: zero, one
use matrix_module, only: matrix_halo, matrix_trans
- use global_module, only: area_exx, id_glob, species_glob
+ use global_module, only: area_exx
+ use GenBlas, only: dot
!
use basic_types, only: primary_set
use primary_module, only: bundle
- use matrix_data, only: mat, Hrange, SXrange, Xrange, Srange, halo
- use mult_module, only: matK, return_matrix_value, mult, S_X_SX, mat_p, matX
+ use matrix_data, only: Hrange, SXrange, Xrange, Srange
+ use mult_module, only: return_matrix_value, S_X_SX
use cover_module, only: BCS_parts
- use group_module, only: parts
!
- use species_module, only: nsf_species, nlpf_species
+ use species_module, only: nsf_species
!
use exx_evalpao, only: exx_phi_on_grid
!
- use exx_types, only: prim_atomic_data, neigh_atomic_data, &
- tmr_std_exx_evalpao, &
- tmr_std_exx_setup, tmr_std_exx_fetch_K, &
- tmr_std_exx_fetch, tmr_std_exx_accumul, &
- tmr_std_exx_matmult, tmr_std_exx_poisson, &
- tmr_std_exx_allocat, tmr_std_exx_dealloc, &
- tmr_std_exx_fetch, &
- !unit_matrix_write, unit_output_write, &
- !unit_timers_write, unit_screen_write, &
- !unit_memory_write, &
- grid_spacing, r_int, extent, &
- ewald_alpha, ewald_charge, ewald_rho, ewald_pot, &
- pulay_radius, p_omega, p_ngauss, p_gauss, w_gauss, &
- exx_psolver,p_scheme, isf_order, ngrid, kernel, &
- exx_alloc, exx_mem, exx_phil, exx_screen_pao, &
- exx_total_time
+ use exx_types, only: prim_atomic_data, neigh_atomic_data,tmr_std_exx_accumul, &
+ grid_spacing, r_int, extent, ewald_charge,p_ngauss,unit_exx_debug, &
+ tmr_std_exx_nsup,phi_i_1d_buffer, phi_j, phi_k, phi_l,Phy_k, &
+ Ome_kj_1d_buffer,work_in_3d,work_out_3d,exx_alloc
!
- use exx_types, only: phi_i, phi_j, phi_k, phi_l, &
- Phy_k, rho_kj, Ome_kj, vhf_kj, &
- work_in_3d, work_out_3d, &
- exx_Kkl, exx_Kij
-
- use exx_module,only: exx_v_on_grid, get_halodat, get_iprimdat
+ use exx_memory, only: exx_mem_alloc
+ use exx_poisson, only: exx_v_on_grid, exx_ewald_charge
!
+ use exx_module, only: get_halodat, get_iprimdat
!
implicit none
!
! Passed variables
- type(matrix_halo) :: ahalo, chalo
- type(matrix_trans) :: at
- integer :: mx_absb, mx_part, mx_iprim, lena, lenb, lenc
- integer :: kpart, k_off
- real(double) :: b(lenb)
- real(double) :: c(lenc)
- integer, optional :: debug
+ type(matrix_halo), intent(in) :: ahalo, chalo
+ type(matrix_trans), intent(in) :: at
+ integer, intent(in) :: mx_absb, mx_part, lenb, lenc
+ integer, intent(in) :: kpart, k_off
+ real(double), intent(in) :: b(lenb)
+ real(double), intent(inout) :: c(lenc)
!
! Remote indices
- integer(integ) :: ib_nd_acc(mx_part)
- integer(integ) :: ibaddr(mx_part)
- integer(integ) :: nbnab(mx_part)
- integer(integ) :: ibpart(mx_part*mx_absb)
- integer(integ) :: ibseq(mx_part*mx_absb)
- integer(integ) :: bndim2(mx_part*mx_absb)
+ integer(integ), intent(in) :: ib_nd_acc(mx_part)
+ integer(integ), intent(in) :: ibaddr(mx_part)
+ integer(integ), intent(in) :: nbnab(mx_part)
+ integer(integ), intent(in) :: ibpart(mx_part*mx_absb)
+ integer(integ), intent(in) :: ibseq(mx_part*mx_absb)
+ integer(integ), intent(in) :: bndim2(mx_part*mx_absb)
!
! Local variables
integer :: jbnab2ch(mx_absb) ! Automatic array
integer :: nbkbeg, k, k_in_part, k_in_halo, j, jpart, jseq
- integer :: i, nabeg, i_in_prim, icad, nbbeg, j_in_halo, ncbeg
- integer :: n1, n2, n3, nb_nd_kbeg
- integer :: nd1, nd2, nd3
- integer :: naaddr, nbaddr, ncaddr
- integer :: lbnab2ch(mx_absb) ! Automatic array
- integer :: l, lseq, lpart, l_in_halo
- integer :: np, ni, iprim
- !
- integer :: unit_exx_debug1
+ integer :: i, i_in_prim, icad, nbbeg, j_in_halo, ncbeg
+ integer :: nb_nd_kbeg
+ integer :: nd1, nd3
+ integer :: nbaddr, ncaddr
+ integer :: l, lseq, lpart
+ integer :: np, ni
!
- real(double), dimension(3) :: xyz_ghost = zero
real(double), dimension(3) :: xyz_zero = zero
- real(double), dimension(3) :: xyz_delta = zero
- real(double), dimension(3) :: xyz_ij = zero
- real(double), dimension(3) :: xyz_kl = zero
- real(double) :: r_ghost = zero
+ real(double) :: dr,dv,K_val
!
- real(double) :: dr,dv,K_val
- real(double) :: exx_mat_elem
- real(double) :: screen_ij, range_ij
- real(double) :: screen_kl, range_kl
+ !
+ ! We allocate pointers here to point at 1D arrays later and allow contiguous access when passing to BLAS dot later
+ real(double), pointer :: phi_i(:,:,:,:), Ome_kj(:,:,:)
!
type(prim_atomic_data) :: ia !i_alpha
type(neigh_atomic_data) :: jb !j_beta
type(neigh_atomic_data) :: kg !k_gamma
type(neigh_atomic_data) :: ld !l_delta
!
- integer :: maxsuppfuncs, nsf1, nsf2, nsf3
- integer :: r, s, t, tmp
+ integer :: maxsuppfuncs, nsf_kg, nsf_ld, nsf_jb, count
!
!
dr = grid_spacing
dv = dr**3
- ewald_alpha = 0.5
maxsuppfuncs = maxval(nsf_species)
- !range_ij = 0.5d0
- !range_kl = 0.5d0
- !unit_exx_debug1 = 333
!
+ count = 1
!
!!$
!!$ ****[ k loop ]****
@@ -764,27 +1029,22 @@ subroutine m_kern_exx(k_off, kpart, ib_nd_acc, ibaddr, nbnab, &
nb_nd_kbeg = ib_nd_acc (k_in_part)
nd3 = ahalo%ndimj(k_in_halo)
call get_halodat(kg,kg,k_in_part,ahalo%i_hbeg(ahalo%lab_hcover(kpart)), &
- ahalo%lab_hcell(kpart),'k',.true.,unit_exx_debug1)
- !
- !print*, 'k',k, 'global_num',kg%global_num,'spe',kg%spec
+ ahalo%lab_hcell(kpart),'k',.true.,unit_exx_debug)
!
+ if ( exx_alloc ) call exx_mem_alloc(extent,kg%nsup,0,'phi_k','alloc')
call exx_phi_on_grid(inode,kg%global_num,kg%spec,extent, &
- xyz_zero,maxsuppfuncs,phi_k,r_int,xyz_zero)
+ xyz_zero,kg%nsup,phi_k,r_int,xyz_zero)
!
jbnab2ch = 0
- !print*, 'nbnab: ',nbnab(k_in_part),k_in_part
do j = 1, nbnab(k_in_part)
jpart = ibpart(nbkbeg+j-1) + k_off
jseq = ibseq (nbkbeg+j-1)
jbnab2ch(j) = chalo%i_halo(chalo%i_hbeg(jpart)+jseq-1)
- !print*, 'jbnab2ch',j, jbnab2ch(j)
end do
!
nbbeg = nb_nd_kbeg
!
- !print*, 'size jbnab2ch', size(jbnab2ch)
- !print*, 'jbnab2ch', jbnab2ch
- !print*
+ if ( exx_alloc ) call exx_mem_alloc(extent,kg%nsup,0,'Phy_k','alloc')
!
Phy_k = zero
!
@@ -792,52 +1052,40 @@ subroutine m_kern_exx(k_off, kpart, ib_nd_acc, ibaddr, nbnab, &
!!$ ****[ l do loop ]****
!!$
do l = 1, nbnab(k_in_part)
- !l_in_halo = lbnab2ch(l)
lpart = ibpart(nbkbeg+l-1) + k_off
lseq = ibseq (nbkbeg+l-1)
call get_halodat(ld,kg,lseq,chalo%i_hbeg(lpart), &
BCS_parts%lab_cell(BCS_parts%inv_lab_cover(lpart)), &
- 'l',.true.,unit_exx_debug1)
- !
- !write(*,*) 'l',l, 'global_num',ld%global_num,'spe',ld%spec
+ 'l',.true.,unit_exx_debug)
!
!!$
!!$ ****[ screening ]****
!!$
- !xyz_kl = kg%xyz - ld%xyz
- !screen_kl = sqrt(dot_product(xyz_kl,xyz_kl))
- !if ( screen_kl < range_kl ) then
+ !
+ if ( exx_alloc ) call exx_mem_alloc(extent,ld%nsup,0,'phi_l','alloc')
!
call exx_phi_on_grid(inode,ld%global_num,ld%spec,extent, &
- ld%xyz,maxsuppfuncs,phi_l,r_int,xyz_zero)
+ ld%xyz,ld%nsup,phi_l,r_int,xyz_zero)
!
- do nsf2 = 1, ld%nsup
+ do nsf_ld = 1, ld%nsup
!
- nbaddr = nbbeg + kg%nsup * (nsf2 - 1)
+ nbaddr = nbbeg + kg%nsup * (nsf_ld - 1)
!
- do nsf1 = 1, kg%nsup
- !
- !call start_timer(tmr_std_exx_fetch_K)
- if (exx_Kkl) then
- K_val = b(nbaddr+nsf1-1)
- else
- K_val = real(1,double)
- end if
+ do nsf_kg = 1, kg%nsup
!
- !write(*,'(7I4,F12.8)') kpart,i,j,k,l,nsf2,nsf1,K_val
+ K_val = b(nbaddr+nsf_kg-1)
!
- !call stop_timer(tmr_std_exx_fetch_K,.true.)
-
call start_timer(tmr_std_exx_accumul)
- Phy_k(:,:,:,nsf1) = Phy_k(:,:,:,nsf1) + K_val*phi_l(:,:,:,nsf2)
+ Phy_k(:,:,:,nsf_kg) = Phy_k(:,:,:,nsf_kg) + K_val*phi_l(:,:,:,nsf_ld)
call stop_timer(tmr_std_exx_accumul,.true.)
-
+
end do
end do
!
- nbbeg = nbbeg + ld%nsup*kg%nsup !nd3 * nd2
+ nbbeg = nbbeg + ld%nsup*kg%nsup
!
- !end if !( screen kl )
+ if ( exx_alloc ) call exx_mem_alloc(extent,ld%nsup,0,'phi_l','dealloc')
+
end do ! End of l = 1, nbnab(k_in_part)
!!$
!!$ ****[ i loop ]****
@@ -848,28 +1096,23 @@ subroutine m_kern_exx(k_off, kpart, ib_nd_acc, ibaddr, nbnab, &
ni = bundle%iprim_seq (i_in_prim)
np = bundle%iprim_part(i_in_prim)
icad = (i_in_prim - 1) * chalo%ni_in_halo !***
- !nbbeg = nb_nd_kbeg
!
- !print*, 'i_in_prim', i_in_prim, 'nd1', nd1, 'ni', ni, 'np', np
+ call get_iprimdat(ia,kg,ni,i_in_prim,np,.true.,unit_exx_debug)
+ if (ia%nsup/=ahalo%ndimi(i_in_prim)) call cq_abort('Error1: ',ia%nsup,ahalo%ndimi(i_in_prim))
!
- call get_iprimdat(ia,kg,ni,i_in_prim,np,.true.,unit_exx_debug1)
- !
- !print*, 'i',i, 'global_num',ia%ip,'spe',ia%spec
+ if ( exx_alloc ) call exx_mem_alloc(extent,ia%nsup,0,'phi_i_1d_buffer','alloc')
+ phi_i(1:2*extent+1, 1:2*extent+1, 1:2*extent+1, 1:ia%nsup) => phi_i_1d_buffer
!
call exx_phi_on_grid(inode,ia%ip,ia%spec,extent, &
- ia%xyz,maxsuppfuncs,phi_i,r_int,xyz_zero)
+ ia%xyz,ia%nsup,phi_i,r_int,xyz_zero)
!
- !print*, size(chalo%i_h2d), shape(chalo%i_h2d)
- !
!!$
!!$ ****[ j loop ]****
-!!$
- do j = 1, nbnab(k_in_part)!mat(np,Xrange)%n_nab(ni)
+!!$
+ do j = 1, nbnab(k_in_part)
nbbeg = nb_nd_kbeg
j_in_halo = jbnab2ch(j) !***
!
- !print*, j, icad, j_in_halo
- !
if ( j_in_halo /= 0 ) then
!
ncbeg = chalo%i_h2d(icad + j_in_halo) !***
@@ -877,148 +1120,798 @@ subroutine m_kern_exx(k_off, kpart, ib_nd_acc, ibaddr, nbnab, &
if ( ncbeg /= 0 ) then
jpart = ibpart(nbkbeg+j-1) + k_off
jseq = ibseq (nbkbeg+j-1)
- call get_halodat(jb,kg,jseq,chalo%i_hbeg(jpart), &
- BCS_parts%lab_cell(BCS_parts%inv_lab_cover(jpart)), &
- 'j',.true.,unit_exx_debug1)
+ call get_halodat(jb,kg,jseq,chalo%i_hbeg(jpart), &
+ BCS_parts%lab_cell(BCS_parts%inv_lab_cover(jpart)), &
+ 'j',.true.,unit_exx_debug)
+ !####
+ if ( sqrt(sum(((ia%xyz_ip-jb%xyz_cv)**2))) < exx_cutoff ) then
+ !####
+
+ if (jb%nsup/=bndim2(nbkbeg+j-1)) call cq_abort('Error2: ',jb%nsup,bndim2(nbkbeg+j-1))
!
-!!$
-!!$ ****[ screening ]****
-!!$
- !xyz_ij = ia%xyz - jb%xyz
- !screen_ij = sqrt(dot_product(xyz_ij,xyz_ij))
- !print*, screen_ij
- !if ( screen_ij < range_ij ) then
- !write(*,*) 'j',j, 'global_num',jb%global_num,'spe',jb%spec
+ if ( exx_alloc ) call exx_mem_alloc(extent,jb%nsup,0,'phi_j','alloc')
!
call exx_phi_on_grid(inode,jb%global_num,jb%spec,extent, &
- jb%xyz,maxsuppfuncs,phi_j,r_int,xyz_zero)
- !
- !Ome_kj = zero
- !
- call start_timer(tmr_std_exx_accumul)
- rho_kj = zero
- do nsf1 = 1, kg%nsup
- do nsf2 = 1, jb%nsup
- rho_kj(:,:,:,nsf1,nsf2) = &
- Phy_k(:,:,:,nsf1) * phi_j(:,:,:,nsf2)
- !do r = 1, 2*extent+1
- ! do s = 1, 2*extent+1
- ! do t = 1, 2*extent+1
- ! if(isnan(rho_kj(r,s,t,nsf1,nsf2))) write(*,*) 'rho: ',r,s,t,nsf1,nsf2
-
- ! if(isnan(Phy_k(r,s,t,nsf1))) write(*,*) 'Phy: ',r,s,t,nsf1,nsf2
- ! if(isnan(phi_j(r,s,t,nsf2))) write(*,*) 'phi: ',r,s,t,nsf1,nsf2
- ! end do
- ! end do
- !end do
- end do
- end do
- call stop_timer(tmr_std_exx_accumul,.true.)
+ jb%xyz,jb%nsup,phi_j,r_int,xyz_zero)
!
- do nsf1 = 1, kg%nsup
- do nsf2 = 1, jb%nsup
-
- call start_timer(tmr_std_exx_poisson)
- work_in_3d = zero
- work_out_3d = zero
- work_in_3d = rho_kj(:,:,:,nsf1,nsf2)
-
- call exx_v_on_grid(inode,extent,work_in_3d,work_out_3d,r_int, &
- exx_psolver,p_scheme,pulay_radius,p_omega,p_ngauss,p_gauss,&
- w_gauss)
-
- vhf_kj(:,:,:,nsf1,nsf2) = work_out_3d
-
- !do r = 1, 2*extent+1
- ! do s = 1, 2*extent+1
- ! do t = 1, 2*extent+1
- ! if(isnan(vhf_kj(r,s,t,nsf1,nsf2))) write(*,*) 'vhf: ',r,s,t,nsf1,nsf2
- ! end do
- ! end do
- !end do
-
- call stop_timer(tmr_std_exx_poisson,.true.)
- end do
- end do
+ ! We allocate a 1D buffer here, instead of 3D, to allow contiguous access when passing to BLAS dot later
!
- Ome_kj = zero
+ if ( exx_alloc ) call exx_mem_alloc(extent,0,0,'Ome_kj_1d_buffer','alloc')
!
- call start_timer(tmr_std_exx_accumul)
- do nsf1 = 1, kg%nsup
- do nsf2 = 1, jb%nsup
- Ome_kj(:,:,:,nsf1,nsf2) = &
- vhf_kj(:,:,:,nsf1,nsf2) * phi_k(:,:,:,nsf1)
- end do
- end do
- call stop_timer(tmr_std_exx_accumul,.true.)
+ call start_timer(tmr_std_exx_nsup)
!
- if(ia%nsup/=ahalo%ndimi(i_in_prim)) write(24,*) 'Error1: ',ia%nsup,ahalo%ndimi(i_in_prim)
- if(jb%nsup/=bndim2(nbkbeg+j-1)) write(24,*) 'Error2: ',jb%nsup,bndim2(nbkbeg+j-1)
+ ! Begin the parallel region here as earlier allocations make it difficult to do before now.
+ ! However, this should be possible in future work.
!
- call start_timer(tmr_std_exx_matmult)
- do nsf2 = 1, jb%nsup
- !
- ncaddr = ncbeg + ia%nsup * (nsf2 - 1)
- !
- do nsf1 = 1, ia%nsup
+ !$omp parallel default(none) reduction(+: c) &
+ !$omp shared(kg,jb,Phy_k,ncbeg,ia,phi_i,extent,dv) &
+ !$omp private(nsf_kg,nsf_jb,work_out_3d,work_in_3d,ewald_charge,Ome_kj_1d_buffer, &
+ !$omp Ome_kj,ncaddr)
+ Ome_kj(1:2*extent+1, 1:2*extent+1, 1:2*extent+1) => Ome_kj_1d_buffer
+ !$omp do schedule(dynamic) collapse(2)
+ do nsf_kg = 1, kg%nsup
+ do nsf_jb = 1, jb%nsup
!
- do nsf3 = 1, kg%nsup
- !
- exx_mat_elem = zero
- !
- do r = 1, 2*extent+1
- do s = 1, 2*extent+1
- do t = 1, 2*extent+1
-
- exx_mat_elem = exx_mat_elem &
- + phi_i(r,s,t,nsf1) &
- * Ome_kj(r,s,t,nsf3,nsf2) * dv
-
- end do
- end do
- end do
- !
- c(ncaddr + nsf1 - 1) = c(ncaddr + nsf1 - 1) + exx_mat_elem
- !
- end do ! nsf3
+ ncaddr = ncbeg + ia%nsup * (nsf_jb - 1)
!
+ call cri_eri_inner_calculation(Phy_k, phi_i, Ome_kj, nsf_kg, nsf_jb, nsf_kg, dv, &
+ 1.0d0, ncaddr, ia%nsup, ewald_charge, work_out_3d, work_in_3d, c, &
+ .false.)
!
- end do ! nsf1
- !
- !
- end do ! nsf2
- call stop_timer(tmr_std_exx_matmult,.true.)
+ end do ! nsf_ld = 1, jb%nsup
+ end do ! nsf_kg = 1, kg%nsup
+ !$omp end do
+ !$omp end parallel
!
-!!$
-!!$
-! end if !( screen ij )
-!!$
-!!$
+ call stop_timer(tmr_std_exx_nsup,.true.)
+ !
+ if ( exx_alloc ) call exx_mem_alloc(extent,0,0,'Ome_kj_1d_buffer','dealloc')
+ if ( exx_alloc ) call exx_mem_alloc(extent,jb%nsup,0,'phi_j','dealloc')
+ !
+ !####
+ end if
+ !####
end if ! ( ncbeg /=0 )
end if ! ( j_in_halo /=0 )
- !
- !nbbeg = nbbeg + ia%nsup * jb%nsup ! nd3 * nd2
- !
!!$
!!$ ****[ j end loop ]****
!!$
- end do ! End of j = 1, mat(np,SXrange)%n_nab(ni)
+ end do ! End of j = 1, nbnab(k_in_part)
!
!!$
!!$ ****[ i end loop ]****
!!$
!
+ if ( exx_alloc ) call exx_mem_alloc(extent,ia%nsup,0,'phi_i_1d_buffer','dealloc')
+ !
end do ! End of i = 1, at%n_hnab(k_in_halo)
!
!!$
!!$ ****[ k end loop ]****
!!$
!
+ if ( exx_alloc ) call exx_mem_alloc(extent,kg%nsup,0,'Phy_k','dealloc')
+ if ( exx_alloc ) call exx_mem_alloc(extent,kg%nsup,0,'phi_k','dealloc')
+ !
end do ! End of k = 1, ahalo%nh_part(kpart)
!
!
return
- end subroutine m_kern_exx
+ end subroutine m_kern_exx_cri
!
- !!***
-end module exx_kernel_default
+
+ !!****f* exx_kernel_default/m_kern_exx_eri *
+ !!
+ !! NAME
+ !! m_kern_exx_eri
+ !!
+ !! PURPOSE
+ !! Compute EXX matrix using GTO-ERI engine. For now
+ !! default is the Taketa, Huzinaga, and O-ohata (HOH)
+ !! approach as given in exx_erigto module
+ !!
+ !! INPUTS
+ !!
+ !! AUTHOR
+ !! L.A.Truflandier/D.R.Bowler
+ !!
+ !! CREATION DATE
+ !! 2020/10/27
+ !!
+ !! MODIFICATION HISTORY
+ !! 2024/05/24 Connor
+ !! - Extract inner calculation into cri_eri_inner_calculation
+ !! - Combine with m_kern_exx_eri_gto
+ !! - Add omp threading
+ !!
+ !! SOURCE
+ !!
+ subroutine m_kern_exx_eri(k_off, kpart, ib_nd_acc, ibaddr, nbnab, &
+ ibpart, ibseq, b, c, ahalo, chalo, at, mx_absb, mx_part, &
+ lenb, lenc, backup_eris )
+
+ use numbers, only: zero
+ use matrix_module, only: matrix_halo, matrix_trans
+ !
+ use primary_module, only: bundle
+ use cover_module, only: BCS_parts
+ !
+ use exx_evalpao, only: exx_phi_on_grid
+ !
+ use exx_evalgto, only: exx_gto_on_grid_prim
+ !
+ use exx_types, only: prim_atomic_data,neigh_atomic_data,grid_spacing,r_int, &
+ extent,ewald_charge,p_ngauss,unit_exx_debug,tmr_std_exx_nsup,eris, &
+ phi_i_1d_buffer,phi_j,phi_k,phi_l,exx_alloc, &
+ Ome_kj_1d_buffer,work_in_3d,work_out_3d, exx_gto
+ !
+ use exx_memory, only: exx_mem_alloc
+ !
+ use exx_module, only: get_halodat, get_iprimdat
+ !
+ use exx_poisson,only: exx_v_on_grid, exx_ewald_charge
+ !
+ ! m_kern_exx_eri_gto imports
+ use exx_erigto, only: compute_eri_hoh
+ !
+ implicit none
+ !
+ ! Passed variables
+ type(matrix_halo), intent(in) :: ahalo, chalo
+ type(matrix_trans), intent(in) :: at
+ integer, intent(in) :: mx_absb, mx_part, lenb, lenc
+ integer, intent(in) :: kpart, k_off
+ real(double), intent(in) :: b(lenb)
+ real(double), intent(inout) :: c(lenc)
+ logical, intent(in) :: backup_eris
+ !
+ ! Remote indices
+ integer(integ), intent(in) :: ib_nd_acc(mx_part)
+ integer(integ), intent(in) :: ibaddr(mx_part)
+ integer(integ), intent(in) :: nbnab(mx_part)
+ integer(integ), intent(in) :: ibpart(mx_part*mx_absb)
+ integer(integ), intent(in) :: ibseq(mx_part*mx_absb)
+ !
+ ! Local variables
+ integer :: jbnab2ch(mx_absb) ! Automatic array
+ integer :: nbkbeg, k, k_in_part, k_in_halo, j, jpart, jseq
+ integer :: i, i_in_prim, icad, nbbeg, j_in_halo, ncbeg
+ integer :: nb_nd_kbeg
+ integer :: nbaddr, ncaddr
+ integer :: l, lseq, lpart
+ integer :: np, ni
+ !
+ real(double), dimension(3) :: xyz_zero = zero
+ !
+ real(double) :: dv,K_val
+ !
+ ! We allocate pointers here to point at 1D arrays later and allow contiguous access when passing to BLAS dot later
+ real(double), pointer :: phi_i(:,:,:,:), Ome_kj(:,:,:), store_eris_ptr(:,:)
+ logical, pointer :: filter_eris_ptr(:,:)
+ !
+ type(prim_atomic_data) :: ia !i_alpha
+ type(neigh_atomic_data) :: jb !j_beta
+ type(neigh_atomic_data) :: kg !k_gamma
+ type(neigh_atomic_data) :: ld !l_delta
+ !
+ integer :: nsf_kg, nsf_ld, nsf_jb, count
+ !
+ logical :: should_allocate, should_compute_eri_hoh
+ !
+ ! m_kern_exx_eri_gto variables
+ character(len=8) :: i_nt, j_nt, k_nt, l_nt
+ !
+ dv = grid_spacing**3
+ count = 0
+ should_allocate = exx_alloc .and. (.not. exx_gto)
+ !
+!!$
+!!$ ****[ k loop ]****
+!!$
+ k_loop: do k = 1, ahalo%nh_part(kpart)
+ !
+ k_in_halo = ahalo%j_beg(kpart) + k - 1
+ k_in_part = ahalo%j_seq(k_in_halo)
+ nbkbeg = ibaddr (k_in_part)
+ nb_nd_kbeg = ib_nd_acc (k_in_part)
+ call get_halodat(kg,kg,k_in_part,ahalo%i_hbeg(ahalo%lab_hcover(kpart)), &
+ ahalo%lab_hcell(kpart),'k',.true.,unit_exx_debug)
+ !
+ if ( should_allocate ) call exx_mem_alloc(extent,kg%nsup,0,'phi_k','alloc')
+ !
+ if (.not. exx_gto) call exx_phi_on_grid(inode,kg%global_num,kg%spec,extent, &
+ xyz_zero,kg%nsup,phi_k,r_int,xyz_zero)
+ !
+ jbnab2ch = 0
+ do j = 1, nbnab(k_in_part)
+ jpart = ibpart(nbkbeg+j-1) + k_off
+ jseq = ibseq (nbkbeg+j-1)
+ jbnab2ch(j) = chalo%i_halo(chalo%i_hbeg(jpart)+jseq-1)
+ end do
+ !
+ nbbeg = nb_nd_kbeg
+ !
+!!$
+!!$ ****[ l do loop ]****
+!!$
+ l_loop: do l = 1, nbnab(k_in_part)
+ lpart = ibpart(nbkbeg+l-1) + k_off
+ lseq = ibseq (nbkbeg+l-1)
+ call get_halodat(ld,kg,lseq,chalo%i_hbeg(lpart), &
+ BCS_parts%lab_cell(BCS_parts%inv_lab_cover(lpart)), &
+ 'l',.true.,unit_exx_debug)
+ !
+ if ( should_allocate ) call exx_mem_alloc(extent,ld%nsup,0,'phi_l','alloc')
+ !
+ if (.not. exx_gto) call exx_phi_on_grid(inode,ld%global_num,ld%spec,extent, &
+ ld%xyz,ld%nsup,phi_l,r_int,xyz_zero)
+ !
+ ld_loop: do nsf_ld = 1, ld%nsup
+ !
+ nbaddr = nbbeg + kg%nsup * (nsf_ld - 1)
+ !
+ kg_loop: do nsf_kg = 1, kg%nsup
+ !
+ if ( backup_eris .and. (.not. exx_gto) ) then
+ K_val = real(1,double)
+ else
+ K_val = b(nbaddr+nsf_kg-1)
+ end if
+!!$
+!!$ ****[ i loop ]****
+!!$
+ i_loop: do i = 1, at%n_hnab(k_in_halo)
+ i_in_prim = at%i_prim(at%i_beg(k_in_halo)+i-1)
+ ni = bundle%iprim_seq (i_in_prim)
+ np = bundle%iprim_part(i_in_prim)
+ icad = (i_in_prim - 1) * chalo%ni_in_halo
+ !
+ call get_iprimdat(ia,kg,ni,i_in_prim,np,.true.,unit_exx_debug)
+ !
+ if ( should_allocate ) call exx_mem_alloc(extent,ia%nsup,0,'phi_i_1d_buffer','alloc')
+ if(.not.exx_gto) then
+ phi_i(1:2*extent+1, 1:2*extent+1, 1:2*extent+1, 1:ia%nsup) => phi_i_1d_buffer
+ !
+ call exx_phi_on_grid(inode,ia%ip,ia%spec,extent, &
+ ia%xyz,ia%nsup,phi_i,r_int,xyz_zero)
+ end if
+ !
+!!$
+!!$ ****[ j loop ]****
+!!$
+ j_loop: do j = 1, nbnab(k_in_part)
+ j_in_halo = jbnab2ch(j)
+ !
+ if ( j_in_halo /= 0 ) then
+ !
+ ncbeg = chalo%i_h2d(icad + j_in_halo)
+ !
+ if ( ncbeg /= 0 ) then
+ jpart = ibpart(nbkbeg+j-1) + k_off
+ jseq = ibseq (nbkbeg+j-1)
+ !
+ call get_halodat(jb,kg,jseq,chalo%i_hbeg(jpart), &
+ BCS_parts%lab_cell(BCS_parts%inv_lab_cover(jpart)), &
+ 'j',.true.,unit_exx_debug)
+ !
+ if ( should_allocate ) call exx_mem_alloc(extent,jb%nsup,0,'phi_j','alloc')
+ !
+ if (.not. exx_gto) call exx_phi_on_grid(inode,jb%global_num,jb%spec,extent, &
+ jb%xyz,jb%nsup,phi_j,r_int,xyz_zero)
+ !
+ if ( should_allocate ) call exx_mem_alloc(extent,0,0,'Ome_kj_1d_buffer','alloc')
+ !
+ call start_timer(tmr_std_exx_nsup)
+ !
+ ! Point at the next block of eris to store and update counter
+ store_eris_ptr(1:ia%nsup, 1:jb%nsup) => eris(kpart)%store_eris(count+1:count + (jb%nsup * ia%nsup))
+ filter_eris_ptr(1:ia%nsup, 1:jb%nsup) => eris(kpart)%filter_eris(count+1:count + (jb%nsup * ia%nsup))
+ count = count + (jb%nsup * ia%nsup)
+ !
+ !should_compute_eri_hoh = sqrt(sum((ia%xyz_ip-kg%xyz_cv)**2)) < ( ia%radi + kg%radi) &
+ ! .and. sqrt(sum((jb%xyz_cv-ld%xyz_cv)**2)) < ( jb%radi + ld%radi)
+ should_compute_eri_hoh = sqrt(sum((ia%xyz_ip-kg%xyz_cv)**2)) < ( exx_cutoff ) &
+ .and. sqrt(sum((jb%xyz_cv-ld%xyz_cv)**2)) < ( exx_cutoff )
+
+ !print*, should_compute_eri_hoh
+ !
+ !$omp parallel default(none) reduction(+: c) &
+ !$omp shared(ld,kg,jb,ia,nsf_kg,nsf_ld,ncbeg,phi_k,phi_j,phi_l,phi_i,extent,dv,eris,K_val, &
+ !$omp backup_eris,phi_i_1d_buffer,kpart,store_eris_ptr,filter_eris_ptr,exx_gto, &
+ !$omp should_compute_eri_hoh) &
+ !$omp private(nsf_jb,work_out_3d,work_in_3d,ewald_charge,Ome_kj_1d_buffer,Ome_kj,ncaddr, &
+ !$omp i_nt,j_nt,k_nt,l_nt)
+ !
+ if(.not.exx_gto) Ome_kj(1:2*extent+1, 1:2*extent+1, 1:2*extent+1) => Ome_kj_1d_buffer
+ !$omp do schedule(dynamic)
+ jb_loop: do nsf_jb = 1, jb%nsup
+ !
+ ncaddr = ncbeg + ia%nsup * (nsf_jb - 1)
+ !
+ if (exx_gto) then
+ !
+ call eri_gto_inner_calculation(ld, kg, jb, ia, nsf_ld, nsf_kg, nsf_jb, ncaddr, c, i_nt, j_nt, &
+ k_nt, l_nt, backup_eris, store_eris_ptr, filter_eris_ptr, should_compute_eri_hoh)
+ !
+ else
+ !
+ call cri_eri_inner_calculation(phi_l, phi_i, Ome_kj, nsf_ld, nsf_jb, nsf_kg, dv, K_val, &
+ ncaddr, ia%nsup, ewald_charge, work_out_3d, work_in_3d, c, &
+ backup_eris, store_eris_ptr)
+ !
+ end if
+ end do jb_loop
+ !$omp end do
+ !$omp end parallel
+ !
+ call stop_timer(tmr_std_exx_nsup,.true.)
+ !
+ if ( should_allocate ) call exx_mem_alloc(extent,0,0,'Ome_kj_1d_buffer','dealloc')
+ if ( should_allocate ) call exx_mem_alloc(extent,jb%nsup,0,'phi_j','dealloc')
+ !
+ end if
+ !
+ end if
+ !
+!!$
+!!$ ****[ j end loop ]****
+!!$
+ !
+ end do j_loop
+ !
+ if ( should_allocate ) call exx_mem_alloc(extent,ia%nsup,0,'phi_i_1d_buffer','dealloc')
+ !
+!!$
+!!$ ****[ i end loop ]****
+!!$
+ !
+ end do i_loop
+ !
+ end do kg_loop
+ !
+ end do ld_loop
+ !
+ if ( should_allocate ) call exx_mem_alloc(extent,ld%nsup,0,'phi_l','dealloc')
+ !
+!!$
+!!$ ****[ l end loop ]****
+!!$
+ !
+ end do l_loop
+ !
+ nbbeg = nbbeg + ld%nsup*kg%nsup
+ !
+ if ( should_allocate ) call exx_mem_alloc(extent,kg%nsup,0,'phi_k','dealloc')
+ !
+!!$
+!!$ ****[ k end loop ]****
+!!$
+ !
+ end do k_loop
+ !
+ return
+ end subroutine m_kern_exx_eri
+ !
+ !!****f* exx_kernel_default/m_kern_exx_dummy *
+ !!
+ !! NAME
+ !! m_kern_exx_dummy
+ !!
+ !! PURPOSE
+ !! (1) count the the number of ERIs on each proc
+ !! to allocate arrays when storage is required
+ !! (2) if filter_eris = .true. prepare EXX calculation
+ !! such as filtering and screening using coarse grid Poisson
+ !! solver for ERI evaluation. Filtering is used only if
+ !! GTO fitting and GTO-ERI engine are used.
+ !! (3) if compute_exx =.true. compute EXX matrix using
+ !! stored ERIs
+ !!
+ !! INPUTS
+ !!
+ !! AUTHOR
+ !! L.A.Truflandier
+ !!
+ !! CREATION DATE
+ !! 2020/10/27
+ !!
+ !! MODIFICATION HISTORY
+ !!
+ !! SOURCE
+ !!
+ subroutine m_kern_exx_dummy(k_off, kpart, ib_nd_acc, ibaddr, nbnab, &
+ ibpart, ibseq, b, c, ahalo, chalo, &
+ at, mx_absb, mx_part, lenb, lenc, &
+ count_eris, compute_exx, filter_eris)
+
+ use global_module, only: iprint_exx
+ use numbers, only: zero, one
+ use matrix_module, only: matrix_halo, matrix_trans
+ use global_module, only: area_exx
+ !
+ use fft_interface_module, only: fft3_init_wrapper
+
+ use basic_types, only: primary_set
+ use primary_module, only: bundle
+ use matrix_data, only: Hrange, SXrange, Xrange, Srange
+ use mult_module, only: return_matrix_value, S_X_SX
+ use cover_module, only: BCS_parts
+ !
+ use species_module, only: nsf_species
+ !
+ use angular_coeff_routines, only: calc_mat_elem_gen
+ !
+ use exx_evalpao, only: exx_phi_on_grid
+ use exx_types, only: reckernel_3d_filter
+ use exx_types, only: prim_atomic_data,neigh_atomic_data, &
+ grid_spacing,r_int,unit_exx_debug,pulay_radius,eris, &
+ p_omega,p_ngauss,p_gauss,w_gauss,exx_psolver, &
+ exx_pscheme,exx_filter_thr,exx_filter_extent, &
+ unit_eri_filter_debug
+
+ use exx_module, only: get_halodat, get_iprimdat
+ !
+ use exx_poisson,only: exx_v_on_grid, exx_scal_rho_3d
+ !
+ implicit none
+ !
+ ! Passed variables
+ type(matrix_halo), intent(in) :: ahalo, chalo
+ type(matrix_trans), intent(in) :: at
+ integer, intent(in) :: mx_absb, mx_part, lenb, lenc
+ integer, intent(in) :: kpart, k_off
+ real(double), intent(in) :: b(lenb)
+ real(double), intent(inout) :: c(lenc)
+ integer, intent(inout) :: count_eris
+ logical, intent(in) :: compute_exx
+ logical, intent(in) :: filter_eris
+ !
+ ! Remote indices
+ integer(integ), intent(in) :: ib_nd_acc(mx_part)
+ integer(integ), intent(in) :: ibaddr(mx_part)
+ integer(integ), intent(in) :: nbnab(mx_part)
+ integer(integ), intent(in) :: ibpart(mx_part*mx_absb)
+ integer(integ), intent(in) :: ibseq(mx_part*mx_absb)
+ !
+ ! Local variables
+ integer :: jbnab2ch(mx_absb) ! Automatic array
+ integer :: nbkbeg, k, k_in_part, k_in_halo, j, jpart, jseq
+ integer :: i, i_in_prim, icad, nbbeg, j_in_halo, ncbeg
+ integer :: nb_nd_kbeg
+ integer :: nd1, nd3
+ integer :: nbaddr, ncaddr
+ integer :: l, lseq, lpart
+ integer :: np, ni
+ !
+ logical :: should_compute_eri_ik, should_compute_eri_jl
+ !
+ real(double), dimension(3) :: xyz_zero = zero
+ !
+ real(double) :: dr, dv, K_val
+ real(double) :: exx_mat_elem
+ !
+ type(prim_atomic_data) :: ia !i_alpha
+ type(neigh_atomic_data) :: jb !j_beta
+ type(neigh_atomic_data) :: kg !k_gamma
+ type(neigh_atomic_data) :: ld !l_delta
+ !
+ integer :: maxsuppfuncs
+ integer :: nsf_kg, nsf_ld, nsf_ia, nsf_jb
+ integer :: r, s, t, stat
+ !
+ real(double), dimension(:,:,:,:), allocatable :: phi_i_filter, phi_j_filter
+ real(double), dimension(:,:,:,:), allocatable :: phi_k_filter, phi_l_filter
+ real(double), dimension(:,:,:), allocatable :: work_in, work_out
+ !
+ dr = grid_spacing
+ dv = dr**3
+ !
+ count_eris = 0
+ !
+ maxsuppfuncs = maxval(nsf_species)
+ !
+ if ( filter_eris ) then
+ allocate( phi_i_filter(2*exx_filter_extent+1,2*exx_filter_extent+1,2*exx_filter_extent+1,maxsuppfuncs), STAT=stat )
+ if(stat/=0) call cq_abort('Error allocating memory to phi_i_filter/exx !',stat)
+ !
+ allocate( phi_j_filter(2*exx_filter_extent+1,2*exx_filter_extent+1,2*exx_filter_extent+1,maxsuppfuncs), STAT=stat )
+ if(stat/=0) call cq_abort('Error allocating memory to phi_j_filter/exx !',stat)
+ !
+ allocate( phi_k_filter(2*exx_filter_extent+1,2*exx_filter_extent+1,2*exx_filter_extent+1,maxsuppfuncs), STAT=stat )
+ if(stat/=0) call cq_abort('Error allocating memory to phi_k_filter/exx !',stat)
+ !
+ allocate( phi_l_filter(2*exx_filter_extent+1,2*exx_filter_extent+1,2*exx_filter_extent+1,maxsuppfuncs), STAT=stat )
+ if(stat/=0) call cq_abort('Error allocating memory to phi_l_filter/exx !',stat)
+ !
+ allocate( work_in(2*exx_filter_extent+1,2*exx_filter_extent+1,2*exx_filter_extent+1), STAT=stat)
+ if(stat/=0) call cq_abort('Error allocating memory to work_in_filter/exx !',stat)
+ !
+ allocate(work_out(2*exx_filter_extent+1,2*exx_filter_extent+1,2*exx_filter_extent+1), STAT=stat)
+ if(stat/=0) call cq_abort('Error allocating memory to work_out_filter/exx !',stat)
+ !
+ call fft3_init_wrapper( 2*exx_filter_extent+1 )
+ !
+ allocate(reckernel_3d_filter(2*exx_filter_extent+1,2*exx_filter_extent+1,2*exx_filter_extent+1), STAT=stat)
+ if(stat/=0) call cq_abort('Error allocating memory to reckernel_3d_filter/exx !',stat)
+
+ call exx_scal_rho_3d(inode,exx_filter_extent,r_int,exx_pscheme,pulay_radius, &
+ p_omega,p_ngauss,p_gauss,w_gauss,reckernel_3d_filter)
+
+ end if
+
+
+!!$
+!!$ ****[ k loop ]****
+!!$
+ k_loop: do k = 1, ahalo%nh_part(kpart)
+ !
+ k_in_halo = ahalo%j_beg(kpart) + k - 1
+ k_in_part = ahalo%j_seq(k_in_halo)
+ nbkbeg = ibaddr (k_in_part)
+ nb_nd_kbeg = ib_nd_acc (k_in_part)
+ nd3 = ahalo%ndimj(k_in_halo)
+ call get_halodat(kg,kg,k_in_part,ahalo%i_hbeg(ahalo%lab_hcover(kpart)), &
+ ahalo%lab_hcell(kpart),'k',.true.,unit_exx_debug)
+ !
+ if ( filter_eris ) then
+ call exx_phi_on_grid(inode,kg%global_num,kg%spec,exx_filter_extent, &
+ xyz_zero,maxsuppfuncs,phi_k_filter,r_int,xyz_zero)
+ end if
+
+ jbnab2ch = 0
+ do j = 1, nbnab(k_in_part)
+ jpart = ibpart(nbkbeg+j-1) + k_off
+ jseq = ibseq (nbkbeg+j-1)
+ jbnab2ch(j) = chalo%i_halo(chalo%i_hbeg(jpart)+jseq-1)
+ end do
+ !
+ nbbeg = nb_nd_kbeg
+ !
+!!$
+!!$ ****[ l do loop ]****
+!!$
+ l_loop: do l = 1, nbnab(k_in_part)
+ lpart = ibpart(nbkbeg+l-1) + k_off
+ lseq = ibseq (nbkbeg+l-1)
+ call get_halodat(ld,kg,lseq,chalo%i_hbeg(lpart), &
+ BCS_parts%lab_cell(BCS_parts%inv_lab_cover(lpart)), &
+ 'l',.true.,unit_exx_debug)
+ !
+ if ( filter_eris ) then
+ !
+ call exx_phi_on_grid(inode,ld%global_num,ld%spec,exx_filter_extent, &
+ ld%xyz,maxsuppfuncs,phi_l_filter,r_int,xyz_zero)
+ !
+ end if
+ !
+ ld_loop: do nsf_ld = 1, ld%nsup
+ !
+ nbaddr = nbbeg + kg%nsup * (nsf_ld - 1)
+ !
+ kg_loop: do nsf_kg = 1, kg%nsup
+ !
+ K_val = b(nbaddr+nsf_kg-1)
+ !
+!!$
+!!$ ****[ i loop ]****
+!!$
+ i_loop: do i = 1, at%n_hnab(k_in_halo)
+ i_in_prim = at%i_prim(at%i_beg(k_in_halo)+i-1)
+ nd1 = ahalo%ndimi (i_in_prim)
+ ni = bundle%iprim_seq (i_in_prim)
+ np = bundle%iprim_part(i_in_prim)
+ icad = (i_in_prim - 1) * chalo%ni_in_halo !***
+ !
+ call get_iprimdat(ia,kg,ni,i_in_prim,np,.true.,unit_exx_debug)
+ !
+ !
+ !should_compute_eri_ik = sqrt(sum( (ia%xyz_ip-kg%xyz_cv)**2)) < ( ia%radi + kg%radi )
+ should_compute_eri_ik = sqrt(sum( (ia%xyz_ip-kg%xyz_cv)**2)) < exx_cutoff
+ !
+ if ( filter_eris .and. should_compute_eri_ik ) then
+ call exx_phi_on_grid(inode,ia%ip,ia%spec,exx_filter_extent, &
+ ia%xyz,maxsuppfuncs,phi_i_filter,r_int,xyz_zero)
+ end if
+ !
+!!$
+!!$ ****[ j loop ]****
+!!$
+ j_loop: do j = 1, nbnab(k_in_part)
+ j_in_halo = jbnab2ch(j) !***
+ !
+ if ( j_in_halo /= 0 ) then
+ !
+ ncbeg = chalo%i_h2d(icad + j_in_halo) !***
+ !
+ if ( ncbeg /= 0 ) then
+ jpart = ibpart(nbkbeg+j-1) + k_off
+ jseq = ibseq (nbkbeg+j-1)
+ !
+ call get_halodat(jb,kg,jseq,chalo%i_hbeg(jpart), &
+ BCS_parts%lab_cell(BCS_parts%inv_lab_cover(jpart)), &
+ 'j',.true.,unit_exx_debug)
+ !
+ !should_compute_eri_jl = sqrt(sum( (jb%xyz_cv-ld%xyz_cv)**2)) < ( jb%radi + ld%radi )
+ should_compute_eri_jl = sqrt(sum( (jb%xyz_cv-ld%xyz_cv)**2)) < ( exx_cutoff )
+ !
+ if ( filter_eris .and. should_compute_eri_jl ) then
+ call exx_phi_on_grid(inode,jb%global_num,jb%spec,exx_filter_extent, &
+ jb%xyz,maxsuppfuncs,phi_j_filter,r_int,xyz_zero)
+ end if
+ !
+ jb_loop: do nsf_jb = 1, jb%nsup
+ !
+ ncaddr = ncbeg + ia%nsup * (nsf_jb - 1)
+ !
+ if ( filter_eris .and. should_compute_eri_jl ) then
+ work_out = zero
+ work_in = phi_l_filter(:,:,:,nsf_ld)*phi_j_filter(:,:,:,nsf_jb)
+ !
+ call exx_v_on_grid(inode,exx_filter_extent,work_in,work_out,r_int, &
+ exx_psolver,exx_pscheme,pulay_radius,p_omega,p_ngauss,p_gauss, &
+ w_gauss,reckernel_3d_filter)
+ !
+ end if
+ !
+ ia_loop: do nsf_ia = 1, ia%nsup
+ !
+ if ( compute_exx ) then
+ !
+ c(ncaddr + nsf_ia - 1) = c(ncaddr + nsf_ia - 1) + &
+ eris(kpart)%store_eris(count_eris + 1) * K_val
+ !
+ else
+ !
+ if ( filter_eris ) then
+ !
+ exx_mat_elem = zero
+ !
+ if ( should_compute_eri_ik .and. should_compute_eri_jl ) then
+ !
+ do r = 1, 2*exx_filter_extent+1
+ do s = 1, 2*exx_filter_extent+1
+ do t = 1, 2*exx_filter_extent+1
+
+ exx_mat_elem = exx_mat_elem &
+ + phi_k_filter(t,s,r,nsf_kg) &
+ * phi_i_filter(t,s,r,nsf_ia) &
+ * work_out(t,s,r) * dv
+ end do
+ end do
+ end do
+ !
+ end if
+ !
+ if ( abs(exx_mat_elem) < exx_filter_thr ) then
+ !
+ eris(kpart)%filter_eris( count_eris + 1) = .false.
+ !
+ end if
+ !
+ if (exx_debug) then
+
+ write(unit_eri_filter_debug,10) count_eris+1, exx_mat_elem, &
+ eris(kpart)%filter_eris(count_eris + 1), &
+ '[',ia%ip, kg%global_num,'|',ld%global_num, jb%global_num,']', &
+ '(',nsf_ia,nsf_kg, '|',nsf_ld,nsf_jb, ')' , &
+ '[',ia%name,kg%name,'|',ld%name,jb%name,']' , &
+ K_val, kg%r, ld%r, ia%r, jb%r
+
+ end if
+ !
+ end if
+ !
+ end if
+ !
+ count_eris = count_eris + 1
+ !
+ end do ia_loop
+ !
+ !
+ end do jb_loop
+ !
+ end if
+ !
+ end if
+ !
+!!$
+!!$ ****[ j end loop ]****
+!!$
+ !
+ end do j_loop
+ !
+!!$
+!!$ ****[ i end loop ]****
+!!$
+ !
+ end do i_loop
+
+ end do kg_loop
+ !
+ end do ld_loop
+ !
+ nbbeg = nbbeg + ld%nsup*kg%nsup
+ !
+!!$
+!!$ ****[ l end loop ]****
+!!$
+ end do l_loop
+!!$
+!!$ ****[ k end loop ]****
+!!$
+ end do k_loop
+ !
+
+ if (iprint_exx > 5) write(io_lun,*) 'Proc :', myid, &
+ 'kpart:', kpart, 'nb. of ERIs:', count_eris
+ !
+
+ if ( filter_eris ) then
+ deallocate( phi_i_filter, STAT=stat )
+ if(stat/=0) call cq_abort('Error allocating memory to phi_i_filter/exx !',stat)
+ !
+ deallocate( phi_j_filter, STAT=stat )
+ if(stat/=0) call cq_abort('Error allocating memory to phi_j_filter/exx !',stat)
+ !
+ deallocate( phi_k_filter, STAT=stat )
+ if(stat/=0) call cq_abort('Error allocating memory to phi_k_filter/exx !',stat)
+ !
+ deallocate( phi_l_filter, STAT=stat )
+ if(stat/=0) call cq_abort('Error allocating memory to phi_l_filter/exx !',stat)
+ !
+ deallocate( work_in, STAT=stat)
+ if(stat/=0) call cq_abort('Error allocating memory to work_in_filter/exx !',stat)
+ !
+ deallocate(work_out, STAT=stat)
+ if(stat/=0) call cq_abort('Error allocating memory to work_out_filter/exx !',stat)
+ !
+ deallocate(reckernel_3d_filter, STAT=stat)
+ if(stat/=0) call cq_abort('Error allocating memory to reckernel_3d_filter/exx !',stat)
+
+ end if
+
+10 format(I8,X,F16.10,X,L,X,A,2I4,A,2I4,A,4X,A,2I4,A,2I4,A,A,2A4,A,2A4,A,X,8F12.6)
+
+
+ return
+ end subroutine m_kern_exx_dummy
+ !
+ subroutine plot1d_obj(obj_on_grid,extent,r_int,unit,filename)
+
+ use numbers, ONLY: zero, twopi
+
+ implicit none
+
+ ! << Passed variables >>
+ integer, intent(in) :: extent
+ integer, intent(in) :: unit
+ real(double),intent(in) :: r_int
+ character(*),intent(in) :: filename
+
+ real(double),intent(inout) :: obj_on_grid(2*extent+1,2*extent+1,2*extent+1)
+
+ ! << Local variables >>
+
+ real(double) :: h
+ integer :: i
+
+
+ h = r_int/real(extent,double)
+
+ open(unit,file=filename)
+
+ do i = 1, 2*extent+1
+ write(unit,'(3F24.16)') &
+ real(i-extent-1,double)*h, &
+ obj_on_grid(extent+1,extent+1,i)
+ end do
+
+ close(unit)
+
+ return
+ end subroutine plot1d_obj
+ !!***
+
+end module exx_kernel_default
+
+
diff --git a/src/exx_memory.f90 b/src/exx_memory.f90
index fa9f117f6..3487b1d7a 100644
--- a/src/exx_memory.f90
+++ b/src/exx_memory.f90
@@ -20,21 +20,24 @@ module exx_memory
use datatypes
- use exx_types, ONLY: phi_i, phi_j, phi_k, phi_l
- use exx_types, ONLY: Phy_k, Ome_kj, rho_kj, vhf_kj
+ use exx_types, ONLY: phi_i, phi_i_1d_buffer, phi_j, phi_k, phi_l
+ use exx_types, ONLY: Phy_k, Ome_kj_1d_buffer
+
use exx_types, ONLY: work_in_3d,work_out_3d
use exx_types, ONLY: reckernel_3d,ewald_rho,ewald_pot
use exx_types, ONLY: isf_rho,isf_pot_ion
use exx_types, ONLY: fftwrho3d
+ use exx_types, ONLY: eris
+
use exx_types, ONLY: tmr_std_exx_allocat, tmr_std_exx_dealloc
use exx_types, ONLY: unit_memory_write
use global_module, ONLY: area_exx, io_lun
use timer_module, ONLY: start_timer, stop_timer, print_timer
- use memory_module, ONLY: reg_alloc_mem, reg_dealloc_mem, type_dbl
+ use memory_module, ONLY: reg_alloc_mem, reg_dealloc_mem, type_dbl, type_cplx
use GenComms, ONLY: cq_abort
use fft_interface_module, ONLY: fft3_init_wrapper
@@ -101,6 +104,15 @@ subroutine exx_mem_alloc(extent,nsf1,nsf2,matrix,flag,unit,n_neigh,neigh)
!write(*,*) '\phi_{i\alpha} allocated', shape(phi_i)
!
!
+ case('phi_i_1d_buffer') ! allocate phi_i_1d_buffer for primary atom
+ allocate(phi_i_1d_buffer(nsf1*(2*extent+1)*(2*extent+1)*(2*extent+1)), STAT=stat)
+ if(stat/=0) call cq_abort('Error allocating memory to phi_i_1d_buffer/exx !',stat)
+ call reg_alloc_mem(area_exx,nsf1*(2*extent+1)*(2*extent+1)*(2*extent+1),&
+ type_dbl,matrix,lun)
+ phi_i_1d_buffer = zero
+ !write(*,*) '\phi_{i\alpha}_1d_buffer allocated', shape(phi_i_1d_buffer)
+ !
+ !
case('phi_j') ! allocate phi_j for neighbour atom [Srange]
allocate(phi_j(2*extent+1,2*extent+1,2*extent+1,nsf1), STAT=stat)
if(stat/=0) call cq_abort('Error allocating memory to phi_j/exx !',stat)
@@ -134,36 +146,18 @@ subroutine exx_mem_alloc(extent,nsf1,nsf2,matrix,flag,unit,n_neigh,neigh)
!!$
!!$
!
- case('rho_kj') ! allocate rho_kj for neighbour[k]/neighbour[j] atoms [Krange/Srange]
- allocate(rho_kj(2*extent+1,2*extent+1,2*extent+1,nsf1,nsf2), STAT=stat)
- if(stat/=0) call cq_abort('Error allocating memory to rho_kj/exx !',stat)
- call reg_alloc_mem(area_exx,nsf1*nsf2*(2*extent+1)*(2*extent+1)*(2*extent+1),&
- type_dbl,matrix,lun)
- rho_kj = zero
- !write(unit,*) '\rho_{k\gamma j\beta} allocated'
- !
- !
- case('Ome_kj') ! allocate Ome_kj
- allocate(Ome_kj(2*extent+1,2*extent+1,2*extent+1,nsf1,nsf2), STAT=stat)
- if(stat/=0) call cq_abort('Error allocating memory to Ome_j/exx !',stat)
- call reg_alloc_mem(area_exx,nsf1*nsf2*(2*extent+1)*(2*extent+1)*(2*extent+1),&
- type_dbl,matrix,lun)
- Ome_kj = zero
- !write(unit,*) '\Ome_{k\gamma}_{j\beta} allocated'
- !
- !
- case('vhf_kj') ! allocate vhf_kj
- allocate(vhf_kj(2*extent+1,2*extent+1,2*extent+1,nsf1,nsf2), STAT=stat)
- if(stat/=0) call cq_abort('Error allocating memory to vhf_kj/exx !',stat)
- call reg_alloc_mem(area_exx,nsf1*nsf2*(2*extent+1)*(2*extent+1)*(2*extent+1),&
+ case('Ome_kj_1d_buffer') ! allocate Ome_kj_1d_buffer
+ allocate(Ome_kj_1d_buffer((2*extent+1)*(2*extent+1)*(2*extent+1)), STAT=stat)
+ if(stat/=0) call cq_abort('Error allocating memory to Ome_kj_1d_buffer/exx !',stat)
+ call reg_alloc_mem(area_exx,(2*extent+1)*(2*extent+1)*(2*extent+1),&
type_dbl,matrix,lun)
- vhf_kj = zero
- !write(unit,*) '\vhf_{k\gamma j\beta} allocated'
+ Ome_kj_1d_buffer = zero
+ !write(unit,*) '\Ome_{k\gamma}_{j\beta}_1d_buffer allocated'
!
!
case('Phy_k')! allocate Phy_k
allocate(Phy_k(2*extent+1,2*extent+1,2*extent+1,nsf1), STAT=stat)
- if(stat/=0) call cq_abort('Error allocating memory to Phy_j/exx !',stat)
+ if(stat/=0) call cq_abort('Error allocating memory to Phy_k/exx !',stat)
call reg_alloc_mem(area_exx,nsf1*(2*extent+1)*(2*extent+1)*(2*extent+1),&
type_dbl,matrix,lun)
Phy_k = zero
@@ -208,7 +202,7 @@ subroutine exx_mem_alloc(extent,nsf1,nsf2,matrix,flag,unit,n_neigh,neigh)
allocate(reckernel_3d(2*extent+1,2*extent+1,2*extent+1), STAT=stat)
if(stat/=0) call cq_abort('Error allocating memory to reckernel_3d/exx !',stat)
call reg_alloc_mem(area_exx,(2*extent+1)*(2*extent+1)*(2*extent+1),&
- type_dbl,matrix,lun)
+ type_cplx,matrix,lun)
reckernel_3d = zero
!write(unit,*) 'reckernel_3d allocated'
!
@@ -238,11 +232,11 @@ subroutine exx_mem_alloc(extent,nsf1,nsf2,matrix,flag,unit,n_neigh,neigh)
allocate(fftwrho3d%arrayin(2*extent+1,2*extent+1,2*extent+1), STAT=stat)
if(stat/=0) call cq_abort('Error allocating memory to fftwin3d/exx !',stat)
call reg_alloc_mem(area_exx,2*(2*extent+1)*(2*extent+1)*(2*extent+1),&
- type_dbl,'fftw_in ',lun)
+ type_cplx,'fftw_in ',lun)
allocate(fftwrho3d%arrayout(2*extent+1,2*extent+1,2*extent+1), STAT=stat)
if(stat/=0) call cq_abort('Error allocating memory to fftwout3d/exx !',stat)
call reg_alloc_mem(area_exx,2*(2*extent+1)*(2*extent+1)*(2*extent+1),&
- type_dbl,'fftw_out',lun)
+ type_cplx,'fftw_out',lun)
!
!**** don't touch
!
@@ -289,6 +283,14 @@ subroutine exx_mem_alloc(extent,nsf1,nsf2,matrix,flag,unit,n_neigh,neigh)
!write(*,*) '\phi_{i\alpha} deallocated'
!
!
+ case('phi_i_1d_buffer')
+ deallocate(phi_i_1d_buffer,STAT=stat)
+ if(stat/=0) call cq_abort('Error deallocating memory to phi_i_1d_buffer/exx !',stat)
+ call reg_dealloc_mem(area_exx,nsf1*(2*extent+1)*(2*extent+1)*(2*extent+1),&
+ type_dbl,matrix,lun)
+ !write(*,*) '\phi_{i\alpha}_1d_buffer deallocated'
+ !
+ !
case('phi_j')
deallocate(phi_j,STAT=stat)
if(stat/=0) call cq_abort('Error deallocating memory to phi_j/exx !',stat)
@@ -313,32 +315,16 @@ subroutine exx_mem_alloc(extent,nsf1,nsf2,matrix,flag,unit,n_neigh,neigh)
!write(*,*) '\phi_{l\delta} deallocated'
!
!
- case('rho_kj') ! allocate rho_kj for neighbour[k]/neighbour[j] atoms [Krange/Srange]
- deallocate(rho_kj, STAT=stat)
- if(stat/=0) call cq_abort('Error deallocating memory to rho_kj/exx !',stat)
- call reg_dealloc_mem(area_exx,nsf1*nsf2*(2*extent+1)*(2*extent+1)*(2*extent+1),&
- type_dbl,matrix,lun)
- !write(unit,*) '\rho_{k\gamma j\beta} deallocated'
- !
- !
- case('Ome_kj')
- deallocate(Ome_kj,STAT=stat)
- if(stat/=0) call cq_abort('Error deallocating memory to Ome_j/exx !',stat)
- call reg_dealloc_mem(area_exx,nsf1*nsf2*(2*extent+1)*(2*extent+1)*(2*extent+1),&
+ case('Ome_kj_1d_buffer')
+ deallocate(Ome_kj_1d_buffer,STAT=stat)
+ if(stat/=0) call cq_abort('Error deallocating memory to Ome_kj_1d_buffer/exx !',stat)
+ call reg_dealloc_mem(area_exx,(2*extent+1)*(2*extent+1)*(2*extent+1),&
type_dbl,matrix,lun)
- !write(unit,*) '\Ome_{k\gamma}_{j\beta} deallocated'
+ !write(unit,*) '\Ome_{k\gamma}_{j\beta}_1d_buffer deallocated'
- case('vhf_kj')
- deallocate(vhf_kj, STAT=stat)
- if(stat/=0) call cq_abort('Error deallocating memory to vhf_kj/exx !',stat)
- call reg_dealloc_mem(area_exx,nsf1*nsf2*(2*extent+1)*(2*extent+1)*(2*extent+1),&
- type_dbl,matrix,lun)
- !write(unit,*) '\vhf_{k\gamma j\beta} deallocated'
- !
- !
case('Phy_k')
deallocate(Phy_k, STAT=stat)
- if(stat/=0) call cq_abort('Error allocating memory to Phy_k/exx !',stat)
+ if(stat/=0) call cq_abort('Error deallocating memory to Phy_k/exx !',stat)
call reg_dealloc_mem(area_exx,nsf1*(2*extent+1)*(2*extent+1)*(2*extent+1),&
type_dbl,matrix,lun)
!write(unit,*) '\Phy_{k\gamma} deallocated'
@@ -402,6 +388,12 @@ subroutine exx_mem_alloc(extent,nsf1,nsf2,matrix,flag,unit,n_neigh,neigh)
call reg_dealloc_mem(area_exx,2*(2*extent+1)*(2*extent+1)*(2*extent+1),&
type_dbl,'fftw_out',lun)
!
+ case('eris')
+ deallocate(eris, STAT=stat)
+ if(stat/=0) call cq_abort('Error deallocating memory to eris/exx !',stat)
+ call reg_dealloc_mem(area_exx,extent,type_dbl,matrix,lun)
+ !write(unit,*) 'ERIs deallocated'
+ !
!
case default
call cq_abort('Error deallocation/exx_mem !',stat)
diff --git a/src/exx_module.f90 b/src/exx_module.f90
index a41181e9f..67b2b91a9 100644
--- a/src/exx_module.f90
+++ b/src/exx_module.f90
@@ -10,7 +10,7 @@
!!***h* Conquest/exx_module *
!! NAME
!! exx_module
-!!
+!!
!! PURPOSE
!! Holds routines called in exx_kernel_module
!! to compute exact exchange
@@ -34,285 +34,38 @@
!! SOURCE
!!
module exx_module
-
+
use datatypes
use GenComms, only: my_barrier, cq_abort, mtime
use GenComms, only: inode, ionode, myid, root
use timer_module, only: start_backtrace, stop_backtrace, cq_timer
!**** ISF Poisson solver Will be available in the forthcoming version
!use Poisson_Solver, only: PSolver, createKernel, gequad
-
+ use global_module, only: io_lun, exx_cutoff
use exx_types, only: reckernel_3d, fftwrho3d, exx_debug
use exx_io
-
+
use fft_interface_module, only: fft3_exec_wrapper, fft3_init_wrapper
-
+
implicit none
! Area identification
integer, parameter, private :: area = 13
-
+
!!***
-
-contains
-
- subroutine exx_scal_rho_3d(inode,extent,r_int,scheme,cutoff,omega,n_gauss, &
- p_gauss,w_gauss)
-
- use datatypes
- use numbers, ONLY: twopi, pi, sqrt_pi, very_small
- use numbers, ONLY: zero, one, two, four, three_halves
-
- implicit none
-
- ! << Passed variables >>
- character(*), intent(in) :: scheme
- integer, intent(in) :: extent
- integer, intent(in) :: inode
- real(double), intent(in) :: r_int
-
- real(double), intent(in) :: cutoff
- real(double), intent(in) :: omega
-
- integer, intent(in) :: n_gauss
- real(double), optional, intent(in) :: p_gauss(n_gauss)
- real(double), optional, intent(in) :: w_gauss(n_gauss)
- ! << Local variables >>
- real(double),dimension(3) :: G
- real(double) :: charge_G
-
- real(double), parameter :: magic_number = 0.1864d0 ! 32/43 = nombre magic !
-
- real(double) :: r_G, r_A, v_G, v_R, sphere, fftwnorm, tmp, alpha
- real(double) :: rho_zero, Gkernel, Gkernel_zero, arg, factor, delta
- real(double) :: max_, min_
-
- integer :: gauss
- integer :: nx, ny, nz, ngrid
- integer :: x, y, z
- integer :: i, j, k
-
- ngrid = 2*extent+1
- fftwnorm = sqrt(real(ngrid**3,double))
-
- r_A = real(2,double)*r_int
- r_G = zero
- G = zero
-
- v_G = (twopi**3)*real(1,double)/(real(2,double)*r_int)**3
- v_R = (real(2,double)*r_int)**3
- sphere = ((twopi*real(1,double)/(real(2,double)*r_int))**3)*(1.0d0/6.0d0*pi)
-
- reckernel_3d = zero
-
- poisson_scheme: select case(scheme)
- case('default')
- delta = zero
- case('ewald')
- delta = zero
- case('pulay')
- delta = zero
- case('yukawa')
- delta = omega
- case('gauss')
- delta = zero
- case default
- delta = zero
- end select poisson_scheme
-
- grid_x_loop: do nx = -extent, extent
- x = nx + extent + 1
- if (nx <= 0) then
- G(1) = twopi*( real(nx+extent+delta,double))/r_A
- else
- G(1) = twopi*(-real(extent-nx+(one-delta),double))/r_A
- end if
-
- grid_y_loop: do ny = -extent, extent
- y = ny + extent + 1
- if (ny <= 0) then
- G(2) = twopi*( real(ny+extent+delta,double))/r_A
- else
- G(2) = twopi*(-real(extent-ny+(one-delta),double))/r_A
- end if
-
- grid_z_loop: do nz = -extent, extent
- z = nz + extent + 1
- if (nz <= 0) then
- G(3) = twopi*( real(nz+extent+delta,double))/r_A
- else
- G(3) = twopi*(-real(extent-nz+(one-delta),double))/r_A
- end if
-
- r_G = sqrt(dot_product(G,G))
-
- !if (scheme == 'yukawa') then
- ! if (r_G > 0.1d0) then
- ! delta = zero
- ! end if
- !end if
-
- if (r_G == zero) then
-
- !write(*,*) x, y, z
- poisson_zero: select case(scheme)
- case('default')
- reckernel_3d(x,y,z) = cmplx(0,0,double_cplx)
- case('ewald')
- reckernel_3d(x,y,z) = cmplx(0,0,double_cplx)
- case('pulay')
- reckernel_3d(x,y,z) = cmplx(cutoff**2/two,0,double_cplx)
- case('yukawa')
- reckernel_3d(x,y,z) = cmplx(0,0,double_cplx)
- case('gauss')
- Gkernel_zero = zero
- do gauss = 1, n_gauss
- Gkernel_zero = Gkernel_zero + &
- w_gauss(gauss)*sqrt_pi/(four*p_gauss(gauss)**three_halves)
- end do
- reckernel_3d(x,y,z) = cmplx(Gkernel_zero,double_cplx)
- case default
- reckernel_3d(x,y,z) = cmplx(zero,zero,double_cplx)
- end select poisson_zero
- else
- poisson_xyz: select case(scheme)
- case('default')
- reckernel_3d(x,y,z) = cmplx(one/r_G**2,zero,double_cplx)
- case('ewald')
- reckernel_3d(x,y,z) = cmplx(one/r_G**2,zero,double_cplx)
- case('pulay')
- reckernel_3d(x,y,z) = (one - cos(r_G*cutoff))/r_G**2
- case('yukawa')
- reckernel_3d(x,y,z) = cmplx(one/r_G**2,zero,double_cplx)
- case('gauss')
- Gkernel = zero
- arg = zero
- factor = zero
-
- do gauss = 1, n_gauss
- factor = w_gauss(gauss)*sqrt(pi)/(four*p_gauss(gauss)**three_halves)
- arg = -(r_G/(two*sqrt(p_gauss(gauss))))**two
- Gkernel = Gkernel + factor*exp(arg)
- max_ = max(max_,arg)
- min_ = min(min_,arg)
-
- end do
- reckernel_3d(x,y,z) = cmplx(Gkernel,zero,double_cplx)
- case default
- reckernel_3d(x,y,z) = cmplx(one/r_G**2,zero,double_cplx)
- end select poisson_xyz
- end if
-
- end do grid_z_loop
- end do grid_y_loop
- end do grid_x_loop
-
- return
- end subroutine exx_scal_rho_3d
- !
- !
- !
- !
- subroutine exx_v_on_grid(inode,extent,rho,potential,r_int,poisson,scheme,&
- alpha,omega,n_gauss,p_gauss,w_gauss)
-
- use numbers, ONLY: zero, one, fourpi
- use exx_types, ONLY: reckernel_3d ! FFTW
- use exx_types, ONLY: kernel, isf_rho, isf_pot_ion ! ISF
- use exx_types, ONLY: pulay_radius, ewald_rho, ewald_pot, ewald_charge
- use exx_types, ONLY: tmr_std_exx_poisson
-
- implicit none
-
- ! << Input variables >>
- integer, intent(in) :: inode
- integer, intent(in) :: extent
- real(double), intent(in) :: r_int
- character(*), intent(in) :: poisson
-
- real(double), dimension(2*extent+1,2*extent+1,2*extent+1), &
- intent(in) :: rho
-
- character(*), intent(in) :: scheme
- real(double), intent(in) :: alpha
- real(double), intent(in) :: omega
- integer, intent(in) :: n_gauss
- real(double), dimension(n_gauss) :: p_gauss, w_gauss
-
- ! << Output variables >>
- real(double), dimension(2*extent+1,2*extent+1,2*extent+1), &
- intent(out) :: potential
-
- ! << Local variables >>
- integer :: ng, i, j, k
- real(double) :: fftwnorm, normr
- real(double) :: grid_spacing
- real(double) :: r(3)
- logical, parameter :: accumulate = .true.
-
- ! ... For Poisson/ISF real space FFT >>
- real(kind=8) :: isf_eh, isf_exc, isf_vxc, isf_spacing
-
- ! ... Dummy variables >>
- real(double), dimension(:,:,:), allocatable :: dum_pot_ion, dum_rho
-
- ng = 2*extent+1
- fftwnorm = sqrt(real(ng**3,double))
- grid_spacing = r_int/real(extent,double)
-
- !call start_timer(tmr_std_exx_poisson)
-
- select case(poisson)
-
- case('fftw')
- potential = zero
-
- ! setup[rho(r)]
- fftwrho3d%arrayin = cmplx(rho,zero,double_cplx)
-
- ! FFT_F[rho(r)] => rho(G)
- call fft3_exec_wrapper( fftwrho3d%arrayin, ng , +1 )
-
- ! scale[rho_(G)] = 4pi*rho(G)/|G|^2
- fftwrho3d%arrayin = fourpi*fftwrho3d%arrayin*reckernel_3d
-
- ! FFT_B[4pi*rho(G)/|G|^2] = V(r')
- call fft3_exec_wrapper( fftwrho3d%arrayin, ng , -1 )
-
- ! Normalization
- potential = real(fftwrho3d%arrayin) / fftwnorm**2
-
- case('isf')
- !
- call cq_abort('EXX: not available yet')
- !
- !isf_rho = rho
- !potential = zero
- !isf_pot_ion = zero
- !
- !call PSolver('F','G',0,1,ng,ng,ng,0,grid_spacing,grid_spacing,grid_spacing, &
- ! isf_rho,kernel,isf_pot_ion,isf_eh,isf_exc,isf_vxc,zero,.false.,1)
- !potential = isf_rho
- !
- end select
-
- !call stop_timer(tmr_std_exx_poisson,accumulate)
-
- return
- end subroutine exx_v_on_grid
- !
+contains
!
subroutine get_X_params(level)
- use exx_types, only: exx_psolver,p_scheme,p_scheme_default,p_cutoff,p_factor,p_omega
+ use exx_types, only: exx_psolver,exx_pscheme,exx_pscheme_default,p_cutoff,p_factor,p_omega
use exx_types, only: pulay_factor,pulay_radius, magic_number,ewald_alpha,isf_order
use exx_types, only: extent,ngrid,r_int,grid_spacing,volume,edge,screen
- use exx_types, only: exx_scheme, exx_phil, exx_mem, exx_screen, exx_alloc, exx_cutoff
- use exx_types, only: exx_cartesian, exx_overlap, exx_radius, exx_screen_pao, exx_hgrid
- use exx_types, only: unit_output_write, exx_phik, exx_gto, exx_debug
- use exx_types, only: tmr_std_exx_setup
+ use exx_types, only: exx_scheme, exx_mem, exx_screen, exx_alloc
+ use exx_types, only: exx_cartesian, exx_overlap, exx_radius, exx_screen_pao
+ use exx_types, only: exx_grid, exx_hgrid, exx_gto, exx_debug
+ use exx_types, only: tmr_std_exx_setup, exx_store_eris
use atomic_density, only: atomic_density_table
use species_module, only: n_species
@@ -352,14 +105,10 @@ subroutine get_X_params(level)
!
! **** This routine need to be re-written !
!
- exx_phil = .false.
- exx_phik = .false.
exx_screen = .false.
exx_screen_pao = .false.
- exx_gto = .false.
- exx_cutoff = zero ! do not touch
- unit = unit_output_write ! do not touch
- !if (exx_mem == 2) exx_alloc = .false.
+ exx_store_eris = .false.
+ !exx_cutoff = zero ! do not touch
!
! Find out the finest grid spacing from input
! Input grid spacing from input (Bohr unit)
@@ -372,8 +121,18 @@ subroutine get_X_params(level)
gs_min = minval(gs)
!
! Setup grid spacing of EXX
- if ( exx_hgrid < very_small .and. exx_hgrid >= zero ) then
- grid_spacing = gs_min
+ if ( exx_hgrid < very_small ) then
+ ! Select by input tag
+ if ( trim(exx_grid) == 'fine' ) then
+ grid_spacing = real(0.2d0,double)
+ else if ( trim(exx_grid) == 'standard' ) then
+ grid_spacing = real(0.4d0,double)
+ else if ( trim(exx_grid) == 'coarse' ) then
+ grid_spacing = real(0.6d0,double)
+ else
+ call cq_abort('EXX: unrecognised grid accuracy')
+ end if
+
else if ( exx_hgrid >= zero ) then
grid_spacing = exx_hgrid
else
@@ -423,16 +182,23 @@ subroutine get_X_params(level)
! Below for output purpose
if (exx_scheme==1) then
eri_scheme = "3center reduction integrals"
- else
+ else if ( exx_scheme==2 ) then
eri_scheme = "4center eris"
- end if
- !
- if (exx_phil) then
- phil_scheme = 'storage'
+ else if ( exx_scheme==3 ) then
+ eri_scheme = "4center eris + storage"
else
- phil_scheme = 'on-the-fly'
+ eri_scheme = "none"
+ exx_psolver = "none"
+ solver = 'none'
+ scheme = trim(exx_psolver)
end if
!
+ !if (exx_phil) then
+ ! phil_scheme = 'storage'
+ !else
+ ! phil_scheme = 'on-the-fly'
+ !end if
+ !
if (exx_alloc) then
alloc_scheme = 'on-the-fly'
else
@@ -445,16 +211,16 @@ subroutine get_X_params(level)
pao_scheme = 'spherical'
end if
!
- if (exx_mem == 1) then
- mem_scheme = 'high'
- else if (exx_mem == 2) then
- mem_scheme = 'low'
- else if (exx_mem == 3) then
- mem_scheme = 'medium'
- else
- mem_scheme = 'low'
- exx_mem = 2
- end if
+ !if (exx_mem == 1) then
+ ! mem_scheme = 'high'
+ !else if (exx_mem == 2) then
+ ! mem_scheme = 'low'
+ !else if (exx_mem == 3) then
+ ! mem_scheme = 'medium'
+ !else
+ ! mem_scheme = 'low'
+ ! exx_mem = 2
+ !end if
!
if (exx_screen) then
if (exx_cutoff > very_small) then
@@ -474,48 +240,48 @@ subroutine get_X_params(level)
if (exx_scheme==2) then
phil_scheme = 'on-the-fly'
alloc_scheme = 'on-the-fly'
- mem_scheme = 'high'
+ !mem_scheme = 'high'
end if
!
- if ( inode == ionode .and. exx_debug ) then
- write(unit,2) ('Entering in the Hartree-Fock module')
- write(unit,41) eri_scheme
- write(unit,42) phil_scheme
- write(unit,43) alloc_scheme
- write(unit,48) mem_scheme
- write(unit,44) exx_screen, scr_scheme, screen, screen*BohrToAng
+ if ( inode == ionode .and. iprint_exx > 3 ) then
+ write(io_lun,2) ('Entering in the EXX module')
+ write(io_lun,41) eri_scheme
+ !write(io_lun,42) phil_scheme
+ write(io_lun,43) alloc_scheme
+ !write(io_lun,48) mem_scheme
+ write(io_lun,44) exx_screen, scr_scheme, screen, screen*BohrToAng
- write(unit,46) exx_overlap
- write(unit,47) pao_scheme
- write(unit,20)
- write(unit,21) r_max, r_max*BohrToAng
- write(unit,22) r_int, r_int*BohrToAng
- write(unit,23) grid_spacing, grid_spacing*BohrToAng
- write(unit,24) ngrid
- write(unit,25)
- write(unit,26) edge, edge*BohrToAng
- write(unit,27) volume, volume*BohrToAng**3
- write(unit,28) ngrid**3
+ write(io_lun,46) exx_overlap
+ write(io_lun,47) pao_scheme
+ write(io_lun,20)
+ write(io_lun,21) r_max, r_max*BohrToAng
+ write(io_lun,22) r_int, r_int*BohrToAng
+ write(io_lun,23) grid_spacing, grid_spacing*BohrToAng
+ write(io_lun,24) ngrid
+ write(io_lun,25)
+ write(io_lun,26) edge, edge*BohrToAng
+ write(io_lun,27) volume, volume*BohrToAng**3
+ write(io_lun,28) ngrid**3
end if
if (exx_psolver == 'fftw') then
- scheme = trim(scheme)//'/'//trim(p_scheme)
- poisson_fftw: select case(p_scheme)
+ scheme = trim(scheme)//'/'//trim(exx_pscheme)
+ poisson_fftw: select case(exx_pscheme)
case('default')
- scheme = trim(scheme)//trim(p_scheme_default)
- if ( inode == ionode ) then
- !write(unit,30) solver, scheme
- !write(unit,31) ('G=0 component neglected... warning: inaccurate !')
+ scheme = trim(scheme)//trim(exx_pscheme_default)
+ if ( inode == ionode .and. iprint_exx > 2 ) then
+ write(io_lun,30) solver, scheme
+ write(io_lun,31) ('G=0 component neglected... warning: inaccurate !')
end if
case('ewald')
if (ewald_alpha < very_small) then
ewald_alpha = real(3.0,double)
end if
- if ( inode == ionode ) then
- !write(unit,30) solver, scheme
- !write(unit,32) ewald_alpha
+ if ( inode == ionode .and. iprint_exx > 2 ) then
+ write(io_lun,30) solver, scheme
+ write(io_lun,32) ewald_alpha
end if
case('pulay')
@@ -529,41 +295,42 @@ subroutine get_X_params(level)
pulay_factor = one
end if
pulay_radius = pulay_factor*pulay_radius
- if ( inode == ionode ) then
- !write(unit,30) solver, scheme
- !write(unit,33) pulay_factor
- !write(unit,34) pulay_radius
+ if ( inode == ionode .and. iprint_exx > 2 ) then
+ write(io_lun,30) solver, scheme
+ write(io_lun,33) pulay_factor
+ write(io_lun,34) pulay_radius
end if
case('yukawa')
if (p_omega < very_small) then
p_omega = magic_number
p_omega = -log(threshold*r_int)/r_int
end if
- !write(unit,30) solver, scheme
- !write(unit,35) p_omega
-
+ if ( inode == ionode .and. iprint_exx > 2 ) then
+ write(io_lun,30) solver, scheme
+ write(io_lun,35) p_omega
+ end if
case('gauss')
- if ( inode == ionode ) then
- !write(unit,30) solver, scheme
+ if ( inode == ionode .and. iprint_exx > 2 ) then
+ write(io_lun,30) solver, scheme
end if
case default
- scheme = trim(p_scheme_default)
- if ( inode == ionode ) then
- !write(unit,30) solver, scheme
- !write(unit,31) ('WARNING: G=0 component neglected !')
+ scheme = trim(exx_pscheme_default)
+ if ( inode == ionode .and. iprint_exx > 2 ) then
+ write(io_lun,30) solver, scheme
+ write(io_lun,31) ('WARNING: G=0 component neglected !')
end if
end select poisson_fftw
else if (exx_psolver == 'isf') then
- if ( inode == ionode ) then
- !write(unit,30) solver, scheme
- !write(unit,36) isf_order
+ if ( inode == ionode .and. iprint_exx > 2 ) then
+ write(io_lun,30) solver, scheme
+ write(io_lun,36) isf_order
end if
end if
!****lat<$
- if (inode == ionode .and. iprint_exx > 2) then
+ if ( inode == ionode .and. iprint_exx > 3 ) then
write (io_lun,50) &
grid_spacing, &
r_int, &
@@ -588,7 +355,7 @@ subroutine get_X_params(level)
!! EXX Formats start here
1 format(/1x,104a/)
-2 format(1x,34a,8x,/)
+2 format(4x,34a,8x,/)
!! Grid settings
20 format(/25x,'Grid Settings: Cubic')
@@ -603,7 +370,7 @@ subroutine get_X_params(level)
28 format( 23x,'n^3_grid_points: ',i12)
!! Poisson solver
-30 format(/24x,'Poisson Solver: ',a20,/32x,'Scheme: ',a20)
+30 format(/20x,'EXX Poisson Solver: ',a20,/32x,'Scheme: ',a20)
! Warning
31 format( 24x,a34)
! Ewald scheme
@@ -630,237 +397,6 @@ subroutine get_X_params(level)
end subroutine get_X_params
!
!
- subroutine exx_ewald_charge(rho,extent,dv,charge)
-
- use numbers, ONLY: zero
-
- implicit none
-
- integer :: extent
- real(double), dimension(2*extent+1,2*extent+1,2*extent+1), &
- intent(in) :: rho
- real(double), intent(in) :: dv
- real(double), intent(out) :: charge
- integer :: i, j, k
-
- charge = zero
-
- do i = 1, 2*extent+1
- do j = 1, 2*extent+1
- do k = 1, 2*extent+1
- charge = charge + rho(i,j,k)*dv
- end do
- end do
- end do
-
- return
- end subroutine exx_ewald_charge
-
- subroutine exx_ewald_rho(gauss,extent,alpha,r_int)
-
- use numbers, ONLY: zero, one, two, three_halves
- use numbers, ONLY: twopi, pi, three_halves
-
- implicit none
-
- integer, intent(in) :: extent
- real(double), intent(inout) :: alpha
- real(double), intent(in) :: r_int
- real(double), dimension(2*extent+1,2*extent+1,2*extent+1), &
- intent(inout) :: gauss
-
- real(double) :: gnorm, dv, factor
- real(double) :: grid_spacing
- real(double) :: r(3)
-
- integer :: i, j, k
-
- grid_spacing = r_int/real(extent,double)
- factor = (alpha/pi)**three_halves
- !factor = one
- dv = grid_spacing**3
-
- gauss = zero
- gnorm = zero
- do i = -extent, extent
- r(1) = real(i,double)*grid_spacing
- do j = -extent, extent
- r(2) = real(j,double)*grid_spacing
- do k = -extent, extent
- r(3) = real(k,double)*grid_spacing
-
- gauss(extent+i+1,extent+j+1,extent+k+1) = &
- exp(-dot_product(r,r)*alpha)
- gnorm = &
- gnorm + gauss(extent+i+1,extent+j+1,extent+k+1)*dv
-
- end do
- end do
- end do
-
- gauss = gauss*factor
- gnorm = gnorm*factor
-
- return
- end subroutine exx_ewald_rho
-
- subroutine exx_ewald_pot(potential,extent,alpha,r_int)
-
- use numbers, ONLY: zero, one, two, twopi, pi
- use functions, ONLY: erfc_cq
-
- implicit none
-
- integer, intent(in) :: extent
- real(double), intent(inout) :: alpha
- real(double), intent(in) :: r_int
- real(double), dimension(2*extent+1,2*extent+1,2*extent+1), &
- intent(inout) :: potential
-
- real(double) :: arg, factor, dv
- real(double) :: grid_spacing, r(3)
-
- integer :: i, j, k
-
- grid_spacing = r_int/real(extent,double)
- dv = grid_spacing**3
-
- potential = zero
- do i = -extent, extent
- r(1) = real(i,double)*grid_spacing
- do j = -extent, extent
- r(2) = real(j,double)*grid_spacing
- do k = -extent, extent
- r(3) = real(k,double)*grid_spacing
-
- if (i == 0 .and. j == 0 .and. k==0) then
- potential(extent+i+1,extent+j+1,extent+k+1) = two*sqrt(alpha/pi)
- else
- arg = sqrt(dot_product(r,r))*sqrt(alpha)
- factor = one/sqrt(dot_product(r,r))
- potential(extent+i+1,extent+j+1,extent+k+1) = (one - erfc_cq(arg))*factor
- end if
-
- end do
- end do
- end do
-
- return
- end subroutine exx_ewald_pot
-
-!!$ For ISF real-space Poisson solver
-!!$
-!!$subroutine createBeylkin(p_gauss,w_gauss,r_int)
-!!$
-!!$ use numbers, ONLY: zero, one, two, twopi, pi
-!!$
-!!$ implicit none
-!!$
-!!$ ! << Passed variables >>
-!!$ real(double), intent(in) :: r_int
-!!$
-!!$ ! << Local variables >>
-!!$ integer, parameter :: n_gauss = 89
-!!$ real(double) :: ur_gauss,dr_gauss,acc_gauss
-!!$ real(double) :: norm, vol, factor1, factor2
-!!$ real(double) :: p_gauss(n_gauss)
-!!$ real(double) :: w_gauss(n_gauss)
-!!$
-!!$ p_gauss = zero
-!!$ w_gauss = zero
-!!$
-!!$ vol = (real(2,double)*r_int)**3
-!!$ norm = sqrt(vol)
-!!$
-!!$ factor1 = one/norm
-!!$ factor2 = one/vol
-!!$
-!!$ call gequad(n_gauss,p_gauss,w_gauss,ur_gauss,dr_gauss,acc_gauss)
-!!$
-!!$ return
-!!$ end subroutine createBeylkin
-
-
- !
-!!$ subroutine get_neighdat(nb,ia,hl,ind,part,verbose,unit)
-!!$
-!!$ use numbers, only: three
-!!$ use group_module, only: parts
-!!$ use cover_module, only: BCS_parts
-!!$ use global_module, only: id_glob,atom_coord
-!!$ use species_module, only: species_label
-!!$ use atomic_density, only: atomic_density_table
-!!$ use numbers, only: zero, one, two, twopi, pi
-!!$ !
-!!$ use matrix_data, only: mat, Hrange, Srange
-!!$ use exx_types, only: prim_atomic_data, neigh_atomic_data
-!!$ use exx_types, only: tmr_std_exx_fetch
-!!$ !
-!!$ !
-!!$ implicit none
-!!$ !
-!!$ type(neigh_atomic_data), intent(inout) :: nb
-!!$ type(prim_atomic_data), intent(inout) :: ia
-!!$ type(neigh_atomic_data), intent(inout) :: hl
-!!$ integer, intent(in) :: ind
-!!$ integer, intent(in) :: part
-!!$ logical, intent(in) :: verbose
-!!$ !
-!!$ real(double) :: xyz_Ang(3)
-!!$ character(len=20) :: filename
-!!$ integer, optional :: unit
-!!$ !
-!!$ call start_timer(tmr_std_exx_fetch)
-!!$ ! Get u(v) data
-!!$ nb%nb = ind
-!!$ nb%ist = mat(part,Hrange)%i_acc(ia%pr) + nb%nb - 1
-!!$ nb%npc = mat(part,Hrange)%i_part(nb%ist)
-!!$ nb%nic = mat(part,Hrange)%i_seq(nb%ist)
-!!$ !
-!!$ nb%global_part = BCS_parts%lab_cell(mat(part,Hrange)%i_part(nb%ist))
-!!$ nb%global_num = id_glob(parts%icell_beg(nb%global_part) + &
-!!$ mat(part,Hrange)%i_seq(nb%ist)-1)
-!!$ !
-!!$ nb%spec = BCS_parts%spec_cover(BCS_parts%icover_ibeg(nb%npc) + nb%nic-1)
-!!$ nb%name = species_label(nb%spec)
-!!$ nb%radi = atomic_density_table(nb%spec)%cutoff
-!!$ nb%nsup = mat(part,Hrange)%ndimj(nb%ist)
-!!$ !
-!!$ ! Calculate R_u
-!!$ nb%xyz_nb(1) = atom_coord(1,nb%global_num)
-!!$ nb%xyz_nb(2) = atom_coord(2,nb%global_num)
-!!$ nb%xyz_nb(3) = atom_coord(3,nb%global_num)
-!!$ !
-!!$ nb%xyz_cv(1) = BCS_parts%xcover(BCS_parts%icover_ibeg(nb%npc) + &
-!!$ nb%nic - 1)
-!!$ nb%xyz_cv(2) = BCS_parts%ycover(BCS_parts%icover_ibeg(nb%npc) + &
-!!$ nb%nic - 1)
-!!$ nb%xyz_cv(3) = BCS_parts%zcover(BCS_parts%icover_ibeg(nb%npc) + &
-!!$ nb%nic - 1)
-!!$ !
-!!$ ! Calculate R_iu
-!!$ nb%xyz(1) = - nb%xyz_nb(1) + hl%xyz_hl(1)
-!!$ nb%xyz(2) = - nb%xyz_nb(2) + hl%xyz_hl(2)
-!!$ nb%xyz(3) = - nb%xyz_nb(3) + hl%xyz_hl(3)
-!!$ nb%r = sqrt(dot_product(nb%xyz,nb%xyz))
-!!$ !
-!!$ ! Calculate D_iu
-!!$ nb%d = sqrt(three)*(nb%radi + hl%radi)
-!!$ !
-!!$ xyz_Ang(1) = nb%xyz_nb(1)
-!!$ xyz_Ang(2) = nb%xyz_nb(2)
-!!$ xyz_Ang(3) = nb%xyz_nb(3)
-!!$ !
-!!$ if ( exx_debug ) then
-!!$ write(unit,'(I8,4X,A9,4X,A,I8,A2,I3,A,6X,A2,X,I8,X,4F12.4,3X,I3,2I8,X,F7.3,F14.8)') &
-!!$ nb%global_part,'{j\beta} ','{',nb%global_num,'\ ',nb%nsup,'}', nb%name, nb%global_num, &
-!!$ xyz_Ang(1), xyz_Ang(2), xyz_Ang(3), zero, nb%spec, ind, nb%nsup, nb%radi,zero
-!!$ end if
-!!$ call stop_timer(tmr_std_exx_fetch,.true.)
-!!$
-!!$ return
-!!$ end subroutine get_neighdat
-
subroutine get_halodat(hl,kl,ind,part_cover,part,which,verbose,unit)
use numbers, only: three
@@ -872,8 +408,11 @@ subroutine get_halodat(hl,kl,ind,part_cover,part,which,verbose,unit)
use numbers, only: zero, one, two, twopi, pi
!
use matrix_data, only: mat, Hrange, Srange
- use exx_types, only: neigh_atomic_data
- use exx_types, only: tmr_std_exx_fetch
+ use exx_types, only: neigh_atomic_data
+ use exx_types, only: tmr_std_exx_fetch
+ use pao_format, only: pao
+ !
+ use species_module, only: nsf_species
!
implicit none
!
@@ -887,9 +426,13 @@ subroutine get_halodat(hl,kl,ind,part_cover,part,which,verbose,unit)
!
real(double) :: xyz_Ang(3)
character(len=20) :: filename
+ integer :: l1, acz1, m1, count, max_nsup
integer, optional :: unit
!
call start_timer(tmr_std_exx_fetch)
+ !
+ max_nsup = maxval(nsf_species)
+ !
! Get u(v) data
hl%npc = part_cover
hl%nic = ind
@@ -920,9 +463,9 @@ subroutine get_halodat(hl,kl,ind,part_cover,part,which,verbose,unit)
hl%xyz_cv(3) = BCS_parts%zcover(part_cover+ind-1)
!
! Calculate R_iu
- hl%xyz(1) = - hl%xyz_hl(1) + kl%xyz_hl(1)
- hl%xyz(2) = - hl%xyz_hl(2) + kl%xyz_hl(2)
- hl%xyz(3) = - hl%xyz_hl(3) + kl%xyz_hl(3)
+ hl%xyz(1) = - hl%xyz_cv(1) + kl%xyz_hl(1)
+ hl%xyz(2) = - hl%xyz_cv(2) + kl%xyz_hl(2)
+ hl%xyz(3) = - hl%xyz_cv(3) + kl%xyz_hl(3)
hl%r = sqrt(dot_product(hl%xyz,hl%xyz))
!
! Calculate D_iu
@@ -937,11 +480,17 @@ subroutine get_halodat(hl,kl,ind,part_cover,part,which,verbose,unit)
write(unit,'(I8,6X,A9,2X,A,I8,A2,I3,A,6X,A2,1X,I8,1X,4F12.4,3X,I3,2I8,1X,F7.3)') &
part,'{k\gamma}','{',hl%global_num,'\ ',hl%nsup,'}', hl%name, hl%global_num, &
xyz_Ang(1), xyz_Ang(2), xyz_Ang(3), zero, hl%spec, ind, hl%nsup, hl%radi
- else
+ else if (which == 'l') then
write(unit,'(I8,6X,A9,2X,A,I8,A2,I3,A,6X,A2,1X,I8,1X,4F12.4,3X,I3,2I8,1X,F7.3)') &
part,'{l\delta}','{',hl%global_num,'\ ',hl%nsup,'}', hl%name, hl%global_num, &
xyz_Ang(1), xyz_Ang(2), xyz_Ang(3), zero, hl%spec, ind, hl%nsup, hl%radi
+ else if (which == 'j') then
+ write(unit,'(I8,6X,A9,2X,A,I8,A2,I3,A,6X,A2,1X,I8,1X,4F12.4,3X,I3,2I8,1X,F7.3)') &
+ part,'{j\beta}','{',hl%global_num,'\ ',hl%nsup,'}', hl%name, hl%global_num, &
+ xyz_Ang(1), xyz_Ang(2), xyz_Ang(3), zero, hl%spec, ind, hl%nsup, hl%radi
end if
+
+
end if
call stop_timer(tmr_std_exx_fetch,.true.)
@@ -1023,35 +572,290 @@ subroutine get_iprimdat(ia,hl,ind,iprim,part,verbose,unit)
return
end subroutine get_iprimdat
-
-!!$ subroutine get_ghostdat(hl)
+ !!
+ !!***
+!!$ subroutine initialise_exx( scheme )
+!!$ !
+!!$ use timer_stdclocks_module, only: tmr_std_exx
+!!$ use global_module, only: iprint_exx
+!!$ use timer_module, only: start_timer, stop_timer
+!!$ use species_module,only: nsf_species
+!!$ use mult_module, only: S_X_SX, mult
!!$
-!!$ use units, only: BohrToAng
-!!$ use numbers, only: very_small, zero, three
-!!$ use primary_module, only: bundle
-!!$ use species_module, only: species_label,nsf_species
-!!$ use atomic_density, only: atomic_density_table
-!!$ use support_spec_format, only: blips_on_atom, flag_one_to_one
+!!$ use exx_types, only: extent, exx_psolver, exx_pscheme, r_int, eris
+!!$ use exx_types, only: ewald_alpha, ewald_charge, ewald_rho, ewald_pot
+!!$ use exx_types, only: p_omega, p_ngauss, p_gauss, w_gauss, pulay_radius
+!!$ use exx_poisson, only: exx_scal_rho_3d, exx_ewald_rho, exx_ewald_pot
+!!$
+!!$ use exx_types, only: tmr_std_exx_setup, unit_eri_debug, unit_exx_debug
+!!$ use exx_types, only: unit_memory_write, unit_timers_write
+!!$ use exx_memory, only: exx_mem_alloc
+!!$
+!!$ integer, intent(in) :: scheme
+!!$
+!!$ character(len=20) :: filename1, filename2, filename3, filename4, filename5, filename6
+!!$ integer :: maxsuppfuncs, stat
+!!$
+!!$ maxsuppfuncs = maxval(nsf_species)
!!$ !
-!!$ use matrix_data, only: mat, Hrange, Srange
-!!$ use exx_types, only: prim_atomic_data, neigh_atomic_data
-!!$ use exx_types, only: tmr_std_exx_fetch
-!!$ use group_module,only: parts
-!!$ use GenComms, only: inode
+!!$ call start_timer(tmr_std_exx)
!!$ !
-!!$ implicit none
+!!$ call start_timer(tmr_std_exx_setup)
!!$ !
-!!$ type(neigh_atomic_data),intent(inout) :: hl
+!!$ if ( iprint_exx > 3 ) then
+!!$
+!!$ call io_assign(unit_timers_write)
+!!$ call get_file_name('exx_timers',numprocs,inode,filename3)
+!!$ open(unit_timers_write,file=filename3)
+!!$ !
+!!$ !
+!!$ call io_assign(unit_memory_write)
+!!$ call get_file_name('exx_memory',numprocs,inode,filename4)
+!!$ open(unit_memory_write,file=filename4)
+!!$
+!!$ end if
+!!$
+!!$ if ( exx_debug ) then
+!!$
+!!$ call io_assign(unit_exx_debug)
+!!$ call get_file_name('exx_debug',numprocs,inode,filename5)
+!!$ open(unit_exx_debug,file=filename5)
+!!$
+!!$ call io_assign(unit_eri_debug)
+!!$ call get_file_name('eri_debug',numprocs,inode,filename6)
+!!$ open(unit_eri_debug,file=filename6)
+!!$
+!!$ !call exx_write_head(unit_exx_debug,inode,bundle%groups_on_node)
+!!$ !
+!!$ !call exx_global_write()
+!!$ !
+!!$ end if
!!$ !
-!!$ !call start_timer(tmr_std_exx_fetch)
-!!$ ! Get u(v) data
-!!$ hl%xyz_hl(1) = 0_double
-!!$ hl%xyz_hl(2) = 0_double
-!!$ hl%xyz_hl(3) = 0_double
-!!$ !call stop_timer(tmr_std_exx_fetch,.true.)
+!!$ maxsuppfuncs = maxval(nsf_species)
!!$ !
-!!$ return
-!!$ end subroutine get_ghostdat
-
- !!***
-end module exx_module
+!!$ if ( scheme > 0 ) then
+!!$ call exx_mem_alloc(extent,0,0,'work_3d' ,'alloc')
+!!$ end if
+!!$ !
+!!$ !DRB! This appears to set up the different Poisson solvers
+!!$ if (exx_psolver == 'fftw') then
+!!$ call exx_mem_alloc(extent,0,0,'fftw_3d','alloc')
+!!$ call exx_mem_alloc(extent,0,0,'reckernel_3d','alloc')
+!!$
+!!$ poisson_fftw: select case(exx_pscheme)
+!!$
+!!$ case('default')
+!!$ call exx_scal_rho_3d(inode,extent,r_int,exx_pscheme,pulay_radius, &
+!!$ p_omega,p_ngauss,p_gauss,w_gauss,reckernel_3d)
+!!$
+!!$ case('ewald')
+!!$ call exx_mem_alloc(extent,0,0,'ewald_3d','alloc')
+!!$ call exx_ewald_rho(ewald_rho,extent,ewald_alpha,r_int)
+!!$ call exx_ewald_pot(ewald_pot,extent,ewald_alpha,r_int)
+!!$ call exx_scal_rho_3d(inode,extent,r_int,exx_pscheme,pulay_radius, &
+!!$ p_omega,p_ngauss,p_gauss,w_gauss,reckernel_3d)
+!!$
+!!$ case('pulay')
+!!$ call exx_scal_rho_3d(inode,extent,r_int,exx_pscheme,pulay_radius, &
+!!$ p_omega,p_ngauss,p_gauss,w_gauss,reckernel_3d)
+!!$
+!!$ case('yukawa')
+!!$ call exx_scal_rho_3d(inode,extent,r_int,exx_pscheme,pulay_radius, &
+!!$ p_omega,p_ngauss,p_gauss,w_gauss,reckernel_3d)
+!!$
+!!$ case('gauss')
+!!$ call cq_abort('EXX: Gaussian representation if 1/r for solving &
+!!$ &the Poisson equation &
+!!$ &is currently under testing...')
+!!$ !call createBeylkin(p_gauss,w_gauss,r_int)
+!!$ !call exx_scal_rho_3d(inode,extent,r_int,exx_pscheme,pulay_radius, &
+!!$ ! p_omega,p_ngauss,p_gauss,w_gauss)
+!!$
+!!$ case default
+!!$ call exx_scal_rho_3d(inode,extent,r_int,exx_pscheme,pulay_radius, &
+!!$ p_omega,p_ngauss,p_gauss,w_gauss,reckernel_3d)
+!!$
+!!$ end select poisson_fftw
+!!$
+!!$ else if (exx_psolver == 'isf') then
+!!$ call cq_abort('EXX: ISF Poisson solver is not available yet ; &
+!!$ &under optimisation...')
+!!$ !call exx_mem_alloc(extent,0,0,'isf_rho','alloc')
+!!$ !call createKernel('F',ngrid,ngrid,ngrid,grid_spacing,grid_spacing,grid_spacing,isf_order,&
+!!$ ! 0,1,kernel)
+!!$
+!!$ end if
+!!$ call stop_timer(tmr_std_exx_setup,.true.)
+!!$
+!!$ if ( scheme > 0 ) then
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_i','alloc')
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_j','alloc')
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_k','alloc')
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_l','alloc')
+!!$ !
+!!$ if ( scheme == 1 ) then
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,0,'Phy_k','alloc')
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'Ome_kj','alloc')
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'rho_kj','alloc')
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'vhf_kj','alloc')
+!!$ !
+!!$ else if ( scheme == 2 ) then
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'rho_ki','alloc')
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'vhf_lj','alloc')
+!!$ !
+!!$ else if ( scheme == 3 ) then
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'rho_ki','alloc')
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'vhf_lj','alloc')
+!!$ !
+!!$ !if ( niter == 1 ) then
+!!$ allocate( eris( mult(S_X_SX)%ahalo%np_in_halo ), STAT=stat)
+!!$ if(stat/=0) call cq_abort('Error allocating memory to eris/exx !',stat)
+!!$ !end if
+!!$ !for now allocated here ; should not ; better to have this before
+!!$ ! SCF calculation ; note that here it is never deallocated!
+!!$ !eris_size = int( sqrt(dble(size( mat_p(matX( exxspin ))%matrix ))) )
+!!$ !print*, 'inode', inode, inode, size( mat_p(matX( exxspin ))%matrix), eris_size, &
+!!$ ! & mat_p(matX( exxspin ))%length, mat_p(matX( exxspin ))%sf1_type, mat_p(matX( exxspin ))%sf2_type
+!!$ !call exx_mem_alloc(eris_size**4,0,0,'eris','alloc')
+!!$ !
+!!$ !
+!!$ end if
+!!$ !
+!!$ !
+!!$ end if
+!!$
+!!$ end subroutine initialise_exx
+!!$ !
+!!$ !
+!!$ subroutine finalise_exx( scheme )
+!!$ !
+!!$ use global_module, only: iprint_exx, area_exx
+!!$ use timer_stdclocks_module, only: tmr_std_exx
+!!$ use timer_module, only: start_timer, stop_timer, print_timer
+!!$ use species_module,only: nsf_species
+!!$ use memory_module, only: write_mem_use
+!!$
+!!$ use exx_types, only: extent, exx_psolver ,kernel, exx_pscheme
+!!$ use exx_types, only: tmr_std_exx_setup, unit_eri_debug, unit_exx_debug
+!!$ use exx_types, only: tmr_std_exx_evalpao, tmr_std_exx_poisson, tmr_std_exx_matmult
+!!$ use exx_types, only: tmr_std_exx_accumul, tmr_std_exx_allocat, tmr_std_exx_dealloc
+!!$ use exx_types, only: tmr_std_exx_fetch, tmr_std_exx_barrier, tmr_std_exx_kernel
+!!$ use exx_types, only: tmr_std_exx_kernel
+!!$ use exx_types, only: exx_total_time
+!!$
+!!$ use exx_types, only: unit_memory_write, unit_eri_debug, unit_exx_debug, unit_timers_write
+!!$ use exx_memory, only: exx_mem_alloc
+!!$ !
+!!$ integer, intent(in) :: scheme
+!!$ integer :: maxsuppfuncs
+!!$
+!!$ maxsuppfuncs = maxval(nsf_species)
+!!$
+!!$ if ( scheme > 0 ) then
+!!$ call exx_mem_alloc(extent,0,0,'work_3d' ,'dealloc')
+!!$ !
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_i','dealloc')
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_j','dealloc')
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_k','dealloc')
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,0,'phi_l','dealloc')
+!!$ !
+!!$ if ( scheme == 1 ) then
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,0,'Phy_k','dealloc')
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'Ome_kj','dealloc')
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'rho_kj','dealloc')
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'vhf_kj','dealloc')
+!!$ !
+!!$ else if( scheme == 2 ) then
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'rho_ki','dealloc')
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'vhf_lj','dealloc')
+!!$ !
+!!$ else if( scheme == 3 ) then
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'rho_ki','dealloc')
+!!$ call exx_mem_alloc(extent,maxsuppfuncs,maxsuppfuncs,'vhf_lj','dealloc')
+!!$ !
+!!$ end if
+!!$ !
+!!$ end if
+!!$ !
+!!$ !
+!!$ if (exx_psolver == 'fftw') then
+!!$ call exx_mem_alloc(extent,0,0,'fftw_3d', 'dealloc')
+!!$ call exx_mem_alloc(extent,0,0,'reckernel_3d','dealloc')
+!!$ select case(exx_pscheme)
+!!$ case('default')
+!!$ case('gauss')
+!!$ case('pulay')
+!!$ case('ewald')
+!!$ call exx_mem_alloc(extent,0,0,'ewald_3d','dealloc')
+!!$ case default
+!!$ end select
+!!$
+!!$ else if (exx_psolver == 'isf') then
+!!$ call exx_mem_alloc(extent,0,0,'isf_rho','dealloc')
+!!$ deallocate(kernel)
+!!$ end if
+!!$ !
+!!$ if (inode == ionode) call write_mem_use(unit_memory_write,area_exx)
+!!$ !
+!!$ call start_timer(tmr_std_exx_barrier)
+!!$ call my_barrier()
+!!$ call stop_timer(tmr_std_exx_barrier,.true.)
+!!$ !
+!!$ call stop_timer(tmr_std_exx,.true.)
+!!$ !
+!!$ ! Timers and elapse time
+!!$ exx_total_time = &
+!!$ tmr_std_exx_evalpao%t_tot + &
+!!$ tmr_std_exx_poisson%t_tot + &
+!!$ tmr_std_exx_matmult%t_tot + &
+!!$ tmr_std_exx_accumul%t_tot + &
+!!$ tmr_std_exx_allocat%t_tot + &
+!!$ tmr_std_exx_dealloc%t_tot + &
+!!$ tmr_std_exx_setup%t_tot + &
+!!$ tmr_std_exx_write%t_tot + &
+!!$ tmr_std_exx_fetch%t_tot + &
+!!$ tmr_std_exx_barrier%t_tot
+!!$
+!!$ if ( iprint_exx > 3 ) then
+!!$
+!!$ call print_timer(tmr_std_exx_setup, "exx_setup time:", unit_timers_write)
+!!$ call print_timer(tmr_std_exx_write, "exx_write time:", unit_timers_write)
+!!$ !call print_timer(tmr_std_exx_kernel, "exx_kernel time:", unit_timers_write)
+!!$ call print_timer(tmr_std_exx_fetch, "exx_fetch time:", unit_timers_write)
+!!$ call print_timer(tmr_std_exx_evalpao,"exx_evalpao time:", unit_timers_write)
+!!$ call print_timer(tmr_std_exx_poisson,"exx_poisson time:", unit_timers_write)
+!!$ call print_timer(tmr_std_exx_matmult,"exx_matmult time:", unit_timers_write)
+!!$ call print_timer(tmr_std_exx_accumul,"exx_accumul time:", unit_timers_write)
+!!$ call print_timer(tmr_std_exx_allocat,"exx_allocat time:", unit_timers_write)
+!!$ call print_timer(tmr_std_exx_dealloc,"exx_dealloc time:", unit_timers_write)
+!!$ call print_timer(tmr_std_exx_barrier,"exx_barrier time:", unit_timers_write)
+!!$ write(unit_timers_write,*)
+!!$ call print_timer(tmr_std_exx_kernel, "exx_kernel time:", unit_timers_write)
+!!$ call print_timer(tmr_std_exx, "exx_total time:", unit_timers_write)
+!!$
+!!$ write(unit=unit_timers_write,fmt='("Timing: Proc ",i6,": Time spent in ", a50, " = ", &
+!!$ &f12.5," s")') inode, 'get_X_matrix', tmr_std_exx%t_tot
+!!$
+!!$ write(unit=unit_timers_write,fmt='("Timing: Proc ",i6,": Time spent in ", a50, " = ", &
+!!$ &f12.5," s")') inode, 'timer calls', tmr_std_exx%t_tot-exx_total_time
+!!$ !call io_close(unit_matrix_write)
+!!$
+!!$ !call io_close(unit_output_write)
+!!$ !call io_close(unit_screen_write)
+!!$ !
+!!$ !call io_close(unit_eri_debug)
+!!$ !call io_close(unit_exx_debug)
+!!$ call io_close(unit_memory_write)
+!!$ call io_close(unit_timers_write)
+!!$ !
+!!$ !
+!!$ end if
+!!$
+!!$ if ( exx_debug ) then
+!!$ call io_close(unit_eri_debug)
+!!$ call io_close(unit_exx_debug)
+!!$ end if
+!!$
+!!$ end subroutine finalise_exx
+ !
+ end module exx_module
diff --git a/src/exx_poisson.f90 b/src/exx_poisson.f90
new file mode 100644
index 000000000..47344b0f0
--- /dev/null
+++ b/src/exx_poisson.f90
@@ -0,0 +1,416 @@
+module exx_poisson
+
+ use GenComms, only: cq_abort
+ use datatypes, only: double, double_cplx
+ !use exx_types, only: fftwrho3d, exx_debug
+ use fft_interface_module,only: fft3_exec_wrapper, fft3_init_wrapper
+
+contains
+ !
+ !
+ subroutine exx_scal_rho_3d(inode,extent,r_int,scheme,cutoff,omega,n_gauss, &
+ p_gauss,w_gauss,reckernel)
+
+ use datatypes
+ use numbers, ONLY: twopi, pi, sqrt_pi, very_small
+ use numbers, ONLY: zero, one, two, four, three_halves
+
+ implicit none
+
+ ! << Passed variables >>
+ character(*), intent(in) :: scheme
+ integer, intent(in) :: extent
+ integer, intent(in) :: inode
+ real(double), intent(in) :: r_int
+
+ real(double), intent(in) :: cutoff
+ real(double), intent(in) :: omega
+
+ integer, intent(in) :: n_gauss
+ real(double), optional, intent(in) :: p_gauss(n_gauss)
+ real(double), optional, intent(in) :: w_gauss(n_gauss)
+
+ complex(double), dimension(2*extent+1,2*extent+1,2*extent+1), intent(out) :: reckernel
+
+
+ ! << Local variables >>
+ real(double),dimension(3) :: G
+ real(double) :: charge_G
+
+ real(double), parameter :: magic_number = 0.1864d0 ! 32/43 = nombre magic !
+
+ real(double) :: r_G, r_A, v_G, v_R, sphere, fftwnorm, tmp, alpha
+ real(double) :: rho_zero, Gkernel, Gkernel_zero, arg, factor, delta
+ real(double) :: max_, min_
+
+ integer :: gauss
+ integer :: nx, ny, nz, ngrid
+ integer :: x, y, z
+ integer :: i, j, k
+
+ ngrid = 2*extent+1
+ fftwnorm = sqrt(real(ngrid**3,double))
+
+ r_A = real(2,double)*r_int
+ r_G = zero
+ G = zero
+
+ v_G = (twopi**3)*real(1,double)/(real(2,double)*r_int)**3
+ v_R = (real(2,double)*r_int)**3
+ sphere = ((twopi*real(1,double)/(real(2,double)*r_int))**3)*(1.0d0/6.0d0*pi)
+
+ reckernel = zero
+
+ poisson_scheme: select case(scheme)
+ case('default')
+ delta = zero
+ case('ewald')
+ delta = zero
+ case('pulay')
+ delta = zero
+ case('yukawa')
+ delta = omega
+ case('gauss')
+ delta = zero
+ case default
+ delta = zero
+ end select poisson_scheme
+
+ grid_x_loop: do nx = -extent, extent
+ x = nx + extent + 1
+ if (nx <= 0) then
+ G(1) = twopi*( real(nx+extent+delta,double))/r_A
+ else
+ G(1) = twopi*(-real(extent-nx+(one-delta),double))/r_A
+ end if
+
+ grid_y_loop: do ny = -extent, extent
+ y = ny + extent + 1
+ if (ny <= 0) then
+ G(2) = twopi*( real(ny+extent+delta,double))/r_A
+ else
+ G(2) = twopi*(-real(extent-ny+(one-delta),double))/r_A
+ end if
+
+ grid_z_loop: do nz = -extent, extent
+ z = nz + extent + 1
+ if (nz <= 0) then
+ G(3) = twopi*( real(nz+extent+delta,double))/r_A
+ else
+ G(3) = twopi*(-real(extent-nz+(one-delta),double))/r_A
+ end if
+
+ r_G = sqrt(dot_product(G,G))
+
+ !if (scheme == 'yukawa') then
+ ! if (r_G > 0.1d0) then
+ ! delta = zero
+ ! end if
+ !end if
+
+ if (r_G == zero) then
+
+ !write(*,*) x, y, z
+ poisson_zero: select case(scheme)
+ case('default')
+ reckernel(x,y,z) = cmplx(0,0,double_cplx)
+ case('ewald')
+ reckernel(x,y,z) = cmplx(0,0,double_cplx)
+ case('pulay')
+ reckernel(x,y,z) = cmplx(cutoff**2/two,0,double_cplx)
+ case('yukawa')
+ reckernel(x,y,z) = cmplx(0,0,double_cplx)
+ case('gauss')
+ Gkernel_zero = zero
+ do gauss = 1, n_gauss
+ Gkernel_zero = Gkernel_zero + &
+ w_gauss(gauss)*sqrt_pi/(four*p_gauss(gauss)**three_halves)
+ end do
+ reckernel(x,y,z) = cmplx(Gkernel_zero,double_cplx)
+ case default
+ reckernel(x,y,z) = cmplx(zero,zero,double_cplx)
+ end select poisson_zero
+ else
+ poisson_xyz: select case(scheme)
+ case('default')
+ reckernel(x,y,z) = cmplx(one/r_G**2,zero,double_cplx)
+ case('ewald')
+ reckernel(x,y,z) = cmplx(one/r_G**2,zero,double_cplx)
+ case('pulay')
+ reckernel(x,y,z) = (one - cos(r_G*cutoff))/r_G**2
+ case('yukawa')
+ reckernel(x,y,z) = cmplx(one/r_G**2,zero,double_cplx)
+ case('gauss')
+ Gkernel = zero
+ arg = zero
+ factor = zero
+
+ do gauss = 1, n_gauss
+ factor = w_gauss(gauss)*sqrt(pi)/(four*p_gauss(gauss)**three_halves)
+ arg = -(r_G/(two*sqrt(p_gauss(gauss))))**two
+ Gkernel = Gkernel + factor*exp(arg)
+ max_ = max(max_,arg)
+ min_ = min(min_,arg)
+
+ end do
+ reckernel(x,y,z) = cmplx(Gkernel,zero,double_cplx)
+ case default
+ reckernel(x,y,z) = cmplx(one/r_G**2,zero,double_cplx)
+ end select poisson_xyz
+ end if
+
+ end do grid_z_loop
+ end do grid_y_loop
+ end do grid_x_loop
+
+ return
+ end subroutine exx_scal_rho_3d
+ !
+ !
+ !
+ !
+ subroutine exx_v_on_grid(inode,extent,rho,potential,r_int,poisson,scheme,&
+ alpha,omega,n_gauss,p_gauss,w_gauss,reckernel)
+
+ use numbers, ONLY: zero, one, fourpi
+ use exx_types, ONLY: fftw3d ! FFTW
+ use exx_types, ONLY: kernel, isf_rho, isf_pot_ion ! ISF
+ use exx_types, ONLY: pulay_radius, ewald_rho, ewald_pot, ewald_charge
+ use exx_types, ONLY: tmr_std_exx_poisson
+ !use Poisson_Solver, only: PSolver
+
+ implicit none
+
+ ! << Input variables >>
+ integer, intent(in) :: inode
+ integer, intent(in) :: extent
+ real(double), intent(in) :: r_int
+ character(*), intent(in) :: poisson
+
+ real(double), dimension(2*extent+1,2*extent+1,2*extent+1), &
+ intent(in) :: rho
+ complex(double), dimension(2*extent+1,2*extent+1,2*extent+1),&
+ intent(in) :: reckernel
+
+ character(*), intent(in) :: scheme
+ real(double), intent(in) :: alpha
+ real(double), intent(in) :: omega
+ integer, intent(in) :: n_gauss
+ real(double), dimension(n_gauss) :: p_gauss, w_gauss
+
+ ! << Output variables >>
+ real(double), dimension(2*extent+1,2*extent+1,2*extent+1), &
+ intent(out) :: potential
+
+ ! << Local variables >>
+ integer :: ng, i, j, k
+ real(double) :: fftwnorm, normr
+ real(double) :: grid_spacing
+ real(double) :: r(3)
+ logical, parameter :: accumulate = .true.
+
+ ! ... For Poisson/ISF real space FFT >>
+ real(kind=8) :: isf_eh, isf_exc, isf_vxc, isf_spacing
+
+ ! This is required to keep this function thread safe. Previously fftwrho%arrayin would have been altered by each thread
+ complex(double), dimension(2*extent+1,2*extent+1,2*extent+1) :: fftwrho_arrayin
+
+ ! ... Dummy variables >>
+ real(double), dimension(:,:,:), allocatable :: dum_pot_ion, dum_rho
+
+ ng = 2*extent+1
+ fftwnorm = sqrt(real(ng**3,double))
+ grid_spacing = r_int/real(extent,double)
+
+ !call start_timer(tmr_std_exx_poisson)
+
+ potential = zero
+
+ select case(poisson)
+
+ case('fftw')
+
+ ! setup[rho(r)]
+ fftwrho_arrayin = cmplx(rho,zero,double_cplx)
+
+ ! FFT_F[rho(r)] => rho(G)
+ call fft3_exec_wrapper( fftwrho_arrayin, ng , +1 )
+
+ ! scale[rho_(G)] = 4pi*rho(G)/|G|^2
+ fftwrho_arrayin = fourpi*fftwrho_arrayin*reckernel
+
+ ! FFT_B[4pi*rho(G)/|G|^2] = V(r')
+ call fft3_exec_wrapper( fftwrho_arrayin, ng , -1 )
+
+ ! Normalization
+ potential = real(fftwrho_arrayin) / fftwnorm**2
+
+ case('isf')
+ !
+ call cq_abort('EXX with ISF Poisson solver disabled')
+ !
+ !isf_rho = rho
+ !isf_pot_ion = zero
+ !
+ !call PSolver('F','G',0,1,ng,ng,ng,0,grid_spacing,grid_spacing,grid_spacing, &
+ ! isf_rho,kernel,isf_pot_ion,isf_eh,isf_exc,isf_vxc,zero,.false.,1)
+ !potential = isf_rho
+ !
+ end select
+
+ !call stop_timer(tmr_std_exx_poisson,accumulate)
+
+ return
+ end subroutine exx_v_on_grid
+ !
+ subroutine exx_ewald_charge(rho,extent,dv,charge)
+
+ use numbers, ONLY: zero
+
+ implicit none
+
+ integer :: extent
+ real(double), dimension(2*extent+1,2*extent+1,2*extent+1), &
+ intent(in) :: rho
+ real(double), intent(in) :: dv
+ real(double), intent(out) :: charge
+ integer :: i, j, k
+
+ charge = zero
+
+ do i = 1, 2*extent+1
+ do j = 1, 2*extent+1
+ do k = 1, 2*extent+1
+ charge = charge + rho(k,j,i)*dv
+ end do
+ end do
+ end do
+
+ return
+ end subroutine exx_ewald_charge
+
+ subroutine exx_ewald_rho(gauss,extent,alpha,r_int)
+
+ use numbers, ONLY: zero, one, two, three_halves
+ use numbers, ONLY: twopi, pi, three_halves
+
+ implicit none
+
+ integer, intent(in) :: extent
+ real(double), intent(inout) :: alpha
+ real(double), intent(in) :: r_int
+ real(double), dimension(2*extent+1,2*extent+1,2*extent+1), &
+ intent(inout) :: gauss
+
+ real(double) :: gnorm, dv, factor
+ real(double) :: grid_spacing
+ real(double) :: r(3)
+
+ integer :: i, j, k
+
+ grid_spacing = r_int/real(extent,double)
+ factor = (alpha/pi)**three_halves
+ !factor = one
+ dv = grid_spacing**3
+
+ gauss = zero
+ gnorm = zero
+ do i = -extent, extent
+ r(1) = real(i,double)*grid_spacing
+ do j = -extent, extent
+ r(2) = real(j,double)*grid_spacing
+ do k = -extent, extent
+ r(3) = real(k,double)*grid_spacing
+
+ gauss(extent+k+1,extent+i+1,extent+j+1) = &
+ exp(-dot_product(r,r)*alpha)
+ gnorm = &
+ gnorm + gauss(extent+k+1,extent+j+1,extent+i+1)*dv
+
+ end do
+ end do
+ end do
+
+ gauss = gauss*factor
+ gnorm = gnorm*factor
+
+ return
+ end subroutine exx_ewald_rho
+
+ subroutine exx_ewald_pot(potential,extent,alpha,r_int)
+
+ use numbers, ONLY: zero, one, two, twopi, pi
+ use functions, ONLY: erfc_cq
+
+ implicit none
+
+ integer, intent(in) :: extent
+ real(double), intent(inout) :: alpha
+ real(double), intent(in) :: r_int
+ real(double), dimension(2*extent+1,2*extent+1,2*extent+1), &
+ intent(inout) :: potential
+
+ real(double) :: arg, factor, dv
+ real(double) :: grid_spacing, r(3)
+
+ integer :: i, j, k
+
+ grid_spacing = r_int/real(extent,double)
+ dv = grid_spacing**3
+
+ potential = zero
+ do i = -extent, extent
+ r(1) = real(i,double)*grid_spacing
+ do j = -extent, extent
+ r(2) = real(j,double)*grid_spacing
+ do k = -extent, extent
+ r(3) = real(k,double)*grid_spacing
+
+ if (i == 0 .and. j == 0 .and. k==0) then
+ potential(extent+k+1,extent+j+1,extent+i+1) = two*sqrt(alpha/pi)
+ else
+ arg = sqrt(dot_product(r,r))*sqrt(alpha)
+ factor = one/sqrt(dot_product(r,r))
+ potential(extent+k+1,extent+j+1,extent+i+1) = (one - erfc_cq(arg))*factor
+ end if
+
+ end do
+ end do
+ end do
+
+ return
+ end subroutine exx_ewald_pot
+
+!!$ For ISF real-space Poisson solver
+!!$
+!!$subroutine createBeylkin(p_gauss,w_gauss,r_int)
+!!$
+!!$ use numbers, ONLY: zero, one, two, twopi, pi
+!!$
+!!$ implicit none
+!!$
+!!$ ! << Passed variables >>
+!!$ real(double), intent(in) :: r_int
+!!$
+!!$ ! << Local variables >>
+!!$ integer, parameter :: n_gauss = 89
+!!$ real(double) :: ur_gauss,dr_gauss,acc_gauss
+!!$ real(double) :: norm, vol, factor1, factor2
+!!$ real(double) :: p_gauss(n_gauss)
+!!$ real(double) :: w_gauss(n_gauss)
+!!$
+!!$ p_gauss = zero
+!!$ w_gauss = zero
+!!$
+!!$ vol = (real(2,double)*r_int)**3
+!!$ norm = sqrt(vol)
+!!$
+!!$ factor1 = one/norm
+!!$ factor2 = one/vol
+!!$
+!!$ call gequad(n_gauss,p_gauss,w_gauss,ur_gauss,dr_gauss,acc_gauss)
+!!$
+!!$ return
+!!$ end subroutine createBeylkin
+
+end module exx_poisson
diff --git a/src/exx_types.f90 b/src/exx_types.f90
index 6cd668bfe..2b59e57b4 100644
--- a/src/exx_types.f90
+++ b/src/exx_types.f90
@@ -55,16 +55,15 @@ module exx_types
! end type fftw1d
! PAOs on grid
- real(double), dimension(:,:,:,:), allocatable :: phi_i
- real(double), dimension(:,:,:,:), allocatable :: phi_j
- real(double), dimension(:,:,:,:), allocatable :: phi_k
- real(double), dimension(:,:,:,:), allocatable :: phi_l
+ real(double), dimension(:,:,:,:), allocatable :: phi_i
+ real(double), dimension(:), allocatable, target :: phi_i_1d_buffer
+ real(double), dimension(:,:,:,:), allocatable :: phi_j
+ real(double), dimension(:,:,:,:), allocatable :: phi_k
+ real(double), dimension(:,:,:,:), allocatable :: phi_l
! Auxiliary densities and potentials
- real(double), dimension(:,:,:,:,:), allocatable :: rho_kj
- real(double), dimension(:,:,:,:,:), allocatable :: Ome_kj
- real(double), dimension(:,:,:,:,:), allocatable :: vhf_kj
- real(double), dimension(:,:,:,:), allocatable :: Phy_k
+ real(double), dimension(:), allocatable, target :: Ome_kj_1d_buffer
+ real(double), dimension(:,:,:,:), allocatable :: Phy_k
! Work matrix
real(double), dimension(:,:,:), allocatable :: work_in_3d
@@ -72,8 +71,11 @@ module exx_types
! For the Poisson equation/FFTW in reciprocal space
type(fftw3d) :: fftwrho3d
+ type(fftw3d) :: fftwrho3d_filter
complex(double), dimension(:,:,:), allocatable :: reckernel_3d
+ complex(double), dimension(:,:,:), allocatable :: reckernel_3d_filter
+
real(double), dimension(:,:,:), allocatable :: ewald_rho
real(double), dimension(:,:,:), allocatable :: ewald_pot
real(double) :: ewald_charge
@@ -84,9 +86,12 @@ module exx_types
real(double), dimension(:,:,:), allocatable :: isf_pot_ion
real(double), pointer :: kernel(:)
+ ! Filter ERIs
+ real(double) :: exx_filter_thr
+
! Poisson solver settings
- character(100), parameter :: p_scheme_default = 'v(G=0)=0'
- character(100) :: p_scheme
+ character(100), parameter :: exx_pscheme_default = 'v(G=0)=0'
+ character(100) :: exx_pscheme
character(100) :: exx_psolver
real(double) :: p_cutoff
real(double) :: p_factor
@@ -104,9 +109,8 @@ module exx_types
integer :: isf_order
real(double) :: edge, volume, screen
-
- ! Grid settings
- integer :: extent
+ ! Grid settings
+ integer :: extent, exx_filter_extent
integer :: ngrid
real(double) :: r_int
real(double) :: grid_spacing
@@ -117,8 +121,8 @@ module exx_types
type(cq_timer), save :: tmr_std_exx_write
type(cq_timer), save :: tmr_std_exx_kernel
type(cq_timer), save :: tmr_std_exx_fetch
- type(cq_timer), save :: tmr_std_exx_fetch_K
type(cq_timer), save :: tmr_std_exx_accumul
+ type(cq_timer), save :: tmr_std_exx_nsup
type(cq_timer), save :: tmr_std_exx_matmult
type(cq_timer), save :: tmr_std_exx_quadrat
@@ -129,37 +133,57 @@ module exx_types
type(cq_timer), save :: tmr_std_exx_evalpao
type(cq_timer), save :: tmr_std_exx_evalgto
type(cq_timer), save :: tmr_std_exx_splitpao
+ type(cq_timer), save :: tmr_std_exx_barrier
+ type(cq_timer), save :: tmr_std_exx_comms
+
real(double) :: exx_total_time
+
+
+ real(double) :: sum_eri_gto
! User settings
integer :: exx_scheme ! 4center ERIs or 3center reduction integrals
integer :: exx_mem ! reduced memory allocation
- logical :: exx_phil ! on-the-fly or storage of phi_l
- logical :: exx_phik ! on-the-fly or storage of phi_k
logical :: exx_overlap ! compute overlap local boxes
logical :: exx_alloc ! on-the-fly or global memory allocation
- logical :: exx_cartesian ! cartesian or spherial representation for PAO
+ logical :: exx_cartesian ! cartesian or spherical calculation for PAO on grid
logical :: exx_screen ! screening
logical :: exx_screen_pao ! method for screening
logical :: exx_gto ! testing
- real(double) :: exx_cutoff ! cutoff for screening (experimental)
+ logical :: exx_gto_poisson ! testing
+
+ logical :: exx_filter
+ logical :: exx_store_eris ! store ERIs at first exx call
+ !real(double) :: exx_cutoff ! cutoff for screening (experimental)
real(double) :: exx_radius ! radius for integration
- real(double) :: exx_hgrid ! radius for integration
+ real(double) :: exx_hgrid ! grid spacing for integration
+ character(len=20) :: exx_grid ! grid spacing selection
! For debuging/testing
logical :: exx_debug
- logical :: exx_Kij
- logical :: exx_Kkl
! I/O
integer :: unit_global_write
integer :: unit_matrix_write
- integer :: unit_output_write
integer :: unit_timers_write
integer :: unit_memory_write
- integer :: unit_screen_write
+ integer :: unit_screen_write
+ integer :: unit_exx_debug
+ integer :: unit_eri_debug
+ integer :: unit_eri_filter_debug
+ character(len=20) :: file_exx_debug, file_exx_memory, file_exx_timers
+ character(len=20) :: file_eri_debug, file_eri_filter_debug
!=================================================================<<
+ type store_eris
+ integer :: part
+ real(double), dimension(:), allocatable :: store_eris
+ logical, dimension(:), allocatable :: filter_eris
+ end type store_eris
+
+ ! Electron repulsion integrals
+ type(store_eris), dimension(:), allocatable, target :: eris
+
type prim_atomic_data
integer :: pr
@@ -200,6 +224,11 @@ module exx_types
real(double), dimension(3) :: xyz
real(double) :: r
real(double) :: d
+ !
+ integer, dimension(:), allocatable :: l1
+ integer, dimension(:), allocatable :: acz1
+ integer, dimension(:), allocatable :: m1
+
end type neigh_atomic_data
end module exx_types
diff --git a/src/force_module.f90 b/src/force_module.f90
index db60122d9..1a0534099 100644
--- a/src/force_module.f90
+++ b/src/force_module.f90
@@ -239,7 +239,7 @@ subroutine force(fixed_potential, vary_mu, n_cg_L_iterations, &
screened_ion_force, screened_ion_stress
use pseudopotential_data, only: non_local
use GenComms, only: my_barrier, inode, ionode, &
- cq_abort, gsum
+ cq_abort, gsum, cq_warn
! TM new pseudo
use pseudopotential_common, only: pseudo_type, OLDPS, SIESTA, &
STATE, ABINIT, core_correction, flag_neutral_atom_projector
@@ -276,7 +276,7 @@ subroutine force(fixed_potential, vary_mu, n_cg_L_iterations, &
use io_module, only: atom_output_threshold, return_prefix
use input_module, only: leqi, io_close
use io_module, only: atom_output_threshold, return_prefix
-
+ use XC, only: flag_functional_type
implicit none
! Passed variables
@@ -524,6 +524,12 @@ subroutine force(fixed_potential, vary_mu, n_cg_L_iterations, &
max_compt = 0
! print in Conquest output
+ if (inode == ionode .and. write_forces .and. (iprint_MD + min_layer>=0 .and. ni_in_cell=0 .and. ni_in_cell4) write(io_lun,fmt='(10x,"Proc: ",i4," done pseudo")') inode
-
+ !
+ call my_barrier()
+ !
+ ! If EXX with GTO open and read species' GTO files
+ if ( flag_exx .and. (exx_gto .or. exx_gto_poisson) ) then
+ !
+ allocate(gto_file(n_species),STAT=stat)
+ if(stat /= 0) call cq_abort("Error allocating gto_file in read_and_write: ",n_species,stat)
+ allocate(gto(n_species),STAT=stat)
+ if(stat /= 0) call cq_abort ("Error allocating gto in read_and_write",stat)
+ !
+ call read_gto_new(inode,ionode,n_species)
+ !call read_gto(inode,ionode,n_species)
+ !
+ end if
+ !
! Initialise group data for partitions and read in partitions and atoms
call my_barrier()
+ !
def = ' '
atom_coord_file = fdf_string(80,'IO.Coordinates',def)
if(leqi(def,atom_coord_file)) call cq_abort("No coordinate file specified: please set with IO.Coordinates")
@@ -532,7 +560,7 @@ subroutine read_and_write(start, start_L, inode, ionode, &
! Set up various lengths, volumes, reciprocals etc. for convenient use
call set_dimensions(inode, ionode,HNL_fac, non_local, n_species, &
non_local_species, core_radius)
-
+ !
! write out some information on the run
if (inode == ionode) &
call write_info(titles, mu, vary_mu, HNL_fac, numprocs)
@@ -769,10 +797,16 @@ end subroutine read_and_write
!! Keywords for equilibration
!! 2020/01/07 tsuyoshi
!! Default setting of MakeInitialChargeFromK has been changed
+ !! 2020/12/14 lionel
+ !! EXX: added filtering option for EXX and cleaning
+ !! 2020/01/14 lionel
+ !! EXX: added GTO option
!! 2022/10/28 15:56 lionel
!! Added ASE output file setup ; default is F
!! 2022/12/14 10:01 dave and tsuyoshi
!! Update test for solution method (diagon vs ordern) following issue #47
+ !! 2024/12/03 lionel
+ !! Added grid specification of EXX coarse/standard/fine
!! TODO
!! SOURCE
!!
@@ -825,7 +859,7 @@ subroutine read_input(start, start_L, titles, vary_mu,&
flag_LmatrixReuse,flag_TmatrixReuse,flag_SkipEarlyDM,McWFreq, &
restart_T,restart_X,flag_XLBOMD,flag_propagateX, &
flag_propagateL,flag_dissipation,integratorXL, flag_FixCOM, &
- flag_exx, exx_alpha, exx_scf, exx_scf_tol, exx_siter, &
+ flag_exx, exx_alpha, exx_scf, exx_scf_tol, exx_siter, exx_cutoff, &
flag_out_wf,max_wf,out_wf,wf_self_con, flag_fire_qMD, &
flag_write_DOS, flag_write_projected_DOS, &
E_wf_min, E_wf_max, flag_wf_range_Ef, &
@@ -841,7 +875,7 @@ subroutine read_input(start, start_L, titles, vary_mu,&
RadiusSupport, RadiusAtomf, RadiusMS, RadiusLD, &
NonLocalFactor, InvSRange, &
min_blip_sp, flag_buffer_old, AtomMove_buffer, &
- r_dft_d2, r_exx
+ r_dft_d2, r_exx, r_exxs
use block_module, only: in_block_x, in_block_y, in_block_z, &
blocks_raster, blocks_hilbert
use species_module, only: species_label, charge, mass, n_species, &
@@ -912,10 +946,11 @@ subroutine read_input(start, start_L, titles, vary_mu,&
use constraint_module, only: flag_RigidBonds,constraints,SHAKE_tol, &
RATTLE_tol,maxiterSHAKE,maxiterRATTLE, &
const_range,n_bond
- use exx_types, only: exx_scheme, exx_mem, exx_overlap, exx_alloc, &
- exx_cartesian, exx_radius, exx_hgrid, exx_psolver, &
- exx_debug, exx_Kij, exx_Kkl, p_scheme
- use multisiteSF_module, only: flag_MSSF_smear, MSSF_Smear_Type, &
+ use exx_types, only: exx_scheme, exx_mem, exx_overlap, exx_alloc, &
+ exx_cartesian, exx_radius, exx_grid, exx_hgrid, exx_psolver, ewald_alpha, &
+ exx_debug, exx_pscheme, exx_filter, exx_filter_thr, exx_filter_extent, &
+ exx_gto, exx_gto_poisson
+ use multisiteSF_module, only: flag_MSSF_smear, MSSF_Smear_Type, &
MSSF_Smear_center, MSSF_Smear_shift, MSSF_Smear_width, &
flag_LFD_ReadTVEC, LFD_TVEC_read, &
LFD_kT, LFD_ChemP, flag_LFD_useChemPsub, &
@@ -974,7 +1009,7 @@ subroutine read_input(start, start_L, titles, vary_mu,&
! spin polarisation
logical :: flag_spin_polarisation
real(double) :: sum_elecN_spin
- real(double) :: charge_tmp
+ real(double) :: charge_tmp, GridSpacing
! Set defaults
vary_mu = .true.
@@ -1159,7 +1194,12 @@ subroutine read_input(start, start_L, titles, vary_mu,&
!
!
! Default to 50 Ha cutoff for grid
- GridCutoff = fdf_double('Grid.GridCutoff',50.0_double)
+ GridSpacing = fdf_double('Grid.GridSpacing',zero)
+ if(GridSpacing>zero) then
+ GridCutoff = half*(pi/GridSpacing)*(pi/GridSpacing)
+ else
+ GridCutoff = fdf_double('Grid.GridCutoff',50.0_double)
+ end if
! Grid points
n_grid_x = fdf_integer('Grid.PointsAlongX',0)
n_grid_y = fdf_integer('Grid.PointsAlongY',0)
@@ -1357,7 +1397,7 @@ subroutine read_input(start, start_L, titles, vary_mu,&
!maxnsf = 0
!max_rc = zero
min_blip_sp = 1.0e8_double
- flag_InitialAtomicSpin = .false.
+ flag_InitialAtomicSpin = .false.
do i=1,n_species
charge(i) = zero
charge_up(i) = zero
@@ -1378,13 +1418,15 @@ subroutine read_input(start, start_L, titles, vary_mu,&
! do while(fdf_bline(bp,line)) ! While there are lines in the block
if(fdf_block(species_label(i))) then
!charge(i) = fdf_double ('Atom.ValenceCharge',zero)
- charge_up(i) = fdf_double ('Atom.SpinNeUp',zero)
- charge_dn(i) = fdf_double ('Atom.SpinNeDn',zero)
- sum_elecN_spin = charge_up(i)+charge_dn(i)
- if (abs(sum_elecN_spin)>RD_ERR) then
- flag_InitialAtomicSpin = .true.
- ! We will check that the sum of charge_up and charge_dn matches charge later
- endif
+ if(flag_spin_polarisation) then
+ charge_up(i) = fdf_double ('Atom.SpinNeUp',zero)
+ charge_dn(i) = fdf_double ('Atom.SpinNeDn',zero)
+ sum_elecN_spin = charge_up(i)+charge_dn(i)
+ if (abs(sum_elecN_spin)>RD_ERR) then
+ flag_InitialAtomicSpin = .true.
+ ! We will check that the sum of charge_up and charge_dn matches charge later
+ endif
+ end if
nsf_species(i) = fdf_integer('Atom.NumberOfSupports',0)
RadiusSupport(i) = fdf_double ('Atom.SupportFunctionRange',zero)
!RadiusAtomf(i) = RadiusSupport(i) ! = r_pao for (atomf=paof) or r_sf for (atomf==sf)
@@ -1589,6 +1631,11 @@ subroutine read_input(start, start_L, titles, vary_mu,&
flag_variable_cell = flag_opt_cell
optcell_method = fdf_integer('AtomMove.OptCellMethod', 1)
cell_constraint_flag = fdf_string(20,'AtomMove.OptCell.Constraint','none')
+ ! Warn user if applying constraints with OptCellMethod 3
+ if(optcell_method==3.and.(.not.leqi(cell_constraint_flag,'none'))) then
+ call cq_warn(sub_name,"Cell constraints NOT applied for OptCellMethod 3")
+ cell_constraint_flag = 'none'
+ end if
cell_en_tol = fdf_double('AtomMove.OptCell.EnTol',0.00001_double)
! It makes sense to use GPa here so I'm changing the default to 0.1GPa
cell_stress_tol = fdf_double('AtomMove.StressTolerance',0.1_double) !005_double)
@@ -1951,14 +1998,15 @@ subroutine read_input(start, start_L, titles, vary_mu,&
!!$
if ( flag_functional_type == functional_hyb_pbe0 ) then
flag_exx = .true.
- exx_siter = fdf_integer('EXX.StartAfterIter', 1 )
+ exx_siter = fdf_integer('EXX.StartAfterIter', 2 )
exx_scf = fdf_integer('EXX.MethodSCF', 0 )
- r_exx = fdf_double ('EXX.Krange' , zero )
+ r_exx = fdf_double ('EXX.Xrange' , zero )
+ r_exxs = fdf_double ('EXX.SXrange' , zero )
!
else if ( flag_functional_type == functional_hartree_fock ) then
flag_exx = .true.
exx_scf = fdf_integer('EXX.MethodSCF', 0)
- r_exx = fdf_double ('EXX.Krange', zero)
+ r_exx = fdf_double ('EXX.Xrange', zero)
!
else
! don't touch we need it because matX is setup in set_dimensions
@@ -1985,20 +2033,32 @@ subroutine read_input(start, start_L, titles, vary_mu,&
end if
! To control accuracy during scf
exx_scf_tol = sc_tolerance
- ! Grid spacing for PAO discretisation in EXX
+ !
+ exx_gto = fdf_boolean('EXX.GTO', .false.)
+ exx_gto_poisson= fdf_boolean('EXX.GTOPoisson', .false.)
+ exx_grid = fdf_string (20,'EXX.Grid','standard')
exx_hgrid = fdf_double ('EXX.GridSpacing',zero)
- exx_radius = fdf_double ('EXX.IntegRadius',0.00_double)
- ! debug mode
- exx_Kij = .true.
- exx_Kkl = .true.
- exx_cartesian = .true.
- exx_overlap = .true.
- exx_alloc = .false.
- exx_psolver = 'fftw'
- p_scheme = 'pulay'
- exx_scheme = 1
- exx_mem = 1
- exx_debug = .false.
+ exx_radius = fdf_double ('EXX.IntegRadius',zero)
+ exx_scheme = fdf_integer('EXX.Scheme', 1 )
+ exx_debug = fdf_boolean('EXX.Debug', .false. )
+ exx_overlap= fdf_boolean('EXX.Overlap',.true. )
+ !
+ exx_filter = fdf_boolean('EXX.Filter', .false. )
+ exx_filter_extent = fdf_integer('EXX.FilterGrid', 2 )
+ exx_filter_thr = fdf_double('EXX.FilterThreshold', 1.0e-10_double )
+ exx_cutoff = fdf_double('EXX.Cutoff', 100.0_double )
+ !
+ exx_cartesian = fdf_boolean('EXX.PAOCartesian', .true.)
+ exx_alloc = fdf_boolean('EXX.DynamicAllocation',.true.)
+ exx_psolver = fdf_string (20,'EXX.PoissonSolver', 'fftw')
+
+ if(exx_psolver == 'fftw') then
+ exx_pscheme = fdf_string (20,'EXX.FFTWSolver','ewald')
+ if(exx_pscheme == 'ewald') then
+ ewald_alpha = fdf_double('EXX.FFTWEwaldAlpha',3.0_double)
+ end if
+ end if
+ !exx_mem = 1
end if
!!$
!!$
@@ -3010,8 +3070,8 @@ subroutine readDiagInfo
! Local variables
character(len=80) :: sub_name = "readDiagInfo"
type(cq_timer) :: backtrace_timer
- integer :: stat, i, j, k, nk_st, nkp_lines
- real(double) :: a, sum, dkx, dky, dkz
+ integer :: stat, i, j, k, nk_st, nkp_lines, nblocks
+ real(double) :: a, sum, dkx, dky, dkz, dk
integer :: proc_per_group
logical :: ms_is_prime
@@ -3097,14 +3157,25 @@ subroutine readDiagInfo
! padH or not :temporary?
flag_padH = fdf_boolean('Diag.PaddingHmatrix',.true.)
- if(fdf_defined('Diag.BlockSizeR')) then
+ if(flag_padH) then
+ ! default block size is 32 (we may change this value in the future)
+ block_size_r = fdf_integer('Diag.BlockSizeR',32)
+ block_size_c = fdf_integer('Diag.BlockSizeC',block_size_r)
+ if(block_size_c .ne. block_size_r) then
+ call cq_warn(sub_name,'PaddingHmatrix: block_size_c needs to be block_size_r')
+ block_size_c = block_size_r
+ endif
+ nblocks = ceiling((real(matrix_size,double)-RD_ERR)/block_size_r)
+ if(nblocks < proc_rows .or. nblocks < proc_cols) then
+ call cq_warn(sub_name,'PaddingHmatrix is forced to be false')
+ flag_padH = .false.
+ endif
+ endif
+
+ if(.not.flag_padH) then
+ if(fdf_defined('Diag.BlockSizeR')) then
block_size_r = fdf_integer('Diag.BlockSizeR',1)
block_size_c = fdf_integer('Diag.BlockSizeC',1)
- if(flag_padH) then
- if(block_size_c .ne. block_size_r) &
- call cq_abort('PaddingHmatrix: block_size_c needs to be block_size_r')
- block_size_c = block_size_r
- else
a = real(matrix_size)/real(block_size_r)
if(a - real(floor(a))>1e-8_double) &
call cq_abort('block_size_r not a factor of matrix size ! ',&
@@ -3113,12 +3184,12 @@ subroutine readDiagInfo
if(a - real(floor(a))>1e-8_double) &
call cq_abort('block_size_c not a factor of matrix size ! ',&
matrix_size, block_size_c)
- endif
- else if ( ms_is_prime ) then
+ else if ( ms_is_prime ) then
block_size_r = 1
block_size_c = block_size_r
+ call cq_warn(sub_name,'Use of PaddingHmatrix is recommended.')
call cq_warn(sub_name,'prime: set block_size_c = block_size_r = 1 ')
- else
+ else !
done = .false.
block_size_r = matrix_size/max(proc_rows,proc_cols)+1
do while(.NOT.done)
@@ -3134,7 +3205,9 @@ subroutine readDiagInfo
end if
end if
block_size_c = block_size_r
- end if
+ end if
+ endif ! flag_padH is False
+
if(iprint_init>1.AND.inode==ionode) then
write(io_lun,2) block_size_r, block_size_c
write(io_lun,3) proc_rows, proc_cols
@@ -3261,7 +3334,7 @@ subroutine readDiagInfo
call fdf_endblock
wtk = wtk/sum
else ! Force gamma point dependence
- if(inode==ionode) write(io_lun,fmt='(4x,"Default k-point sampling of Gamma point only")')
+ if(inode==ionode) write(io_lun,fmt='(/4x,"Default k-point sampling of Gamma point only")')
nkp = 1
kk(1,1) = zero
kk(2,1) = zero
@@ -3281,11 +3354,18 @@ subroutine readDiagInfo
! Read Monkhorst-Pack mesh coefficients
! Default is Gamma point only
if(iprint_init>1.AND.inode==ionode) &
- write(io_lun,fmt='(/8x,"Reading Monkhorst-Pack Kpoint mesh"//)')
+ write(io_lun,fmt='(/8x,"Using Monkhorst-Pack Kpoint mesh"//)')
flag_gamma = fdf_boolean('Diag.GammaCentred',.false.)
- mp(1) = fdf_integer('Diag.MPMeshX',1)
- mp(2) = fdf_integer('Diag.MPMeshY',1)
- mp(3) = fdf_integer('Diag.MPMeshZ',1)
+ dk = fdf_double('Diag.dk',zero)
+ if(dk>zero) then
+ mp(1) = ceiling(two*pi/(dk*rcellx))
+ mp(2) = ceiling(two*pi/(dk*rcelly))
+ mp(3) = ceiling(two*pi/(dk*rcellz))
+ else
+ mp(1) = fdf_integer('Diag.MPMeshX',1)
+ mp(2) = fdf_integer('Diag.MPMeshY',1)
+ mp(3) = fdf_integer('Diag.MPMeshZ',1)
+ end if
if(iprint_init>0.AND.inode==ionode) then
if(flag_gamma) then
write (io_lun,fmt='(/8x,a, i3," x ",i3," x ",i3," gamma-centred")') &
@@ -3300,7 +3380,7 @@ subroutine readDiagInfo
else
suffix = " "
end if
- write (io_lun,fmt='(4x,"Using a MP mesh for k-points: ", i3," x ",i3," x ",i3,a2)') &
+ write (io_lun,fmt='(/4x,"Using a MP mesh for k-points: ", i3," x ",i3," x ",i3,a2)') &
(mp(i), i=1,3), suffix
end if
if (mp(1) <= 0 .OR. mp(2) <= 0 .OR. mp(3) <= 0) &
diff --git a/src/initialisation_module.f90 b/src/initialisation_module.f90
index bf13962fa..6ede3b9b9 100644
--- a/src/initialisation_module.f90
+++ b/src/initialisation_module.f90
@@ -109,8 +109,10 @@ module initialisation
!! Changes to new XC interface
!! 2019/12/26 tsuyoshi
!! Removed flag_no_atomic_densities
+ !! 2020/12/13 lionel
+ !! Added EXX initialise and finalise
!! 2022/06/09 08:35 dave
- !! Changed name of D2 set-up routine, added only to module use
+ !! Changed name of D2 set-up routine, added only to module usep
!! SOURCE
!!
subroutine initialise(vary_mu, fixed_potential, mu, total_energy)
@@ -122,7 +124,8 @@ subroutine initialise(vary_mu, fixed_potential, mu, total_energy)
flag_only_dispersion, flag_neutral_atom, &
flag_atomic_stress, flag_heat_flux, &
flag_full_stress, area_moveatoms, &
- atomic_stress, non_atomic_stress, min_layer
+ atomic_stress, non_atomic_stress, &
+ min_layer, flag_self_consistent
use GenComms, only: inode, ionode, my_barrier, end_comms, &
cq_abort
use initial_read, only: read_and_write
@@ -133,7 +136,7 @@ subroutine initialise(vary_mu, fixed_potential, mu, total_energy)
use cover_module, only: make_cs, D2_CS
use dimens, only: r_dft_d2
use DFT_D2, only: set_para_D2, dispersion_D2
- use pseudo_tm_module, only: make_neutral_atom
+ use pseudo_tm_module, only: make_neutral_atom
use angular_coeff_routines, only: set_fact
use maxima_module, only: lmax_ps, lmax_pao
use XC, only: init_xc
diff --git a/src/io_module.f90 b/src/io_module.f90
index 3f4854a34..83008c3eb 100644
--- a/src/io_module.f90
+++ b/src/io_module.f90
@@ -2870,10 +2870,11 @@ end subroutine write_xsf
!! CREATION DATE
!! 2021/10/18
!! MODIFICATION HISTORY
- !!
+ !! 2024/11/04 Augustin Lu
+ !! Add stress tensor
!! SOURCE
!!
- subroutine write_extxyz(filename, energy0, atom_force)
+ subroutine write_extxyz(filename, energy0, atom_force, stress_tensor)
use datatypes
use timer_module
@@ -2889,6 +2890,7 @@ subroutine write_extxyz(filename, energy0, atom_force)
character(len=*) :: filename
real(double) :: energy0
real(double), dimension(3,ni_in_cell) :: atom_force
+ real(double), dimension(3,3) :: stress_tensor
! Local variables
integer :: lun, i, j, title_length
@@ -2896,7 +2898,9 @@ subroutine write_extxyz(filename, energy0, atom_force)
character(len=432) :: comment
character(len=45) :: vec_a, vec_b, vec_c, energy_str
character(len=80) :: titles_xyz
- real(double) :: for_conv_loc, en_conv_loc, dist_conv_loc
+ character(len=135) :: stress_str
+
+ real(double) :: for_conv_loc, en_conv_loc, dist_conv_loc, volume
if(inode==ionode) then
if (iprint_init>2) write(io_lun, &
@@ -2930,6 +2934,21 @@ subroutine write_extxyz(filename, energy0, atom_force)
comment=TRIM(comment)//' Properties=species:S:1:pos:R:3:forces:R:3 potential_energy='
write(energy_str,'(f0.8)') energy0 * en_conv_loc
comment = TRIM(comment)//TRIM(energy_str)//' pbc="T T T" '
+
+ volume = r_super_x*r_super_y*r_super_z*BohrToAng**3
+
+ ! Convert each row to string
+ write(stress_str(1:45), '(3f15.8)') stress_tensor(1,1)*HaToeV/volume,&
+ stress_tensor(1,2)*HaToeV/volume,&
+ stress_tensor(1,3)*HaToeV/volume
+ write(stress_str(46:90), '(3f15.8)') stress_tensor(2,1)*HaToeV/volume,&
+ stress_tensor(2,2)*HaToeV/volume,&
+ stress_tensor(2,3)*HaToeV/volume
+ write(stress_str(91:135), '(3f15.8)') stress_tensor(3,1)*HaToeV/volume,&
+ stress_tensor(3,2)*HaToeV/volume,&
+ stress_tensor(3,3)*HaToeV/volume
+ comment = TRIM(comment)//' stress=" '//TRIM(stress_str)//'" '
+
write(lun,'(a)') TRIM(comment)
do i=1,ni_in_cell
@@ -3267,7 +3286,7 @@ subroutine print_atomic_positions
integer :: i
if(inode==ionode) then
- write(io_lun,fmt='(/6x,"Simulation cell dimensions: ",f10.4,a3," x ",f10.4,a3," x ",f10.4,a3)') &
+ write(io_lun,fmt='(/4x,"Simulation cell dimensions: ",f10.4,a3," x ",f10.4,a3," x ",f10.4,a3)') &
r_super_x*dist_conv, d_units(dist_units), r_super_y*dist_conv, d_units(dist_units), &
r_super_z*dist_conv, d_units(dist_units)
if(flag_coords_xyz) then
@@ -3378,6 +3397,9 @@ end subroutine write_velocity
!! MODIFICATION HISTORY
!! 2011/10/20 09:59 dave
!! Syntax correction for rewind
+ !! 2024/05/21 TM
+ !! Ordering has been changed from partition labeling to the globa one (in coordinate file)
+ !! I assume the passed array will be changed from ion_velocity -> atom_vel
!! SOURCE
!!
subroutine read_velocity(velocity, filename)
@@ -3392,24 +3414,15 @@ subroutine read_velocity(velocity, filename)
character(len=50),intent(in) :: filename
! Local variables
- integer :: id_global, ni , ni2, id_tmp
- integer :: lun
+ integer :: ni, id_tmp, lun
if(inode == ionode) then
- if(iprint_init>2) write(io_lun,'(10x,a40,a20)') 'Entering read_velocity; reading ', filename
+ if(iprint_init>2) write(io_lun,'(10x,a40,a20)') 'Entering NEW read_velocity; reading ', filename
call io_assign(lun)
open(unit=lun,file=filename)
rewind(unit=lun)
- do id_global=1,ni_in_cell
- ni=id_glob_inv(id_global)
- if(id_glob(ni) /= id_global) &
- call cq_abort(' ERROR in global labelling ',id_global,id_glob(ni))
- read(lun,101) id_tmp, ni2, velocity(1:3, ni)
- if(ni2 /= ni) write(io_lun,fmt='(4x,a,i6,a,i6,a,i6)') &
- ' Order of atom has changed for global id (file_labelling) = ',id_global, &
- ' : corresponding labelling (NOprt labelling) used to be ',ni2,&
- ' : but now it is ',ni
-101 format(2i8,3e20.12)
+ do ni=1,ni_in_cell
+ read(lun,*) id_tmp, velocity(1:3, ni)
enddo
call io_close(lun)
endif ! (inode == ionode) then
diff --git a/src/matrix_comms_module.f90 b/src/matrix_comms_module.f90
index 2f0b28384..736ba709a 100644
--- a/src/matrix_comms_module.f90
+++ b/src/matrix_comms_module.f90
@@ -75,10 +75,10 @@ subroutine end_part_comms(myid,n_cont, &
! Passed variables
integer :: myid
integer :: n_cont,ncover_yz,ncoverz
- integer(integ) :: nbnab_rem(:)
- integer(integ) :: ibind_rem(:)
- integer(integ) :: ibpart_rem(:)
- integer(integ) :: npxyz_rem(:)
+ integer(integ), intent(in) :: nbnab_rem(:)
+ integer(integ), intent(in) :: ibind_rem(:)
+ integer(integ), intent(in) :: npxyz_rem(:)
+ integer(integ), intent(out) :: ibpart_rem(:)
! Local variables
integer :: noff,ierr,ni,k, len1, len2
diff --git a/src/matrix_module.f90 b/src/matrix_module.f90
index 7e9def8ea..79a3002e4 100644
--- a/src/matrix_module.f90
+++ b/src/matrix_module.f90
@@ -121,16 +121,16 @@ module matrix_module
type matrix_halo
integer :: np_in_halo ! Partns in halo
integer :: ni_in_halo ! Atoms in halo
- integer,pointer :: nh_part(:) ! No of halo atoms in halo part
- integer,pointer :: j_beg(:) ! accumulator of nh_part
- integer,pointer :: lab_hcell(:) ! sim cell part (CC) = halo part
- integer,pointer :: lab_hcover(:) ! CS part (CC) = halo part
- integer,pointer :: j_seq(:) ! Part seq of halo atom
- integer,pointer :: i_h2d(:) ! halo->neigh trans for halo atom
- integer,pointer :: i_halo(:) ! halo seq of atom in CS
- integer,pointer :: i_hbeg(:) ! Where CS part starts in i_halo
- integer,pointer :: ndimi(:)
- integer,pointer :: ndimj(:)
+ integer,allocatable :: nh_part(:) ! No of halo atoms in halo part
+ integer,allocatable :: j_beg(:) ! accumulator of nh_part
+ integer,allocatable :: lab_hcell(:) ! sim cell part (CC) = halo part
+ integer,allocatable :: lab_hcover(:) ! CS part (CC) = halo part
+ integer,allocatable :: j_seq(:) ! Part seq of halo atom
+ integer,allocatable :: i_h2d(:) ! halo->neigh trans for halo atom
+ integer,allocatable :: i_halo(:) ! halo seq of atom in CS
+ integer,allocatable :: i_hbeg(:) ! Where CS part starts in i_halo
+ integer,allocatable :: ndimi(:)
+ integer,allocatable :: ndimj(:)
! This type's values for maxima
integer :: mx_part,mx_halo
end type matrix_halo
diff --git a/src/md_misc_module.f90 b/src/md_misc_module.f90
index 3cb524d4c..501127b4d 100644
--- a/src/md_misc_module.f90
+++ b/src/md_misc_module.f90
@@ -137,20 +137,24 @@ subroutine init_md(baro, thermo, mdl, md_ndof, nequil, second_call)
! unified md checkpoint file easier - zamaan
ion_velocity = zero
if (flag_read_velocity) then
- call read_velocity(ion_velocity, file_velocity)
+ !call read_velocity(ion_velocity, file_velocity)
+ call read_velocity(atom_vels, file_velocity)
+ do i=1,ni_in_cell
+ ion_velocity(1,i) = atom_vels(1,id_glob(i))
+ ion_velocity(2,i) = atom_vels(2,id_glob(i))
+ ion_velocity(3,i) = atom_vels(3,id_glob(i))
+ end do
else
if(temp_ion > RD_ERR) then
call init_velocity(ni_in_cell, temp_ion, ion_velocity, ion_ke)
end if
+ ! atom_vels : 2020/Jul/30 -> 2024/May/21
+ do i=1,ni_in_cell
+ atom_vels(1,id_glob(i)) = ion_velocity(1,i)
+ atom_vels(2,id_glob(i)) = ion_velocity(2,i)
+ atom_vels(3,id_glob(i)) = ion_velocity(3,i)
+ end do
end if
-
- ! atom_vels : 2020/Jul/30
- do i=1,ni_in_cell
- atom_vels(1,id_glob(i)) = ion_velocity(1,i)
- atom_vels(2,id_glob(i)) = ion_velocity(2,i)
- atom_vels(3,id_glob(i)) = ion_velocity(3,i)
- end do
-
end if
if(leqi(md_thermo_type,'svr').AND.md_tau_T mx_matrices) &
call cq_abort("Matrix error in matrix_sum: ", &
matrix_index(B), B)
- call scal(mat_p(A)%length, alpha, mat_p(A)%matrix, 1)
call matrix_add(alpha, mat_p(A)%matrix, mat_p(A)%length, &
mat(:,matrix_index(A)), beta, mat_p(B)%matrix, &
mat_p(B)%length, mat(:,matrix_index(B)), &
@@ -2761,6 +2766,8 @@ end subroutine matrix_scale
!! Changed MPI_allreduce to gsum
!! 2008/05/22 ast
!! Added timers
+ !! 2024/05/27 nakata
+ !! bugfix: corrected sf to sf1 for loc to check overflow
!! SOURCE
!!
real(double) function matrix_trace(A)
@@ -2788,7 +2795,7 @@ real(double) function matrix_trace(A)
do i = 1, bundle%nm_nodgroup(np) ! Loop over atoms in partition
iprim = iprim + 1
sf1 = mat(np,Ah)%ndimi(i)
- loc = (sf - 1) * sf1 + sf - 1 + mat(np,Ah)%onsite(i)
+ loc = (sf1 - 1) * sf1 + sf1 - 1 + mat(np,Ah)%onsite(i)
if (loc > mat_p(A)%length) &
call cq_abort("Overflow error in trace: ", &
loc, mat_p(A)%length)
diff --git a/src/multiply_kernel_ompGemm_m.f90 b/src/multiply_kernel_ompGemm_m.f90
index ecf9fa338..93926c477 100644
--- a/src/multiply_kernel_ompGemm_m.f90
+++ b/src/multiply_kernel_ompGemm_m.f90
@@ -135,8 +135,6 @@ subroutine m_kern_max(k_off, kpart, ib_nd_acc, ibaddr, nbnab, &
lenc, debug)
use datatypes
use matrix_module
- use basic_types, only: primary_set
- use primary_module, only: bundle
use numbers, only: zero, one
implicit none
@@ -159,116 +157,79 @@ subroutine m_kern_max(k_off, kpart, ib_nd_acc, ibaddr, nbnab, &
integer(integ), intent(in) :: bndim2(:)
! Local variables
integer :: jbnab2ch(mx_absb) ! Automatic array
- integer :: nbkbeg, k, k_in_part, k_in_halo, j, jpart, jseq
- integer :: i, nabeg, i_in_prim, icad, nbbeg, j_in_halo, ncbeg
- integer :: n1, n2, n3, nb_nd_kbeg
+ integer :: i,j,k, k_in_halo, k_in_part
+ integer :: nbkbeg, nabeg, naend, i_in_prim, icad, ncbeg, ncend
+ integer :: tcbeg, tcend
+ integer :: nb_nd_kbeg
integer :: nd1, nd2, nd3
- integer :: naaddr, nbaddr, ncaddr
- real(double), allocatable, dimension(:,:) :: tempb, tempa, tempc
- integer :: sofar, maxnd1, maxnd2, maxnd3, maxlen
+ real(double), allocatable, dimension(:,:) :: tempc
+ integer :: maxnd1, maxnd2, maxnd3, maxlen
+ integer :: nbbeg, nbend, tbend
external :: dgemm
! OpenMP required indexing variables
- integer :: nd1_1st(at%mx_halo), nd2_1st(mx_absb)
+ integer :: nd1_vector(at%mx_halo), nd2_vector(mx_absb), nd2_array(mx_absb)
+ integer :: n1, n2, ncaddr
- ! Allocate tempa, tempb, tempc to largest possible size outside the loop
+ ! Allocate tempc to largest possible size outside the loop
maxnd1 = maxval(ahalo%ndimi)
maxnd2 = maxval(bndim2)
maxnd3 = maxval(ahalo%ndimj)
maxlen = maxval(nbnab) * maxnd2
- allocate(tempa(maxnd1,maxnd3), tempc(maxnd1,maxlen), tempb(maxnd3,maxlen))
- tempa = zero
- tempb = zero
- tempc = zero
+ allocate(tempc(maxnd1,maxlen))
+ ! When the beta argument to dgemm is zero, C does not need to be set. See
+ ! https://netlib.org/lapack/explore-html/d7/d2b/dgemm_8f_source.html
+
! Loop over atoms k in current A-halo partn
do k = 1, ahalo%nh_part(kpart)
- k_in_halo = ahalo%j_beg(kpart) + k - 1
- k_in_part = ahalo%j_seq(k_in_halo)
- nbkbeg = ibaddr(k_in_part)
- nb_nd_kbeg = ib_nd_acc(k_in_part)
- nd3 = ahalo%ndimj(k_in_halo)
- ! if (PRESENT(debug)) write (21+debug,*) 'Details1: ', k, nb_nd_kbeg
- ! for OpenMP sub-array indexing
- nd1_1st(1) = 0
- do i = 2, at%n_hnab(k_in_halo)
- i_in_prim = at%i_prim(at%i_beg(k_in_halo)+i-2)
- nd1_1st(i) = nd1_1st(i-1) + nd3 * ahalo%ndimi(i_in_prim)
- end do
- nd2_1st(1) = 0
- do j = 2, nbnab(k_in_part)
- nd2_1st(j) = nd2_1st(j-1) + nd3 * bndim2(nbkbeg+j-2)
- end do
- ! transcription of j from partition to C-halo labelling
- do j = 1, nbnab(k_in_part)
- jpart = ibpart(nbkbeg+j-1) + k_off
- jseq = ibseq(nbkbeg+j-1)
- jbnab2ch(j) = chalo%i_halo(chalo%i_hbeg(jpart)+jseq-1)
- end do
-!$omp do schedule(runtime)
+
+ call precompute_indices(jbnab2ch, nd1_vector, nd2_vector, nd2_array, &
+ nd3, nbkbeg, k_in_halo, k_in_part, nb_nd_kbeg, &
+ k, kpart, k_off, ahalo, chalo, at, &
+ ib_nd_acc, ibaddr, nbnab, ibpart, ibseq, bndim2)
+
+ ! Compute indices to B for dgemm call
+ nd2 = bndim2(nbkbeg + nbnab(k_in_part))
+ nbbeg = nd2_vector(1)
+ nbend = nd2_vector(nbnab(k_in_part)) + nd3 * nd2 - 1
+ tbend = nd2_array(nbnab(k_in_part)) + nd2 - 1
+
! Loop over primary-set A-neighbours of k
- do i = 1, at%n_hnab(k_in_halo)
- ! nabeg = at%i_beg(k_in_halo) + i - 1
- i_in_prim = at%i_prim(at%i_beg(k_in_halo)+i-1)
- nd1 = ahalo%ndimi(i_in_prim)
- nabeg = at%i_nd_beg(k_in_halo) + nd1_1st(i)
- do n1 = 1, nd1
- naaddr = nabeg + nd3 * (n1 - 1)
- do n3 = 1, nd3
- tempa(n1,n3) = a(naaddr+n3-1)
- end do
- end do
+ !$omp do schedule(runtime)
+ ANeighbours: do i = 1, at%n_hnab(k_in_halo)
+ i_in_prim = at%i_prim(at%i_beg(k_in_halo) + i - 1)
icad = (i_in_prim - 1) * chalo%ni_in_halo
- sofar = 0
- ! Loop over B-neighbours of atom k
- do j = 1, nbnab(k_in_part)
- nd2 = bndim2(nbkbeg+j-1)
- nbbeg = nb_nd_kbeg + nd2_1st(j)
- j_in_halo = jbnab2ch(j)
- if (j_in_halo /= 0) then
- ncbeg = chalo%i_h2d(icad+j_in_halo)
- if (ncbeg /= 0) then ! multiplication of ndim x ndim blocks
- ! if (present(debug)) &
- ! write (21+debug,*) 'Details2: ', j, nd2, &
- ! (nabeg-1)/(nd1*nd3), &
- ! (ncbeg-1)/(nd1*nd2), &
- ! (nbbeg-1)/(nd2*nd3)
-!DIR$ NOPATTERN
- do n2 = 1, nd2
- nbaddr = nbbeg + nd3 * (n2 - 1)
- do n3 = 1, nd3
- tempb(n3,sofar+n2) = b(nbaddr+n3-1)
- end do
- end do
- sofar = sofar + nd2
- end if
- end if ! End of if (j_in_halo /= 0)
- end do ! End of j = 1, nbnab
- if (sofar > 0) then
- ! m, n, k, alpha, a, lda, b, ldb, beta, c, ldc
- call dgemm('n', 'n', nd1, sofar, nd3, one, tempa, &
- maxnd1, tempb, maxnd3, zero, tempc, maxnd1)
- end if
- sofar = 0
- ! Loop over B-neighbours of atom k
- do j = 1, nbnab(k_in_part)
- nd2 = bndim2(nbkbeg+j-1)
- j_in_halo = jbnab2ch(j)
- if (j_in_halo /= 0) then
- ncbeg = chalo%i_h2d(icad+j_in_halo)
- if (ncbeg /= 0) then ! multiplication of ndim x ndim blocks
- do n2 = 1, nd2
- ncaddr = ncbeg + nd1 * (n2 - 1)
+
+ ! Compute indices to A for dgemm call
+ nd1 = ahalo%ndimi(i_in_prim)
+ nabeg = at%i_nd_beg(k_in_halo) + nd1_vector(i)
+ naend = nabeg + (nd1 * nd3 - 1)
+
+ ! Compute A*B using and store the result in tempc
+ call dgemm('t', 'n', nd1, tbend, nd3, one, A(nabeg:naend), &
+ nd3, B(nbbeg:nbend), nd3, zero, tempc, maxnd1)
+
+ ! Copy result back from tempc and add to C
+ copy_c: do j = 1, nbnab(k_in_part)
+ if (jbnab2ch(j) /= 0) then
+ ncbeg = chalo%i_h2d(icad+jbnab2ch(j))
+ if (ncbeg /= 0) then
+ nd2 = bndim2(nbkbeg+j)
+ tcbeg = nd2_array(j)
+ tcend = tcbeg + nd2 - 1
+ do n2 = tcbeg, tcend
do n1 = 1, nd1
- c(ncaddr+n1-1) = c(ncaddr+n1-1) + tempc(n1,sofar+n2)
+ ncaddr = ncbeg + (n2 - tcbeg) * nd1 + n1 - 1
+ c(ncaddr) = c(ncaddr) + tempc(n1,n2)
end do
end do
- sofar = sofar + nd2
end if
end if
- end do ! end of j = 1, nbnab(k_in_part)
- end do ! end of i = 1, at%n_hnab
-!$omp end do
+ end do copy_c
+
+ end do ANeighbours
+ !$omp end do
end do ! end of k = 1, nahpart
- deallocate(tempa, tempb, tempc)
+ deallocate(tempc)
return
end subroutine m_kern_max
!!*****
@@ -377,8 +338,6 @@ subroutine m_kern_min(k_off, kpart, ib_nd_acc, ibaddr, nbnab, &
lenc)
use datatypes
use matrix_module
- use basic_types, only: primary_set
- use primary_module, only: bundle
use numbers, only: one, zero
implicit none
@@ -401,93 +360,150 @@ subroutine m_kern_min(k_off, kpart, ib_nd_acc, ibaddr, nbnab, &
integer(integ), intent(in) :: bndim2(:)
! Local variables
integer :: jbnab2ch(mx_absb)
- integer :: k, k_in_part, k_in_halo, nbkbeg, j, jpart, jseq
- integer :: i, nabeg, i_in_prim, icad, nbbeg, j_in_halo, ncbeg
- integer :: n1, n2, n3, nb_nd_kbeg
+ integer :: i,j,k, k_in_halo, k_in_part, nbkbeg
+ integer :: nabeg, i_in_prim, icad, nbbeg, ncbeg
+ integer :: n2, nbaddr, ncaddr
+ integer :: n2beg, n2end
+ integer :: nb_nd_kbeg
integer :: nd1, nd2, nd3
- integer :: naaddr, nbaddr, ncaddr
- integer :: sofar, maxnd1, maxnd2, maxnd3, maxlen
+ integer :: maxlen, maxnd1, maxnd2, maxnd3
real(double), allocatable, dimension(:,:) :: tempb, tempc
external :: dgemm
! OpenMP required indexing variables
- integer :: nd1_1st(at%mx_halo), nd2_1st(mx_absb)
+ integer :: nd1_vector(at%mx_halo), nd2_vector(mx_absb), nd2_array(mx_absb)
+
+ integer :: sofar
maxnd1 = maxval(ahalo%ndimi)
maxnd2 = maxval(bndim2)
maxnd3 = maxval(ahalo%ndimj)
maxlen = maxval(nbnab) * maxnd2
allocate(tempb(maxnd3,maxlen), tempc(maxlen,maxnd1))
- tempb = zero
- tempc = zero
! Loop over atoms k in current A-halo partn
do k = 1, ahalo%nh_part(kpart)
- k_in_halo = ahalo%j_beg(kpart) + k - 1
- k_in_part = ahalo%j_seq(k_in_halo)
- nbkbeg = ibaddr(k_in_part)
- nb_nd_kbeg = ib_nd_acc(k_in_part)
- nd3 = ahalo%ndimj(k_in_halo)
- ! for OpenMP sub-array indexing
- nd1_1st(1) = 0
- do i = 2, at%n_hnab(k_in_halo)
- i_in_prim = at%i_prim(at%i_beg(k_in_halo)+i-2)
- nd1_1st(i) = nd1_1st(i-1) + nd3 * ahalo%ndimi(i_in_prim)
- end do
- nd2_1st(1) = 0
- do j = 2, nbnab(k_in_part)
- nd2_1st(j) = nd2_1st(j-1) + nd3 * bndim2(nbkbeg+j-2)
- end do
- ! transcription of j from partition to C-halo labelling
- do j = 1, nbnab(k_in_part)
- jpart = ibpart(nbkbeg+j-1) + k_off
- jseq = ibseq(nbkbeg+j-1)
- jbnab2ch(j) = chalo%i_halo(chalo%i_hbeg(jpart)+jseq-1)
- end do
-!$omp do schedule(runtime)
+
+ call precompute_indices(jbnab2ch, nd1_vector, nd2_vector, nd2_array, &
+ nd3, nbkbeg, k_in_halo, k_in_part, nb_nd_kbeg, &
+ k, kpart, k_off, ahalo, chalo, at, &
+ ib_nd_acc, ibaddr, nbnab, ibpart, ibseq, bndim2)
+
! Loop over primary-set A-neighbours of k
+ !$omp do schedule(runtime)
do i = 1, at%n_hnab(k_in_halo)
- ! nabeg = at%i_beg(k_in_halo) + i - 1
i_in_prim = at%i_prim(at%i_beg(k_in_halo)+i-1)
nd1 = ahalo%ndimi(i_in_prim)
- nabeg = at%i_nd_beg(k_in_halo) + nd1_1st(i)
icad = (i_in_prim-1) * chalo%ni_in_halo
+ nabeg = at%i_nd_beg(k_in_halo) + nd1_vector(i)
sofar = 0
! Loop over B-neighbours of atom k
+
do j = 1, nbnab(k_in_part)
- ! nbbeg = nbkbeg + j - 1
- nd2 = bndim2(nbkbeg+j-1)
- nbbeg = nb_nd_kbeg + nd2_1st(j)
- j_in_halo = jbnab2ch(j)
- if (j_in_halo /= 0) then
- ! nd2 = chalo%ndimj(j_in_halo)
- ncbeg = chalo%i_h2d(icad+j_in_halo)
+ if (jbnab2ch(j) /= 0) then
+ ncbeg = chalo%i_h2d(icad + jbnab2ch(j))
if (ncbeg /= 0) then ! multiplication of ndim x ndim blocks
-!DIR$ NOPATTERN
+ nd2 = bndim2(nbkbeg + j)
+ nbbeg = nd2_vector(j)
+
+ ! Vectorized version of temporary copies. Intel ifort compiler 2021.6
+ ! on myriad
+ ! compiles the memory copies into AVX2 instructions, but efficiency
+ ! is poor in the test cases I tried because nd1 and nd3 are small.
+ ! Tuomas Koskela (ARC) 21 Mar 2024 eCSE08 project
+ ! nbend = nbbeg + nd3 * nd2 - 1
+ ! ncend = ncbeg + nd1 * nd2 - 1
+ ! n2beg = sofar + 1
+ ! n2end = sofar + nd2
+ ! tempb(1:nd3, n2beg:n2end) = reshape(b(nbbeg:nbend), [nd3, nd2], order=[1,2])
+ ! tempc(n2beg:n2end, 1:nd1) = reshape(c(ncbeg:ncend), [nd2, nd1], order=[2,1])
+
do n2 = 1, nd2
nbaddr = nbbeg + nd3 * (n2 - 1)
ncaddr = ncbeg + nd1 * (n2 - 1)
- do n3 = 1, nd3
- tempb(n3,sofar+n2) = b(nbaddr+n3-1)
- end do
- do n1 = 1, nd1
- tempc(sofar+n2,n1) = c(ncaddr+n1-1)
- end do
+ tempb(1:nd3,sofar+n2) = b(nbaddr:nbaddr+nd3-1)
+ tempc(sofar+n2,1:nd1) = c(ncaddr:ncaddr+nd1-1)
end do
+
sofar = sofar + nd2
+
end if
end if
end do
+
if (sofar > 0) then
! m, n, k, alpha, a, lda, b, ldb, beta, c, ldc
call dgemm('n', 'n', nd3, nd1, sofar, one, tempb, &
- maxnd3, tempc, maxlen, one, a(nabeg:), nd3)
+ maxnd3, tempc, maxlen, one, a(nabeg:), nd3)
end if
+
end do
-!$omp end do
+ !$omp end do
end do
deallocate(tempb, tempc)
return
end subroutine m_kern_min
!!*****
-end module multiply_kernel
+ ! Precompute indices for parallel loop. These indices are starting indices
+ ! of slices to A, B and C. The ending indices are computed on the fly.
+ ! nd1_vector accumulates steps of size nd3 * ahalo%ndimi. This is used for indexing
+ ! the 1d vector storing the A matrix
+ ! nd2_vector accumulates steps of size nd3 * nd2. This is used for indexing
+ ! 1d vectors storing the B and C matrices
+ ! nd2_array accumulates steps of size nd2. This is used for indexing the
+ ! 2d arrays storing the B and C matrices
+ subroutine precompute_indices(jbnab2ch, nd1_vector, nd2_vector, nd2_array, &
+ nd3, nbkbeg, k_in_halo, k_in_part, nb_nd_kbeg, &
+ k, kpart, k_off, ahalo, chalo, at, &
+ ib_nd_acc, ibaddr, nbnab, ibpart, ibseq, bndim2)
+
+ use datatypes
+ use matrix_module, only: matrix_halo, matrix_trans
+ integer, intent(out) :: jbnab2ch(:), nd1_vector(:), nd2_vector(:), nd2_array(:)
+ integer, intent(out) :: nd3, nbkbeg, k_in_halo, nb_nd_kbeg
+ integer, intent(in) :: k, kpart, k_off
+ integer(integ), intent(in) :: ib_nd_acc(:)
+ integer(integ), intent(in) :: ibaddr(:)
+ integer(integ), intent(in) :: nbnab(:)
+ integer(integ), intent(in) :: ibpart(:)
+ integer(integ), intent(in) :: ibseq(:)
+ integer(integ), intent(in) :: bndim2(:)
+ type(matrix_halo), intent(in) :: ahalo, chalo
+ type(matrix_trans), intent(in) :: at
+
+ integer :: i, j, nd2_prev, i_in_prim_prev
+
+ ! Indices that depend on k
+ k_in_halo = ahalo%j_beg(kpart) + k - 1
+ k_in_part = ahalo%j_seq(k_in_halo)
+ nbkbeg = ibaddr(k_in_part) - 1
+ nb_nd_kbeg = ib_nd_acc(k_in_part)
+ nd3 = ahalo%ndimj(k_in_halo)
+
+ nd1_vector(1) = 0
+ nd2_vector(1) = nb_nd_kbeg
+ nd2_array(1) = 1
+
+ do i = 2, at%n_hnab(k_in_halo)
+ i_in_prim_prev = at%i_prim(at%i_beg(k_in_halo) + i - 2)
+ nd1_vector(i) = nd1_vector(i-1) + nd3 * ahalo%ndimi(i_in_prim_prev)
+ end do
+
+ ! transcription of j from partition to C-halo labelling
+ do j = 1, nbnab(k_in_part)
+ ! Also precompute jbnab2ch to be used later in the parallel loop.
+ jpart = ibpart(nbkbeg + j) + k_off
+ jseq = ibseq(nbkbeg + j)
+ jbnab2ch(j) = chalo%i_halo(chalo%i_hbeg(jpart) + jseq - 1)
+
+ if (j .gt. 1) then
+ nd2_prev = bndim2(nbkbeg + j - 1)
+ nd2_vector(j) = nd2_vector(j - 1) + nd3 * nd2_prev
+ nd2_array(j) = nd2_array(j - 1) + nd2_prev
+ end if
+
+ end do
+
+ end subroutine precompute_indices
+
+end module multiply_kernel
diff --git a/src/multiply_module.f90 b/src/multiply_module.f90
index f50098e27..c8283131b 100644
--- a/src/multiply_module.f90
+++ b/src/multiply_module.f90
@@ -151,14 +151,14 @@ subroutine mat_mult(myid,a,lena,b,lenb,c,lenc,a_b_c,debug)
integer(integ),allocatable :: ibpart_rem(:)
real(double),allocatable :: b_rem(:)
! Remote variables which will point to part_array
- integer(integ),pointer :: nbnab_rem(:)
- integer(integ),pointer :: ibseq_rem(:)
- integer(integ),pointer :: ibind_rem(:)
- integer(integ),pointer :: ib_nd_acc_rem(:)
- integer(integ),pointer :: npxyz_rem(:)
- integer(integ),pointer :: ibndimj_rem(:)
+ integer(integ) :: nbnab_rem_beg, nbnab_rem_end
+ integer(integ) :: ibseq_rem_beg, ibseq_rem_end
+ integer(integ) :: ibind_rem_beg, ibind_rem_end
+ integer(integ) :: ib_nd_acc_rem_beg, ib_nd_acc_rem_end
+ integer(integ) :: npxyz_rem_beg, npxyz_rem_end
+ integer(integ) :: ibndimj_rem_beg, ibndimj_rem_end
! Arrays for remote variables to point to
- integer, target :: part_array(3*a_b_c%parts%mx_mem_grp+ &
+ integer :: part_array(3*a_b_c%parts%mx_mem_grp+ &
5*a_b_c%parts%mx_mem_grp*a_b_c%bmat(1)%mx_abs)
integer, dimension(:), allocatable :: nreqs
integer :: offset,sends,i,j
@@ -220,7 +220,7 @@ subroutine mat_mult(myid,a,lena,b,lenb,c,lenc,a_b_c,debug)
icall=1
ind_part = a_b_c%ahalo%lab_hcell(kpart)
new_partition = .true.
-
+
! Check if this is a periodic image of the previous partition
if(kpart>1) then
if(ind_part.eq.a_b_c%ahalo%lab_hcell(kpart-1)) then
@@ -247,43 +247,58 @@ subroutine mat_mult(myid,a,lena,b,lenb,c,lenc,a_b_c,debug)
mx_msg_per_part,a_b_c%parts,a_b_c%prim,a_b_c%gcs,(recv_part(nnode)-1)*2)
! Now point the _rem variables at the appropriate parts of
! the array where we will receive the data
- offset = 0
- nbnab_rem => part_array(offset+1:offset+n_cont)
- offset = offset+n_cont
- ibind_rem => part_array(offset+1:offset+n_cont)
- offset = offset+n_cont
- ib_nd_acc_rem => part_array(offset+1:offset+n_cont)
- offset = offset+n_cont
- ibseq_rem => part_array(offset+1:offset+ilen2)
- offset = offset+ilen2
- npxyz_rem => part_array(offset+1:offset+3*ilen2)
- offset = offset+3*ilen2
- ibndimj_rem => part_array(offset+1:offset+ilen2)
- if(offset+ilen2>3*a_b_c%parts%mx_mem_grp+ &
+ nbnab_rem_beg = 1
+ nbnab_rem_end = n_cont
+ ibind_rem_beg = nbnab_rem_end + 1
+ ibind_rem_end = nbnab_rem_end + n_cont
+ ib_nd_acc_rem_beg = ibind_rem_end + 1
+ ib_nd_acc_rem_end = ibind_rem_end + n_cont
+ ibseq_rem_beg = ib_nd_acc_rem_end + 1
+ ibseq_rem_end = ib_nd_acc_rem_end + ilen2
+ npxyz_rem_beg = ibseq_rem_end + 1
+ npxyz_rem_end = ibseq_rem_end + 3 * ilen2
+ ibndimj_rem_beg = npxyz_rem_end + 1
+ ibndimj_rem_end = npxyz_rem_end + ilen2
+
+ if(ibndimj_rem_end .gt. &
+ 3*a_b_c%parts%mx_mem_grp+ &
5*a_b_c%parts%mx_mem_grp*a_b_c%bmat(1)%mx_abs) then
call cq_abort('mat_mult: error pointing to part_array ',kpart)
end if
! Create ibpart_rem
- call end_part_comms(myid,n_cont,nbnab_rem,ibind_rem,npxyz_rem,&
+ call end_part_comms(myid,n_cont, &
+ part_array(nbnab_rem_beg:nbnab_rem_end), &
+ part_array(ibind_rem_beg:ibind_rem_end), &
+ part_array(npxyz_rem_beg:npxyz_rem_end), &
ibpart_rem,ncover_yz,a_b_c%gcs%ncoverz)
end if
-
+
k_off=a_b_c%ahalo%lab_hcover(kpart) ! --- offset for pbcs
! Omp master doesn't include a implicit barrier. We want master
! to be finished with comms before calling the multiply kernels
! hence the explicit barrier
!$omp end master
!$omp barrier
-
+
if(a_b_c%mult_type.eq.1) then ! C is full mult
- call m_kern_max( k_off,kpart,ib_nd_acc_rem, ibind_rem,nbnab_rem,&
- ibpart_rem,ibseq_rem,ibndimj_rem,&
+ call m_kern_max( k_off,kpart,&
+ part_array(ib_nd_acc_rem_beg:ib_nd_acc_rem_end), &
+ part_array(ibind_rem_beg:ibind_rem_end),&
+ part_array(nbnab_rem_beg:nbnab_rem_end),&
+ ibpart_rem,&
+ part_array(ibseq_rem_beg:ibseq_rem_end),&
+ part_array(ibndimj_rem_beg:ibndimj_rem_end),&
atrans,b_rem,c,a_b_c%ahalo,a_b_c%chalo,a_b_c%ltrans,&
a_b_c%bmat(1)%mx_abs,a_b_c%parts%mx_mem_grp, &
a_b_c%prim%mx_iprim, lena, lenb_rem, lenc)
else if(a_b_c%mult_type.eq.2) then ! A is partial mult
- call m_kern_min( k_off,kpart,ib_nd_acc_rem, ibind_rem,nbnab_rem,&
- ibpart_rem,ibseq_rem,ibndimj_rem,&
+ call m_kern_min( k_off,kpart, &
+ part_array(ib_nd_acc_rem_beg:ib_nd_acc_rem_end), &
+ part_array(ibind_rem_beg:ibind_rem_end),&
+ part_array(nbnab_rem_beg:nbnab_rem_end),&
+ ibpart_rem,&
+ part_array(ibseq_rem_beg:ibseq_rem_end),&
+ part_array(ibndimj_rem_beg:ibndimj_rem_end),&
atrans,b_rem,c,a_b_c%ahalo,a_b_c%chalo,a_b_c%ltrans,&
a_b_c%bmat(1)%mx_abs,a_b_c%parts%mx_mem_grp, &
a_b_c%prim%mx_iprim, lena, lenb_rem, lenc)
@@ -306,30 +321,30 @@ subroutine mat_mult(myid,a,lena,b,lenb,c,lenc,a_b_c,debug)
!write(io_lun,*) 'Send done ',i,myid
end do
end if
- call my_barrier
+ !call my_barrier
call start_timer(tmr_std_allocation)
deallocate(nreqs,STAT=stat)
if(stat/=0) call cq_abort('mat_mult: error deallocating nreqs')
call stop_timer(tmr_std_allocation)
- call my_barrier
+ !call my_barrier
! --- for type 2, make backward local transpose of A-matrix -----------
if(a_b_c%mult_type.eq.2) then
invdir=1
call loc_trans( a_b_c%ltrans, a_b_c%ahalo,a,lena,atrans,lena,invdir)
end if
- call my_barrier
+ !call my_barrier
call start_timer(tmr_std_allocation)
deallocate(atrans,STAT=stat)
if(stat/=0) call cq_abort('mat_mult: error deallocating atrans')
call stop_timer(tmr_std_allocation)
- call my_barrier
+ !call my_barrier
call start_timer(tmr_std_allocation)
deallocate(ibpart_rem,STAT=stat)
if(stat/=0) call cq_abort('mat_mult: error deallocating ibpart_rem')
deallocate(recv_part,STAT=stat)
if(stat/=0) call cq_abort('mat_mult: error deallocating recv_part')
call stop_timer(tmr_std_allocation)
- call my_barrier
+ !call my_barrier
!deallocate(b_rem,STAT=stat)
!if(stat/=0) call cq_abort('mat_mult: error deallocating b_rem')
!call my_barrier
diff --git a/src/ol_ang_coeff_subs.f90 b/src/ol_ang_coeff_subs.f90
index 30dc724f8..e9720b4b3 100644
--- a/src/ol_ang_coeff_subs.f90
+++ b/src/ol_ang_coeff_subs.f90
@@ -1,4 +1,4 @@
-! -*- mode: F90; mode: font-lock -*-
+! -*- mode: F90; mode: font-lock; column-number-mode: true; vc-back-end: CVS -*-
! ------------------------------------------------------------------------------
! $Id$
! ------------------------------------------------------------------------------
@@ -34,6 +34,9 @@
!! Remove calculation of (-1)**m throughout (replace with test for m even/odd
!! and scaling factor of 1 or -1; also added numbers for module use. Also
!! introduced a universal epsilon parameter for small angles
+!! 2021/02/14 17:30 lionel
+!! Added function for the norm of the cartesian spherical harmonics (re_cart_norm)
+!! Now re_cart_hrmnc depends on re_cart_norm
!! SOURCE
!!
@@ -44,11 +47,17 @@ module angular_coeff_routines
use bessel_integrals, only: fact, doublefact!, lmax_fact
use numbers, only: zero, quarter, half, one, three_halves, two, &
three, pi, eight, very_small
+ use GenComms, only: cq_abort
use timer_module, only: start_timer, stop_timer
use timer_stdclocks_module, only: tmr_std_allocation, tmr_std_basis
implicit none
+ ! -------------------------------------------------------
+ ! RCS ident string for object file id
+ ! -------------------------------------------------------
+ character(len=80), private :: RCSid = "$Id$"
+
! Parameter to avoid small angle errors throughout code
real(double), parameter :: epsilon = 1.0e-4_double
real(double), allocatable, dimension(:,:) :: prefac
@@ -807,8 +816,9 @@ subroutine convert_basis(x,y,z,r,thet,phi)
r = mod_r
end subroutine convert_basis
- !!***
+!!***
+
!!****f* angular_coeff_routines/evaluate_pao *
!!
!! NAME
@@ -830,10 +840,12 @@ end subroutine convert_basis
!! MODIFICATION HISTORY
!! 2019/08/16 15:57 dave
!! Replace spline_ol_intval_new2
+!! 2020/01/21 14:54 Lionel
+!! Add optional possibility for NOT working in polar coord.
+!! ie. stay in Cartesian ones (should be more efficient)
!! SOURCE
!!
-
- subroutine evaluate_pao(i_vector,sp,l,nz,m,x,y,z,pao_val)
+ subroutine evaluate_pao(i_vector,sp,l,nz,m,x,y,z,pao_val,system)
use datatypes
use numbers
@@ -844,20 +856,32 @@ subroutine evaluate_pao(i_vector,sp,l,nz,m,x,y,z,pao_val)
integer, intent(in) :: i_vector ! dummy argument, included to satisfy interface in PAO_grid_transform_module
integer, intent(in) :: sp,l,nz,m
real(double), intent(in) :: x,y,z
+ logical, intent(in), optional :: system
real(double), intent(out) :: pao_val
+ !
real(double) :: r,theta,phi,del_r,y_val,val
- integer :: npts, j
real(double) :: a, b, c, d, r1, r2, r3, r4, rr
+ integer :: npts, j
+ logical :: cartesian
- !convert Cartesians into spherical polars
- call convert_basis(x,y,z,r,theta,phi)
+ ! do we choose which coordinate system (sph is default)
+ if ( present(system) ) then
+ cartesian = system
+ else
+ cartesian = .false.
+ end if
+ !
+ !compute radius
+ r = sqrt(x*x+y*y+z*z)
+ !
!interpolate for required value of radial function
- npts = pao(sp)%angmom(l)%zeta(nz)%length
+ npts = pao(sp)%angmom(l)%zeta(nz)%length
del_r = (pao(sp)%angmom(l)%zeta(nz)%cutoff/&
&(pao(sp)%angmom(l)%zeta(nz)%length-1))
+ !
j = floor(r/del_r) + 1
- pao_val = zero
- if(j+1<=npts) then
+ !
+ if( j+1 <= npts ) then
rr = real(j,double)*del_r
a = (rr - r)/del_r
b = one - a
@@ -868,24 +892,42 @@ subroutine evaluate_pao(i_vector,sp,l,nz,m,x,y,z,pao_val)
r3 = pao(sp)%angmom(l)%zeta(nz)%table2(j)
r4 = pao(sp)%angmom(l)%zeta(nz)%table2(j+1)
pao_val = a*r1 + b*r2 + c*r3 + d*r4
+ else
+ pao_val = zero
end if
- !now multiply by value of spherical harmonic
- y_val = re_sph_hrmnc(l,m,theta,phi)
-
- pao_val = pao_val*y_val
- ! Scale by r**l to remove Siesta normalisation
- if(l==1) then ! p
- pao_val = pao_val*r
- else if(l==2) then ! d
- pao_val = pao_val*r*r
- else if(l==3) then ! f
- pao_val = pao_val*r*r*r
- else if(l>3) then
- write(io_lun,*) '*** ERROR *** ! Angular momentum l>3 not implemented !'
+ !
+ if ( .not. cartesian ) then ! if want to work in Polar coordinates
+ !
+ !convert Cartesians into spherical polars
+ call convert_basis(x,y,z,r,theta,phi)
+ !
+ !now multiply by value of spherical harmonic
+ y_val = re_sph_hrmnc(l,m,theta,phi)
+ !
+ pao_val = pao_val * y_val
+ !
+ ! Scale by r**l to remove Siesta normalisation
+ if(l == 1) then ! p
+ pao_val = pao_val*r
+ else if(l == 2) then ! d
+ pao_val = pao_val*r*r
+ else if(l == 3) then ! f
+ pao_val = pao_val*r*r*r
+ else if(l > 3) then
+ write(io_lun,*) '*** ERROR *** ! Angular momentum l>3 not implemented !'
+ end if
+ !
+ else ! if want to stay in Cartesian
+ !
+ !multiply by value of Cartesian harmonic
+ y_val = re_cart_hrmnc(l,m,x,y,z)
+ !
+ pao_val = pao_val * y_val
+ !
end if
end subroutine evaluate_pao
- !!***
-
+!!***
+
!!****f* angular_coeff_routines/pp_elem *
!!
!! NAME
@@ -957,10 +999,11 @@ end subroutine pp_elem
!! CREATION DATE
!! 30/09/03
!! MODIFICATION HISTORY
-!!
+!! 2023/11/15 lionel
+!! Added dummy argument to satisfy interface in PAO_grid_transform_module
!! SOURCE
!!
- subroutine pao_elem_derivative_2(i_vector,spec,l,nzeta,m,x_i,y_i,z_i,drvtv_val)
+ subroutine pao_elem_derivative_2(i_vector,spec,l,nzeta,m,x_i,y_i,z_i,drvtv_val,sys_dummy)
use datatypes
use numbers
@@ -970,6 +1013,7 @@ subroutine pao_elem_derivative_2(i_vector,spec,l,nzeta,m,x_i,y_i,z_i,drvtv_val)
!RC 09/11/03 using (now debugged) routine pp_elem_derivative (see
! above) as template for this sbrt pao_elem_derivative
real(double), intent(in) :: x_i,y_i,z_i
+ logical, intent(in), optional :: sys_dummy
real(double), intent(out) :: drvtv_val
integer, intent(in) :: i_vector, l, m, spec, nzeta
integer :: n1,n2
@@ -2064,8 +2108,233 @@ subroutine set_prefac_real(n)
call stop_timer(tmr_std_basis)
return
end subroutine set_prefac_real
+ !!***
+
+!!****f* angular_coeff_routines/re_cart_norm *
+!!
+!! NAME
+!! re_sph_hrmnc
+!! USAGE
+!! re_cart_nom(l,m,norm)
+!! PURPOSE
+!! return the value of the cartesian spherical harmonic
+!! INPUTS
+!! l,m angular momenta
+!! USES
+!! datatypes
+!! AUTHOR
+!! L Truflandier
+!! CREATION DATE
+!! 20/01/21
+!! MODIFICATION HISTORY
+!!
+!! SOURCE
+!!
+ function re_cart_norm(l,m)
+
+ use datatypes
+ use numbers
+ use GenComms,ONLY: cq_abort
+
+ implicit none
+ !
+ integer, intent(in) :: l, m
+ !
+ real(double), parameter :: a1g_norm = sqrt(one/(four*pi))
+ real(double), parameter :: t1u_norm = sqrt(three/(four*pi))
+ real(double), parameter :: t2g_norm = sqrt(fifteen/(four*pi))
+ real(double), parameter :: eg_a_norm = sqrt(fifteen/(sixteen*pi))
+ real(double), parameter :: eg_b_norm = sqrt(five/(sixteen*pi))
+ !
+ real(double), parameter :: f0_norm = sqrt(seven/(sixteen*pi))
+ real(double), parameter :: f1_norm = sqrt( 21.0_double/(sixteen*two*pi))
+ real(double), parameter :: f2_norm = sqrt(105.0_double/(sixteen*pi))
+ real(double), parameter :: f3_norm = sqrt( 35.0_double/(sixteen*two*pi))
+ !
+ real(double) :: norm, re_cart_norm
+ !
+ if(l == 0) then !s-type function
+ !
+ norm = a1g_norm
+ !
+ else if(l == 1) then !p-type function
+ !
+ norm = t1u_norm
+ !
+ else if(l == 2) then !d-type function
+ !
+ select case( m )
+
+ case( 2 ) ! d_{x2-y2}
+ norm = eg_a_norm !(x*x-y*y)
+ case( 1 ) ! d_{xz}
+ norm = t2g_norm !(x*z)
+ case( 0 ) ! d_{z2}
+ norm = eg_b_norm!(3*z*z-r*r)
+ case(-1 ) ! d_{yz}
+ norm = t2g_norm !(y*z)
+ case(-2 ) ! d_{xy}
+ norm = t2g_norm !(x*y)
+ case default
+ call cq_abort('re_cart_norm/problem with (l,m) =',l,m)
+ end select
+ !
+ else if(l == 3) then !f-type function
+ !
+ select case( m )
+ case( 3 ) ! f_{x3-xy2}
+ norm = f3_norm !*(x*x - 3*y*y)*x
+ case( 2 ) ! f_{zx2-zy2}
+ norm = f2_norm !*(x*x - y*y)*z
+ case( 1 ) ! f_{xz2}
+ norm = f1_norm !*(5*z*z - r*r)*x
+ case( 0 ) ! f_{z3}
+ norm = f0_norm !*(5*z*z - 3*r*r)*z
+ case(-1 ) ! f_{yz2}
+ norm = f1_norm !(5*z*z - r*r)*y
+ case(-2 ) ! f_{xyz}
+ norm = f2_norm !x*y*z
+ case(-3 ) ! f_{3yx2-y3}
+ norm = f3_norm !(3*x*x - y*y)*y
+ case default
+ call cq_abort('re_cart_norm/problem with (l,m) =',l,m)
+ end select
+ !
+ else if( l > 3) then
+ call cq_abort('re_cart_norm/not implemented for l > 3')
+ else
+ call cq_abort('re_cart_norm/problem with l =',l)
+ end if
+
+ re_cart_norm = norm
+
+ end function re_cart_norm
!!***
+!!****f* angular_coeff_routines/re_cart_hrmnc *
+!!
+!! NAME
+!! re_cart_hrmnc
+!! USAGE
+!! re_cart_hrmnc(l,m,x,y,z)
+!! PURPOSE
+!! calculates value of real Cartesian harmonic
+!! INPUTS
+!! l,m angular momenta
+!! x,y,z Cartesian coordinates
+!! USES
+!! datatypes
+!! AUTHOR
+!! L Truflandier
+!! CREATION DATE
+!! 20/01/21
+!! MODIFICATION HISTORY
+!!
+!! SOURCE
+!!
+ function re_cart_hrmnc(l,m,x,y,z)
+
+ use datatypes
+ use numbers
+
+ implicit none
+ !
+ !function to return the value of real Cartesian harmonic
+ !at given position (x,y,z)
+ !
+ integer, intent(in) :: l, m
+ real(double), intent(in) :: x, y, z
+ !
+ real(double) :: r, re_cart_hrmnc, y_val
+ integer :: i
+ !
+ r = sqrt(x*x+y*y+z*z) ; y_val = zero
+ !
+ !
+ if(l == 0) then !s-type function
+ !
+ y_val = one
+ !
+ else if(l == 1) then !p-type function
+ !
+ r_p: if (r > zero) then
+ !
+ select case( m )
+ case( 1 ) !p_x
+ y_val = x
+ case( 0 ) !p_z
+ y_val = z
+ case(-1 ) !p_y
+ y_val = y
+ case default
+ call cq_abort('re_cart_hrmnc/problem with (l,m) =',l,m)
+ end select
+ !
+ else
+ y_val = zero
+ end if r_p
+ !
+ else if(l == 2) then !d-type function
+ !
+ r_d: if (r > zero) then
+ !
+ select case( m )
+ case( 2 ) ! d_{x2-y2}
+ y_val = (x*x-y*y)
+ case( 1 ) ! d_{xz}
+ y_val = (x*z)
+ case( 0 ) ! d_{z2}
+ y_val = (3*z*z-r*r)
+ case(-1 ) ! d_{yz}
+ y_val = (y*z)
+ case(-2 ) ! d_{xy}
+ y_val = -(x*y) ! take care phase factor
+ case default
+ call cq_abort('re_cart_hrmnc/problem with (l,m) =',l,m)
+ end select
+ !
+ else
+ y_val = zero
+ end if r_d
+ !
+ else if(l == 3) then !f-type function
+ !
+ r_f: if (r > zero) then
+ !
+ select case( m )
+ case( 3 ) ! f_{x3-xy2}
+ y_val = (x*x - 3*y*y)*x
+ case( 2 ) ! f_{zx2-zy2}
+ y_val = (x*x - y*y)*z
+ case( 1 ) ! f_{xz2}
+ y_val = (5*z*z - r*r)*x
+ case( 0 ) ! f_{z3}
+ y_val = (5*z*z - 3*r*r)*z
+ case(-1 ) ! f_{yz2}
+ y_val = (5*z*z - r*r)*y
+ case(-2 ) ! f_{xyz}
+ y_val = x*y*z
+ case(-3 ) ! f_{3yx2-y3}
+ y_val = (3*x*x - y*y)*y
+ case default
+ call cq_abort('re_cart_hrmnc/problem with (l,m) =',l,m)
+ end select
+ !
+ else
+ y_val = zero
+ end if r_f
+ !
+ else if( l > 3) then
+ call cq_abort('re_cart_hrmnc/not implemented for l > 3')
+ else
+ call cq_abort('re_cart_hrmnc/problem with l =',l)
+ end if
+
+ re_cart_hrmnc = y_val * re_cart_norm(l,m)
+
+ end function re_cart_hrmnc
+!!***
+
!!****f* angular_coeff_routines/re_sph_hrmnc *
!!
!! NAME
diff --git a/src/pseudo_tm_info.f90 b/src/pseudo_tm_info.f90
index fcc3ea170..3a02a6880 100644
--- a/src/pseudo_tm_info.f90
+++ b/src/pseudo_tm_info.f90
@@ -1052,9 +1052,20 @@ subroutine read_header_tmp(n_orbnl, lmax_basis, n_pjnl, zval, z, unit, xc_func,
if(leqi(trim_line(2:4),'ATM')) pseudo_type = 1 ! Siesta-type
end if
else if (leqi(trim_line(1:14),' 2) verbose = .true.
+
+ call start_timer(tmr_std_initialisation)
+
+ species_loop: do nsp = 1, n_species
+
+ l_nzeta = 0
+ !
+ if(inode == ionode) then
+ !
+ ! setup gto filename, eg for H atom we get H.gto
+ gto_file(nsp) = trim(species_label(nsp))//trim('.gto')
+ gto(nsp)%label = trim(species_label(nsp))
+ !
+ open(unit=gto_unit,file=gto_file(nsp),status="old",action="read", &
+ iostat=ios,position="rewind")
+ if(ios /= 0) call cq_abort('read_gto: failed to open input file')
+ !
+ match = 0
+ !
+ ! search for atom name
+ do while (match == 0)
+ read(unit=gto_unit,fmt=*,iostat=ios) match_atom
+ match_atom = trim(match_atom)
+ if (ios < 0) call cq_abort('read_gto: end error GTO data file', gto_unit)
+ if (ios > 0) call cq_abort('read_gto: read error GTO data file',gto_unit)
+ if (match_atom == gto(nsp)%label) then
+ match = 1
+ end if
+ end do
+ !
+ ! get total number of zeta
+ read(gto_unit,fmt=*,iostat=ios) gto(nsp)%n_zeta_tot
+ if (ios < 0) call cq_abort('read_gto: end error GTO data file',gto_unit)
+ if (ios > 0) call cq_abort('read_gto: read error GTO data file',gto_unit)
+ !
+ if (iprint > 2) write(io_lun,fmt='(10x,"######## read GTO for ",A2,"/n_zeta_tot =",I3," ########")') &
+ gto(nsp)%label, gto(nsp)%n_zeta_tot
+ !
+ end if
+ !
+ if(inode == ionode) then
+ !
+ gto(nsp)%nsf_gto_tot = 0
+ gto(nsp)%nsf_sph_tot = 0
+ !
+ ! search for greatest angular momentum among zetas
+ do i = 1, gto(nsp)%n_zeta_tot
+ !
+ read(unit=gto_unit,fmt=*,iostat=ios) tmp_nl, tmp_nG, tmp_occ, tmp_kind
+ if (ios < 0) call cq_abort('read_gto: end error GTO data file', gto_unit)
+ if (ios > 0) call cq_abort('read_gto: read error GTO data file',gto_unit)
+ !
+ ! convert angular momentum name to integer
+ tmp_n = tmp_nl(1:1)
+ tmp_l = tmp_nl(2:2)
+ !
+ call angmom_convert(tmp_l,l_value)
+ !write(*,*) 'inode', inode, 'nsp', nsp, 'n_zeta', i,'tmp_nl', tmp_nl, 'l_value', l_value
+ !
+ l_max = 0
+ ! get max angular momentum value
+ if ( l_value > l_max ) then
+ l_max = l_value
+ end if
+ !
+ ! count and store number of zeta for each l value
+ do l = 0, max_angmom
+ if ( l_value == l ) then
+ l_nzeta(l) = l_nzeta(l) + 1
+ end if
+ end do
+ !
+ ! pass through GTO's parameters
+ do j = 1, tmp_nG
+ read(unit=gto_unit,fmt=*,iostat=ios)
+ if (ios < 0) call cq_abort('read_gto: end error GTO data file', gto_unit)
+ if (ios > 0) call cq_abort('read_gto: read error GTO data file',gto_unit)
+ !
+ end do
+ !
+ end do
+ !
+ gto(nsp)%greatest_angmom = l_max
+ !
+ !if ( sum(l_nzeta) /= gto(nsp)%n_zeta_tot ) &
+ ! call cq_abort('read_gto: problem with number of zeta', gto_unit)
+ !
+ end if
+ ! Broadcast to all the proc.
+ call gcopy( gto(nsp)%label, 2)
+ call gcopy( gto(nsp)%greatest_angmom )
+ call gcopy( gto(nsp)%n_zeta_tot )
+ !
+ !write(*,*) 'inode', inode, 'nsp', nsp, 'gto(nsp)%greatest_angmom', gto(nsp)%greatest_angmom
+ !write(*,*) 'inode', inode, 'nsp', nsp, 'gto(nsp)%label', gto(nsp)%label
+ if ( inode == ionode .and. iprint > 2 ) write(io_lun,fmt='(10x,"greatest angular momentum =",i4)')&
+ gto(nsp)%greatest_angmom
+ !
+ allocate( gto(nsp)%angmom( 0:gto(nsp)%greatest_angmom ) )
+ !
+ if(inode == ionode) then
+ do i = 0, gto(nsp)%greatest_angmom
+ gto(nsp)%angmom(i)%n_zeta_in_angmom = l_nzeta(i)
+ gto(nsp)%angmom(i)%l_value = i
+ gto(nsp)%angmom(i)%l_name = l_name_uppercase(i)
+ !write(*,*) 'inode', inode, 'nsp', nsp, 'angmom', i
+ !write(*,*) 'inode', inode, ' gto(nsp)%angmom(i)%n_zeta_in_angmom', gto(nsp)%angmom(i)%n_zeta_in_angmom
+ !write(*,*) 'inode', inode, ' gto(nsp)%angmom(i)%l_value', gto(nsp)%angmom(i)%l_value
+ !write(*,*) 'inode', inode, ' gto(nsp)%angmom(i)%l_name ', gto(nsp)%angmom(i)%l_name
+
+ end do
+ end if
+ !
+ do i = 0, gto(nsp)%greatest_angmom
+ !
+ call gcopy( gto(nsp)%angmom(i)%n_zeta_in_angmom )
+ call gcopy( gto(nsp)%angmom(i)%l_value )
+ call gcopy( gto(nsp)%angmom(i)%l_name, 1)
+ !
+ !write(*,*) 'inode', inode, 'nsp', nsp, 'angmom', i
+ !write(*,*) 'inode', inode,'nsp', nsp, 'i', i, gto(nsp)%angmom(i)%n_zeta_in_angmom
+ !write(*,*) 'inode', inode, ' gto(nsp)%angmom(i)%l_value', gto(nsp)%angmom(i)%l_value
+ !write(*,*) 'inode', inode, ' gto(nsp)%angmom(i)%l_name ', gto(nsp)%angmom(i)%l_name
+ !
+ allocate( gto(nsp)%angmom(i)%zeta( gto(nsp)%angmom(i)%n_zeta_in_angmom ) )
+ !
+ end do
+
+ if ( inode == ionode ) then
+ !
+ ! rewind and perform reading to grab GTO parameters
+ rewind(gto_unit,iostat=ios)
+ if (ios > 0) call cq_abort('read_gto: rewind error',gto_unit)
+ !
+ ! skip first 2 lines
+ read(gto_unit,fmt=*,iostat=ios)
+ read(gto_unit,fmt=*,iostat=ios)
+ end if
+ !
+ do l = 0, gto(nsp)%greatest_angmom
+ !
+ do i = 1, gto(nsp)%angmom(l)%n_zeta_in_angmom
+ !
+ if ( inode == ionode ) then
+ !
+ read(unit=gto_unit,fmt=*,iostat=ios) tmp_nl, tmp_nG, tmp_occ, tmp_kind
+ if (ios < 0) call cq_abort('read_gto: end error GTO data file', gto_unit)
+ if (ios > 0) call cq_abort('read_gto: read error GTO data file',gto_unit)
+ !
+ gto(nsp)%angmom(l)%zeta(i)%ngto = tmp_nG
+ gto(nsp)%angmom(l)%zeta(i)%occ = tmp_occ
+ gto(nsp)%angmom(l)%zeta(i)%kind = tmp_kind
+
+ tmp_n = tmp_nl(1:1) ; read(tmp_n,*) tmp_n_int
+ gto(nsp)%angmom(l)%zeta(i)%n = tmp_n_int
+ !
+ end if
+ !
+ call gcopy(gto(nsp)%angmom(l)%zeta(i)%ngto)
+ call gcopy(gto(nsp)%angmom(l)%zeta(i)%occ )
+ call gcopy(gto(nsp)%angmom(l)%zeta(i)%kind)
+ call gcopy(gto(nsp)%angmom(l)%zeta(i)%n )
+ !
+ if ( inode == ionode .and. iprint > 2 ) then
+ write(io_lun,fmt='(10x,">> zeta:",x,i2," / state",x,i2,A)') &
+ i, gto(nsp)%angmom(l)%zeta(i)%n, gto(nsp)%angmom(l)%l_name
+ write(io_lun,fmt='(10x,"occupation =",x,f4.2)') &
+ gto(nsp)%angmom(l)%zeta(i)%occ
+ write(io_lun,fmt='(10x,"kind =",x,a12)') &
+ zeta_kind (gto(nsp)%angmom(l)%zeta(i)%kind )
+ end if
+
+ allocate( gto(nsp)%angmom(l)%zeta(i)%a ( gto(nsp)%angmom(l)%zeta(i)%ngto) )
+ gto(nsp)%angmom(l)%zeta(i)%a = zero
+ allocate( gto(nsp)%angmom(l)%zeta(i)%d ( gto(nsp)%angmom(l)%zeta(i)%ngto) )
+ gto(nsp)%angmom(l)%zeta(i)%d = zero
+ allocate( gto(nsp)%angmom(l)%zeta(i)%c ( gto(nsp)%angmom(l)%zeta(i)%ngto) )
+ gto(nsp)%angmom(l)%zeta(i)%c = zero
+ !
+ if ( inode == ionode ) then
+ !
+ do j = 1, gto(nsp)%angmom(l)%zeta(i)%ngto
+ !
+ read(unit=gto_unit,fmt=*,iostat=ios) &
+ gto(nsp)%angmom(l)%zeta(i)%a(j), &
+ gto(nsp)%angmom(l)%zeta(i)%d(j), &
+ gto(nsp)%angmom(l)%zeta(i)%c(j)
+ if (ios < 0) call cq_abort('read_gto: end error GTO data file', gto_unit)
+ if (ios > 0) call cq_abort('read_gto: read error GTO data file',gto_unit)
+ !
+ if ( iprint > 2 ) write(io_lun,fmt='(10x,"GTO primitive",x,i3,":",x,"a =",x,f16.10,x,"d =",x,f16.10)') &
+ j, gto(nsp)%angmom(l)%zeta(i)%a(j), gto(nsp)%angmom(l)%zeta(i)%d(j)
+ !
+ end do
+ !
+ end if
+ !
+ call gcopy( gto(nsp)%angmom(l)%zeta(i)%a, gto(nsp)%angmom(l)%zeta(i)%ngto )
+ call gcopy( gto(nsp)%angmom(l)%zeta(i)%d, gto(nsp)%angmom(l)%zeta(i)%ngto )
+ call gcopy( gto(nsp)%angmom(l)%zeta(i)%c, gto(nsp)%angmom(l)%zeta(i)%ngto )
+ !
+ end do
+ !
+ if ( inode == ionode ) then
+ ! given angular momentum, compute the number of cartesian Gaussian functions
+ gto(nsp)%angmom(l)%nf_gto = (l+1)*(l+2)/2
+ ! given angular momentum, accumulate the number of cartesian Gaussian functions
+ do i = 1, gto(nsp)%angmom(l)%n_zeta_in_angmom
+ gto(nsp)%nsf_gto_tot = gto(nsp)%nsf_gto_tot + gto(nsp)%angmom(l)%nf_gto
+ end do
+ !
+ ! given angular momentum, compute the number of spherical harmonic functions
+ gto(nsp)%angmom(l)%nf_sph = 2*l + 1
+ ! given angular momentum, accumulate the number of spherical harmonic functions
+ do i = 1, gto(nsp)%angmom(l)%n_zeta_in_angmom
+ gto(nsp)%nsf_sph_tot = gto(nsp)%nsf_sph_tot + gto(nsp)%angmom(l)%nf_sph
+ end do
+ !
+ end if
+ !
+ call gcopy( gto(nsp)%angmom(l)%nf_gto )
+ call gcopy( gto(nsp)%angmom(l)%nf_sph )
+ !
+ if (inode == ionode .and. iprint > 2 ) write(io_lun,fmt='(10x,"number of cartesian Gaussian functions =",x,i4)') &
+ gto(nsp)%angmom(l)%nf_gto
+ !
+ allocate( gto(nsp)%angmom(l)%nx( (l+1)*(l+2)/2 ) )
+ allocate( gto(nsp)%angmom(l)%ny( (l+1)*(l+2)/2 ) )
+ allocate( gto(nsp)%angmom(l)%nz( (l+1)*(l+2)/2 ) )
+ allocate( gto(nsp)%angmom(l)%nt( (l+1)*(l+2)/2 ) )
+ allocate( gto(nsp)%angmom(l)%norm( (l+1)*(l+2)/2 ) )
+ !
+ if ( inode == ionode ) then
+ !
+ call cart_gauss_function( inode, ionode, &
+ gto(nsp)%angmom(l)%l_value, &
+ gto(nsp)%angmom(l)%l_name, &
+ 0.0d0,&
+ gto(nsp)%angmom(l)%nx, &
+ gto(nsp)%angmom(l)%ny, &
+ gto(nsp)%angmom(l)%nz, &
+ gto(nsp)%angmom(l)%nt, verbose )
+ !
+ end if
+ !
+ call gcopy( gto(nsp)%angmom(l)%nx, gto(nsp)%angmom(l)%nf_gto )
+ call gcopy( gto(nsp)%angmom(l)%ny, gto(nsp)%angmom(l)%nf_gto )
+ call gcopy( gto(nsp)%angmom(l)%nz, gto(nsp)%angmom(l)%nf_gto )
+ !
+ do j = 1, gto(nsp)%angmom(l)%nf_gto
+ call gcopy( gto(nsp)%angmom(l)%nt(j), 12 )
+ end do
+ !
+ end do
+ !
+ if (inode == ionode .and. iprint > 2 ) write(io_lun,fmt='(10x,">> size of the cartesian gaussian basis set =", i4)') &
+ gto(nsp)%nsf_gto_tot
+ !
+ call gcopy( gto(nsp)%nsf_gto_tot )
+ call gcopy( gto(nsp)%nsf_sph_tot )
+ !
+ do l1 = 0, gto(nsp)%greatest_angmom
+
+ allocate( gto(nsp)%angmom(l1)%transform_sph(-l1:+l1) )
+ !if (inode == ionode) write(io_lun,*) l1
+ if (inode == ionode .and. iprint > 2 ) write(io_lun,fmt='(10x,"number of cartesian spherical functions =",x,i4)') &
+ gto(nsp)%angmom(l1)%nf_sph
+
+ do m1 = -l1, +l1
+
+ if ( inode == ionode ) then
+
+ call sph_gauss_function( inode, ionode, l1, m1, sph_size, sph_nx, sph_ny, sph_nz, sph_coef, sph_name, verbose)
+ gto(nsp)%angmom(l1)%transform_sph(m1)%size = sph_size
+
+ !write(*,*) 'nsp, l1, m1, coef 0', nsp, l1, m1, sph_coef
+
+ end if
+ !
+ call gcopy( gto(nsp)%angmom(l1)%transform_sph(m1)%size )
+ !
+ allocate( gto(nsp)%angmom(l1)%transform_sph(m1)%nx( gto(nsp)%angmom(l1)%transform_sph(m1)%size ) )
+ allocate( gto(nsp)%angmom(l1)%transform_sph(m1)%ny( gto(nsp)%angmom(l1)%transform_sph(m1)%size ) )
+ allocate( gto(nsp)%angmom(l1)%transform_sph(m1)%nz( gto(nsp)%angmom(l1)%transform_sph(m1)%size ) )
+ allocate( gto(nsp)%angmom(l1)%transform_sph(m1)%c ( gto(nsp)%angmom(l1)%transform_sph(m1)%size ) )
+ !
+ if ( inode == ionode ) then
+ !
+ gto(nsp)%angmom(l1)%transform_sph(m1)%nt = sph_name
+ !
+ gto(nsp)%angmom(l1)%transform_sph(m1)%nx = sph_nx ( 1:gto(nsp)%angmom(l1)%transform_sph(m1)%size )
+ gto(nsp)%angmom(l1)%transform_sph(m1)%ny = sph_ny ( 1:gto(nsp)%angmom(l1)%transform_sph(m1)%size )
+ gto(nsp)%angmom(l1)%transform_sph(m1)%nz = sph_nz ( 1:gto(nsp)%angmom(l1)%transform_sph(m1)%size )
+ gto(nsp)%angmom(l1)%transform_sph(m1)%c = sph_coef(1:gto(nsp)%angmom(l1)%transform_sph(m1)%size )
+ !write(*,*) 'nsp, l1, m1, coef 1', nsp, l1, m1, sph_coef(1:gto(nsp)%angmom(l1)%transform_sph(m1)%size)
+
+ !write(*,*) 'ionode', inode, gto(nsp)%angmom(l1)%transform_sph(m1)%nx, gto(nsp)%angmom(l1)%transform_sph(m1)%ny,&
+ ! gto(nsp)%angmom(l1)%transform_sph(m1)%nz, gto(nsp)%angmom(l1)%transform_sph(m1)%c
+ end if
+ !
+ call gcopy( gto(nsp)%angmom(l1)%transform_sph(m1)%nt, 12 )
+ !
+ call gcopy( gto(nsp)%angmom(l1)%transform_sph(m1)%nx, gto(nsp)%angmom(l1)%transform_sph(m1)%size )
+ call gcopy( gto(nsp)%angmom(l1)%transform_sph(m1)%ny, gto(nsp)%angmom(l1)%transform_sph(m1)%size )
+ call gcopy( gto(nsp)%angmom(l1)%transform_sph(m1)%nz, gto(nsp)%angmom(l1)%transform_sph(m1)%size )
+ !if (inode == ionode) write(*,*) 'nsp, l1, m1, coef 2', nsp, l1, m1, gto(nsp)%angmom(l1)%transform_sph(m1)%c
+ call gcopy( gto(nsp)%angmom(l1)%transform_sph(m1)%c, gto(nsp)%angmom(l1)%transform_sph(m1)%size )
+
+ end do
+ end do
+ !
+ if (inode == ionode .and. iprint > 2) write(io_lun,fmt='(10x,">> size of the cartesian spherical basis set =", i4)') &
+ gto(nsp)%nsf_sph_tot
+ !
+ !#############################
+ ! sf derived type for Conquest
+ !
+ allocate( gto(nsp)%sf( gto(nsp)%nsf_sph_tot ) )
+ !
+ count = 1
+ angu_loop: do l1 = 0, gto(nsp)%greatest_angmom
+
+ zeta_loop: do acz1 = 1, gto(nsp)%angmom(l1)%n_zeta_in_angmom
+
+ magn_loop: do m1 = -l1, l1
+
+ if ( inode == ionode ) gto(nsp)%sf(count)%sph_size = gto(nsp)%angmom(l1)%transform_sph(m1)%size
+
+ call gcopy( gto(nsp)%sf( count )%sph_size )
+
+ allocate( gto(nsp)%sf(count)%sph_nx ( gto(nsp)%angmom(l1)%transform_sph(m1)%size ) )
+ allocate( gto(nsp)%sf(count)%sph_ny ( gto(nsp)%angmom(l1)%transform_sph(m1)%size ) )
+ allocate( gto(nsp)%sf(count)%sph_nz ( gto(nsp)%angmom(l1)%transform_sph(m1)%size ) )
+ allocate( gto(nsp)%sf(count)%sph_c ( gto(nsp)%angmom(l1)%transform_sph(m1)%size ) )
+
+ sph_loop: do n1 = 1, gto(nsp)%angmom(l1)%transform_sph(m1)%size
+
+ if ( inode == ionode ) then
+ gto(nsp)%sf( count )%sph_nx(n1) = gto(nsp)%angmom(l1)%transform_sph(m1)%nx( n1 )
+ gto(nsp)%sf( count )%sph_ny(n1) = gto(nsp)%angmom(l1)%transform_sph(m1)%ny( n1 )
+ gto(nsp)%sf( count )%sph_nz(n1) = gto(nsp)%angmom(l1)%transform_sph(m1)%nz( n1 )
+ gto(nsp)%sf( count )%sph_c (n1) = gto(nsp)%angmom(l1)%transform_sph(m1)%c ( n1 )
+
+ !write(*,*) 'l1, acz1, m1, n1', l1, acz1, m1, n1, 'nx', gto(nsp)%sf( count )%sph_nx(n1), &
+ ! 'ny', gto(nsp)%sf( count )%sph_ny(n1), 'nz', gto(nsp)%sf( count )%sph_nz(n1), inode
+
+ end if
+
+ call gcopy( gto(nsp)%sf( count )%sph_nx(n1) )
+ call gcopy( gto(nsp)%sf( count )%sph_ny(n1) )
+ call gcopy( gto(nsp)%sf( count )%sph_nz(n1) )
+ call gcopy( gto(nsp)%sf( count )%sph_c (n1) )
+
+ end do sph_loop
+
+ !if ( inode == 1 ) write(*,*) inode, 'l1, acz1, m1', l1, acz1, m1, 'nx', gto(nsp)%sf( count )%sph_nx
+ !if ( inode == 1 ) write(*,*) inode, 'l1, acz1, m1', l1, acz1, m1, 'ny', gto(nsp)%sf( count )%sph_ny
+ !if ( inode == 1 ) write(*,*) inode, 'l1, acz1, m1', l1, acz1, m1, 'nz', gto(nsp)%sf( count )%sph_nz
+
+ !if ( inode == 2 ) write(*,*) inode, 'l1, acz1, m1', l1, acz1, m1, 'nx', gto(nsp)%sf( count )%sph_nx
+ !if ( inode == 2 ) write(*,*) inode, 'l1, acz1, m1', l1, acz1, m1, 'ny', gto(nsp)%sf( count )%sph_ny
+ !if ( inode == 2 ) write(*,*) inode, 'l1, acz1, m1', l1, acz1, m1, 'nz', gto(nsp)%sf( count )%sph_nz
+
+ gto(nsp)%sf( count )%nt = gto(nsp)%angmom(l1)%transform_sph(m1)%nt
+ gto(nsp)%sf( count )%ngto = gto(nsp)%angmom(l1)%zeta(acz1)%ngto
+ gto(nsp)%sf( count )%norm = re_cart_norm(l1,m1)
+
+ call gcopy( gto(nsp)%sf( count )%nt, 12 )
+ call gcopy( gto(nsp)%sf( count )%ngto )
+ call gcopy( gto(nsp)%sf( count )%norm )
+
+ !write(*,*) 'inode', inode, 'l1, acz1, m1', l1, acz1, m1, 'ex, ey, ez', &
+ ! gto(nsp)%sf( count )%sph_nx, gto(nsp)%sf( count )%sph_ny, gto(nsp)%sf( count )%sph_nz, &
+ ! 'nt', gto(nsp)%sf( count )%nt, 'norm', gto(nsp)%sf( count )%norm, 'count', count, &
+ ! 'ngto', gto(nsp)%sf( count )%ngto
+
+ allocate( gto(nsp)%sf( count )%a( gto(nsp)%sf( count )%ngto ) )
+ allocate( gto(nsp)%sf( count )%d( gto(nsp)%sf( count )%ngto ) )
+ allocate( gto(nsp)%sf( count )%c( gto(nsp)%sf( count )%ngto ) )
+
+ primitive: do p = 1, gto(nsp)%angmom(l1)%zeta(acz1)%ngto
+
+ if ( inode == ionode ) then
+
+ gto(nsp)%sf( count )%a( p ) = gto(nsp)%angmom(l1)%zeta(acz1)%a( p )
+ gto(nsp)%sf( count )%d( p ) = gto(nsp)%angmom(l1)%zeta(acz1)%d( p )
+ gto(nsp)%sf( count )%c( p ) = gto(nsp)%angmom(l1)%zeta(acz1)%c( p )
+
+ end if
+
+ !write(*,*) 'inode', inode, 'nsp', nsp, 'count', count, 'p', p, ' gto(nsp)%sf( count )%a( p )', &
+ ! gto(nsp)%sf( count )%a( p )
+ !write(*,*) 'inode', inode, 'nsp', nsp, 'count', count, 'p', p, ' gto(nsp)%sf( count )%d( p )', &
+ ! gto(nsp)%sf( count )%d( p )
+ !write(*,*) 'inode', inode, 'nsp', nsp, 'count', count, 'p', p, ' gto(nsp)%sf( count )%c( p )', &
+ ! gto(nsp)%sf( count )%c( p )
+
+
+ end do primitive
+ call gcopy( gto(nsp)%sf( count )%a, gto(nsp)%angmom(l1)%zeta(acz1)%ngto )
+ call gcopy( gto(nsp)%sf( count )%d, gto(nsp)%angmom(l1)%zeta(acz1)%ngto )
+ call gcopy( gto(nsp)%sf( count )%c, gto(nsp)%angmom(l1)%zeta(acz1)%ngto )
+
+ !write(*,*) 'inode', inode, 'nsp', nsp, 'count', count, 'p', p, ' gto(nsp)%sf( count )%a( p )', &
+ ! gto(nsp)%sf( count )%a
+ !write(*,*) 'inode', inode, 'nsp', nsp, 'count', count, 'p', p, ' gto(nsp)%sf( count )%d( p )', &
+ ! gto(nsp)%sf( count )%d
+ !write(*,*) 'inode', inode, 'nsp', nsp, 'count', count, 'p', p, ' gto(nsp)%sf( count )%c( p )', &
+ ! gto(nsp)%sf( count )%c
+
+ count = count + 1
+ end do magn_loop
+ end do zeta_loop
+ end do angu_loop
+
+
+!!$ allocate( gto(nsp)%sf( gto(nsp)%nsf_gto_tot ) )
+!!$ !
+!!$ count = 1
+!!$ angu_loop: do l1 = 0, gto(nsp)%greatest_angmom
+!!$
+!!$ zeta_loop: do acz1 = 1, gto(nsp)%angmom(l1)%n_zeta_in_angmom
+!!$
+!!$ magn_loop: do m1 = 1, gto(nsp)%angmom(l1)%nf_gto
+!!$
+!!$
+!!$
+!!$ if ( inode == ionode ) then
+!!$ gto(nsp)%sf( count )%nx = gto(nsp)%angmom(l1)%nx( m1 )
+!!$ gto(nsp)%sf( count )%ny = gto(nsp)%angmom(l1)%ny( m1 )
+!!$ gto(nsp)%sf( count )%nz = gto(nsp)%angmom(l1)%nz( m1 )
+!!$ gto(nsp)%sf( count )%nt = gto(nsp)%angmom(l1)%nt( m1 )
+!!$ gto(nsp)%sf( count )%ngto = gto(nsp)%angmom(l1)%zeta(acz1)%ngto
+!!$ !gto(nsp)%sf( count )%norm = l_cart_norm(l1)
+!!$ gto(nsp)%sf( count )%norm = re_cart_norm(l1,m1-l1-1)
+!!$ end if
+!!$
+!!$ call gcopy( gto(nsp)%sf( count )%nx )
+!!$ call gcopy( gto(nsp)%sf( count )%ny )
+!!$ call gcopy( gto(nsp)%sf( count )%nz )
+!!$ call gcopy( gto(nsp)%sf( count )%nt, 12)
+!!$ call gcopy( gto(nsp)%sf( count )%ngto)
+!!$ call gcopy( gto(nsp)%sf( count )%norm)
+!!$
+!!$ print*,'inode', inode, 'l1, acz1, m1', l1, acz1, m1, 'ex, ey, ez', &
+!!$ gto(nsp)%sf( count )%nx, gto(nsp)%sf( count )%ny, gto(nsp)%sf( count )%nz, &
+!!$ 'nt', gto(nsp)%sf( count )%nt, 'norm', gto(nsp)%sf( count )%norm, 'count', count, &
+!!$ 'ngto', gto(nsp)%sf( count )%ngto
+!!$
+!!$ !if (.not. allocated( gto(nsp)%sf( count )%a ) ) &
+!!$ allocate( gto(nsp)%sf( count )%a( gto(nsp)%sf( count )%ngto ) )
+!!$ !if (.not. allocated( gto(nsp)%sf( count )%d ) ) &
+!!$ allocate( gto(nsp)%sf( count )%d( gto(nsp)%sf( count )%ngto ) )
+!!$ !if (.not. allocated( gto(nsp)%sf( count )%c ) ) &
+!!$ allocate( gto(nsp)%sf( count )%c( gto(nsp)%sf( count )%ngto ) )
+!!$
+!!$ primitive: do p = 1, gto(nsp)%angmom(l1)%zeta(acz1)%ngto
+!!$
+!!$ if ( inode == ionode ) then
+!!$
+!!$ gto(nsp)%sf( count )%a( p ) = gto(nsp)%angmom(l1)%zeta(acz1)%a( p )
+!!$ gto(nsp)%sf( count )%d( p ) = gto(nsp)%angmom(l1)%zeta(acz1)%d( p )
+!!$ gto(nsp)%sf( count )%c( p ) = gto(nsp)%angmom(l1)%zeta(acz1)%c( p )
+!!$
+!!$ end if
+!!$
+!!$ !print*,'inode', inode, 'nsp', nsp, 'count', count, 'p', p, ' gto(nsp)%sf( count )%a( p )', &
+!!$ ! gto(nsp)%sf( count )%a( p )
+!!$ !print*,'inode', inode, 'nsp', nsp, 'count', count, 'p', p, ' gto(nsp)%sf( count )%d( p )', &
+!!$ ! gto(nsp)%sf( count )%d( p )
+!!$ !print*,'inode', inode, 'nsp', nsp, 'count', count, 'p', p, ' gto(nsp)%sf( count )%c( p )', &
+!!$ ! gto(nsp)%sf( count )%c( p )
+!!$
+!!$
+!!$ end do primitive
+!!$ call gcopy( gto(nsp)%sf( count )%a, gto(nsp)%angmom(l1)%zeta(acz1)%ngto )
+!!$ call gcopy( gto(nsp)%sf( count )%d, gto(nsp)%angmom(l1)%zeta(acz1)%ngto )
+!!$ call gcopy( gto(nsp)%sf( count )%c, gto(nsp)%angmom(l1)%zeta(acz1)%ngto )
+!!$
+!!$ print*,'inode', inode, 'nsp', nsp, 'count', count, 'p', p, ' gto(nsp)%sf( count )%a( p )', &
+!!$ gto(nsp)%sf( count )%a
+!!$ print*,'inode', inode, 'nsp', nsp, 'count', count, 'p', p, ' gto(nsp)%sf( count )%d( p )', &
+!!$ gto(nsp)%sf( count )%d
+!!$ print*,'inode', inode, 'nsp', nsp, 'count', count, 'p', p, ' gto(nsp)%sf( count )%c( p )', &
+!!$ gto(nsp)%sf( count )%c
+!!$
+!!$
+!!$ count = count + 1
+!!$ end do magn_loop
+!!$ end do zeta_loop
+!!$ end do angu_loop
+!!$
+!!$
+!!$ deallocate( gto(nsp)%sf )
+!!$
+!!$ do i = 1, count-1
+!!$ deallocate( gto(nsp)%sf( i )%a )
+!!$ deallocate( gto(nsp)%sf( i )%d )
+!!$ deallocate( gto(nsp)%sf( i )%c )
+!!$ end do
+!!$
+!!$ count2 = 1
+!!$ angu_loop2: do l1 = 0, gto(nsp)%greatest_angmom
+!!$
+!!$ zeta_loop2: do acz1 = 1, gto(nsp)%angmom(l1)%n_zeta_in_angmom
+!!$
+!!$ magn_loop2: do m1 = -l1, +l1
+!!$
+!!$ sph_loop2: do n1 = 1, gto(nsp)%angmom(l1)%transform_sph(m1)%size
+!!$
+!!$ if (inode == ionode ) then
+!!$
+!!$ print*, 'l1, acz1, m1, n1', l1, acz1, m1, n1
+!!$ end if
+!!$
+!!$
+!!$
+!!$ end do sph_loop2
+!!$
+!!$
+!!$ count2 = count2 + 1
+!!$
+!!$ end do magn_loop2
+!!$ end do zeta_loop2
+!!$ end do angu_loop2
+!!$
+ !write(*,*)'inode', inode, 'fin'
+
+ end do species_loop
+
+
+ call stop_timer(tmr_std_initialisation)
+
+ return
+ end subroutine read_gto_new
+ !
+ !
+ !
+ subroutine sph_gauss_function( inode, ionode, l, m, size, nx, ny, nz, c, name, verbose )
+
+ use GenComms, only: cq_abort
+
+ implicit none
+
+ integer, intent(in) :: inode, ionode
+ integer, intent(in) :: l ! angular momentum
+ integer, intent(in) :: m ! magnetic moment
+ logical, intent(in) :: verbose
+
+ character(len=12),intent(out) :: name
+ integer, intent(out) :: size
+ integer, intent(out), dimension( 5 ) :: nx, ny, nz
+ real(double), intent(out), dimension( 5 ) :: c
+
+ size = 0; nx = 0; ny = 0; nz = 0; c = 0.0d0
+
+ if(inode == ionode) then
+ !
+ select case(l)
+ case(0)
+ !
+ select case(m)
+ case(0) ! s
+ size = 1
+ nx(1) = 0; ny(1) = 0; nz(1) = 0
+ c (1) = 1.0d0
+ name = 'S'
+ !
+ if (verbose) write(io_lun,'(12x,"(nx, ny, nz) = (",I2,x,I2,x,I2,") =",x,A12)') &
+ nx(1), ny(1), nz(1), name
+ !
+ case default
+ call cq_abort('sph_gauss_function: error angular magnetic moment',l,m)
+ end select
+ !
+ case(1)
+ !
+ select case(m)
+ case(-1) ! py
+ size = 1
+ nx(1) = 0; ny(1) = 1; nz(1) = 0
+ c (1) = 1.0d0
+ name = 'P_{y}'
+ if (verbose) write(io_lun,'(12x,"(nx, ny, nz) = (",I2,x,I2,x,I2,") =",x,A12)') &
+ nx(1), ny(1), nz(1), name
+ !
+ case( 0) ! pz
+ size = 1
+ nx(1) = 0; ny(1) = 0; nz(1) = 1
+ c (1) = 1.0d0
+ name = 'P_{z}'
+ if (verbose) write(io_lun,'(12x,"(nx, ny, nz) = (",I2,x,I2,x,I2,") =",x,A12)') &
+ nx(1), ny(1), nz(1), name
+ !
+ case(+1) ! px
+ size = 1
+ nx(1) = 1; ny(1) = 0; nz(1) = 0
+ c (1) = 1.0d0
+ name = 'P_{x}'
+ if (verbose) write(io_lun,'(12x,"(nx, ny, nz) = (",I2,x,I2,x,I2,") =",x,A12)') &
+ nx(1), ny(1), nz(1), name
+ !
+ case default
+ call cq_abort('sph_gauss_function: error angular magnetic moment',l,m)
+ end select
+ !
+ case(2)
+ !
+ select case(m)
+ case(-2) ! d_{xy} = (x*y)
+ size = 1
+ nx(1) = 1; ny(1) = 1; nz(1) = 0
+ c (1) =-1.0d0 ! phase factor
+ name = 'D_{xy}'
+ if (verbose) write(io_lun,'(12x,"(nx, ny, nz) = (",I2,x,I2,x,I2,") =",x,A12)') &
+ nx(1), ny(1), nz(1), name
+ !
+ case(-1) ! d_{yz} = (y*z)
+ size = 1
+ nx(1) = 0; ny(1) = 1; nz(1) = 1
+ c (1) = 1.0d0
+ name = 'D_{yz}'
+ if (verbose) write(io_lun,'(12x,"(nx, ny, nz) = (",I2,x,I2,x,I2,") =",x,A12)') &
+ nx(1), ny(1), nz(1), name
+ !
+ case( 0) ! d_{z2} = (3*z*z-r*r) = (2*z*z-x*x-y*y)
+ size = 3
+ nx(1) = 0; ny(1) = 0; nz(1) = 2
+ nx(2) = 2; ny(2) = 0; nz(2) = 0
+ nx(3) = 0; ny(3) = 2; nz(3) = 0
+ c (1) = 2.0d0
+ c (2) =-1.0d0
+ c (3) =-1.0d0
+ name = 'D_{3z2-r2}'
+ if (verbose) write(io_lun,'(12x, "(nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4)') &
+ nx(1), ny(1), nz(1), c(1)
+ if (verbose) write(io_lun,'(10x,"+ (nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4)') &
+ nx(2), ny(2), nz(2), c(2)
+ if (verbose) write(io_lun,'(10x,"+ (nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4,x,"=",x,A12)') &
+ nx(3), ny(3), nz(3), c(3), name
+ !
+ case(+1) ! d_{xz} = (x*z)
+ size = 1
+ nx(1) = 1; ny(1) = 0; nz(1) = 1
+ c (1) = 1.0d0
+ name = 'D_{xz}'
+ if (verbose) write(io_lun,'(12x,"(nx, ny, nz) = (",I2,x,I2,x,I2,") =",x,A12)') &
+ nx(1), ny(1), nz(1), name
+ !
+ case(+2) ! d_{x2-y2} = (x*x-y*y)
+ size = 2
+ nx(1) = 2; ny(1) = 0; nz(1) = 0
+ nx(2) = 0; ny(2) = 2; nz(2) = 0
+ c (1) = 1.0d0
+ c (2) =-1.0d0
+ name = 'D_{x2-y2}'
+ if (verbose) write(io_lun,'(10x,"+ (nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4)') &
+ nx(1), ny(1), nz(1), c(1)
+ if (verbose) write(io_lun,'(10x,"+ (nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4,x,"=",x,A12)') &
+ nx(2), ny(2), nz(2), c(2), name
+ !
+ case default
+ call cq_abort('sph_gauss_function: error angular magnetic moment',l,m)
+ end select
+ !
+ case(3)
+ !
+ select case(m)
+ case(-3) ! f_{y(3x2-y2)} = (3x*x*y-y*y*y)
+ size = 2
+ nx(1) = 2; ny(1) = 1; nz(1) = 0
+ nx(2) = 0; ny(2) = 3; nz(2) = 0
+ c (1) = 3.0d0
+ c (2) =-1.0d0
+ name = 'F_{y(3x2-y2)}'
+ if (verbose) write(io_lun,'(12x, "(nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4)') &
+ nx(1), ny(1), nz(1), c(1)
+ if (verbose) write(io_lun,'(10x,"+ (nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4,x,"=",x,A12)') &
+ nx(3), ny(3), nz(3), c(3), name
+ !
+ case(-2) ! f_{xyz} = (x*y*z)
+ size = 1
+ nx(1) = 1; ny(1) = 1; nz(1) = 1
+ c (1) = 1.0d0
+ name = 'D_{xyz}'
+ if (verbose) write(io_lun,'(12x,"(nx, ny, nz) = (",I2,x,I2,x,I2,") =",x,A12)') &
+ nx(1), ny(1), nz(1), name
+ !
+ case(-1) ! f_{yz2} = (4*z*z*y-y*x*x-y*y*y)
+ size = 3
+ nx(1) = 0; ny(1) = 1; nz(1) = 2
+ nx(2) = 2; ny(2) = 1; nz(2) = 0
+ nx(3) = 0; ny(3) = 3; nz(3) = 0
+ c (1) = 4.0d0
+ c (2) =-1.0d0
+ c (3) =-1.0d0
+ name = 'F_{yz2}'
+ if (verbose) write(io_lun,'(12x, "(nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4)') &
+ nx(1), ny(1), nz(1), c(1)
+ if (verbose) write(io_lun,'(10x,"+ (nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4)') &
+ nx(2), ny(2), nz(2), c(2)
+ if (verbose) write(io_lun,'(10x,"+ (nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4,x,"=",x,A12)') &
+ nx(3), ny(3), nz(3), c(3), name
+ !
+ case( 0) ! f_{z3} = (2*z*z*z-3*x*x*z-3*y*y*z)
+ size = 3
+ nx(1) = 0; ny(1) = 0; nz(1) = 3
+ nx(2) = 2; ny(2) = 0; nz(2) = 1
+ nx(3) = 0; ny(3) = 2; nz(3) = 1
+ c (1) = 2.0d0
+ c (2) =-3.0d0
+ c (3) =-3.0d0
+ name = 'F_{z3}'
+ if (verbose) write(io_lun,'(12x, "(nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4)') &
+ nx(1), ny(1), nz(1), c(1)
+ if (verbose) write(io_lun,'(10x,"+ (nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4)') &
+ nx(2), ny(2), nz(2), c(2)
+ if (verbose) write(io_lun,'(10x,"+ (nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4,x,"=",x,A12)') &
+ nx(3), ny(3), nz(3), c(3), name
+ !
+ case(+1) ! f_{xz2} = (4*x*z*z-x*x*x-x*y*y)
+ size = 3
+ nx(1) = 1; ny(1) = 0; nz(1) = 2
+ nx(2) = 3; ny(2) = 0; nz(2) = 0
+ nx(3) = 1; ny(3) = 2; nz(3) = 0
+ c (1) = 4.0d0
+ c (2) =-1.0d0
+ c (3) =-1.0d0
+ name = 'F_{xz2}'
+ if (verbose) write(io_lun,'(12x, "(nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4)') &
+ nx(1), ny(1), nz(1), c(1)
+ if (verbose) write(io_lun,'(10x,"+ (nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4)') &
+ nx(2), ny(2), nz(2), c(2)
+ if (verbose) write(io_lun,'(10x,"+ (nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4,x,"=",x,A12)') &
+ nx(3), ny(3), nz(3), c(3), name
+ !
+ case(+2) ! f_{z(x2-y2)} = (x*x*z-y*y*z)
+ size = 2
+ nx(1) = 2; ny(1) = 0; nz(1) = 1
+ nx(2) = 0; ny(2) = 2; nz(2) = 1
+ c (1) = 1.0d0
+ c (2) =-1.0d0
+ name = 'F_{z(x2-y2)}'
+ if (verbose) write(io_lun,'(12x, "(nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4)') &
+ nx(1), ny(1), nz(1), c(1)
+ if (verbose) write(io_lun,'(10x,"+ (nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4,x,"=",x,A12)') &
+ nx(2), ny(2), nz(2), c(2), name
+ !
+ case(+3) ! f_{x(x2-3y2)} = (x*x*x-3*x*y*y)
+ size = 2
+ nx(1) = 3; ny(1) = 0; nz(1) = 0
+ nx(2) = 1; ny(2) = 2; nz(2) = 0
+ c (1) = 1.0d0
+ c (2) =-3.0d0
+ name = 'F_{x(x2-3y2}'
+ if (verbose) write(io_lun,'(12x, "(nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4)') &
+ nx(1), ny(1), nz(1), c(1)
+ if (verbose) write(io_lun,'(10x,"+ (nx, ny, nz) = (",I2,x,I2,x,I2,")",x,"x",x,f8.4,x,"=",x,A12)') &
+ nx(2), ny(2), nz(2), c(2), name
+
+ !
+ case default
+ call cq_abort('sph_gauss_function: error angular magnetic moment',l,m)
+ end select
+ !
+ case default
+ call cq_abort('sph_gauss_function: error angular momentum',l)
+ end select
+ !
+ end if
+ !
+ end subroutine sph_gauss_function
+ !
+ !
+ !
+ subroutine cart_gauss_function( inode, ionode, lambda, name, a, nx, ny, nz, nt, verbose )
+
+ implicit none
+
+ integer, intent(in) :: lambda
+ integer, intent(in) :: inode, ionode
+ character(len=1), intent(in) :: name
+ real(double), intent(in) :: a
+ logical, intent(in) :: verbose
+
+ integer, intent(out), dimension( (lambda+1)*(lambda+2)/2 ) :: nx, ny, nz
+ character(len=12), intent(out), dimension( (lambda+1)*(lambda+2)/2 ) :: nt
+ character(len=12) :: charx, chary, charz
+ integer :: x, y, z, k, index
+
+ if(inode == ionode) then
+
+ index = 1
+ do x = 0, lambda
+ do z = 0, lambda - x
+ y = lambda - (x + z)
+ !
+ if(inode == ionode) then
+ ! Exponents for Cartesian Gaussian functions
+ nx(index) = x !x
+ ny(index) = y !y
+ nz(index) = z !z
+ !
+ end if
+ !
+ charx = '' ; chary = '' ; charz = ''
+ if (x > 0) then
+ do k = 1, x
+ charx = trim(charx)//'x'
+ end do
+ end if
+ if (y > 0) then
+ do k = 1, y
+ chary = trim(chary)//'y'
+ end do
+ end if
+ if (z > 0) then
+ do k = 1, z
+ charz = trim(charz)//'z'
+ end do
+ end if
+ !
+ nt(index) = trim(name)//'_{'//trim(charx)//trim(chary)//trim(charz)//'}'
+ !
+ !norm(index)= norm_gto( &
+ ! a, & ! alpha
+ ! nx(index), & ! l
+ ! ny(index), & ! m
+ ! nz(index)) ! n
+ !
+ if (verbose) write(io_lun,'(12x,"(nx, ny, nz) = (",I2,x,I2,x,I2,") =",x,A12)') &
+ nx(index), &
+ ny(index), &
+ nz(index), &
+ nt(index)
+ !
+ index = index + 1
+ !
+ end do
+ end do
+ end if
+ !
+ end subroutine cart_gauss_function
+ !
+ !
+ !
+ subroutine angmom_convert(l_name,l_value)
+
+ use GenComms, ONLY: cq_abort
+
+ implicit none
+
+ character(len=1), intent(inout) :: l_name
+ integer, intent(out) :: l_value
+ !
+ integer :: i, l, lambda
+ !
+ ! if necessary convert lowercase to uppercase
+ do l = 0, size(l_name_lowercase)-1
+ if ( l_name == l_name_lowercase(l)) then
+ l_name = l_name_uppercase(l)
+ end if
+ end do
+ !
+ l_value = -1
+ do l = 0, size(l_name_uppercase)-1
+ if ( l_name == l_name_uppercase(l)) then
+ l_value = l
+ end if
+ end do
+ !
+ if ( l_value == -1 ) then
+ call cq_abort('read_gto: error angular momentum convert')
+ end if
+ !
+ !select case(l_name)
+ !case('S')
+ ! lambda = 0
+ !case('P')
+ ! lambda = 1
+ !case('D')
+ ! lambda = 2
+ !case('F')
+ ! lambda = 3
+ !case('G')
+ ! lambda = 4
+ !case('H')
+ ! lambda = 5
+ !case default
+ ! call cq_abort('read_gto: error angular momentum')
+ !end select
+ !l_value = lambda
+
+ return
+ end subroutine angmom_convert
+
+
+!!$ subroutine read_gto(inode,ionode,n_species)
+!!$
+!!$ use gto_format, ONLY: gto
+!!$ use species_module, ONLY: gto_file, species_label
+!!$ use GenComms, ONLY: cq_abort, gcopy, my_barrier
+!!$ use exx_erigto, ONLY: norm_gto, overlap_gto
+!!$
+!!$ implicit none
+!!$
+!!$ ! Arguments
+!!$ integer, intent(in) :: inode, ionode, n_species
+!!$
+!!$ ! Local variables
+!!$ integer :: ios, match, tmp_int, gto_unit, nsp
+!!$ character(len=256) :: match_atom
+!!$ character(len=8) :: charx, chary, charz
+!!$
+!!$ integer :: i, j, k, l, lambda
+!!$ integer :: x, y, z, index, count
+!!$ integer :: l1, m1, n1, l2, m2, n2
+!!$ real(double) :: x1, y1, z1
+!!$ real(double) :: x2, y2, z2
+!!$ real(double) :: test, norm, S_12, alpha1, alpha2
+!!$
+!!$ !
+!!$ ! gto_file(nsp) allocated in initial_read.module
+!!$ ! gto(nsp) allocated in pseudo_tm_info
+!!$ !
+!!$
+!!$ gto_unit = 1000
+!!$
+!!$ call start_timer(tmr_std_initialisation)
+!!$
+!!$ species_loop: do nsp = 1, n_species
+!!$
+!!$ if(inode == ionode) then
+!!$
+!!$ gto_file(nsp) = trim(species_label(nsp))//trim('.gto')
+!!$ gto(nsp)%label = trim(species_label(nsp))
+!!$ !
+!!$ open(unit=gto_unit,file=gto_file(nsp),status="old",action="read", &
+!!$ iostat=ios,position="rewind")
+!!$ if(ios /= 0) call cq_abort('read_gto: failed to open input file')
+!!$ !
+!!$ !call gcopy(gto(nsp)%label,2)
+!!$ !
+!!$ match = 0
+!!$ count = 1
+!!$ !
+!!$ do while (match == 0)
+!!$ read(unit=gto_unit,fmt=*,iostat=ios) match_atom
+!!$ match_atom = trim(match_atom)
+!!$ if (ios < 0) call cq_abort('read_gto: end error GTO data file', gto_unit)
+!!$ if (ios > 0) call cq_abort('read_gto: read error GTO data file',gto_unit)
+!!$ if (match_atom == gto(nsp)%label) then
+!!$ match = 1
+!!$ end if
+!!$ end do
+!!$ !
+!!$ read(gto_unit,fmt=*,iostat=ios) gto(nsp)%nshell
+!!$ if (ios < 0) call cq_abort('read_gto: end error GTO data file',gto_unit)
+!!$ if (ios > 0) call cq_abort('read_gto: read error GTO data file',gto_unit)
+!!$ !
+!!$ write(*,*)
+!!$ write(*,fmt='("#### read GTO for ",A2,"/nshell =",I3," ####")') gto(nsp)%label, gto(nsp)%nshell
+!!$ !
+!!$ !write(*,fmt='(2x,"nshell = ",I3)') gto(nsp)%nshell
+!!$ !
+!!$ end if
+!!$ !
+!!$ call gcopy(gto(nsp)%label,2)
+!!$ call gcopy(gto(nsp)%nshell)
+!!$ !
+!!$ allocate(gto(nsp)%shell(gto(nsp)%nshell))
+!!$ !print*, 'node', inode, allocated(gto(nsp)%shell), size(gto(nsp)%shell)
+!!$ !
+!!$ !
+!!$ gto(nsp)%nprim = 0
+!!$ gto(nsp)%nang = 0
+!!$ !
+!!$ shell_loop: do i = 1, gto(nsp)%nshell
+!!$ !
+!!$ if(inode == ionode) then
+!!$ !
+!!$ read(gto_unit,fmt=*,iostat=ios) &
+!!$ gto(nsp)%shell(i)%t, & ! type s,p,sp,d,f...
+!!$ gto(nsp)%shell(i)%n, & ! number of primitive
+!!$ gto(nsp)%shell(i)%f ! scaling factor
+!!$ if (ios < 0) call cq_abort('read_gto: end error GTO data file', gto_unit)
+!!$ if (ios > 0) call cq_abort('read_gto: read error GTO data file',gto_unit)
+!!$ !
+!!$ write(*,'(">>> shell ",I3)') i
+!!$ write(*,'(2x,"type =",3x,A2)' ) gto(nsp)%shell(i)%t
+!!$ write(*,'(2x,"scaling factor =",3x,F8.6)' ) gto(nsp)%shell(i)%f
+!!$
+!!$ select case(gto(nsp)%shell(i)%t)
+!!$ case('S')
+!!$ lambda = 0
+!!$ !gto(nsp)%shell(i)%nn = 0
+!!$ !gto(nsp)%shell(i)%nf = 1
+!!$ case('P')
+!!$ lambda = 1
+!!$ !gto(nsp)%shell(i)%nn = 1
+!!$ !gto(nsp)%shell(i)%nf = 3
+!!$ case('D')
+!!$ lambda = 2
+!!$ !gto(nsp)%shell(i)%nn = 2
+!!$ !gto(nsp)%shell(i)%nf = 6
+!!$ case('F')
+!!$ lambda = 3
+!!$ !gto(nsp)%shell(i)%nn = 3
+!!$ !gto(nsp)%shell(i)%nf = 10
+!!$ case('G')
+!!$ lambda = 4
+!!$ !gto(nsp)%shell(i)%nn = 4
+!!$ !gto(nsp)%shell(i)%nf = 15
+!!$ case('H')
+!!$ lambda = 5
+!!$ !gto(nsp)%shell(i)%nn = 5
+!!$ !gto(nsp)%shell(i)%nf = 24
+!!$ case default
+!!$ call cq_abort('read_gto: error angular momentum',gto(nsp)%shell(i)%nn)
+!!$ end select
+!!$ !
+!!$ gto(nsp)%shell(i)%nn = lambda
+!!$ gto(nsp)%shell(i)%nf = (lambda+1)*(lambda+2)/2
+!!$ gto(nsp)%nang = gto(nsp)%nang + gto(nsp)%shell(i)%nf
+!!$ gto(nsp)%nprim = gto(nsp)%nprim + gto(nsp)%shell(i)%n*gto(nsp)%shell(i)%nf
+!!$ !
+!!$ write(*,'(2x,"angular momentum l =",I3)') gto(nsp)%shell(i)%nn
+!!$ write(*,'(2x,"number of values for m =",I3)') gto(nsp)%shell(i)%nf
+!!$ write(*,'(2x,"number of primitives =",I3)') gto(nsp)%shell(i)%n
+!!$ !
+!!$ !
+!!$ end if
+!!$ !
+!!$ call gcopy(gto(nsp)%shell(i)%t,2)
+!!$ call gcopy(gto(nsp)%shell(i)%n )
+!!$ call gcopy(gto(nsp)%shell(i)%f )
+!!$ call gcopy(gto(nsp)%shell(i)%nn )
+!!$ call gcopy(gto(nsp)%shell(i)%nf )
+!!$ !
+!!$ allocate(gto(nsp)%shell(i)%ak( gto(nsp)%shell(i)%n ))
+!!$ allocate(gto(nsp)%shell(i)%dk( gto(nsp)%shell(i)%n ))
+!!$ allocate(gto(nsp)%shell(i)%Nk( gto(nsp)%shell(i)%n,gto(nsp)%shell(i)%nf ))
+!!$ !
+!!$ allocate(gto(nsp)%shell(i)%nx( gto(nsp)%shell(i)%nf ))
+!!$ allocate(gto(nsp)%shell(i)%ny( gto(nsp)%shell(i)%nf ))
+!!$ allocate(gto(nsp)%shell(i)%nz( gto(nsp)%shell(i)%nf ))
+!!$ allocate(gto(nsp)%shell(i)%nt( gto(nsp)%shell(i)%nf ))
+!!$ allocate(gto(nsp)%shell(i)%norm( gto(nsp)%shell(i)%nf ))
+!!$ !
+!!$ prim_loop: do j = 1, gto(nsp)%shell(i)%n
+!!$ !
+!!$ if(inode == ionode) then
+!!$
+!!$ read(gto_unit,fmt=*,iostat=ios) &
+!!$ gto(nsp)%shell(i)%ak(j), &
+!!$ gto(nsp)%shell(i)%dk(j)
+!!$ if (ios < 0) call cq_abort('read_gto: end error GTO data file', gto_unit)
+!!$ if (ios > 0) call cq_abort('read_gto: read error GTO data file',gto_unit)
+!!$
+!!$ write(*,'(2x,"primitive",x,"(a",I3,", d",I3,") = (",F14.8,x,F14.8,")")') j, j, &
+!!$ gto(nsp)%shell(i)%ak(j), &
+!!$ gto(nsp)%shell(i)%dk(j)
+!!$
+!!$ !write(*,'(6x,"(a",I3,", d",I3,") = (",F14.8,x,F14.8,")")') j, j, &
+!!$ !gto(nsp)%shell(i)%ak(j), &
+!!$ !gto(nsp)%shell(i)%dk(j)
+!!$ end if
+!!$ !
+!!$ call gcopy(gto(nsp)%shell(i)%ak(j))
+!!$ call gcopy(gto(nsp)%shell(i)%dk(j))
+!!$ !
+!!$ index = 1
+!!$ lambda = gto(nsp)%shell(i)%nn
+!!$ do x = 0, lambda
+!!$ do y = 0, lambda - x
+!!$ z = lambda - (x + y)
+!!$ !
+!!$ if(inode == ionode) then
+!!$ ! Exponents for Cartesian Gaussian functions
+!!$ gto(nsp)%shell(i)%nx(index) = x!x
+!!$ gto(nsp)%shell(i)%ny(index) = y!y
+!!$ gto(nsp)%shell(i)%nz(index) = z!z
+!!$ !
+!!$ end if
+!!$ !
+!!$ charx = '' ; chary = '' ; charz = ''
+!!$ if (x > 0) then
+!!$ do k = 1, x
+!!$ charx = trim(charx)//'x'
+!!$ end do
+!!$ end if
+!!$ if (y > 0) then
+!!$ do k = 1, y
+!!$ chary = trim(chary)//'y'
+!!$ end do
+!!$ end if
+!!$ if (z > 0) then
+!!$ do k = 1, z
+!!$ charz = trim(charz)//'z'
+!!$ end do
+!!$ end if
+!!$ !
+!!$ if(inode == ionode) then
+!!$ !
+!!$ gto(nsp)%shell(i)%nt(index) = &
+!!$ trim(gto(nsp)%shell(i)%t)//trim(charx)//trim(chary)//trim(charz)
+!!$ !
+!!$ end if
+!!$ !
+!!$ call gcopy(gto(nsp)%shell(i)%nt(index),16)
+!!$ !
+!!$ if(inode == ionode) then
+!!$ ! Compute the norm of each Cartesian components
+!!$
+!!$ gto(nsp)%shell(i)%Nk(j,index) = norm_gto( &
+!!$ gto(nsp)%shell(i)%ak(j), & ! alpha
+!!$ gto(nsp)%shell(i)%nx(index), & ! l
+!!$ gto(nsp)%shell(i)%ny(index), & ! m
+!!$ gto(nsp)%shell(i)%nz(index)) ! n
+!!$ !
+!!$ write(*,'(6x,"(nx, ny, nz) = (",I2,x,I2,x,I2,") =",x,A6,"/","norm = ",F14.8,I8)') &
+!!$ gto(nsp)%shell(i)%nx(index), &
+!!$ gto(nsp)%shell(i)%ny(index), &
+!!$ gto(nsp)%shell(i)%nz(index), &
+!!$ gto(nsp)%shell(i)%nt(index), &
+!!$ gto(nsp)%shell(i)%Nk(j,index), index
+!!$
+!!$ end if
+!!$ !
+!!$ call gcopy(gto(nsp)%shell(i)%Nk(j,index))
+!!$ !
+!!$ index = index + 1
+!!$ count = count + 1
+!!$ !
+!!$ end do
+!!$ end do
+!!$ !
+!!$ end do prim_loop
+!!$ !
+!!$ if(inode == ionode) then
+!!$ !
+!!$ gto(nsp)%shell(i)%norm(:) = zero
+!!$ !
+!!$ do j = 1, gto(nsp)%shell(i)%n
+!!$ !
+!!$ do k = 1, gto(nsp)%shell(i)%n
+!!$
+!!$ do l = 1, gto(nsp)%shell(i)%nf
+!!$
+!!$ alpha1 = gto(nsp)%shell(i)%ak(j)
+!!$ l1 = gto(nsp)%shell(i)%nx(l)
+!!$ m1 = gto(nsp)%shell(i)%ny(l)
+!!$ n1 = gto(nsp)%shell(i)%nz(l)
+!!$ x1 = zero ; y1 = zero ; z1 = zero
+!!$
+!!$ alpha2 = gto(nsp)%shell(i)%ak(k)
+!!$ l2 = gto(nsp)%shell(i)%nx(l)
+!!$ m2 = gto(nsp)%shell(i)%ny(l)
+!!$ n2 = gto(nsp)%shell(i)%nz(l)
+!!$ x2 = zero ; y2 = zero ; z2 = zero
+!!$
+!!$ S_12 = overlap_gto(alpha1,l1,m1,n1,x1,y1,z1, &
+!!$ alpha2,l2,m2,n2,x2,y2,z2)
+!!$
+!!$ !print*, j, k, l1, m1, n1, l2, m2, n2, alpha1, alpha2, l, S_12
+!!$
+!!$ gto(nsp)%shell(i)%norm(l) = gto(nsp)%shell(i)%norm(l) + &
+!!$ gto(nsp)%shell(i)%ak(j) * gto(nsp)%shell(i)%ak(k) * S_12
+!!$ !
+!!$ end do
+!!$ !
+!!$ end do
+!!$ !
+!!$ end do
+!!$ !
+!!$ end if
+!!$ !
+!!$ if(inode == ionode) then
+!!$ !
+!!$ write(*,'(2x,"number of angular funtions = ",I3)') gto(nsp)%shell(i)%nf
+!!$ !
+!!$ do l = 1, gto(nsp)%shell(i)%nf
+!!$ write(*,'(2x,"norm =",F12.6)') gto(nsp)%shell(i)%norm(l)
+!!$ end do
+!!$ !
+!!$ end if
+!!$ !
+!!$ call gcopy( gto(nsp)%shell(i)%norm, gto(nsp)%shell(i)%nf)
+!!$ !
+!!$ !
+!!$ end do shell_loop
+!!$
+!!$ if(inode == ionode) then
+!!$ !
+!!$ write(*,'(">>> total number of angular functions =",I10)') gto(nsp)%nang
+!!$ write(*,'(">>> total number of primitives =",I10)') gto(nsp)%nprim
+!!$ !
+!!$ close(unit=gto_unit,iostat=ios)
+!!$ if(ios /= 0) call cq_abort('read_gto: failed to close input file',gto_unit)
+!!$ end if
+!!$
+!!$ call gcopy(gto(nsp)%nang )
+!!$ call gcopy(gto(nsp)%nprim)
+!!$
+!!$ end do species_loop
+!!$
+!!$ call stop_timer(tmr_std_initialisation)
+!!$
+!!$ return
+!!$ end subroutine read_gto
+ !
+end module read_gto_info
diff --git a/src/species_module.f90 b/src/species_module.f90
index d452ade18..23349d5d6 100644
--- a/src/species_module.f90
+++ b/src/species_module.f90
@@ -43,6 +43,8 @@
!! Added charge_up and charge_dn
!! 2017/11/27 15:50 dave
!! Added NA projector count per species
+!! 2020/01/14 17:27 Lionel
+!! Added gto_files
!! SOURCE
!!
module species_module
@@ -61,6 +63,7 @@ module species_module
character(len=50), allocatable, dimension(:) :: ps_file
character(len=40), allocatable, dimension(:) :: ch_file
character(len=40), allocatable, dimension(:) :: phi_file
+ character(len=40), allocatable, dimension(:) :: gto_file
!
character(len=30), allocatable, dimension(:) :: species_label
character(len=80), allocatable, dimension(:) :: species_file
diff --git a/src/store_matrix_module.f90 b/src/store_matrix_module.f90
index 1bf28dd34..811998d00 100644
--- a/src/store_matrix_module.f90
+++ b/src/store_matrix_module.f90
@@ -1549,4 +1549,136 @@ subroutine dump_XL()
return
end subroutine dump_XL
!!***
+
+ ! -----------------------------------------------------------------------
+ ! Subroutine write_Rij_MatrixElements
+ ! -----------------------------------------------------------------------
+
+ !!****f* store_matrix/write_Rij_MatrixElements *
+ !!
+ !! NAME
+ !! write_Rij_MatrixElements : made from dump_matrix2
+ !! USAGE
+ !! call write_Rij_MatrixElements('K',matK,Hrange,n_matrix=nspin,index=10)
+ !! will generate the file "Kmatrix_plot.i10.p000000".
+ !! You can omit "index=10", then the default value of index = 00.
+ !!
+ !! At present, it prints out the matrix elements only for inode = 1
+ !! (you can print out the matrix elements for all nodes, simply by
+ !! commenting out the IF statements
+ !!
+ !! PURPOSE
+ !! writes Rij and abs(MatElements(ij))
+ !! INPUTS
+ !!
+ !! USES
+ !!
+ !! AUTHOR
+ !! Tsuyoshi Miyazaki
+ !! CREATION DATE
+ !! 2024/08/30
+ !! MODIFICATION
+ !!
+ !! SOURCE
+ !!
+ subroutine write_Rij_MatrixElements(stub,matA,range,n_matrix,index)
+
+ use GenComms, ONLY: inode, ionode, cq_abort
+ use global_module, ONLY: numprocs, id_glob
+ use io_module, ONLY: get_file_name, get_file_name_2rank
+ use global_module, ONLY: rcellx, rcelly, rcellz
+
+ implicit none
+
+ ! Passed variables
+ character(len=*),intent(in) :: stub
+ integer,intent(in) :: n_matrix
+ integer,intent(in) :: matA(n_matrix)
+ integer,intent(in) :: range
+ integer,optional,intent(in) :: index
+
+ ! Local variables
+ type(matrix_store):: tmp_matrix_store
+ integer :: lun, iprim, nprim, jmax, jj, ibeg, jbeta_alpha, len, istat
+ character(80) :: file_name
+ integer :: index_local, nn
+ integer :: ibeg2, n1, n2, nspin_local
+ real(double) :: Rij(1:3), Rij_2
+
+ index_local=0; if(present(index)) index_local=index
+
+ IF(INODE == IONODE) THEN
+
+ ! set_matrix_store : build tmp_matrix_store
+ call set_matrix_store(stub,matA,range,n_matrix,tmp_matrix_store)
+
+ ! Actual Dump (from dump_matrix2)
+ ! First, get the name of a file based upon the node ID or rank.
+ if(flag_MatrixFile_RankFromZero) then
+ call get_file_name_2rank(stub//'matrix_plot',file_name,index_local,myid)
+ else
+ call get_file_name_2rank(stub//'matrix_plot',file_name,index_local,inode)
+ endif
+ call io_assign(lun)
+
+ open (lun,file=file_name,form='formatted')
+
+ ! 1. node ID, no. of PS of atoms "i".
+ nprim=tmp_matrix_store%n_prim
+ write (lun,*) "# inode,nprim = ",inode, nprim
+ ! 2. no. of alpha for each "i".
+ write (lun,*) "# n_alpha = ",tmp_matrix_store%nsf_spec_i(1:nprim)
+ ! NOTE: The followings are written out with neighbour-labelling
+ ! 3. no. of the neighbours "j" for each "i".
+ ! 4. no. of "neighbour-j x beta" for each "i".
+ ! 5. no. of matrices whose elements will be printed out
+ !write (lun,*) tmp_matrix_store%nspin
+
+ !I will change the order of dumping in the following, later. 2016/09/30: TM@UCL
+ if(nprim .GT. 0) then
+ do iprim=1,nprim
+ jmax = tmp_matrix_store%jmax_i(iprim)
+ ibeg = tmp_matrix_store%ibeg_Rij(iprim)
+ !write (lun,*) tmp_matrix_store%idglob_i(iprim)
+ !write (lun,*) tmp_matrix_store%beta_j(ibeg:ibeg+jmax-1)
+ !write (lun,*) tmp_matrix_store%idglob_j(ibeg:ibeg+jmax-1)
+
+ ibeg2 = tmp_matrix_store%ibeg_data_matrix(iprim)
+ jbeta_alpha=0
+
+ do jj=1,jmax
+ Rij(1:3) = tmp_matrix_store%vec_Rij(1:3,ibeg+jj-1)
+ Rij(1) = Rij(1)*rcellx
+ Rij(2) = Rij(2)*rcelly
+ Rij(3) = Rij(3)*rcellz
+ Rij_2 = Rij(1)**2 + Rij(2)**2 + Rij(3)**2
+ nspin_local=tmp_matrix_store%nspin
+ do n2=1,tmp_matrix_store%beta_j(ibeg+jj-1)
+ do n1=1,tmp_matrix_store%nsf_spec_i(iprim)
+ jbeta_alpha=jbeta_alpha+1
+ write (lun,fmt='(2x,2e20.10)') sqrt(Rij_2), abs(tmp_matrix_store%data_matrix(ibeg2+jbeta_alpha-1,1:nspin_local))
+ enddo
+ enddo
+ enddo !jj=1,jmax
+
+ if(iprim < nprim) then
+ len = tmp_matrix_store%ibeg_data_matrix(iprim+1)-tmp_matrix_store%ibeg_data_matrix(iprim)
+ else
+ len = tmp_matrix_store%matrix_size-tmp_matrix_store%ibeg_data_matrix(iprim)+1
+ endif
+ write(*,*) ' Subroutine: write_Rij_MatrixElements :: iprim, jbeta_alpha, len = ',iprim,jbeta_alpha,len
+ enddo !iprim=1,nprim
+ endif ! (nprim .GT. 0)
+
+ ! Close the file in the end.
+ call io_close(lun)
+
+ ! free_matrix_store : free tmp_matrix_store
+ call free_matrix_store(tmp_matrix_store)
+
+ ENDIF ! (INODE == IONODE)
+
+ return
+ end subroutine write_Rij_MatrixElements
+
end module store_matrix
diff --git a/src/system/system.archer2.make b/src/system/system.archer2.make
new file mode 100644
index 000000000..e7bfd6fdd
--- /dev/null
+++ b/src/system/system.archer2.make
@@ -0,0 +1,57 @@
+# This is a system-specific makefile for ARCHER2.
+# See https://docs.archer2.ac.uk/ for user documentation
+# This requires the gnu programming environment
+# and the cray-libsci and cray-fftw modules
+# Starting from default modules, use
+# module swap PrgEnv-cray PrgEnv-gnu
+# module load cray-fftw
+
+# Set compilers
+FC=mpif90
+
+# OpenMP flags
+# Set this to "OMPFLAGS= " if compiling without openmp
+# Set this to "OMPFLAGS= -fopenmp" if compiling with openmp
+OMPFLAGS=-fopenmp
+# Set this to "OMP_DUMMY = " if compiling without openmp
+# Set this to "OMP_DUMMY = " if compiling with openmp
+OMP_DUMMY=
+
+# Set BLAS and LAPACK libraries
+BLAS=
+# Full scalapack library call; remove -lscalapack if using dummy diag module.
+# If using OpenMPI, use -lscalapack-openmpi instead.
+# If using Cray-libsci, use -llibsci_cray_mpi instead.
+SCALAPACK=
+
+# LibXC: choose between LibXC compatibility below or Conquest XC library
+
+# Conquest XC library
+XC_LIBRARY = CQ
+XC_LIB =
+XC_COMPFLAGS =
+
+# LibXC compatibility. Archer2 doesn't provide a module for LibXC, to use it
+# install it under your user directory and link as in the example below
+#XC_LIBRARY = LibXC_v5
+#XC_LIB = -L/mnt/lustre/a2fs-work2/work/ecseah10/ecseah10/tk-ecse08/excalibur-tests/benchmarks/spack/archer2/compute-node/opt/linux-sles15-zen2/gcc-11.2.0/libxc-5.2.3-sq6g4ckyvauupz6rfd2f5uwqp47cb5bl/lib -lxcf90 -lxc
+#XC_COMPFLAGS = -I/mnt/lustre/a2fs-work2/work/ecseah10/ecseah10/tk-ecse08/excalibur-tests/benchmarks/spack/archer2/compute-node/opt/linux-sles15-zen2/gcc-11.2.0/libxc-5.2.3-sq6g4ckyvauupz6rfd2f5uwqp47cb5bl/include
+
+# Set FFT library
+FFT_LIB=-L$(FFTW_ROOT)/lib -lfftw3
+FFT_OBJ=fft_fftw3.o
+
+LIBS= $(FFT_LIB) $(XC_LIB) $(BLAS)
+
+# Compilation flags
+# NB for gcc10 you need to add -fallow-argument-mismatch
+COMPFLAGS= -O3 -fallow-argument-mismatch -fopenmp $(XC_COMPFLAGS)
+
+# Linking flags
+LINKFLAGS= -fopenmp -L$(LIBSCI_BASE_DIR)/gnu/9.1/x86_64/lib -lsci_gnu_mpi -lsci_gnu
+
+
+# Matrix multiplication kernel type
+MULT_KERN = ompGemm_m
+# Use dummy DiagModule or not
+DIAG_DUMMY =
diff --git a/src/system/system.cosma.make b/src/system/system.cosma.make
new file mode 100644
index 000000000..965007117
--- /dev/null
+++ b/src/system/system.cosma.make
@@ -0,0 +1,40 @@
+# system.make for cosma8 (apr 2023)
+# For user docs see https://cosma.readthedocs.io/en/latest/
+# This has been tested using the following modules:
+# module load intel_comp/2022.3.0 compiler mpi mkl
+# module load fftw/3.3.10cosma8
+
+
+# Set compilers
+FC=mpif90
+F77=mpif77
+
+# Linking flags
+LINKFLAGS= ${MKLROOT}/lib/intel64/libmkl_blas95_lp64.a ${MKLROOT}/lib/intel64/libmkl_lapack95_lp64.a -L${MKLROOT}/lib/intel64 -lmkl_scalapack_lp64 -lmkl_intel_lp64 -lmkl_intel_thread -lmkl_core -lmkl_blacs_intelmpi_lp64 -liomp5 -lpthread -lm -ldl -fopenmp
+ARFLAGS=
+
+# Compilation flags
+# NB for gcc10 you need to add -fallow-argument-mismatch
+COMPFLAGS= -g -fopenmp -O3 $(XC_COMPFLAGS) -I${MKLROOT}/include/intel64/lp64 -I"${MKLROOT}/include" -fno-omit-frame-pointer -xHost
+COMPFLAGS_F77= $(COMPFLAGS)
+
+# LibXC compatibility (LibXC below) or Conquest XC library
+
+# Conquest XC library
+XC_LIBRARY = CQ
+XC_LIB =
+XC_COMPFLAGS =
+
+# Set FFT library
+FFT_LIB=-lmkl_rt
+FFT_OBJ=fft_fftw3.o
+
+# Full library call; remove scalapack if using dummy diag module
+LIBS= $(FFT_LIB) $(XC_LIB)
+
+# Matrix multiplication kernel type
+MULT_KERN = default
+# Use dummy DiagModule or not
+DIAG_DUMMY =
+
+
diff --git a/src/system/system.mac.make b/src/system/system.mac.make
new file mode 100644
index 000000000..99a0e1434
--- /dev/null
+++ b/src/system/system.mac.make
@@ -0,0 +1,56 @@
+# This is an example system-specific makefile. You will need to adjust
+# it for the actual system you are running on.
+
+# Set compilers
+FC=/opt/homebrew/bin/mpifort
+
+# OpenMP flags
+# Set this to "OMPFLAGS= " if compiling without openmp
+# Set this to "OMPFLAGS= -fopenmp" if compiling with openmp
+OMPFLAGS= -fopenmp
+# Set this to "OMP_DUMMY = DUMMY" if compiling without openmp
+# Set this to "OMP_DUMMY = " if compiling with openmp
+OMP_DUMMY =
+
+# Set BLAS and LAPACK libraries
+# MacOS X
+# BLAS= -lvecLibFort
+# Intel MKL use the Intel tool
+# Generic
+BLAS= -llapack -lblas
+# Full scalapack library call; remove -lscalapack if using dummy diag module.
+# If using OpenMPI, use -lscalapack-openmpi instead.
+# If using Cray-libsci, use -llibsci_cray_mpi instead.
+SCALAPACK = -lscalapack
+
+# LibXC: choose between LibXC compatibility below or Conquest XC library
+
+# Conquest XC library
+#XC_LIBRARY = CQ
+#XC_LIB =
+#XC_COMPFLAGS =
+
+# LibXC compatibility
+# Choose LibXC version: v4 (deprecated) or v5/6 (v5 and v6 have the same interface)
+#XC_LIBRARY = LibXC_v4
+XC_LIBRARY = LibXC_v5
+XC_LIB = -lxcf90 -lxc
+XC_COMPFLAGS = -I/opt/homebrew/Cellar/libxc/6.2.2/include
+
+# Set FFT library
+FFT_LIB=-lfftw3
+FFT_OBJ=fft_fftw3.o
+
+LIBS= $(FFT_LIB) $(XC_LIB) $(SCALAPACK) $(BLAS)
+
+# Compilation flags
+# NB for gcc10 you need to add -fallow-argument-mismatch
+COMPFLAGS= -fallow-argument-mismatch -O3 $(OMPFLAGS) $(XC_COMPFLAGS) -I/opt/homebrew/Cellar/openblas/0.3.27/include -I/opt/homebrew/Cellar/lapack/3.12.0/include -I/opt/homebrew/Cellar/fftw/3.3.10_1/include
+
+# Linking flags
+LINKFLAGS= $(OMPFLAGS) -L/opt/homebrew/Cellar/openblas/0.3.27/lib -L/opt/homebrew/Cellar/lapack/3.12.0/lib -L/opt/homebrew/Cellar/fftw/3.3.10_1/lib -L/opt/homebrew/Cellar/libxc/6.2.2/lib -L/opt/homebrew/Cellar/scalapack/2.2.0_1/lib
+
+# Matrix multiplication kernel type
+MULT_KERN = default
+# Use dummy DiagModule or not
+DIAG_DUMMY =
diff --git a/src/system/system.myriad.make b/src/system/system.myriad.make
new file mode 100644
index 000000000..74ddec687
--- /dev/null
+++ b/src/system/system.myriad.make
@@ -0,0 +1,63 @@
+# This is a system.make file for the UCL Myriad machine. See
+# https://www.rc.ucl.ac.uk/docs/Clusters/Myriad/ for details
+# module load gcc-libs/10.2.0
+# module load compilers/intel/2022.2
+# module load mpi/intel/2021.6.0
+# module load libxc/6.2.2/intel-2022
+
+# Set compilers
+FC=mpif90
+F77=mpif77
+
+# OpenMP flags
+# Set this to "OMPFLAGS= " if compiling without openmp
+# Set this to "OMPFLAGS= -fopenmp" if compiling with openmp
+OMPFLAGS= -fopenmp
+
+# Set BLAS and LAPACK libraries
+# MacOS X
+# BLAS= -lvecLibFort
+# Intel MKL use the Intel tool
+# Generic
+#BLAS= -llapack -lblas
+
+# LibXC: choose between LibXC compatibility below or Conquest XC library
+
+# Conquest XC library
+#XC_LIBRARY = CQ
+#XC_LIB =
+#XC_COMPFLAGS =
+
+# LibXC compatibility
+# Choose LibXC version: v4 (deprecated) or v5/6 (v5 and v6 have the same interface)
+XC_LIBRARY = LibXC_v5
+XC_LIB = -lxcf90 -lxc
+XC_COMPFLAGS = -I/usr/local/include
+
+# Compilation flags
+# NB for gcc10 you need to add -fallow-argument-mismatch
+COMPFLAGS= -O3 -g $(OMPFLAGS) $(XC_COMPFLAGS) -I"${MKLROOT}/include"
+COMPFLAGS_F77= $(COMPFLAGS)
+
+# Set FFT library
+FFT_LIB=-lmkl_rt
+FFT_OBJ=fft_fftw3.o
+
+# Full library call; remove scalapack if using dummy diag module
+# If using OpenMPI, use -lscalapack-openmpi instead.
+#LIBS= $(FFT_LIB) $(XC_LIB) -lscalapack $(BLAS)
+LIBS= $(FFT_LIB) $(XC_LIB)
+
+# Linking flags
+LINKFLAGS= -L${MKLROOT}/lib/intel64 -lmkl_scalapack_lp64 -lmkl_cdft_core -lmkl_intel_lp64 -lmkl_intel_thread -lmkl_core -lmkl_blacs_intelmpi_lp64 -liomp5 -lpthread -ldl $(OMPFLAGS) $(XC_LIB)
+ARFLAGS=
+
+# Matrix multiplication kernel type
+MULT_KERN = ompGemm_m
+# Use dummy DiagModule or not
+DIAG_DUMMY =
+# Use dummy omp_module or not.
+# Set this to "OMP_DUMMY = DUMMY" if compiling without openmp
+# Set this to "OMP_DUMMY = " if compiling with openmp
+OMP_DUMMY =
+
diff --git a/src/system/system.ubuntu.make b/src/system/system.ubuntu.make
new file mode 100644
index 000000000..66e1f1006
--- /dev/null
+++ b/src/system/system.ubuntu.make
@@ -0,0 +1,47 @@
+# (2024/09/04) Makefile for Ubuntu
+# Set compilers
+FC=mpif90
+
+# OpenMP flags
+# Set this to "OMPFLAGS= " if compiling without openmp
+# Set this to "OMPFLAGS= -fopenmp" if compiling with openmp
+OMPFLAGS=
+# Set this to "OMP_DUMMY = DUMMY" if compiling without openmp
+# Set this to "OMP_DUMMY = " if compiling with openmp
+OMP_DUMMY = DUMMY
+
+# Set BLAS and LAPACK libraries
+# MacOS X
+# BLAS= -lvecLibFort
+# Intel MKL use the Intel tool
+# Generic
+BLAS= -llapack -lblas
+# Full scalapack library call; remove -lscalapack if using dummy diag module.
+# If using OpenMPI, use -lscalapack-openmpi instead.
+# If using Cray-libsci, use -llibsci_cray_mpi instead.
+SCALAPACK = -lscalapack-openmpi
+
+# LibXC compatibility
+# Choose LibXC version: v4 (deprecated) or v5/6 (v5 and v6 have the same interface)
+# XC_LIBRARY = LibXC_v4
+XC_LIBRARY = LibXC_v5
+XC_LIB = -lxcf90 -lxc
+XC_COMPFLAGS = -I${HOME}/local/include -I/usr/local/include
+
+# Set FFT library
+FFT_LIB=-lfftw3
+FFT_OBJ=fft_fftw3.o
+
+LIBS= $(FFT_LIB) $(XC_LIB) $(SCALAPACK) $(BLAS)
+
+# Compilation flags
+# NB for gcc10 you need to add -fallow-argument-mismatch
+COMPFLAGS= -O3 $(OMPFLAGS) $(XC_COMPFLAGS) -fallow-argument-mismatch
+
+# Linking flags
+LINKFLAGS= -L${HOME}/local/lib -L/usr/local/lib $(OMPFLAGS)
+
+# Matrix multiplication kernel type
+MULT_KERN = default
+# Use dummy DiagModule or not
+DIAG_DUMMY =
\ No newline at end of file
diff --git a/testsuite/.gitignore b/testsuite/.gitignore
index 9e9eba2f1..2d316f004 100644
--- a/testsuite/.gitignore
+++ b/testsuite/.gitignore
@@ -5,3 +5,4 @@ Conquest_w*
*.bib
*.dat
*.log
+fort.*
\ No newline at end of file
diff --git a/testsuite/test_003_bulk_BTO_polarisation/Ba.ion b/testsuite/test_003_bulk_BTO_polarisation/Ba.ion
index 4f24f591b..d2306074a 100644
--- a/testsuite/test_003_bulk_BTO_polarisation/Ba.ion
+++ b/testsuite/test_003_bulk_BTO_polarisation/Ba.ion
@@ -8,7 +8,7 @@
Hamann input file name: Ba.in (appended at end of file)
Core radii (bohr) : l=0 2.150 l=1 1.900 l=2 2.150
3 valence shells : 5s 5p 6s
- XC functional code : -001012
+ XC functional code : 3
XC description : Perdew & Wang
Includes partial core corrections
diff --git a/testsuite/test_003_bulk_BTO_polarisation/O.ion b/testsuite/test_003_bulk_BTO_polarisation/O.ion
index 87ae0e208..418d7d946 100644
--- a/testsuite/test_003_bulk_BTO_polarisation/O.ion
+++ b/testsuite/test_003_bulk_BTO_polarisation/O.ion
@@ -8,7 +8,7 @@
Hamann input file name: O.in (appended at end of file)
Core radii (bohr) : l=0 1.350 l=1 1.450 l=2 1.350
2 valence shells : 2s 2p
- XC functional code : -001012
+ XC functional code : 3
XC description : Perdew & Wang
Includes partial core corrections
diff --git a/testsuite/test_003_bulk_BTO_polarisation/Ti.ion b/testsuite/test_003_bulk_BTO_polarisation/Ti.ion
index f3fdd3a84..5196782ff 100644
--- a/testsuite/test_003_bulk_BTO_polarisation/Ti.ion
+++ b/testsuite/test_003_bulk_BTO_polarisation/Ti.ion
@@ -8,7 +8,7 @@
Hamann input file name: Ti.in (appended at end of file)
Core radii (bohr) : l=0 1.350 l=1 1.300 l=2 1.650
4 valence shells : 3s 3p 4s 3d
- XC functional code : -001012
+ XC functional code : 3
XC description : Perdew & Wang
Includes partial core corrections
diff --git a/testsuite/test_004_isol_C2H4_4proc_PBE0CRI/C_PBE_SZP_CQ.ion b/testsuite/test_004_isol_C2H4_4proc_PBE0CRI/C_PBE_SZP_CQ.ion
new file mode 100644
index 000000000..d02721f29
--- /dev/null
+++ b/testsuite/test_004_isol_C2H4_4proc_PBE0CRI/C_PBE_SZP_CQ.ion
@@ -0,0 +1,3983 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2023/11/30 at 18:44
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: C.in (appended at end of file)
+ Core radii (bohr) : l=0 1.200 l=1 1.250
+ 2 valence shells : 2s 2p
+ XC functional code : 000101
+ XC description : GGA PBE96
+ Includes partial core corrections
+
+
+C basis set with GGA PBE96 functional
+n = 2, l = 0, 1 zetas
+ Radii: 6.25
+n = 2, l = 1, 1 zetas
+ Radii: 6.25
+n = 3, l = 2, 1 zetas, perturbative polarisation shell
+ Radii: 6.25
+
+
+ C pb nrl pcec
+
+
+C # Element symbol
+C # Label
+ 6.00 # Atomic number
+ 4.0000000000 # Valence charge
+ 12.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 2 3 # Lmax for basis, no of orbitals
+ 1 4 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 2 1 0 2.000000 #orbital l, n, z, is_polarized, population
+ 625 0.0100114372662820 6.2471368541599936
+ 0.00000000000 0.36399167361
+ 0.01001143727 0.36419984924
+ 0.02002287453 0.36482394184
+ 0.03003431180 0.36586265061
+ 0.04004574907 0.36731381168
+ 0.05005718633 0.36917440439
+ 0.06006862360 0.37144056001
+ 0.07008006086 0.37410757294
+ 0.08009149813 0.37716991423
+ 0.09010293540 0.38062124745
+ 0.10011437266 0.38445444689
+ 0.11012580993 0.38866161785
+ 0.12013724720 0.39323411912
+ 0.13014868446 0.39816258747
+ 0.14016012173 0.40343696403
+ 0.15017155899 0.40904652250
+ 0.16018299626 0.41497989916
+ 0.17019443353 0.42122512431
+ 0.18020587079 0.42776965532
+ 0.19021730806 0.43460041100
+ 0.20022874533 0.44170380712
+ 0.21024018259 0.44906579307
+ 0.22025161986 0.45667188949
+ 0.23026305712 0.46450722667
+ 0.24027449439 0.47255658362
+ 0.25028593166 0.48080442768
+ 0.26029736892 0.48923495457
+ 0.27030880619 0.49783212865
+ 0.28032024346 0.50657972332
+ 0.29033168072 0.51546136139
+ 0.30034311799 0.52446055533
+ 0.31035455525 0.53356074727
+ 0.32036599252 0.54274534856
+ 0.33037742979 0.55199777883
+ 0.34038886705 0.56130150444
+ 0.35040030432 0.57064007616
+ 0.36041174159 0.57999716604
+ 0.37042317885 0.58935660331
+ 0.38043461612 0.59870240924
+ 0.39044605338 0.60801883088
+ 0.40045749065 0.61729037362
+ 0.41046892792 0.62650183241
+ 0.42048036518 0.63563832169
+ 0.43049180245 0.64468530387
+ 0.44050323972 0.65362861635
+ 0.45051467698 0.66245449707
+ 0.46052611425 0.67114960839
+ 0.47053755152 0.67970105955
+ 0.48054898878 0.68809642732
+ 0.49056042605 0.69632377514
+ 0.50057186331 0.70437167056
+ 0.51058330058 0.71222920099
+ 0.52059473785 0.71988598774
+ 0.53060617511 0.72733219852
+ 0.54061761238 0.73455855805
+ 0.55062904965 0.74155635721
+ 0.56064048691 0.74831746040
+ 0.57065192418 0.75483431136
+ 0.58066336144 0.76109993730
+ 0.59067479871 0.76710795150
+ 0.60068623598 0.77285255436
+ 0.61069767324 0.77832853290
+ 0.62070911051 0.78353125883
+ 0.63072054778 0.78845668508
+ 0.64073198504 0.79310134107
+ 0.65074342231 0.79746232653
+ 0.66075485957 0.80153730400
+ 0.67076629684 0.80532449018
+ 0.68077773411 0.80882264598
+ 0.69078917137 0.81203106546
+ 0.70080060864 0.81494956363
+ 0.71081204591 0.81757846331
+ 0.72082348317 0.81991858091
+ 0.73083492044 0.82197121132
+ 0.74084635770 0.82373811198
+ 0.75085779497 0.82522148606
+ 0.76086923224 0.82642396504
+ 0.77088066950 0.82734859044
+ 0.78089210677 0.82799879510
+ 0.79090354404 0.82837838385
+ 0.80091498130 0.82849151363
+ 0.81092641857 0.82834267332
+ 0.82093785584 0.82793666313
+ 0.83094929310 0.82727857373
+ 0.84096073037 0.82637376517
+ 0.85097216763 0.82522784562
+ 0.86098360490 0.82384665004
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+ 0.88100647943 0.82040277645
+ 0.89101791670 0.81835271032
+ 0.90102935397 0.81609254966
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+# Vna:_______________
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+# Core:__________________________
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+ 2.39475451558 0.00000007854
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+ 2.41479430232 0.00000007002
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+ 2.45487387581 0.00000004886
+ 2.46489376918 0.00000004334
+ 2.47491366255 0.00000003791
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+ 2.49495344929 0.00000002768
+ 2.50497334266 0.00000002302
+ 2.51499323603 0.00000001872
+ 2.52501312940 0.00000001484
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+ 2.55507280951 0.00000000590
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+ 2.58513248962 0.00000000113
+ 2.59515238299 0.00000000044
+ 2.60517227637 0.00000000010
+ 2.61519216974 0.00000000000
+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+C 6.00 1 2 4 upf
+#
+# n l f energy (Ha)
+1 0 2.00
+2 0 2.00
+2 1 2.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.20000 -0.50533 4 7 9.00000
+1 1.25000 -0.19424 4 8 9.40000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 1.20000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 2.00000
+1 2 1.50000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+3 4.00000 1.55000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+6.00 0.01
+
diff --git a/testsuite/test_004_isol_C2H4_4proc_PBE0CRI/Conquest_coord b/testsuite/test_004_isol_C2H4_4proc_PBE0CRI/Conquest_coord
new file mode 100644
index 000000000..ce2e9ebf2
--- /dev/null
+++ b/testsuite/test_004_isol_C2H4_4proc_PBE0CRI/Conquest_coord
@@ -0,0 +1,10 @@
+22.676714 0.000000 0.000000
+0.000000 22.676714 0.000000
+0.000000 0.000000 22.676714
+6
+ 0.50000000 0.50000000 0.44437500 2 T T T
+ 0.50000000 0.50000000 0.55562500 2 T T T
+ 0.57859183 0.50000000 0.39900000 1 T T T
+ 0.57859183 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.39900000 1 T T T
diff --git a/testsuite/test_004_isol_C2H4_4proc_PBE0CRI/Conquest_input b/testsuite/test_004_isol_C2H4_4proc_PBE0CRI/Conquest_input
new file mode 100644
index 000000000..aaf3cd3e8
--- /dev/null
+++ b/testsuite/test_004_isol_C2H4_4proc_PBE0CRI/Conquest_input
@@ -0,0 +1,37 @@
+IO.Title isolated C2H4 with PBE0
+IO.Coordinates Conquest_coord
+IO.FractionalCoordinates T
+IO.Iprint 0
+
+## General Parameters
+General.NumberOfSpecies 2
+General.DifferentFunctional T
+General.FunctionalType 201
+General.PAOFromFiles T
+
+## Moving Atoms
+AtomMove.TypeOfRun static
+
+## Basis Sets
+Basis.BasisSet PAOs
+
+## Energy Minimisation
+minE.SelfConsistent T
+minE.SCTolerance 1.0e-7
+
+## Integration Grid
+Grid.GridCutoff 90
+
+## Finding Density Matrix
+DM.SolutionMethod diagon
+
+## EXX Parameters
+EXX.GridSpacing 0.6
+EXX.Scheme 1
+
+## Atomic Information
+%block ChemicalSpeciesLabel
+1 1.0080 H H_PBE_SZ_CQ.ion
+2 12.0110 C C_PBE_SZP_CQ.ion
+%endblock
+
diff --git a/testsuite/test_004_isol_C2H4_4proc_PBE0CRI/Conquest_out.ref b/testsuite/test_004_isol_C2H4_4proc_PBE0CRI/Conquest_out.ref
new file mode 100644
index 000000000..69d76b9ff
--- /dev/null
+++ b/testsuite/test_004_isol_C2H4_4proc_PBE0CRI/Conquest_out.ref
@@ -0,0 +1,97 @@
+ ________________________________________________________________________
+
+ CONQUEST
+
+ Concurrent Order N QUantum Electronic STructure
+ ________________________________________________________________________
+
+ Conquest lead developers:
+ D.R.Bowler (UCL, NIMS), T.Miyazaki (NIMS), A.Nakata (NIMS),
+ L. Truflandier (U. Bordeaux)
+
+ Developers:
+ M.Arita (NIMS), J.S.Baker (UCL), V.Brazdova (UCL), R.Choudhury (UCL),
+ S.Y.Mujahed (UCL), J.T.Poulton (UCL), Z.Raza (NIMS), A.Sena (UCL),
+ U.Terranova (UCL), L.Tong (UCL), A.Torralba (NIMS)
+
+ Early development:
+ I.J.Bush (STFC), C.M.Goringe (Keele), E.H.Hernandez (Keele)
+
+ Original inspiration and project oversight:
+ M.J.Gillan (Keele, UCL)
+ ________________________________________________________________________
+
+ Simulation cell dimensions: 22.6767 a0 x 22.6767 a0 x 22.6767 a0
+
+ Atomic coordinates (a0)
+ Atom X Y Z Species
+ 1 11.3384 11.3384 10.0770 2
+ 2 11.3384 11.3384 12.5997 2
+ 3 13.1206 11.3384 9.0480 1
+ 4 13.1206 11.3384 13.6287 1
+ 5 9.5562 11.3384 13.6287 1
+ 6 9.5562 11.3384 9.0480 1
+
+ Default k-point sampling of Gamma point only
+
+ This job was run on 2024/12/03 at 15:37 +0100
+ Code was compiled on 2024/12/03 at 14:46 +0100
+ Version comment: Git Branch: f-exx-opt; tag, hash: v1.3-256-gfe08b5ca
+
+ Job title: isolated C2H4 with PBE0
+ Job to be run: static calculation
+
+ Ground state search:
+ Support functions represented with PAO basis
+ 1:1 PAO to SF mapping
+ Non-spin-polarised electrons
+ Solving for the K matrix using diagonalisation
+
+ Integration grid spacing: 0.227 a0 x 0.227 a0 x 0.227 a0
+
+ Number of species: 2
+ --------------------------------------------------------
+ | # mass (au) Charge (e) SF Rad (a0) NSF Label |
+ --------------------------------------------------------
+ | 1 1.008 1.000 7.030 1 H |
+ | 2 12.011 4.000 6.576 9 C |
+ --------------------------------------------------------
+
+ The calculation will be performed on 4 processes
+
+ The calculation will be performed on 1 thread
+
+ Using the default matrix multiplication kernel
+
+ The functional used will be hyb PBE0
+
+ PulayMixSC: Reached SCF tolerance of 0.79157E-07 after 15 iterations
+ | Number of electrons = 12.000013
+ |* Harris-Foulkes energy = -13.959870942283880 Ha
+
+ force: Forces on atoms (Ha/a0)
+ force: Atom X Y Z
+ force: 1 -0.0000000000 -0.0000000000 -0.0093924506
+ force: 2 0.0000000000 -0.0000000000 0.0093924506
+ force: 3 0.0921431811 0.0000000000 -0.0532306082
+ force: 4 0.0921431811 -0.0000000000 0.0532306082
+ force: 5 -0.0921431811 0.0000000000 0.0532306082
+ force: 6 -0.0921431811 0.0000000000 -0.0532306082
+
+ force: Maximum force : 0.09214318(Ha/a0) on atom 5 in x direction
+ force: Force Residual: 0.08705543 Ha/a0
+ force: Total stress: -1.65650483 -0.00122588 -1.29183090 GPa
+
+ BIBLIOGRAPHY: Please consider citing the following references in the conquest.bib file
+
+ CONQUEST: Bowler2002pt, Miyazaki2004, Nakata2020
+ Basis: Bowler2019
+ DM: Bowler:2006xr
+ Pseudopotentials: Hamann2013, Bowler2019
+
+
+ Warnings written to file Conquest_warnings; please check
+
+ Max total mem use is 147.712 MB
+
+ Total run time was: 15.510 seconds
diff --git a/testsuite/test_004_isol_C2H4_4proc_PBE0CRI/H_PBE_SZ_CQ.ion b/testsuite/test_004_isol_C2H4_4proc_PBE0CRI/H_PBE_SZ_CQ.ion
new file mode 100644
index 000000000..134fc4206
--- /dev/null
+++ b/testsuite/test_004_isol_C2H4_4proc_PBE0CRI/H_PBE_SZ_CQ.ion
@@ -0,0 +1,2378 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2021/02/06 at 16:18
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: H.in (appended at end of file)
+ Core radii (bohr) : l=0 1.000 l=1 0.700
+ 1 valence shells : 1s
+ XC functional code : 000101
+ XC description : GGA PBE96
+
+
+H basis set with GGA PBE96 functional
+n = 1, l = 0, 1 zetas
+ Radii: 6.73
+
+
+ H pb nrl nc
+
+
+H # Element symbol
+H # Label
+ 1.00 # Atomic number
+ 1.0000000000 # Valence charge
+ 1.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 0 1 # Lmax for basis, no of orbitals
+ 1 3 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 1 1 0 1.000000 #orbital l, n, z, is_polarized, population
+ 673 0.0100108094935117 6.7272639796398339
+ 0.00000000000 1.56155255224
+ 0.01001080949 1.56134081579
+ 0.02002161899 1.56070586103
+ 0.03003242848 1.55964896338
+ 0.04004323797 1.55817219676
+ 0.05005404747 1.55627843492
+ 0.06006485696 1.55397133802
+ 0.07007566645 1.55125532942
+ 0.08008647595 1.54813556702
+ 0.09009728544 1.54461791016
+ 0.10010809494 1.54070888255
+ 0.11011890443 1.53641563176
+ 0.12012971392 1.53174588577
+ 0.13014052342 1.52670790712
+ 0.14015133291 1.52131044519
+ 0.15016214240 1.51556268735
+ 0.16017295190 1.50947420926
+ 0.17018376139 1.50305492529
+ 0.18019457088 1.49631503919
+ 0.19020538038 1.48926499595
+ 0.20021618987 1.48191543510
+ 0.21022699936 1.47427714601
+ 0.22023780886 1.46636102560
+ 0.23024861835 1.45817803890
+ 0.24025942784 1.44973918268
+ 0.25027023734 1.44105545246
+ 0.26028104683 1.43213781311
+ 0.27029185632 1.42299717314
+ 0.28030266582 1.41364436277
+ 0.29031347531 1.40409011574
+ 0.30032428481 1.39434505482
+ 0.31033509430 1.38441968091
+ 0.32034590379 1.37432436547
+ 0.33035671329 1.36406934614
+ 0.34036752278 1.35366472507
+ 0.35037833227 1.34312046995
+ 0.36038914177 1.33244641697
+ 0.37039995126 1.32165227563
+ 0.38041076075 1.31074763480
+ 0.39042157025 1.29974196964
+ 0.40043237974 1.28864464905
+ 0.41044318923 1.27746494296
+ 0.42045399873 1.26621202936
+ 0.43046480822 1.25489500038
+ 0.44047561771 1.24352286722
+ 0.45048642721 1.23210456360
+ 0.46049723670 1.22064894730
+ 0.47050804620 1.20916479960
+ 0.48051885569 1.19766082252
+ 0.49052966518 1.18614563362
+ 0.50054047468 1.17462775819
+ 0.51055128417 1.16311561896
+ 0.52056209366 1.15161752334
+ 0.53057290316 1.14014164812
+ 0.54058371265 1.12869602198
+ 0.55059452214 1.11728850594
+ 0.56060533164 1.10592677176
+ 0.57061614113 1.09461827923
+ 0.58062695062 1.08337025177
+ 0.59063776012 1.07218965161
+ 0.60064856961 1.06108315432
+ 0.61065937910 1.05005712345
+ 0.62067018860 1.03911758559
+ 0.63068099809 1.02827020618
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+ 0.65070261708 1.00687264443
+ 0.66071342657 0.99633179185
+ 0.67072423607 0.98590172198
+ 0.68073504556 0.97558599407
+ 0.69074585505 0.96538770341
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+ 0.71076747404 0.94535345800
+ 0.72077828353 0.93552133092
+ 0.73078909303 0.92581430161
+ 0.74079990252 0.91623311803
+ 0.75081071201 0.90677808017
+ 0.76082152151 0.89744905638
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+ 0.78084314049 0.87916648941
+ 0.79085394999 0.87021072173
+ 0.80086475948 0.86137657557
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+# KBs:_______________
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+# Vna:_______________
+ 673 0.01001080949 6.72726397964 # npts, delta, cutoff
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+ 6.59712345622 -0.15158167173
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+ 6.71725317015 -0.14887081359
+ 6.72726397964 -0.14864884194
+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+H 1.00 0 1 4 upf
+#
+# n l f energy (Ha)
+1 0 1.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.00000 -0.23860 4 7 8.50000
+1 0.70000 0.05000 4 7 11.00000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 0.70000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 1.00000
+1 1 1.00000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+0 0.00000 0.00000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+3.00 0.01
+
diff --git a/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/C.gto b/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/C.gto
new file mode 100644
index 000000000..fb84513f9
--- /dev/null
+++ b/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/C.gto
@@ -0,0 +1,14 @@
+C
+3
+2S 3 2.0 0
+ 3.0500154803 -0.8718503385 0.0000000000
+ 0.1599863956 0.3605314379 0.0000000000
+ 0.5242567425 0.8731953379 0.0000000000
+2P 3 2.0 0
+ 0.1720417090 0.1855258456 0.0000000000
+ 2.7272258524 1.7315939925 0.0000000000
+ 0.7055493743 0.8775500569 0.0000000000
+3D 3 0.0 1
+ 86.0321546336 0.6114404190 0.0000000000
+ 3.6206685167 1.5850293864 0.0000000000
+ 0.5229417354 0.5889629298 0.0000000000
diff --git a/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/C_PBE_SZP_CQ.ion b/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/C_PBE_SZP_CQ.ion
new file mode 100644
index 000000000..d02721f29
--- /dev/null
+++ b/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/C_PBE_SZP_CQ.ion
@@ -0,0 +1,3983 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2023/11/30 at 18:44
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: C.in (appended at end of file)
+ Core radii (bohr) : l=0 1.200 l=1 1.250
+ 2 valence shells : 2s 2p
+ XC functional code : 000101
+ XC description : GGA PBE96
+ Includes partial core corrections
+
+
+C basis set with GGA PBE96 functional
+n = 2, l = 0, 1 zetas
+ Radii: 6.25
+n = 2, l = 1, 1 zetas
+ Radii: 6.25
+n = 3, l = 2, 1 zetas, perturbative polarisation shell
+ Radii: 6.25
+
+
+ C pb nrl pcec
+
+
+C # Element symbol
+C # Label
+ 6.00 # Atomic number
+ 4.0000000000 # Valence charge
+ 12.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 2 3 # Lmax for basis, no of orbitals
+ 1 4 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 2 1 0 2.000000 #orbital l, n, z, is_polarized, population
+ 625 0.0100114372662820 6.2471368541599936
+ 0.00000000000 0.36399167361
+ 0.01001143727 0.36419984924
+ 0.02002287453 0.36482394184
+ 0.03003431180 0.36586265061
+ 0.04004574907 0.36731381168
+ 0.05005718633 0.36917440439
+ 0.06006862360 0.37144056001
+ 0.07008006086 0.37410757294
+ 0.08009149813 0.37716991423
+ 0.09010293540 0.38062124745
+ 0.10011437266 0.38445444689
+ 0.11012580993 0.38866161785
+ 0.12013724720 0.39323411912
+ 0.13014868446 0.39816258747
+ 0.14016012173 0.40343696403
+ 0.15017155899 0.40904652250
+ 0.16018299626 0.41497989916
+ 0.17019443353 0.42122512431
+ 0.18020587079 0.42776965532
+ 0.19021730806 0.43460041100
+ 0.20022874533 0.44170380712
+ 0.21024018259 0.44906579307
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+# Vna:_______________
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+ 5.99685092250 -0.66701750053
+ 6.00686235977 -0.66590580389
+ 6.01687379704 -0.66479780674
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+ 6.03689667157 -0.66259283725
+ 6.04690810883 -0.66149582841
+ 6.05691954610 -0.66040244603
+ 6.06693098337 -0.65931267217
+ 6.07694242063 -0.65822648899
+ 6.08695385790 -0.65714387877
+ 6.09696529517 -0.65606482391
+ 6.10697673243 -0.65498930693
+ 6.11698816970 -0.65391731045
+ 6.12699960696 -0.65284881723
+ 6.13701104423 -0.65178381010
+ 6.14702248150 -0.65072227205
+ 6.15703391876 -0.64966418615
+ 6.16704535603 -0.64860953558
+ 6.17705679330 -0.64755830364
+ 6.18706823056 -0.64651047374
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+ 6.20709110509 -0.64442495420
+ 6.21710254236 -0.64338723191
+ 6.22711397963 -0.64235284634
+ 6.23712541689 -0.64132178143
+ 6.24713685416 -0.64029332051
+# Core:__________________________
+ 262 0.01001989337 2.61519216974 # npts, delta, cutoff
+ 0.00000000000 0.87236701390
+ 0.01001989337 0.87200154737
+ 0.02003978674 0.87090598593
+ 0.03005968011 0.86908291315
+ 0.04007957348 0.86653661495
+ 0.05009946685 0.86327306742
+ 0.06011936022 0.85929991675
+ 0.07013925359 0.85462645159
+ 0.08015914697 0.84926356764
+ 0.09017904034 0.84322372913
+ 0.10019893371 0.83652092332
+ 0.11021882708 0.82917060772
+ 0.12023872045 0.82118965753
+ 0.13025861382 0.81259630320
+ 0.14027850719 0.80341006345
+ 0.15029840056 0.79365167872
+ 0.16031829393 0.78334303544
+ 0.17033818730 0.77250708996
+ 0.18035808067 0.76116778731
+ 0.19037797404 0.74934997856
+ 0.20039786741 0.73707933484
+ 0.21041776078 0.72438225958
+ 0.22043765415 0.71128579873
+ 0.23045754752 0.69781755035
+ 0.24047744090 0.68400557257
+ 0.25049733427 0.66987829152
+ 0.26051722764 0.65546440905
+ 0.27053712101 0.64079281080
+ 0.28055701438 0.62589247505
+ 0.29057690775 0.61079238242
+ 0.30059680112 0.59552142736
+ 0.31061669449 0.58010833106
+ 0.32063658786 0.56458155717
+ 0.33065648123 0.54896922904
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+ 0.35069626797 0.51759823149
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+ 0.40079573483 0.43954324378
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+ 0.73145221606 0.07722203008
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+ 0.75149200280 0.06655961951
+ 0.76151189617 0.06165690581
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+ 0.78155168291 0.05266592032
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+ 0.83165114976 0.03451963474
+ 0.84167104313 0.03155899046
+ 0.85169093650 0.02879949555
+ 0.86171082987 0.02623190812
+ 0.87173072325 0.02384707401
+ 0.88175061662 0.02163595358
+ 0.89177050999 0.01958964636
+ 0.90179040336 0.01769941385
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+ 0.92183019010 0.01435315056
+ 0.93185008347 0.01288062835
+ 0.94186997684 0.01153122939
+ 0.95188987021 0.01029729490
+ 0.96190976358 0.00917142238
+ 0.97192965695 0.00814647470
+ 0.98194955032 0.00721558735
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+ 1.00198933706 0.00560993109
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+ 2.24445611502 0.00000003644
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+ 2.29455558188 0.00000007182
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+ 2.31459536862 0.00000008100
+ 2.32461526199 0.00000008411
+ 2.33463515536 0.00000008620
+ 2.34465504873 0.00000008725
+ 2.35467494210 0.00000008729
+ 2.36469483547 0.00000008637
+ 2.37471472884 0.00000008455
+ 2.38473462221 0.00000008191
+ 2.39475451558 0.00000007854
+ 2.40477440895 0.00000007454
+ 2.41479430232 0.00000007002
+ 2.42481419569 0.00000006508
+ 2.43483408906 0.00000005983
+ 2.44485398244 0.00000005439
+ 2.45487387581 0.00000004886
+ 2.46489376918 0.00000004334
+ 2.47491366255 0.00000003791
+ 2.48493355592 0.00000003267
+ 2.49495344929 0.00000002768
+ 2.50497334266 0.00000002302
+ 2.51499323603 0.00000001872
+ 2.52501312940 0.00000001484
+ 2.53503302277 0.00000001139
+ 2.54505291614 0.00000000841
+ 2.55507280951 0.00000000590
+ 2.56509270288 0.00000000385
+ 2.57511259625 0.00000000226
+ 2.58513248962 0.00000000113
+ 2.59515238299 0.00000000044
+ 2.60517227637 0.00000000010
+ 2.61519216974 0.00000000000
+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+C 6.00 1 2 4 upf
+#
+# n l f energy (Ha)
+1 0 2.00
+2 0 2.00
+2 1 2.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.20000 -0.50533 4 7 9.00000
+1 1.25000 -0.19424 4 8 9.40000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 1.20000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 2.00000
+1 2 1.50000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+3 4.00000 1.55000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+6.00 0.01
+
diff --git a/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/Conquest_coord b/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/Conquest_coord
new file mode 100644
index 000000000..ce2e9ebf2
--- /dev/null
+++ b/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/Conquest_coord
@@ -0,0 +1,10 @@
+22.676714 0.000000 0.000000
+0.000000 22.676714 0.000000
+0.000000 0.000000 22.676714
+6
+ 0.50000000 0.50000000 0.44437500 2 T T T
+ 0.50000000 0.50000000 0.55562500 2 T T T
+ 0.57859183 0.50000000 0.39900000 1 T T T
+ 0.57859183 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.39900000 1 T T T
diff --git a/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/Conquest_input b/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/Conquest_input
new file mode 100644
index 000000000..1592f812a
--- /dev/null
+++ b/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/Conquest_input
@@ -0,0 +1,37 @@
+IO.Title isolated C2H4 with PBE0
+IO.Coordinates Conquest_coord
+IO.FractionalCoordinates T
+IO.Iprint 0
+
+## General Parameters
+General.NumberOfSpecies 2
+General.DifferentFunctional T
+General.FunctionalType 201
+General.PAOFromFiles T
+
+## Moving Atoms
+AtomMove.TypeOfRun static
+
+## Basis Sets
+Basis.BasisSet PAOs
+
+## Energy Minimisation
+minE.SelfConsistent T
+minE.SCTolerance 1.0e-7
+
+## Integration Grid
+Grid.GridCutoff 90
+
+## Finding Density Matrix
+DM.SolutionMethod diagon
+
+## EXX Parameters
+EXX.Scheme 3
+EXX.GTO T
+
+## Atomic Information
+%block ChemicalSpeciesLabel
+1 1.0080 H H_PBE_SZ_CQ.ion
+2 12.0110 C C_PBE_SZP_CQ.ion
+%endblock
+
diff --git a/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/Conquest_out.ref b/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/Conquest_out.ref
new file mode 100644
index 000000000..c7ca7139f
--- /dev/null
+++ b/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/Conquest_out.ref
@@ -0,0 +1,95 @@
+ ________________________________________________________________________
+
+ CONQUEST
+
+ Concurrent Order N QUantum Electronic STructure
+ ________________________________________________________________________
+
+ Conquest lead developers:
+ D.R.Bowler (UCL, NIMS), T.Miyazaki (NIMS), A.Nakata (NIMS),
+ L. Truflandier (U. Bordeaux)
+
+ Developers:
+ M.Arita (NIMS), J.S.Baker (UCL), V.Brazdova (UCL), R.Choudhury (UCL),
+ S.Y.Mujahed (UCL), J.T.Poulton (UCL), Z.Raza (NIMS), A.Sena (UCL),
+ U.Terranova (UCL), L.Tong (UCL), A.Torralba (NIMS)
+
+ Early development:
+ I.J.Bush (STFC), C.M.Goringe (Keele), E.H.Hernandez (Keele)
+
+ Original inspiration and project oversight:
+ M.J.Gillan (Keele, UCL)
+ ________________________________________________________________________
+
+ Simulation cell dimensions: 22.6767 a0 x 22.6767 a0 x 22.6767 a0
+
+ Atomic coordinates (a0)
+ Atom X Y Z Species
+ 1 11.3384 11.3384 10.0770 2
+ 2 11.3384 11.3384 12.5997 2
+ 3 13.1206 11.3384 9.0480 1
+ 4 13.1206 11.3384 13.6287 1
+ 5 9.5562 11.3384 13.6287 1
+ 6 9.5562 11.3384 9.0480 1
+
+ Default k-point sampling of Gamma point only
+
+ This job was run on 2023/11/30 at 18:50 +0100
+ Code was compiled on 2023/11/30 at 17:50 +0100
+ Version comment: Git Branch: f-exx-opt; tag, hash: v1.2-164-ga1b33add
+
+ Job title: isolated C2H4 with PBE0
+ Job to be run: static calculation
+
+ Ground state search:
+ Support functions represented with PAO basis
+ 1:1 PAO to SF mapping
+ Non-spin-polarised electrons
+ Solving for the K matrix using diagonalisation
+
+ Integration grid spacing: 0.227 a0 x 0.227 a0 x 0.227 a0
+
+ Number of species: 2
+ --------------------------------------------------------
+ | # mass (au) Charge (e) SF Rad (a0) NSF Label |
+ --------------------------------------------------------
+ | 1 1.008 1.000 7.030 1 H |
+ | 2 12.011 4.000 6.576 9 C |
+ --------------------------------------------------------
+
+ The calculation will be performed on 4 processes
+
+ The calculation will be performed on 1 thread
+
+ The functional used will be hyb PBE0
+
+ PulayMixSC: Reached SCF tolerance of 0.78125E-07 after 14 iterations
+ | Number of electrons = 12.000012
+ |* Harris-Foulkes energy = -13.983024122331756 Ha
+
+ force: Forces on atoms (Ha/a0)
+ force: Atom X Y Z
+ force: 1 -0.0000000000 0.0000000000 0.0148165310
+ force: 2 -0.0000000000 0.0000000000 -0.0148165310
+ force: 3 0.0881663197 0.0000000000 -0.0516876916
+ force: 4 0.0881663197 0.0000000000 0.0516876916
+ force: 5 -0.0881663197 0.0000000000 0.0516876916
+ force: 6 -0.0881663197 -0.0000000000 -0.0516876916
+
+ force: Maximum force : 0.08816632(Ha/a0) on atom 6 in x direction
+ force: Force Residual: 0.08388358 Ha/a0
+ force: Total stress: -1.58499899 -0.00124317 -1.10220619 GPa
+
+ BIBLIOGRAPHY: Please consider citing the following references in the conquest.bib file
+
+ CONQUEST: Bowler2002pt, Miyazaki2004, Nakata2020
+ Basis: Bowler2019
+ DM: Bowler:2006xr
+ Pseudopotentials: Hamann2013, Bowler2019
+
+
+ Warnings written to file Conquest_warnings; please check
+
+ Max total mem use is 282.486 MB
+
+ Total run time was: 54.395 seconds
diff --git a/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/H.gto b/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/H.gto
new file mode 100644
index 000000000..bfd323fbb
--- /dev/null
+++ b/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/H.gto
@@ -0,0 +1,6 @@
+H
+1
+1S 3 1.0 0
+ 0.5275548833 0.6715259742 0.0000000000
+ 2.7696756637 0.5826356048 0.0000000000
+ 0.1171533321 0.3049461604 0.0000000000
diff --git a/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/H_PBE_SZ_CQ.ion b/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/H_PBE_SZ_CQ.ion
new file mode 100644
index 000000000..134fc4206
--- /dev/null
+++ b/testsuite/test_005_isol_C2H4_4proc_PBE0GTO/H_PBE_SZ_CQ.ion
@@ -0,0 +1,2378 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2021/02/06 at 16:18
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: H.in (appended at end of file)
+ Core radii (bohr) : l=0 1.000 l=1 0.700
+ 1 valence shells : 1s
+ XC functional code : 000101
+ XC description : GGA PBE96
+
+
+H basis set with GGA PBE96 functional
+n = 1, l = 0, 1 zetas
+ Radii: 6.73
+
+
+ H pb nrl nc
+
+
+H # Element symbol
+H # Label
+ 1.00 # Atomic number
+ 1.0000000000 # Valence charge
+ 1.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 0 1 # Lmax for basis, no of orbitals
+ 1 3 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 1 1 0 1.000000 #orbital l, n, z, is_polarized, population
+ 673 0.0100108094935117 6.7272639796398339
+ 0.00000000000 1.56155255224
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+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+H 1.00 0 1 4 upf
+#
+# n l f energy (Ha)
+1 0 1.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.00000 -0.23860 4 7 8.50000
+1 0.70000 0.05000 4 7 11.00000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 0.70000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 1.00000
+1 1 1.00000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+0 0.00000 0.00000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+3.00 0.01
+
diff --git a/testsuite/test_006_isol_C2H4_4proc_PBE0ERI/C_PBE_SZP_CQ.ion b/testsuite/test_006_isol_C2H4_4proc_PBE0ERI/C_PBE_SZP_CQ.ion
new file mode 100644
index 000000000..d02721f29
--- /dev/null
+++ b/testsuite/test_006_isol_C2H4_4proc_PBE0ERI/C_PBE_SZP_CQ.ion
@@ -0,0 +1,3983 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2023/11/30 at 18:44
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: C.in (appended at end of file)
+ Core radii (bohr) : l=0 1.200 l=1 1.250
+ 2 valence shells : 2s 2p
+ XC functional code : 000101
+ XC description : GGA PBE96
+ Includes partial core corrections
+
+
+C basis set with GGA PBE96 functional
+n = 2, l = 0, 1 zetas
+ Radii: 6.25
+n = 2, l = 1, 1 zetas
+ Radii: 6.25
+n = 3, l = 2, 1 zetas, perturbative polarisation shell
+ Radii: 6.25
+
+
+ C pb nrl pcec
+
+
+C # Element symbol
+C # Label
+ 6.00 # Atomic number
+ 4.0000000000 # Valence charge
+ 12.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 2 3 # Lmax for basis, no of orbitals
+ 1 4 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 2 1 0 2.000000 #orbital l, n, z, is_polarized, population
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+# Vna:_______________
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+ 2.39475451558 0.00000007854
+ 2.40477440895 0.00000007454
+ 2.41479430232 0.00000007002
+ 2.42481419569 0.00000006508
+ 2.43483408906 0.00000005983
+ 2.44485398244 0.00000005439
+ 2.45487387581 0.00000004886
+ 2.46489376918 0.00000004334
+ 2.47491366255 0.00000003791
+ 2.48493355592 0.00000003267
+ 2.49495344929 0.00000002768
+ 2.50497334266 0.00000002302
+ 2.51499323603 0.00000001872
+ 2.52501312940 0.00000001484
+ 2.53503302277 0.00000001139
+ 2.54505291614 0.00000000841
+ 2.55507280951 0.00000000590
+ 2.56509270288 0.00000000385
+ 2.57511259625 0.00000000226
+ 2.58513248962 0.00000000113
+ 2.59515238299 0.00000000044
+ 2.60517227637 0.00000000010
+ 2.61519216974 0.00000000000
+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+C 6.00 1 2 4 upf
+#
+# n l f energy (Ha)
+1 0 2.00
+2 0 2.00
+2 1 2.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.20000 -0.50533 4 7 9.00000
+1 1.25000 -0.19424 4 8 9.40000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 1.20000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 2.00000
+1 2 1.50000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+3 4.00000 1.55000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+6.00 0.01
+
diff --git a/testsuite/test_006_isol_C2H4_4proc_PBE0ERI/Conquest_coord b/testsuite/test_006_isol_C2H4_4proc_PBE0ERI/Conquest_coord
new file mode 100644
index 000000000..ce2e9ebf2
--- /dev/null
+++ b/testsuite/test_006_isol_C2H4_4proc_PBE0ERI/Conquest_coord
@@ -0,0 +1,10 @@
+22.676714 0.000000 0.000000
+0.000000 22.676714 0.000000
+0.000000 0.000000 22.676714
+6
+ 0.50000000 0.50000000 0.44437500 2 T T T
+ 0.50000000 0.50000000 0.55562500 2 T T T
+ 0.57859183 0.50000000 0.39900000 1 T T T
+ 0.57859183 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.60100000 1 T T T
+ 0.42140817 0.50000000 0.39900000 1 T T T
diff --git a/testsuite/test_006_isol_C2H4_4proc_PBE0ERI/Conquest_input b/testsuite/test_006_isol_C2H4_4proc_PBE0ERI/Conquest_input
new file mode 100644
index 000000000..86f74cd05
--- /dev/null
+++ b/testsuite/test_006_isol_C2H4_4proc_PBE0ERI/Conquest_input
@@ -0,0 +1,38 @@
+IO.Title isolated C2H4 with PBE0
+IO.Coordinates Conquest_coord
+IO.FractionalCoordinates T
+IO.Iprint 0
+
+## General Parameters
+General.NumberOfSpecies 2
+General.DifferentFunctional T
+General.FunctionalType 201
+General.PAOFromFiles T
+
+## Moving Atoms
+AtomMove.TypeOfRun static
+
+## Basis Sets
+Basis.BasisSet PAOs
+
+## Energy Minimisation
+minE.SelfConsistent T
+minE.SCTolerance 1.0e-7
+
+## Integration Grid
+Grid.GridCutoff 90
+
+## Finding Density Matrix
+DM.SolutionMethod diagon
+
+## EXX Parameters
+EXX.Scheme 3
+EXX.GridSpacing 0.6
+EXX.GTO F
+
+## Atomic Information
+%block ChemicalSpeciesLabel
+1 1.0080 H H_PBE_SZ_CQ.ion
+2 12.0110 C C_PBE_SZP_CQ.ion
+%endblock
+
diff --git a/testsuite/test_006_isol_C2H4_4proc_PBE0ERI/Conquest_out.ref b/testsuite/test_006_isol_C2H4_4proc_PBE0ERI/Conquest_out.ref
new file mode 100644
index 000000000..6e6b6a0f6
--- /dev/null
+++ b/testsuite/test_006_isol_C2H4_4proc_PBE0ERI/Conquest_out.ref
@@ -0,0 +1,97 @@
+ ________________________________________________________________________
+
+ CONQUEST
+
+ Concurrent Order N QUantum Electronic STructure
+ ________________________________________________________________________
+
+ Conquest lead developers:
+ D.R.Bowler (UCL, NIMS), T.Miyazaki (NIMS), A.Nakata (NIMS),
+ L. Truflandier (U. Bordeaux)
+
+ Developers:
+ M.Arita (NIMS), J.S.Baker (UCL), V.Brazdova (UCL), R.Choudhury (UCL),
+ S.Y.Mujahed (UCL), J.T.Poulton (UCL), Z.Raza (NIMS), A.Sena (UCL),
+ U.Terranova (UCL), L.Tong (UCL), A.Torralba (NIMS)
+
+ Early development:
+ I.J.Bush (STFC), C.M.Goringe (Keele), E.H.Hernandez (Keele)
+
+ Original inspiration and project oversight:
+ M.J.Gillan (Keele, UCL)
+ ________________________________________________________________________
+
+ Simulation cell dimensions: 22.6767 a0 x 22.6767 a0 x 22.6767 a0
+
+ Atomic coordinates (a0)
+ Atom X Y Z Species
+ 1 11.3384 11.3384 10.0770 2
+ 2 11.3384 11.3384 12.5997 2
+ 3 13.1206 11.3384 9.0480 1
+ 4 13.1206 11.3384 13.6287 1
+ 5 9.5562 11.3384 13.6287 1
+ 6 9.5562 11.3384 9.0480 1
+
+ Default k-point sampling of Gamma point only
+
+ This job was run on 2024/12/03 at 15:41 +0100
+ Code was compiled on 2024/12/03 at 14:46 +0100
+ Version comment: Git Branch: f-exx-opt; tag, hash: v1.3-256-gfe08b5ca
+
+ Job title: isolated C2H4 with PBE0
+ Job to be run: static calculation
+
+ Ground state search:
+ Support functions represented with PAO basis
+ 1:1 PAO to SF mapping
+ Non-spin-polarised electrons
+ Solving for the K matrix using diagonalisation
+
+ Integration grid spacing: 0.227 a0 x 0.227 a0 x 0.227 a0
+
+ Number of species: 2
+ --------------------------------------------------------
+ | # mass (au) Charge (e) SF Rad (a0) NSF Label |
+ --------------------------------------------------------
+ | 1 1.008 1.000 7.030 1 H |
+ | 2 12.011 4.000 6.576 9 C |
+ --------------------------------------------------------
+
+ The calculation will be performed on 4 processes
+
+ The calculation will be performed on 1 thread
+
+ Using the default matrix multiplication kernel
+
+ The functional used will be hyb PBE0
+
+ PulayMixSC: Reached SCF tolerance of 0.79157E-07 after 15 iterations
+ | Number of electrons = 12.000013
+ |* Harris-Foulkes energy = -13.959870942283889 Ha
+
+ force: Forces on atoms (Ha/a0)
+ force: Atom X Y Z
+ force: 1 -0.0000000000 -0.0000000000 -0.0093924506
+ force: 2 0.0000000000 -0.0000000000 0.0093924506
+ force: 3 0.0921431811 0.0000000000 -0.0532306082
+ force: 4 0.0921431811 0.0000000000 0.0532306082
+ force: 5 -0.0921431811 0.0000000000 0.0532306082
+ force: 6 -0.0921431811 0.0000000000 -0.0532306082
+
+ force: Maximum force : 0.09214318(Ha/a0) on atom 5 in x direction
+ force: Force Residual: 0.08705543 Ha/a0
+ force: Total stress: -1.65650483 -0.00122588 -1.29183090 GPa
+
+ BIBLIOGRAPHY: Please consider citing the following references in the conquest.bib file
+
+ CONQUEST: Bowler2002pt, Miyazaki2004, Nakata2020
+ Basis: Bowler2019
+ DM: Bowler:2006xr
+ Pseudopotentials: Hamann2013, Bowler2019
+
+
+ Warnings written to file Conquest_warnings; please check
+
+ Max total mem use is 148.349 MB
+
+ Total run time was: 23.710 seconds
diff --git a/testsuite/test_006_isol_C2H4_4proc_PBE0ERI/H_PBE_SZ_CQ.ion b/testsuite/test_006_isol_C2H4_4proc_PBE0ERI/H_PBE_SZ_CQ.ion
new file mode 100644
index 000000000..134fc4206
--- /dev/null
+++ b/testsuite/test_006_isol_C2H4_4proc_PBE0ERI/H_PBE_SZ_CQ.ion
@@ -0,0 +1,2378 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2021/02/06 at 16:18
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: H.in (appended at end of file)
+ Core radii (bohr) : l=0 1.000 l=1 0.700
+ 1 valence shells : 1s
+ XC functional code : 000101
+ XC description : GGA PBE96
+
+
+H basis set with GGA PBE96 functional
+n = 1, l = 0, 1 zetas
+ Radii: 6.73
+
+
+ H pb nrl nc
+
+
+H # Element symbol
+H # Label
+ 1.00 # Atomic number
+ 1.0000000000 # Valence charge
+ 1.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 0 1 # Lmax for basis, no of orbitals
+ 1 3 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 1 1 0 1.000000 #orbital l, n, z, is_polarized, population
+ 673 0.0100108094935117 6.7272639796398339
+ 0.00000000000 1.56155255224
+ 0.01001080949 1.56134081579
+ 0.02002161899 1.56070586103
+ 0.03003242848 1.55964896338
+ 0.04004323797 1.55817219676
+ 0.05005404747 1.55627843492
+ 0.06006485696 1.55397133802
+ 0.07007566645 1.55125532942
+ 0.08008647595 1.54813556702
+ 0.09009728544 1.54461791016
+ 0.10010809494 1.54070888255
+ 0.11011890443 1.53641563176
+ 0.12012971392 1.53174588577
+ 0.13014052342 1.52670790712
+ 0.14015133291 1.52131044519
+ 0.15016214240 1.51556268735
+ 0.16017295190 1.50947420926
+ 0.17018376139 1.50305492529
+ 0.18019457088 1.49631503919
+ 0.19020538038 1.48926499595
+ 0.20021618987 1.48191543510
+ 0.21022699936 1.47427714601
+ 0.22023780886 1.46636102560
+ 0.23024861835 1.45817803890
+ 0.24025942784 1.44973918268
+ 0.25027023734 1.44105545246
+ 0.26028104683 1.43213781311
+ 0.27029185632 1.42299717314
+ 0.28030266582 1.41364436277
+ 0.29031347531 1.40409011574
+ 0.30032428481 1.39434505482
+ 0.31033509430 1.38441968091
+ 0.32034590379 1.37432436547
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+ 0.34036752278 1.35366472507
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+ 0.36038914177 1.33244641697
+ 0.37039995126 1.32165227563
+ 0.38041076075 1.31074763480
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+# Vna:_______________
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+ 6.61714507521 -0.15112302683
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+ 6.71725317015 -0.14887081359
+ 6.72726397964 -0.14864884194
+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+H 1.00 0 1 4 upf
+#
+# n l f energy (Ha)
+1 0 1.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.00000 -0.23860 4 7 8.50000
+1 0.70000 0.05000 4 7 11.00000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 0.70000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 1.00000
+1 1 1.00000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+0 0.00000 0.00000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+3.00 0.01
+
diff --git a/testsuite/test_007_isol_CH_spinpol_1proc_PBE0CRI/C_PBE_SZP_CQ.ion b/testsuite/test_007_isol_CH_spinpol_1proc_PBE0CRI/C_PBE_SZP_CQ.ion
new file mode 100644
index 000000000..d02721f29
--- /dev/null
+++ b/testsuite/test_007_isol_CH_spinpol_1proc_PBE0CRI/C_PBE_SZP_CQ.ion
@@ -0,0 +1,3983 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2023/11/30 at 18:44
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: C.in (appended at end of file)
+ Core radii (bohr) : l=0 1.200 l=1 1.250
+ 2 valence shells : 2s 2p
+ XC functional code : 000101
+ XC description : GGA PBE96
+ Includes partial core corrections
+
+
+C basis set with GGA PBE96 functional
+n = 2, l = 0, 1 zetas
+ Radii: 6.25
+n = 2, l = 1, 1 zetas
+ Radii: 6.25
+n = 3, l = 2, 1 zetas, perturbative polarisation shell
+ Radii: 6.25
+
+
+ C pb nrl pcec
+
+
+C # Element symbol
+C # Label
+ 6.00 # Atomic number
+ 4.0000000000 # Valence charge
+ 12.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 2 3 # Lmax for basis, no of orbitals
+ 1 4 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 2 1 0 2.000000 #orbital l, n, z, is_polarized, population
+ 625 0.0100114372662820 6.2471368541599936
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+ 2.58513248962 0.00000000113
+ 2.59515238299 0.00000000044
+ 2.60517227637 0.00000000010
+ 2.61519216974 0.00000000000
+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+C 6.00 1 2 4 upf
+#
+# n l f energy (Ha)
+1 0 2.00
+2 0 2.00
+2 1 2.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.20000 -0.50533 4 7 9.00000
+1 1.25000 -0.19424 4 8 9.40000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 1.20000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 2.00000
+1 2 1.50000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+3 4.00000 1.55000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+6.00 0.01
+
diff --git a/testsuite/test_007_isol_CH_spinpol_1proc_PBE0CRI/Conquest_coord b/testsuite/test_007_isol_CH_spinpol_1proc_PBE0CRI/Conquest_coord
new file mode 100644
index 000000000..9a671acc5
--- /dev/null
+++ b/testsuite/test_007_isol_CH_spinpol_1proc_PBE0CRI/Conquest_coord
@@ -0,0 +1,6 @@
+37.794523 0.000000 0.000000
+0.000000 37.794523 0.000000
+0.000000 0.000000 37.794523
+2
+ 0.500000000000 0.500000000000 0.528013000000 2 T T T
+ 0.500000000000 0.500000000000 0.471987000000 1 T T T
diff --git a/testsuite/test_007_isol_CH_spinpol_1proc_PBE0CRI/Conquest_input b/testsuite/test_007_isol_CH_spinpol_1proc_PBE0CRI/Conquest_input
new file mode 100644
index 000000000..135308b4b
--- /dev/null
+++ b/testsuite/test_007_isol_CH_spinpol_1proc_PBE0CRI/Conquest_input
@@ -0,0 +1,41 @@
+IO.Title isolated CH with PBE0
+IO.Coordinates Conquest_coord
+IO.FractionalCoordinates T
+IO.Iprint 0
+
+## General Parameters
+General.NumberOfSpecies 2
+General.DifferentFunctional T
+General.FunctionalType 201
+General.PAOFromFiles T
+
+## Moving Atoms
+AtomMove.TypeOfRun static
+
+## Basis Sets
+Basis.BasisSet PAOs
+
+## Energy Minimisation
+minE.SelfConsistent T
+minE.SCTolerance 1.0e-3
+
+## Spin Polarisation
+Spin.SpinPolarised T
+Spin.FixSpin F
+Spin.Magn 1.0000
+
+## Integration Grid
+Grid.GridCutoff 90
+
+## Finding Density Matrix
+DM.SolutionMethod diagon
+
+## EXX Parameters
+EXX.GridSpacing 0.6
+EXX.Scheme 1
+
+## Atomic Information
+%block ChemicalSpeciesLabel
+1 1.0080 H H_PBE_SZ_CQ.ion
+2 12.0110 C C_PBE_SZP_CQ.ion
+%endblock
diff --git a/testsuite/test_007_isol_CH_spinpol_1proc_PBE0CRI/Conquest_out.ref b/testsuite/test_007_isol_CH_spinpol_1proc_PBE0CRI/Conquest_out.ref
new file mode 100644
index 000000000..9c105ade5
--- /dev/null
+++ b/testsuite/test_007_isol_CH_spinpol_1proc_PBE0CRI/Conquest_out.ref
@@ -0,0 +1,91 @@
+ ________________________________________________________________________
+
+ CONQUEST
+
+ Concurrent Order N QUantum Electronic STructure
+ ________________________________________________________________________
+
+ Conquest lead developers:
+ D.R.Bowler (UCL, NIMS), T.Miyazaki (NIMS), A.Nakata (NIMS),
+ L. Truflandier (U. Bordeaux)
+
+ Developers:
+ M.Arita (NIMS), J.S.Baker (UCL), V.Brazdova (UCL), R.Choudhury (UCL),
+ S.Y.Mujahed (UCL), J.T.Poulton (UCL), Z.Raza (NIMS), A.Sena (UCL),
+ U.Terranova (UCL), L.Tong (UCL), A.Torralba (NIMS)
+
+ Early development:
+ I.J.Bush (STFC), C.M.Goringe (Keele), E.H.Hernandez (Keele)
+
+ Original inspiration and project oversight:
+ M.J.Gillan (Keele, UCL)
+ ________________________________________________________________________
+
+ Simulation cell dimensions: 37.7945 a0 x 37.7945 a0 x 37.7945 a0
+
+ Atomic coordinates (a0)
+ Atom X Y Z Species
+ 1 18.8973 18.8973 19.9560 2
+ 2 18.8973 18.8973 17.8385 1
+
+ Default k-point sampling of Gamma point only
+
+ This job was run on 2024/12/03 at 18:59 +0100
+ Code was compiled on 2024/12/03 at 18:05 +0100
+ Version comment: Git Branch: f-exx-opt; tag, hash: v1.3-266-g018f6d62
+
+ Job title: isolated CH with PBE0
+ Job to be run: static calculation
+
+ Ground state search:
+ Support functions represented with PAO basis
+ 1:1 PAO to SF mapping
+ Spin-polarised electrons; population difference free
+ Solving for the K matrix using diagonalisation
+
+ Integration grid spacing: 0.210 a0 x 0.210 a0 x 0.210 a0
+
+ Number of species: 2
+ --------------------------------------------------------
+ | # mass (au) Charge (e) SF Rad (a0) NSF Label |
+ --------------------------------------------------------
+ | 1 1.008 1.000 7.139 1 H |
+ | 2 12.011 4.000 6.509 9 C |
+ --------------------------------------------------------
+
+ The calculation will be performed on 1 process
+
+ The calculation will be performed on 2 threads
+
+ Using the default matrix multiplication kernel
+
+ The functional used will be hyb PBE0
+
+ PulayMixSC: Reached SCF tolerance of 0.57025E-03 after 4 iterations
+ | Number of electrons (u/d)= 3.000002 2.000002
+ |* Harris-Foulkes energy = -6.192977992070597 Ha
+
+ WARNING: For hybrid PBE0 forces are not consistent!
+
+ force: Forces on atoms (Ha/a0)
+ force: Atom X Y Z
+ force: 1 0.0000000000 0.0000000000 0.1280359876
+ force: 2 0.0000000000 0.0000000000 -0.1224210376
+
+ force: Maximum force : 0.12803599(Ha/a0) on atom 1 in z direction
+ force: Force Residual: 0.12525998 Ha/a0
+ force: Total stress: -0.00069579 -0.00069579 -0.14086907 GPa
+
+ BIBLIOGRAPHY: Please consider citing the following references in the conquest.bib file
+
+ CONQUEST: Bowler2002pt, Miyazaki2004, Nakata2020
+ Basis: Bowler2019
+ DM: Bowler:2006xr
+ Pseudopotentials: Hamann2013, Bowler2019
+
+
+ Warnings written to file Conquest_warnings; please check
+
+ Max total mem use is 1981.173 MB
+
+ Total run time was: 48.339 seconds
diff --git a/testsuite/test_007_isol_CH_spinpol_1proc_PBE0CRI/H_PBE_SZ_CQ.ion b/testsuite/test_007_isol_CH_spinpol_1proc_PBE0CRI/H_PBE_SZ_CQ.ion
new file mode 100644
index 000000000..134fc4206
--- /dev/null
+++ b/testsuite/test_007_isol_CH_spinpol_1proc_PBE0CRI/H_PBE_SZ_CQ.ion
@@ -0,0 +1,2378 @@
+
+
+ Git Branch: develop; tag, hash: v1.0.2-pre-32-g9f3c7e79
+ Date generated : 2021/02/06 at 16:18
+
+
+ Hamann code version : v3.3.1
+ Hamann input file name: H.in (appended at end of file)
+ Core radii (bohr) : l=0 1.000 l=1 0.700
+ 1 valence shells : 1s
+ XC functional code : 000101
+ XC description : GGA PBE96
+
+
+H basis set with GGA PBE96 functional
+n = 1, l = 0, 1 zetas
+ Radii: 6.73
+
+
+ H pb nrl nc
+
+
+H # Element symbol
+H # Label
+ 1.00 # Atomic number
+ 1.0000000000 # Valence charge
+ 1.0100000000 # Mass
+ 0.0000000000 # Self energy
+ 0 1 # Lmax for basis, no of orbitals
+ 1 3 # Lmax for projectors, no of proj
+# PAOs:_______________
+ 0 1 1 0 1.000000 #orbital l, n, z, is_polarized, population
+ 673 0.0100108094935117 6.7272639796398339
+ 0.00000000000 1.56155255224
+ 0.01001080949 1.56134081579
+ 0.02002161899 1.56070586103
+ 0.03003242848 1.55964896338
+ 0.04004323797 1.55817219676
+ 0.05005404747 1.55627843492
+ 0.06006485696 1.55397133802
+ 0.07007566645 1.55125532942
+ 0.08008647595 1.54813556702
+ 0.09009728544 1.54461791016
+ 0.10010809494 1.54070888255
+ 0.11011890443 1.53641563176
+ 0.12012971392 1.53174588577
+ 0.13014052342 1.52670790712
+ 0.14015133291 1.52131044519
+ 0.15016214240 1.51556268735
+ 0.16017295190 1.50947420926
+ 0.17018376139 1.50305492529
+ 0.18019457088 1.49631503919
+ 0.19020538038 1.48926499595
+ 0.20021618987 1.48191543510
+ 0.21022699936 1.47427714601
+ 0.22023780886 1.46636102560
+ 0.23024861835 1.45817803890
+ 0.24025942784 1.44973918268
+ 0.25027023734 1.44105545246
+ 0.26028104683 1.43213781311
+ 0.27029185632 1.42299717314
+ 0.28030266582 1.41364436277
+ 0.29031347531 1.40409011574
+ 0.30032428481 1.39434505482
+ 0.31033509430 1.38441968091
+ 0.32034590379 1.37432436547
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+ 0.36038914177 1.33244641697
+ 0.37039995126 1.32165227563
+ 0.38041076075 1.31074763480
+ 0.39042157025 1.29974196964
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+# KBs:_______________
+ 0 1 -3.4022469484000002 #kb l, n (seq), energy in Ry
+ 103 0.0100165306087297 1.0216861220904290
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+ 0 2 -1.0689678359999999 #kb l, n (seq), energy in Ry
+ 103 0.0100165306087297 1.0216861220904290
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+ 1 1 -1.0066422298000000 #kb l, n (seq), energy in Ry
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+# Vna:_______________
+ 673 0.01001080949 6.72726397964 # npts, delta, cutoff
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+ 673 0.01001080949 6.72726397964 # npts, delta, cutoff
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+ 4.69506965246 -0.21299000454
+ 4.70508046195 -0.21253683593
+ 4.71509127144 -0.21208559159
+ 4.72510208094 -0.21163625929
+ 4.73511289043 -0.21118882691
+ 4.74512369992 -0.21074328241
+ 4.75513450942 -0.21029961387
+ 4.76514531891 -0.20985780948
+ 4.77515612841 -0.20941785751
+ 4.78516693790 -0.20897974633
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+ 4.80518855689 -0.20810900031
+ 4.81519936638 -0.20767634270
+ 4.82521017587 -0.20724548033
+ 4.83522098537 -0.20681640204
+ 4.84523179486 -0.20638909679
+ 4.85524260435 -0.20596355360
+ 4.86525341385 -0.20553976159
+ 4.87526422334 -0.20511770999
+ 4.88527503283 -0.20469738809
+ 4.89528584233 -0.20427878528
+ 4.90529665182 -0.20386189104
+ 4.91530746131 -0.20344669493
+ 4.92531827081 -0.20303318659
+ 4.93532908030 -0.20262135576
+ 4.94533988979 -0.20221119223
+ 4.95535069929 -0.20180268592
+ 4.96536150878 -0.20139582680
+ 4.97537231828 -0.20099060491
+ 4.98538312777 -0.20058701041
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+ 5.01541555625 -0.19938589376
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+ 5.03543717524 -0.19859310893
+ 5.04544798473 -0.19819907596
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+ 5.06546960372 -0.19741568229
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+ 5.11552365118 -0.19548402633
+ 5.12553446068 -0.19510222241
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+ 5.14555607966 -0.19434307138
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+ 5.16557769865 -0.19358980518
+ 5.17558850815 -0.19321535755
+ 5.18559931764 -0.19284235564
+ 5.19561012713 -0.19247079109
+ 5.20562093663 -0.19210065562
+ 5.21563174612 -0.19173194100
+ 5.22564255561 -0.19136463906
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+ 5.24566417460 -0.19063424088
+ 5.25567498409 -0.19027112861
+ 5.26568579359 -0.18990939699
+ 5.27569660308 -0.18954903815
+ 5.28570741257 -0.18919004429
+ 5.29571822207 -0.18883240767
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+ 5.31573984105 -0.18812117546
+ 5.32575065055 -0.18776756469
+ 5.33576146004 -0.18741528077
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+ 5.68613979231 -0.17586680953
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+ 5.79625869674 -0.17252564240
+ 5.80626950624 -0.17222818419
+ 5.81628031573 -0.17193174991
+ 5.82629112522 -0.17163633430
+ 5.83630193472 -0.17134193212
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+ 5.89636679168 -0.16959651188
+ 5.90637760117 -0.16930905987
+ 5.91638841067 -0.16902258061
+ 5.92639922016 -0.16873706918
+ 5.93641002965 -0.16845252067
+ 5.94642083915 -0.16816893023
+ 5.95643164864 -0.16788629302
+ 5.96644245813 -0.16760460425
+ 5.97645326763 -0.16732385914
+ 5.98646407712 -0.16704405297
+ 5.99647488661 -0.16676518103
+ 6.00648569611 -0.16648723866
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+ 6.04652893408 -0.16538467247
+ 6.05653974357 -0.16511130895
+ 6.06655055307 -0.16483884761
+ 6.07656136256 -0.16456728400
+ 6.08657217206 -0.16429661369
+ 6.09658298155 -0.16402683226
+ 6.10659379104 -0.16375793536
+ 6.11660460054 -0.16348991864
+ 6.12661541003 -0.16322277777
+ 6.13662621952 -0.16295650847
+ 6.14663702902 -0.16269110649
+ 6.15664783851 -0.16242656759
+ 6.16665864800 -0.16216288758
+ 6.17666945750 -0.16190006227
+ 6.18668026699 -0.16163808752
+ 6.19669107648 -0.16137695922
+ 6.20670188598 -0.16111667326
+ 6.21671269547 -0.16085722558
+ 6.22672350496 -0.16059861213
+ 6.23673431446 -0.16034082889
+ 6.24674512395 -0.16008387188
+ 6.25675593344 -0.15982773713
+ 6.26676674294 -0.15957242070
+ 6.27677755243 -0.15931791866
+ 6.28678836193 -0.15906422714
+ 6.29679917142 -0.15881134226
+ 6.30680998091 -0.15855926019
+ 6.31682079041 -0.15830797710
+ 6.32683159990 -0.15805748921
+ 6.33684240939 -0.15780779273
+ 6.34685321889 -0.15755888393
+ 6.35686402838 -0.15731075909
+ 6.36687483787 -0.15706341450
+ 6.37688564737 -0.15681684650
+ 6.38689645686 -0.15657105143
+ 6.39690726635 -0.15632602567
+ 6.40691807585 -0.15608176561
+ 6.41692888534 -0.15583826766
+ 6.42693969483 -0.15559552828
+ 6.43695050433 -0.15535354391
+ 6.44696131382 -0.15511231105
+ 6.45697212332 -0.15487182619
+ 6.46698293281 -0.15463208586
+ 6.47699374230 -0.15439308661
+ 6.48700455180 -0.15415482501
+ 6.49701536129 -0.15391729765
+ 6.50702617078 -0.15368050113
+ 6.51703698028 -0.15344443210
+ 6.52704778977 -0.15320908720
+ 6.53705859926 -0.15297446310
+ 6.54706940876 -0.15274055650
+ 6.55708021825 -0.15250736412
+ 6.56709102774 -0.15227488269
+ 6.57710183724 -0.15204310896
+ 6.58711264673 -0.15181203971
+ 6.59712345622 -0.15158167173
+ 6.60713426572 -0.15135200182
+ 6.61714507521 -0.15112302683
+ 6.62715588470 -0.15089474361
+ 6.63716669420 -0.15066714901
+ 6.64717750369 -0.15044023994
+ 6.65718831319 -0.15021401330
+ 6.66719912268 -0.14998846601
+ 6.67720993217 -0.14976359502
+ 6.68722074167 -0.14953939729
+ 6.69723155116 -0.14931586981
+ 6.70724236065 -0.14909300957
+ 6.71725317015 -0.14887081359
+ 6.72726397964 -0.14864884194
+
+# ATOM AND REFERENCE CONFIGURATION
+# atsym z nc nv iexc psfile
+H 1.00 0 1 4 upf
+#
+# n l f energy (Ha)
+1 0 1.00
+#
+# PSEUDOPOTENTIAL AND OPTIMIZATION
+# lmax
+1
+#
+# l, rc, ep, ncon, nbas, qcut
+0 1.00000 -0.23860 4 7 8.50000
+1 0.70000 0.05000 4 7 11.00000
+#
+# LOCAL POTENTIAL
+# lloc, lpopt, rc(5), dvloc0
+4 5 0.70000 0.00000
+#
+# VANDERBILT-KLEINMAN-BYLANDER PROJECTORs
+# l, nproj, debl
+0 2 1.00000
+1 1 1.00000
+#
+# MODEL CORE CHARGE
+# icmod, fcfact, rcfact
+0 0.00000 0.00000
+#
+# LOG DERIVATIVE ANALYSIS
+# epsh1, epsh2, depsh
+-12.00 12.00 0.02
+#
+# OUTPUT GRID
+# rlmax, drl
+3.00 0.01
+
diff --git a/testsuite/test_check_output.py b/testsuite/test_check_output.py
index b429321a2..901aa52f9 100644
--- a/testsuite/test_check_output.py
+++ b/testsuite/test_check_output.py
@@ -89,3 +89,44 @@ def test_003(self, key, testsuite_directory):
path = os.path.join(testsuite_directory, "test_003_bulk_BTO_polarisation")
res = results(path, key)
np.testing.assert_allclose(res[0], res[1], rtol = precision(key), verbose = True)
+
+ @pytest.mark.parametrize("key",['Harris-Foulkes energy',
+ 'Max force',
+ 'Force residual',
+ 'Total stress'])
+ def test_004(self, key, testsuite_directory):
+
+ path = os.path.join(testsuite_directory, "test_004_isol_C2H4_4proc_PBE0CRI")
+ res = results(path, key)
+ np.testing.assert_allclose(res[0], res[1], rtol = precision(key), verbose = True)
+
+ @pytest.mark.parametrize("key",['Harris-Foulkes energy',
+ 'Max force',
+ 'Force residual',
+ 'Total stress'])
+ def test_005(self, key, testsuite_directory):
+
+ path = os.path.join(testsuite_directory, "test_005_isol_C2H4_4proc_PBE0GTO")
+ res = results(path, key)
+ np.testing.assert_allclose(res[0], res[1], rtol = precision(key), verbose = True)
+
+ @pytest.mark.parametrize("key",['Harris-Foulkes energy',
+ 'Max force',
+ 'Force residual',
+ 'Total stress'])
+ def test_006(self, key, testsuite_directory):
+
+ path = os.path.join(testsuite_directory, "test_006_isol_C2H4_4proc_PBE0ERI")
+ res = results(path, key)
+ np.testing.assert_allclose(res[0], res[1], rtol = precision(key), verbose = True)
+
+ @pytest.mark.parametrize("key",['Harris-Foulkes energy',
+ 'Max force',
+ 'Force residual',
+ 'Total stress'])
+ def test_007(self, key, testsuite_directory):
+
+ path = os.path.join(testsuite_directory, "test_007_isol_CH_spinpol_1proc_PBE0CRI")
+ res = results(path, key)
+ np.testing.assert_allclose(res[0], res[1], rtol = precision(key), verbose = True)
+
diff --git a/tools/BasisGeneration/Makefile b/tools/BasisGeneration/Makefile
index 020359289..9df533359 100644
--- a/tools/BasisGeneration/Makefile
+++ b/tools/BasisGeneration/Makefile
@@ -1,7 +1,24 @@
TARGET = MakeIonFiles
default: $(TARGET)
.SUFFIXES: .f90
-include system.make
+#Include system-dependent variables
+ifneq ($(SYSTEM),)
+$(info System is $(SYSTEM))
+SYSTEM_PATH = ../../src/system/system.$(SYSTEM).make
+else
+SYSTEM_PATH=../../src/system/system.make
+endif
+ifneq ("$(wildcard $(SYSTEM_PATH))","")
+$(info Building using system file $(SYSTEM_PATH))
+include $(SYSTEM_PATH)
+else
+$(info Cannot find system file $(SYSTEM_PATH). Please make one,)
+$(info using system/system.example.make as an example, or choose)
+$(info an existing file from the system directory using make SYSTEM=label)
+$(info to select system/system.label.make)
+$(error Compilation aborted.)
+endif
+
COMMENT = verstr.f90
ECHOSTR = @echo
SHELL = /bin/sh
diff --git a/tools/BasisGeneration/pseudo_atom_info_module.f90 b/tools/BasisGeneration/pseudo_atom_info_module.f90
index 7fe2a30c0..7a4984db3 100644
--- a/tools/BasisGeneration/pseudo_atom_info_module.f90
+++ b/tools/BasisGeneration/pseudo_atom_info_module.f90
@@ -40,6 +40,14 @@ module pseudo_atom_info
real(double), pointer, dimension(:) :: width, prefac ! Parameters for exponential confinement
end type pao
+ type hgh_info
+ character(len=2) :: symbol
+ real(double) :: Zion, rloc, c1, c2, c3, c4
+ integer :: maxl
+ real(double), dimension(:), allocatable :: r
+ real(double), dimension(:,:), allocatable :: h, k
+ end type hgh_info
+
type valence_info
integer, pointer, dimension(:) :: n, l, semicore, nkb, npao, inner
integer :: n_shells, n_occ, functional
@@ -49,13 +57,17 @@ module pseudo_atom_info
type(pao) :: paos
type(potential_vkb) :: local_and_vkb
type(valence_info) :: val
+ type(hgh_info), dimension(:), allocatable :: hgh_data
logical :: flag_default_cutoffs
+ ! Value at which KB projectors are cutoff, defaults to 1e-8
+ real(double) :: kb_thresh
integer :: pseudo_type
logical :: flag_plot_output, flag_use_Vl
real(double) :: deltaE_large_radius! = 0.00073498_double
+ real(double) :: deltaE_large_radius_semicore_hgh ! = 1e-6
real(double) :: deltaE_small_radius! = 0.073498_double
! Useful parameters to improve code readability
@@ -186,6 +198,7 @@ subroutine allocate_vkb(ngrid,i_species)
allocate(local_and_vkb%local(ngrid))
local_and_vkb%local = zero
i = maxval(local_and_vkb%n_proj)
+ if(i==0) i=1
allocate(local_and_vkb%projector(ngrid,i,0:pseudo(i_species)%lmax))
local_and_vkb%projector = zero
allocate(local_and_vkb%semilocal_potential(ngrid,0:pseudo(i_species)%lmax))
diff --git a/tools/BasisGeneration/read_module.f90 b/tools/BasisGeneration/read_module.f90
index 120824f1d..528f5e68d 100644
--- a/tools/BasisGeneration/read_module.f90
+++ b/tools/BasisGeneration/read_module.f90
@@ -3,6 +3,7 @@ module read
use datatypes
use GenComms, ONLY: cq_abort
use global_module, ONLY: iprint
+ use pseudo_atom_info, only: kb_thresh
implicit none
@@ -15,13 +16,20 @@ module read
integer, parameter :: small = 2
integer, parameter :: medium = 3
integer, parameter :: full = 4
+ ! Pseudopotential formats
+ integer, parameter :: oncvpsp = 1
+ integer, parameter :: hgh = 2
+ integer :: ps_format
integer :: energy_units ! Local for reading; 1 is Ha, 2 is eV
+ integer :: max_scf_iters, max_solver_iters
real(double) :: energy_conv ! Define a factor for energy conversion (often 1.0)
real(double) :: energy_semicore ! Threshold for semi-core states
real(double) :: shallow_state_energy ! Energy to define shallow states (maybe too large)
real(double), save :: gen_energy_semicore ! System-wide threshold for semi-core states
real(double) :: width, prefac ! Defaults
+ real(double) :: alpha_scf
+ real(double) :: e_step
logical, save :: flag_gen_use_Vl
logical :: flag_adjust_deltaE = .false.
@@ -35,13 +43,14 @@ subroutine read_general_input
use numbers
use species_module, only: n_species
use input_module, only: load_input, fdf_integer, fdf_double, fdf_boolean, &
- fdf_block, block_start, block_end, input_array, fdf_endblock
+ fdf_block, block_start, block_end, input_array, fdf_endblock, fdf_string, leqi
use pseudo_tm_info, ONLY: pseudo
- use pseudo_atom_info, ONLY: flag_default_cutoffs, flag_plot_output
+ use pseudo_atom_info, ONLY: flag_default_cutoffs, flag_plot_output, hgh_data
implicit none
integer :: i, j, ios
+ character(len=80) :: input_string
!
! Load the Conquest_ion_input file into memory
@@ -58,6 +67,15 @@ subroutine read_general_input
! Species
!
n_species = fdf_integer('General.NumberOfSpecies',1)
+ input_string = fdf_string(80,'General.PSFormat','oncvpsp') ! Or 'hgh'
+ if(leqi(input_string(1:3),'onc').or.leqi(input_string(1:3),'ham')) then
+ ps_format = oncvpsp
+ else if(leqi(input_string(1:3),'hgh').or.leqi(input_string(1:3),'gth')) then
+ ps_format = hgh
+ allocate(hgh_data(n_species))
+ else
+ call cq_abort("Unrecognised pseudopotential format "//trim(input_string))
+ end if
allocate(pseudo(n_species)) ! Preserve compatibility with Conquest
!
! Read species labels
@@ -82,6 +100,20 @@ subroutine read_general_input
gen_energy_semicore = fdf_double('General.SemicoreEnergy',-one)
if(gen_energy_semicore>zero) &
write(*,fmt='(4x,"Error: your semi-core threshold is positive ! ",f6.3)') gen_energy_semicore
+ !
+ ! SCF parameters
+ !
+ alpha_scf = fdf_double('General.SCFMixing',half)
+ max_scf_iters = fdf_integer('General.SCFMaxIters',200)
+ !
+ ! Solver parameters
+ !
+ e_step = fdf_double('General.SolverStep',0.1_double)
+ max_solver_iters = fdf_integer('General.SolverMaxIters',200)
+ !
+ ! Threshold for KB projectors
+ !
+ kb_thresh = fdf_double('General.KBThresh',1e-8_double)
return
end subroutine read_general_input
@@ -93,7 +125,8 @@ subroutine read_species_input(species)
use input_module, ONLY: fdf_block, fdf_string, leqi, fdf_integer, fdf_double, fdf_boolean, &
fdf_endblock
use pseudo_atom_info, ONLY: paos, flag_use_Vl, val, deltaE_large_radius, deltaE_small_radius, &
- flag_default_cutoffs, pao_cutoff_energies, pao_cutoff_radii, pao_cutoff_default
+ flag_default_cutoffs, pao_cutoff_energies, pao_cutoff_radii, pao_cutoff_default, &
+ deltaE_large_radius_semicore_hgh
use units, ONLY: HaToeV
use mesh, ONLY: mesh_type, hamann, siesta, alpha, beta, delta_r_reg
@@ -115,13 +148,6 @@ subroutine read_species_input(species)
! Energy which detects a state near zero which might have too large a radius
shallow_state_energy = fdf_double('Atom.ShallowEnergy',-0.152_double)
!
- ! Get Hamann input and output file names and read files
- !
- pseudo_file_name = fdf_string(80,'Atom.PseudopotentialFile',' ')
- call read_hamann_input(species)
- vkb_file_name = fdf_string(80,'Atom.VKBFile',' ')
- call read_vkb(species)
- !
! Mesh
!
mesh_type = hamann
@@ -129,6 +155,23 @@ subroutine read_species_input(species)
beta = fdf_double("Mesh.Beta",beta)
delta_r_reg = fdf_double("Atom.RegularSpacing",0.01_double)
!
+ ! Get Hamann input and output file names and read files
+ !
+ pseudo_file_name = fdf_string(80,'Atom.PseudopotentialFile',' ')
+ if(ps_format==oncvpsp) then
+ call read_hamann_input(species)
+ else if(ps_format==hgh) then
+ call read_hgh_input(species)
+ else
+ call cq_abort("Unrecognised pseudopotential format")
+ end if
+ if(ps_format==oncvpsp) then
+ vkb_file_name = fdf_string(80,'Atom.VKBFile',' ')
+ call read_vkb(species)
+ else if(ps_format/=hgh) then
+ call cq_abort("Unrecognised pseudopotential format")
+ end if
+ !
! Form for zetas: compress or split norm
!
input_string = fdf_string(80,'Atom.ZetaForm','split')
@@ -168,11 +211,14 @@ subroutine read_species_input(species)
energy_conv = one / HaToeV
deltaE_large_radius = fdf_double("Atom.dE_large_radius",0.02_double)
deltaE_small_radius = fdf_double("Atom.dE_small_radius",two)
+ deltaE_large_radius = fdf_double("Atom.dE_large_radius_semicore_hgh",2.72e-5_double)
deltaE_large_radius = deltaE_large_radius / HaToeV
+ deltaE_large_radius_semicore_hgh = deltaE_large_radius_semicore_hgh / HaToeV
deltaE_small_radius = deltaE_small_radius / HaToeV
else if(leqi(input_string(1:2),"Ha")) then
deltaE_large_radius = fdf_double("Atom.dE_large_radius",0.00073498_double)
deltaE_small_radius = fdf_double("Atom.dE_small_radius",0.073498_double)
+ deltaE_large_radius_semicore_hgh = fdf_double("Atom.dE_large_radius_semicore_hgh",1e-6_double)
end if
if(flag_adjust_deltaE) then
deltaE_large_radius = deltaE_large_radius*two
@@ -449,6 +495,342 @@ subroutine line_read_error(basis_block_string,ios,j)
call cq_abort("System-dependent read error: ",ios)
endif
end subroutine line_read_error
+
+ subroutine read_hgh_input(i_species)
+
+ use numbers
+ use pseudo_tm_info, ONLY: pseudo
+ use input_module, ONLY: io_assign, io_close, leqi
+ use mesh, ONLY: alpha, beta, rr_squared, drdi
+ use pseudo_atom_info, ONLY: val, allocate_val, local_and_vkb, allocate_vkb, hamann_version, &
+ deltaE_large_radius, hgh_data, kb_thresh, input_file_length
+ use pseudo_tm_info, ONLY: alloc_pseudo_info, pseudo
+ use periodic_table, ONLY: pte, n_species
+ use radial_xc, ONLY: flag_functional_type, init_xc, functional_lda_pz81, functional_gga_pbe96, &
+ functional_description
+
+ implicit none
+
+ ! Passed variables
+ integer :: i_species
+
+ ! Local variables
+ integer :: ios, lun, ngrid, ell, en, i, j, k, jp, n_occ, n_read, max_l, zeta, iexc
+ integer :: n_shells, n_nl_proj, this_l, number_of_this_l, max_nl_proj, n_r_proj_max
+ integer :: info, lwork
+ integer, dimension(0:4) :: count_func
+ integer, dimension(3,0:4) :: index_count_func
+ character(len=2) :: char_in
+ character(len=80) :: line, a
+ logical :: flag_core_done = .false.
+ logical, dimension(3,0:3) :: flag_min
+ real(double) :: dummy, dummy2, highest_energy, root_two, proj, rr_lp, pj, pjp, r_core, r_core_2, c_core
+ real(double) :: rl_base, rl_sqrt, rr, rr_l, rr_rl, rr_rl2, rr_rl4, rr_rl6, charge
+ real(double), dimension(:,:), allocatable :: gamma_fac
+ real(double), dimension(:,:), allocatable :: hnl
+ real(double), dimension(:,:,:), allocatable :: hnl_pass, hnl_store
+ real(double), dimension(3) :: eval
+ real(double), dimension(15):: work
+ real(double), dimension(3,3) :: tmp
+
+ write(*,fmt='("Using GTH/HGH pseudopotential")')
+ !
+ ! Zero arrays
+ !
+ count_func = 0
+ index_count_func = 0
+ input_file_length = 0
+ !
+ ! Open file
+ !
+ call io_assign(lun)
+ open(unit=lun, file=pseudo_file_name, status='old', iostat=ios)
+ if ( ios > 0 ) call cq_abort('Error opening HGH pseudopotential file: '//pseudo_file_name)
+ pseudo(i_species)%filename = pseudo_file_name
+ a = get_input_line(lun,ios)
+ read(a,*) max_l, iexc
+ !
+ ! Assign and initialise XC functional for species
+ !
+ if(iexc==3) then
+ flag_functional_type = functional_lda_pz81
+ else if(iexc==4) then
+ flag_functional_type = functional_gga_pbe96
+ else if(iexc<0) then
+ flag_functional_type = iexc
+ else
+ call cq_abort("Error: unrecognised iexc value: ",iexc)
+ end if
+ call init_xc
+ !
+ ! Set maximum l value and zero arrays
+ !
+ hgh_data(i_species)%maxl = max_l
+ pseudo(i_species)%lmax = max_l
+ pseudo(i_species)%flag_pcc = .false. ! Read this somewhere later
+ allocate(hgh_data(i_species)%r(0:max_l), hgh_data(i_species)%h(3,0:max_l))
+ hgh_data(i_species)%r = zero
+ hgh_data(i_species)%h = zero
+ write(*,fmt='("Maximum angular momentum for pseudopotential is l=",i1)') hgh_data(i_species)%maxl!pseudo(i_species)%lmax
+ !
+ ! Read in parameters for local potential
+ !
+ a = get_input_line(lun,ios)
+ read(a,*) char_in,hgh_data(i_species)%Zion,hgh_data(i_species)%rloc,&
+ hgh_data(i_species)%c1,hgh_data(i_species)%c2,hgh_data(i_species)%c3,hgh_data(i_species)%c4
+ ! Now identify element number
+ pseudo(i_species)%zval = hgh_data(i_species)%Zion
+ do i=1,n_species
+ if(leqi(char_in,pte(i))) then
+ pseudo(i_species)%z = i
+ exit
+ end if
+ end do
+ pseudo(i_species)%zcore = pseudo(i_species)%z - hgh_data(i_species)%Zion
+ write(*,fmt='("There are ",f6.2," core and ",f6.2," valence electrons")') pseudo(i_species)%zcore, pseudo(i_species)%zval
+ write(*,fmt='("The atomic number is",f6.2)') pseudo(i_species)%z
+ !
+ ! Read data for non-local projectors
+ !
+ max_nl_proj = 0
+ local_and_vkb%n_proj = 0
+ local_and_vkb%n_nl_proj = 0
+ ! hnl_pass is used for building diagonal projectors; hnl_store stores original parameters
+ allocate(hnl_pass(3,3,0:max_l))
+ allocate(hnl_store(3,3,0:max_l))
+ hnl_pass = zero
+ hnl_store = zero
+ do ell = 0,max_l
+ ! Read number of projectors for this l
+ a = get_input_line(lun,ios)
+ read(a,*) max_nl_proj
+ if(max_nl_proj>0) then
+ allocate(hnl(max_nl_proj,max_nl_proj))
+ hnl = zero
+ local_and_vkb%n_proj(ell) = max_nl_proj
+ local_and_vkb%n_nl_proj = local_and_vkb%n_nl_proj + local_and_vkb%n_proj(ell)
+ ! Read table of projectors
+ a = get_input_line(lun,ios)
+ read(a,*) hgh_data(i_species)%r(ell),(hnl(1,j),j=1,max_nl_proj)
+ if(max_nl_proj>1) then
+ do i=2,max_nl_proj
+ a = get_input_line(lun,ios)
+ read(a,*) (hnl(i,j),j=i,max_nl_proj)
+ end do
+ do i=1,max_nl_proj
+ do j=i+1,max_nl_proj
+ hnl(j,i) = hnl(i,j)
+ end do
+ end do
+ ! Store original data
+ hnl_pass(1:max_nl_proj,1:max_nl_proj,ell) = hnl
+ hnl_store(1:max_nl_proj,1:max_nl_proj,ell) = hnl
+ ! Diagonalise h matrix
+ eval = zero
+ lwork = 15
+ info = 0
+ call dsyev('V','U',max_nl_proj,hnl_pass(1:max_nl_proj,1:max_nl_proj,ell), &
+ max_nl_proj,eval(1:max_nl_proj),work,lwork,info)
+ ! Store diagonal values
+ do i=1,max_nl_proj
+ hgh_data(i_species)%h(i,ell) = eval(i)
+ end do
+ else
+ hgh_data(i_species)%h(1,ell) = hnl(1,1)
+ hnl_store(1,1,ell) = hnl(1,1)
+ end if
+ deallocate(hnl)
+ else
+ a = get_input_line(lun,ios)
+ read(a,*) hgh_data(i_species)%r(ell)
+ local_and_vkb%n_proj(ell) = max_nl_proj
+ local_and_vkb%n_nl_proj = local_and_vkb%n_nl_proj + local_and_vkb%n_proj(ell)
+ hgh_data(i_species)%h(:,ell) = zero
+ end if
+ end do
+ !
+ ! Transfer data into Conquest structures
+ !
+ write(*,fmt='("Total number of VKB projectors: ",i2)') local_and_vkb%n_nl_proj
+ call alloc_pseudo_info(pseudo(i_species),local_and_vkb%n_nl_proj)
+ i=0
+ do ell=0,pseudo(i_species)%lmax
+ zeta=0
+ do j=1,local_and_vkb%n_proj(ell)
+ i=i+1
+ zeta = zeta+1
+ pseudo(i_species)%pjnl_l(i) = ell
+ pseudo(i_species)%pjnl_n(i) = zeta
+ end do
+ end do
+ pseudo(i_species)%flag_pcc = .false.
+ ! Identify n_shells and n, l, occupancy for valence electrons and set PS energy to zero
+ a = get_input_line(lun,ios)
+ read(a,*) n_shells
+ call allocate_val(n_shells)
+ n_occ = 0
+ do i=1,n_shells
+ a = get_input_line(lun,ios)
+ read(a,*) val%n(i), val%l(i), val%occ(i), val%semicore(i)
+ val%en_ps(i) = zero
+ if(val%occ(i)>RD_ERR) n_occ = n_occ + 1
+ write(*,fmt='("n, l and occupancy: ",i1," ",i1,f6.2)') val%n(i), val%l(i), val%occ(i)
+ end do
+ val%n_occ = n_occ
+ ! Test for PCC
+ ios = 0
+ r_core = zero
+ c_core = zero
+ n_read = 0 ! Compatibility with CP2K files; not used
+ a = get_input_line(lun,ios)
+ if(ios==0) then
+ pseudo(i_species)%flag_pcc = .true.
+ write(*,fmt='("This pseudopotential includes partial core corrections")')
+ read(a,*) r_core, n_read, c_core
+ end if
+ call io_close(lun)
+ !
+ ! Grid size
+ !
+ ngrid = log(45.0_double/(beta/pseudo(i_species)%z))/log(1.012_double) ! Following Hamann
+ if(iprint>2) write(*,fmt='("Number of grid points ",i5)') ngrid
+ call allocate_vkb(ngrid,i_species)
+ ! Assign pseudo-n value for nodes
+ do i = 1,n_shells
+ ! Check for inner shells: count shells with this l and store
+ this_l = val%l(i)
+ number_of_this_l = count_func(this_l) + 1
+ count_func(this_l) = number_of_this_l
+ index_count_func(number_of_this_l, this_l) = i
+ if(number_of_this_l>1) val%inner(i) = index_count_func(number_of_this_l-1,this_l)
+ ! Set n for PAO (sets number of nodes)
+ val%npao(i) = this_l + number_of_this_l
+ end do
+ if(iprint>3) write(*,fmt='(i2," valence shells, with ",i2," occupied")') n_shells, n_occ
+ root_two = sqrt(two)
+ ! Read density from charge.dat or set to zero if file not present
+ open(unit=40,file='charge.dat',status='old',iostat=ios)
+ if(ios==0) then
+ !charge = zero
+ do i=1,ngrid
+ read(40,*) rr,local_and_vkb%charge(i)
+ charge = charge + alpha*rr*rr*rr*local_and_vkb%charge(i)
+ end do
+ close(40)
+ if(iprint>4) write(*,*) 'Charge read in integrates to : ',charge
+ ! Normalise
+ local_and_vkb%charge = local_and_vkb%charge*pseudo(i_species)%zval/charge
+ else
+ local_and_vkb%charge = zero
+ end if
+ ! Create local potential
+ do i=1,ngrid
+ rr = (beta/pseudo(i_species)%z)*exp(alpha*real(i-1,double))
+ local_and_vkb%rr(i) = rr
+ rr_rl = rr/hgh_data(i_species)%rloc
+ rr_rl2 = rr_rl*rr_rl
+ rr_rl4 = rr_rl2*rr_rl2
+ rr_rl6 = rr_rl4*rr_rl2
+ local_and_vkb%local(i) = (-hgh_data(i_species)%Zion/rr)*erf(rr_rl/root_two) + &
+ exp(-0.5*rr_rl2)*(hgh_data(i_species)%c1 + hgh_data(i_species)%c2*rr_rl2 + &
+ hgh_data(i_species)%c3*rr_rl4 + hgh_data(i_species)%c4*rr_rl6)
+ end do
+ local_and_vkb%r_vkb = local_and_vkb%rr(ngrid)
+ local_and_vkb%ngrid_vkb = ngrid
+ !
+ ! Create PCC
+ !
+ if(pseudo(i_species)%flag_pcc) then
+ allocate(local_and_vkb%pcc(ngrid))
+ local_and_vkb%pcc = zero
+ ! There is a parameter n_read above which is currently unused
+ r_core_2 = r_core*r_core
+ ! Willand paper values
+ !dummy = four*pi*(pseudo(i_species)%z - pseudo(i_species)%zval)/(sqrt(twopi)*r_core)**3
+ ! CP2K values
+ dummy = one
+ do i=1,ngrid
+ rr = local_and_vkb%rr(i)
+ local_and_vkb%pcc(i) = c_core*dummy*exp(-half*rr*rr/r_core_2) ! May need to remove factor of 4pi
+ end do
+ end if
+ !
+ ! Create non-local projectors
+ !
+ ! i from 1 to 3
+ ! l from 0 to lmax
+ ! Precalculate normalisation
+ allocate(gamma_fac(3,0:max_l))
+ gamma_fac = zero
+ ! l + (4i-1)/2 gives l+3/2 = (l+1)+0.5; then l+3 and l+5
+ do ell = 0,max_l
+ rl_sqrt = sqrt(hgh_data(i_species)%r(ell))
+ do i=1,local_and_vkb%n_proj(ell)
+ ! l + 2i -1 + 0.5
+ rl_base = rl_sqrt*hgh_data(i_species)%r(ell)**real(ell+2*i-1,double)
+ gamma_fac(i,ell) = rl_base*sqrt(gamma(real(ell+(four*real(i,double)-one)/two,double)))
+ end do
+ end do
+ ! Set logarithmic grid and work out projector radius
+ n_r_proj_max = 1
+ flag_min = .true.
+ do i=1,ngrid
+ if(local_and_vkb%rr(i)>half) then
+ do ell = 0,max_l
+ if(local_and_vkb%n_proj(ell)>0) then
+ rr_rl = local_and_vkb%rr(i)/hgh_data(i_species)%r(ell)
+ do j = 1,local_and_vkb%n_proj(ell)
+ rr_l = local_and_vkb%rr(i)**(ell + 2*(j-1))
+ proj = root_two*rr_l*exp(-0.5*rr_rl*rr_rl)/gamma_fac(j,ell)
+ if(abs(proj)local_and_vkb%core_radius(ell)) local_and_vkb%core_radius(ell) = local_and_vkb%rr(i)
+ if(local_and_vkb%rr(i)>local_and_vkb%rr(n_r_proj_max)) n_r_proj_max = i
+ flag_min(j,ell) = .false.
+ end if
+ end do
+ end if
+ end do
+ end if
+ end do
+ do ell = 0,max_l
+ write(*,'("l=",i1," core radius ",f6.3," bohr")') ell, local_and_vkb%core_radius(ell)
+ end do
+ ! Now calculate projectors
+ local_and_vkb%r_vkb = local_and_vkb%rr(n_r_proj_max)
+ local_and_vkb%ngrid_vkb = n_r_proj_max
+ local_and_vkb%projector = zero
+ do i=1,local_and_vkb%ngrid_vkb
+ rr = local_and_vkb%rr(i)
+ do ell = 0,max_l
+ rr_rl = rr/hgh_data(i_species)%r(ell)
+ do j = 1,local_and_vkb%n_proj(ell)
+ rr_l = rr**(ell + 2*(j-1))
+ ! r**(l + 2*(i-1))
+ ! i=1 gives r**l; i=2 gives r**(l+2); i=3 gives r**(l+4)
+ if(local_and_vkb%n_proj(ell)>1) then
+ do jp=1,local_and_vkb%n_proj(ell)
+ local_and_vkb%projector(i,jp,ell) = local_and_vkb%projector(i,jp,ell) + &
+ hnl_pass(j,jp,ell)*rr*root_two*rr_l*exp(-0.5*rr_rl*rr_rl)/gamma_fac(j,ell)
+ end do
+ else
+ local_and_vkb%projector(i,j,ell) = rr*root_two*rr_l*exp(-0.5*rr_rl*rr_rl)/gamma_fac(j,ell)
+ end if
+ end do
+ end do
+ end do
+ deallocate(gamma_fac,hnl_pass)
+ ! Store values in Conquest structures
+ n_read = 1
+ do ell=0,pseudo(i_species)%lmax
+ do j = 1,local_and_vkb%n_proj(ell)
+ pseudo(i_species)%pjnl_ekb(n_read) = hgh_data(i_species)%h(j,ell)
+ n_read = n_read + 1
+ end do
+ if(iprint>4) write(*,fmt='(i3,4f10.5)') ell, &
+ pseudo(i_species)%pjnl_ekb(n_read-local_and_vkb%n_proj(ell):n_read-1)
+ end do
+ return
+ end subroutine read_hgh_input
! Read semi-local potentials output by a DRB patch to Hamann's code
! Now read KB potentials
@@ -457,7 +839,6 @@ subroutine read_vkb(i_species)
use numbers
use pseudo_tm_info, ONLY: pseudo
use input_module, ONLY: io_assign, io_close
- use mesh, ONLY: siesta
use pseudo_atom_info, ONLY: val, allocate_val, local_and_vkb, allocate_vkb, hamann_version, deltaE_large_radius
implicit none
@@ -641,7 +1022,7 @@ subroutine read_hamann_input(i_species)
if ( ios > 0 ) call cq_abort('Error opening Hamann input file: '//pseudo_file_name)
input_file_length = 0
pseudo(i_species)%filename = pseudo_file_name
- a = get_hamann_line(lun)
+ a = get_input_line(lun,ios)
read(a,*) sym,z,nc,nv,iexc,file_format
write(*,fmt='(/"Information about pseudopotential for species: ",a2/)') sym
pseudo(i_species)%z = z
@@ -659,7 +1040,7 @@ subroutine read_hamann_input(i_species)
end if
call init_xc
write(*,fmt='("There are ",i2," core and ",i2," valence shells")') nc,nv
- a = get_hamann_line(lun)
+ a = get_input_line(lun,ios)
!
! Read n, l, filling for core
!
@@ -667,7 +1048,7 @@ subroutine read_hamann_input(i_species)
do i_shell = 1, nc
read(a,*) en,ell,fill
zcore = zcore + fill
- a = get_hamann_line(lun)
+ a = get_input_line(lun,ios)
end do
pseudo(i_species)%zcore = zcore
! Read n, l, filling for valence
@@ -675,7 +1056,7 @@ subroutine read_hamann_input(i_species)
do i_shell = 1, nv
read(a,*) en,ell,fill
zval = zval + fill
- a = get_hamann_line(lun)
+ a = get_input_line(lun,ios)
end do
pseudo(i_species)%zval = zval
write(*,fmt='("The atomic number is",f6.2,", with valence charge ",f5.2," (core electrons: ",f5.2,")")') z,zval,zcore
@@ -688,26 +1069,26 @@ subroutine read_hamann_input(i_species)
! Projector radii etc
!
local_and_vkb%core_radius = zero
- a = get_hamann_line(lun)
+ a = get_input_line(lun,ios)
do ell = 0, pseudo(i_species)%lmax
read(a,*) en, local_and_vkb%core_radius(ell)
write(*,'("l=",i1," core radius ",f6.3," bohr")') ell, local_and_vkb%core_radius(ell)
- a = get_hamann_line(lun)
+ a = get_input_line(lun,ios)
end do
!
! Local potential read above in final step of loop, so leave
!
- !a = get_hamann_line(lun)
+ !a = get_input_line(lun,ios)
!
! Numbers of projectors
!
local_and_vkb%n_proj = 0
local_and_vkb%n_nl_proj = 0
- a = get_hamann_line(lun)
+ a = get_input_line(lun,ios)
do ell = 0, pseudo(i_species)%lmax
read(a,*) en,local_and_vkb%n_proj(en),fill
local_and_vkb%n_nl_proj = local_and_vkb%n_nl_proj + local_and_vkb%n_proj(en)
- a = get_hamann_line(lun)
+ a = get_input_line(lun,ios)
end do
write(*,fmt='("Total number of VKB projectors: ",i2)') local_and_vkb%n_nl_proj
call alloc_pseudo_info(pseudo(i_species),local_and_vkb%n_nl_proj)
@@ -733,34 +1114,40 @@ subroutine read_hamann_input(i_species)
write(*,fmt='("This pseudopotential does not include partial core corrections"/)')
end if
! Last two categories: tests and grid size
- a = get_hamann_line(lun)
- a = get_hamann_line(lun)
+ a = get_input_line(lun,ios)
+ a = get_input_line(lun,ios)
call io_close(lun)
end subroutine read_hamann_input
! Check for comment markers
- function get_hamann_line(lun)
+ function get_input_line(lun,ios)
use pseudo_atom_info, ONLY: input_file_length, input_file
implicit none
integer :: lun
- character(len=80) :: get_hamann_line
+ integer :: ios
+ character(len=80) :: get_input_line
character(len=80) :: a
- read(lun,'(a)') a
- input_file_length = input_file_length+1
- input_file(input_file_length) = a
- get_hamann_line = adjustl(a)
- do while(get_hamann_line(1:1).eq.'#')
- read(lun,'(a)') a
+ ios=0
+ read(lun,'(a)',iostat=ios) a
+ if(ios==0) then
input_file_length = input_file_length+1
input_file(input_file_length) = a
- get_hamann_line = adjustl(a)
- end do
+ get_input_line = adjustl(a)
+ do while(get_input_line(1:1).eq.'#')
+ read(lun,'(a)') a
+ input_file_length = input_file_length+1
+ input_file(input_file_length) = a
+ get_input_line = adjustl(a)
+ end do
+ else
+ a = ' '
+ end if
return
- end function get_hamann_line
+ end function get_input_line
! Set up PAO basis in case of default, or check user-specified basis
subroutine set_pao_initial(i_species)
diff --git a/tools/BasisGeneration/schro_module.f90 b/tools/BasisGeneration/schro_module.f90
index 5a4999459..0efe1d837 100644
--- a/tools/BasisGeneration/schro_module.f90
+++ b/tools/BasisGeneration/schro_module.f90
@@ -90,7 +90,11 @@ subroutine find_unconfined_valence_states(i_species,vha,vxc)
use datatypes
use numbers
- use mesh, ONLY: rr, nmesh
+ use mesh, ONLY: rr, nmesh, drdi_squared, rr_squared,drdi
+ use radial_xc, ONLY: get_vxc
+ use read, ONLY: ps_format, hgh, alpha_scf, max_scf_iters
+ use pseudo_tm_info, ONLY: pseudo
+ use GenComms, ONLY: cq_abort
implicit none
@@ -99,33 +103,113 @@ subroutine find_unconfined_valence_states(i_species,vha,vxc)
real(double), dimension(nmesh) :: vha, vxc
! Local variables
- integer :: i_shell, ell, en
- real(double) :: radius_large, large_energy
- real(double), allocatable, dimension(:) :: psi
+ integer :: i_shell, ell, en, i, iter, maxiter
+ real(double) :: radius_large, large_energy, resid, total_charge, check
+ real(double), allocatable, dimension(:) :: psi, newcharge
- allocate(psi(nmesh))
+ allocate(psi(nmesh),newcharge(nmesh))
psi = zero
-
+ newcharge = zero
+ maxiter = max_scf_iters
+ iter = 0
if(iprint>2) write(*,fmt='(/2x,"Finding unconfined energies for valence states")')
- do i_shell = 1, val%n_occ
- if(iprint>2) write(*,fmt='(2x,"n=",i2," l=",i2)') val%n(i_shell), val%l(i_shell)
- radius_large = rr(nmesh)
- ell = val%l(i_shell)
- en = val%npao(i_shell)
- large_energy = val%en_ps(i_shell)
- call find_eigenstate_and_energy_vkb(i_species,en,ell,radius_large, psi,large_energy,vha,vxc)
- val%en_pao(i_shell) = large_energy
- end do
- if(iprint>0) then
- write(*,fmt='(/2x,"Unconfined valence state energies (Ha)")')
- write(*,fmt='(2x," n l AE energy PAO energy")')
+ resid = one
+ !
+ ! SCF iteration needed for HGH where we do not have an atomic density supplied
+ ! I have found that if we start from no charge density then it's better to allow
+ ! the charge to gradually change towards the correct ionic charge rather than
+ ! rescaling after the first iteration
+ !
+ do while(resid>1e-12_double.and.iter2) write(*,fmt='(2x,"n=",i2," l=",i2)') val%n(i_shell), val%l(i_shell)
+ radius_large = rr(nmesh)
ell = val%l(i_shell)
- en = val%n(i_shell)
- write(*,fmt='(2x,2i3,2f18.10)') en, ell, val%en_ps(i_shell), &
- val%en_pao(i_shell)
+ en = val%npao(i_shell)
+ large_energy = val%en_ps(i_shell)
+ if(ps_format==hgh) then
+ !if(resid<0.01_double) then
+ ! large_energy = val%en_ps(i_shell)
+ !else
+ large_energy = zero!half*val%en_ps(i_shell)
+ !end if
+ end if
+ !if(abs(large_energy)1) large_energy = val%en_pao(i_shell-1)
+ call find_eigenstate_and_energy_vkb(i_species,en,ell,radius_large, psi,large_energy,vha,vxc)
+ val%en_pao(i_shell) = large_energy
+ ! Accumulate output charge
+ if(ell==0) then
+ newcharge = newcharge + val%occ(i_shell)*psi*psi
+ else if(ell==1) then
+ newcharge = newcharge + val%occ(i_shell)*psi*psi*rr*rr
+ else if(ell==2) then
+ newcharge = newcharge + val%occ(i_shell)*psi*psi*rr*rr*rr*rr
+ end if
end do
+ ! Find residual
+ resid = zero
+ check = zero
+ do i=1,nmesh
+ resid = resid + drdi(i)*rr_squared(i)*(local_and_vkb%charge(i)-newcharge(i))**2
+ check = check + drdi(i)*rr_squared(i)*local_and_vkb%charge(i)
+ end do
+ ! Simple linear mixing
+ local_and_vkb%charge = alpha_scf*newcharge + (one-alpha_scf)*local_and_vkb%charge
+ ! We can use these lines to write out the charge for future solvers
+ !open(unit=70,file='charge_out.dat',position="append")
+ !do i=1,nmesh
+ ! write(70,*) rr(i), newcharge(i)
+ !end do
+ !close(70)
+ ! Integrate
+ total_charge = zero
+ check = zero
+ do i=1,nmesh
+ resid = resid + drdi(i)*rr_squared(i)*(local_and_vkb%charge(i)-newcharge(i))**2
+ total_charge = total_charge + drdi(i)*rr_squared(i)*newcharge(i)
+ check = check + drdi(i)*rr_squared(i)*local_and_vkb%charge(i)
+ end do
+ ! This rescales charge to have full valence value, but can be unstable
+ !if(abs(check-total_charge)>RD_ERR) local_and_vkb%charge = local_and_vkb%charge*total_charge/check
+ if(iprint>2) write(*,fmt='("Iteration ",i4," residual ",e14.6)') iter,resid
+ if(ps_format==hgh) then
+ do i_shell = 1, val%n_occ
+ val%en_ps(i_shell) = val%en_pao(i_shell)
+ end do
+ end if
+ call radial_hartree(nmesh,local_and_vkb%charge,vha)
+ if(pseudo(i_species)%flag_pcc) local_and_vkb%charge = local_and_vkb%charge + local_and_vkb%pcc
+ call get_vxc(nmesh,rr,local_and_vkb%charge,vxc)
+ if(pseudo(i_species)%flag_pcc) local_and_vkb%charge = local_and_vkb%charge - local_and_vkb%pcc
+ end do
+ if(iprint>=0) then
+ write(*,fmt='(/2x,"Unconfined valence state energies (Ha)")')
+ if(ps_format==hgh) then
+ write(*,fmt='(2x," n l PAO energy")')
+ do i_shell = 1, val%n_occ
+ ell = val%l(i_shell)
+ en = val%n(i_shell)
+ write(*,fmt='(2x,2i3,f18.10)') en, ell,val%en_pao(i_shell)
+ end do
+ else
+ write(*,fmt='(2x," n l AE energy PAO energy")')
+ do i_shell = 1, val%n_occ
+ ell = val%l(i_shell)
+ en = val%n(i_shell)
+ write(*,fmt='(2x,2i3,2f18.10)') en, ell, val%en_ps(i_shell), &
+ val%en_pao(i_shell)
+ end do
+ end if
end if
+ if(iter>maxiter) call cq_abort("Exceeded iterations in SCF")
+ ! We can use these lines to write out the charge for future solvers
+ !open(unit=70,file='charge_out.dat')
+ !do i=1,nmesh
+ ! write(70,*) rr(i), newcharge(i)!local_and_vkb%charge(i)
+ !end do
+ !close(70)
return
end subroutine find_unconfined_valence_states
@@ -266,6 +350,10 @@ subroutine solve_for_occupied_paos(i_species,vha,vxc,atomic_density)
end if
! Accumulate atomic charge density
atomic_density = atomic_density + val%occ(i_shell)*psi*psi
+ !do i=1,nmesh
+ ! write(50+ell,*) rr(i),psi(i)*psi(i)*val%occ(i_shell)
+ !end do
+ !flush(50+ell)
end if
! These lines orthogonalise to semi-core states where necessary
! They are left for completeness, but I found that they can cause
@@ -485,6 +573,7 @@ subroutine interpolate_potentials(i_species,vha_conf)
use mesh, ONLY: nmesh, rr, delta_r_reg, interpolate, make_mesh_reg, convert_r_to_i
use pseudo_tm_info, ONLY: pseudo, rad_alloc
use write, ONLY: write_pao_plot
+ use read, ONLY: ps_format, oncvpsp
implicit none
@@ -507,9 +596,11 @@ subroutine interpolate_potentials(i_species,vha_conf)
do i=1,local_and_vkb%n_proj(ell)
j = j+1
! Scale projector by r**(l+1)
+ !if(ps_format==oncvpsp) then
do k=0,ell
local_and_vkb%projector(:,i,ell) = local_and_vkb%projector(:,i,ell)/rr
end do
+ !end if
! Find actual cutoff: two successive points with magnitude less than RD_ERR
! We may want to start this somewhere r=0.1 to avoid errors
nrc = local_and_vkb%ngrid_vkb
@@ -603,6 +694,7 @@ subroutine find_default_cutoffs(i_species,vha,vxc)
use numbers
use mesh, ONLY: nmesh, rr, delta_r_reg, convert_r_to_i
use units, ONLY: HaToeV
+ use read, ONLY: ps_format, oncvpsp
implicit none
@@ -620,13 +712,19 @@ subroutine find_default_cutoffs(i_species,vha,vxc)
allocate(large_cutoff(val%n_occ),small_cutoff(val%n_occ))
large_cutoff = zero
small_cutoff = zero
- write(*,fmt='(/4x,"Default energy shifts")')
+ write(*,fmt='(/4x,"Energy shifts")')
write(*,fmt='(4x," n l delta E (Ha) delta E (eV)")')
! Loop over valence states, find large/small cutoffs
do i_shell = 1, val%n_occ !paos%n_shells-1
- if(iprint>3) write(*,*) '# Finding radius for ',paos%npao(i_shell), paos%l(i_shell)
- call find_radius_from_energy(i_species,paos%npao(i_shell), paos%l(i_shell), &
- large_cutoff(i_shell), val%en_ps(i_shell)+deltaE_large_radius, vha, vxc, .false.)
+ if(iprint>3) write(*,*) '# Finding radius for ',paos%npao(i_shell), paos%l(i_shell), &
+ val%en_ps(i_shell)+deltaE_large_radius
+ if(val%semicore(i_shell)==0.or.ps_format==oncvpsp) then
+ call find_radius_from_energy(i_species,paos%npao(i_shell), paos%l(i_shell), &
+ large_cutoff(i_shell), val%en_ps(i_shell)+deltaE_large_radius, vha, vxc, .false.)
+ else
+ call find_radius_from_energy(i_species,paos%npao(i_shell), paos%l(i_shell), &
+ large_cutoff(i_shell), val%en_ps(i_shell)+deltaE_large_radius_semicore_hgh, vha, vxc, .false.)
+ end if
! Round to grid step
if(val%semicore(i_shell)==0) then
write(*,fmt='(4x,2i3,2f13.8," (large radius)")') paos%n(i_shell), paos%l(i_shell), &
@@ -636,10 +734,16 @@ subroutine find_default_cutoffs(i_species,vha,vxc)
call find_radius_from_energy(i_species,paos%npao(i_shell), paos%l(i_shell), &
small_cutoff(i_shell), val%en_ps(i_shell)+deltaE_small_radius, vha, vxc, .false.)
else
- write(*,fmt='(4x,2i3,2f13.8," (only radius)")') paos%n(i_shell), paos%l(i_shell), &
- deltaE_large_radius, deltaE_large_radius*HaToeV
+ if(ps_format==oncvpsp) then
+ write(*,fmt='(4x,2i3,2f13.8," (only radius)")') paos%n(i_shell), paos%l(i_shell), &
+ deltaE_large_radius, deltaE_large_radius*HaToeV
+ else
+ write(*,fmt='(4x,2i3,2f13.8," (only radius)")') paos%n(i_shell), paos%l(i_shell), &
+ deltaE_large_radius_semicore_hgh, deltaE_large_radius_semicore_hgh*HaToeV
+ end if
small_cutoff(i_shell) = large_cutoff(i_shell)
end if
+ if(iprint>3) write(*,*) '# Radii: ',large_cutoff(i_shell),small_cutoff(i_shell)
end do
! Create cutoffs based on defaults chosen by user
if(paos%flag_cutoff==pao_cutoff_energies.OR.paos%flag_cutoff==pao_cutoff_default) then ! Same energy for all l/n shells
@@ -758,7 +862,7 @@ subroutine find_radius_from_energy(i_species,en,ell,Rc,energy,vha,vxc,flag_use_s
nmax = nmesh
n_crossings = 0
if(flag_use_semilocal) then
- !write(*,*) '# Using semi-local potential'
+ write(*,*) '# Using semi-local potential'
do i=1,nmesh
potential(i) = local_and_vkb%semilocal_potential(i,ell) + vha(i) + vxc(i)
g_temp = (drdi_squared(i)*(two*(energy - potential(i))-l_l_plus_one/rr_squared(i)) - alpha_sq_over_four)/twelve
@@ -801,6 +905,7 @@ subroutine find_radius_from_energy(i_species,en,ell,Rc,energy,vha,vxc,flag_use_s
end if
end do
end if
+ !write(*,*) '# Crossings, nodes: ',n_crossings, n_nodes
if(n_crossings5) write(*,*) '# Found radius ',Rc
+ if(abs(Rc - rr(local_and_vkb%ngrid_vkb))<0.1_double) then ! Arbitrary but reasonable
+ write(*,fmt='(/"For l=",i1," Rpao is close to RKB: ",2f7.4)') ell,Rc,rr(local_and_vkb%ngrid_vkb)
+ write(*,fmt='("Consider increasing Rpao or decreasing RKB"/)')
+ end if
deallocate(f,potential,psi)
return
end subroutine find_radius_from_energy
@@ -824,6 +933,7 @@ subroutine find_eigenstate_and_energy_vkb(i_species,en,ell,Rc,psi,energy,vha,vxc
use GenComms, ONLY: cq_abort
use mesh, ONLY: rr, rr_squared, nmesh, alpha, make_mesh, beta, drdi, drdi_squared, convert_r_to_i
use pseudo_tm_info, ONLY: pseudo
+ use read, ONLY: e_step, max_solver_iters
implicit none
@@ -833,7 +943,7 @@ subroutine find_eigenstate_and_energy_vkb(i_species,en,ell,Rc,psi,energy,vha,vxc
real(double), OPTIONAL :: width, prefac
! Local variables
- real(double) :: g_temp, dy_L, dy_R
+ real(double) :: g_temp, dy_L, dy_R, ipsi_in, ipsi_out
real(double), dimension(:), allocatable :: f, potential
integer :: classical_tp, i, n_crossings, n_nodes, n_loop, loop, nmax, n_kink, n_nodes_lower, n_nodes_upper, n_kink_vkb
real(double) :: l_half_sq, dx_sq_over_twelve, fac, norm, d_energy, e_lower, e_upper, df_cusp, cusp_psi, tol
@@ -858,30 +968,30 @@ subroutine find_eigenstate_and_energy_vkb(i_species,en,ell,Rc,psi,energy,vha,vxc
n_nodes = en - ell - 1
allocate(f(nmesh),potential(nmesh))
if(abs(energy)4) write(*,fmt='(2x,"Kink is at ",f18.10," with ",i2," crossings")') rr(n_kink),n_crossings
! If we haven't found enough nodes, we need to try further
- if(n_crossings/=n_nodes) then
+ !if(n_crossings/=n_nodes) then
+ if(n_crossings4) write(*,fmt='(2x,"Kink is at ",f18.10)') rr(n_kink)
@@ -921,16 +1037,30 @@ subroutine find_eigenstate_and_energy_vkb(i_species,en,ell,Rc,psi,energy,vha,vxc
if(n_kink == nmax) then
if(iprint>4) write(*,fmt='(2x,"No kink found - adjusting lower bound")')
e_lower = energy
- energy = half*(e_lower+e_upper)
+ if(e_upper-e_lower>e_step) then
+ energy = energy + e_step
+ else
+ energy = half*(e_lower+e_upper)
+ end if
cycle
end if
if(n_crossings /= n_nodes) then
if ( n_crossings > n_nodes ) then
e_upper = energy
+ if(e_upper-e_lower>e_step) then
+ energy = energy - e_step
+ else
+ energy = half * ( e_upper + e_lower )
+ end if
else
e_lower = energy
+ if(e_upper-e_lower>e_step) then
+ energy = energy + e_step
+ else
+ energy = half * ( e_upper + e_lower )
+ end if
end if
- energy = half * ( e_upper + e_lower )
+ !energy = half * ( e_upper + e_lower )
if(iprint>4) write(*,fmt='(2x,"Nodes found: ",i3," but required: ",i3)') n_crossings, n_nodes
cycle
end if
@@ -947,7 +1077,7 @@ subroutine find_eigenstate_and_energy_vkb(i_species,en,ell,Rc,psi,energy,vha,vxc
psi(n_kink:nmax) = psi(n_kink:nmax)*fac
xin = psi(n_kink)*f(n_kink)- psi(n_kink+1)*f(n_kink+1)
gin = psi(n_kink)
- gsgin = psi(n_kink)*psi(n_kink)*drdi_squared(n_kink)
+ gsgin = psi(n_kink)*psi(n_kink)*drdi_squared(n_kink)
! Remember that psi is y in numerov - don't forget factor of root(r)
! Normalise
norm = zero
@@ -981,19 +1111,53 @@ subroutine find_eigenstate_and_energy_vkb(i_species,en,ell,Rc,psi,energy,vha,vxc
if(iprint>5) write(*,fmt='(2x,"Energies (low, mid, high): ",3f18.10)') e_lower,energy,e_upper
if(iprint>4) write(*,fmt='(2x,"Energy shift : ",f18.10)') d_energy
! Alternate approach
- cusp_psi = xin + xout
- cusp_psi = cusp_psi + twelve*(one-f(n_kink))*gout
- cusp_psi = cusp_psi*gout/(gsgin + gsgout)
- d_energy = cusp_psi
+ !cusp_psi = xin + xout
+ !cusp_psi = cusp_psi + twelve*(one-f(n_kink))*gout
+ !cusp_psi = cusp_psi*gout/(gsgin + gsgout)
+ !d_energy = cusp_psi
if(iprint>4) write(*,fmt='(2x,"Energy shift (alt): ",f18.10)') cusp_psi
if(iprint>5) write(*,fmt='(2x,"Number of nodes: ",i4)') n_crossings
+ !! Integrate to kink in both directions - this is another estimate of the
+ !! energy change required but is rather approximate because of the method
+ !! used to calculate dpsi/dr
+ !ipsi_out = zero
+ !do i=1,n_kink
+ ! ipsi_out = ipsi_out + psi(i)*psi(i)*drdi_squared(i)
+ !end do
+ !ipsi_out = ipsi_out/(psi(n_kink)*psi(n_kink))
+ !ipsi_in = zero
+ !do i=n_kink,nmax
+ ! ipsi_in = ipsi_in + psi(i)*psi(i)*drdi_squared(i)
+ !end do
+ !ipsi_in = ipsi_in/(psi(n_kink)*psi(n_kink))
+ !!dy_L = (psi(n_kink)*sqrt(drdi(n_kink))/rr(n_kink)-psi(n_kink-1)*sqrt(drdi(n_kink-1))/rr(n_kink-1)) &
+ !! /(rr(n_kink)-rr(n_kink-1))
+ !!dy_R = (psi(n_kink+1)*sqrt(drdi(n_kink+1))/rr(n_kink+1)-psi(n_kink)*sqrt(drdi(n_kink))/rr(n_kink)) &
+ !! /(rr(n_kink+1)-rr(n_kink))
+ !dy_L = (psi(n_kink)*drdi(n_kink)-psi(n_kink-1)*drdi(n_kink-1)) &
+ ! /(rr(n_kink)-rr(n_kink-1))
+ !dy_R = (psi(n_kink+1)*drdi(n_kink+1)-psi(n_kink)*drdi(n_kink)) &
+ ! /(rr(n_kink+1)-rr(n_kink))
+ !d_energy = -(dy_L/psi(n_kink) - dy_R/psi(n_kink))/(ipsi_in + ipsi_out)
+ !write(*,*) 'New d_energy is ',d_energy
+ ! Write out psi here?
if ( n_crossings /= n_nodes) then
if ( n_crossings > n_nodes ) then
e_upper = energy
+ if(e_upper-e_lower>e_step) then
+ energy = energy - e_step
+ else
+ energy = half * ( e_upper + e_lower )
+ end if
else
e_lower = energy
+ if(e_upper-e_lower>e_step) then
+ energy = energy + e_step
+ else
+ energy = half * ( e_upper + e_lower )
+ end if
end if
- energy = half * ( e_upper + e_lower )
+ !energy = half * ( e_upper + e_lower )
cycle
end if
if(d_energy>zero) then
@@ -1002,13 +1166,21 @@ subroutine find_eigenstate_and_energy_vkb(i_species,en,ell,Rc,psi,energy,vha,vxc
e_upper = energy
end if
if(energy+d_energye_lower) then
- energy = energy + d_energy
+ if(abs(d_energy)zero) then
+ energy = energy + e_step
+ else
+ energy = energy - e_step
+ end if
+ end if
else
energy = half*(e_lower + e_upper)
end if
if(abs(d_energy)=100.AND.abs(d_energy)>tol) call cq_abort("Error: failed to find energy for n,l: ",en,ell)
+ if(loop>=n_loop.AND.abs(d_energy)>tol) call cq_abort("Error: failed to find energy for n,l: ",en,ell)
if(iprint>2) write(*,fmt='(2x,"Final energy found: ",f11.6," Ha")') energy
! Rescale - remove factor of sqrt r
do i=1,nmax
@@ -1138,7 +1310,7 @@ subroutine integrate_vkb_outwards(i_species,n_kink,ell,psi,f,n_crossings,n_nodes
use datatypes
use numbers
- use mesh, ONLY: rr, nmesh, drdi, drdi_squared
+ use mesh, ONLY: rr, nmesh, drdi, drdi_squared, convert_r_to_i
use pseudo_tm_info, ONLY: pseudo
use GenComms, ONLY: cq_abort
@@ -1155,12 +1327,17 @@ subroutine integrate_vkb_outwards(i_species,n_kink,ell,psi,f,n_crossings,n_nodes
real(double), allocatable, dimension(:) :: pot_vector, psi_h, s, integrand
real(double), allocatable, dimension(:,:) :: pot_matrix, psi_inh
- allocate(pot_matrix(local_and_vkb%n_proj(ell),local_and_vkb%n_proj(ell)),pot_vector(local_and_vkb%n_proj(ell)))
- pot_matrix = zero
- pot_vector = zero
- allocate(psi_h(nmesh),psi_inh(nmesh,local_and_vkb%n_proj(ell)))
- psi_h = zero
- psi_inh = zero
+ !if(local_and_vkb%n_proj(ell)>0) then
+ allocate(pot_matrix(local_and_vkb%n_proj(ell),local_and_vkb%n_proj(ell)),pot_vector(local_and_vkb%n_proj(ell)))
+ pot_matrix = zero
+ pot_vector = zero
+ allocate(psi_h(nmesh),psi_inh(nmesh,local_and_vkb%n_proj(ell)))
+ psi_h = zero
+ psi_inh = zero
+ !else
+ ! allocate(psi_h(nmesh))
+ ! psi_h = zero
+ !end if
if(ell == 0) then
nproj_acc = 0
else
@@ -1169,6 +1346,7 @@ subroutine integrate_vkb_outwards(i_species,n_kink,ell,psi,f,n_crossings,n_nodes
! Homogeneous - standard numerov - but only to projector radius
psi_h = zero
n_kink = local_and_vkb%ngrid_vkb
+ if(n_kink<5) call convert_r_to_i(two,n_kink)
if(iprint>5) write(*,fmt='("In integrate_vkb, outer limit is ",f18.10)') rr(n_kink)
allocate(s(n_kink),integrand(n_kink))
s = zero
@@ -1210,10 +1388,14 @@ subroutine integrate_vkb_outwards(i_species,n_kink,ell,psi,f,n_crossings,n_nodes
end do
!write(*,*) '# Pot mat and vec: ',pot_matrix, pot_vector
! Invert matrix
- call dgesv(local_and_vkb%n_proj(ell), 1, pot_matrix, local_and_vkb%n_proj(ell), ipiv, &
- pot_vector, local_and_vkb%n_proj(ell), info)
- if(info/=0) call cq_abort("Error from dgesv called in integrate_vkb_outward: ",info)
- if(iprint>6) write(*,fmt='("In integrate_vkb, coefficients are ",3f18.10)') pot_vector
+ if(local_and_vkb%n_proj(ell)>0) then
+ call dgesv(local_and_vkb%n_proj(ell), 1, pot_matrix, local_and_vkb%n_proj(ell), ipiv, &
+ pot_vector, local_and_vkb%n_proj(ell), info)
+ if(info/=0) call cq_abort("Error from dgesv called in integrate_vkb_outward: ",info)
+ if(iprint>6) write(*,fmt='("In integrate_vkb, coefficients are ",3f18.10)') pot_vector
+ else
+ pot_vector = zero
+ end if
! Construct total outward wavefunction
psi(1:n_kink) = psi_h(1:n_kink)
do i_proj=1,local_and_vkb%n_proj(ell)
@@ -1225,7 +1407,11 @@ subroutine integrate_vkb_outwards(i_species,n_kink,ell,psi,f,n_crossings,n_nodes
do i=2,n_kink
if(rr(i)>half.AND.psi(i)*psi(i-1)0) then
+ deallocate(pot_matrix, pot_vector, s, psi_h, psi_inh, integrand)
+ !else
+ ! deallocate(s, psi_h, integrand)
+ !end if
end subroutine integrate_vkb_outwards
subroutine find_polarisation(i_species,en,ell,Rc,psi_l,psi_pol,energy,vha,vxc,pf_sign)
diff --git a/tools/BasisGeneration/write_module.f90 b/tools/BasisGeneration/write_module.f90
index 5fbab8204..31537f744 100644
--- a/tools/BasisGeneration/write_module.f90
+++ b/tools/BasisGeneration/write_module.f90
@@ -14,6 +14,7 @@ subroutine write_header(i_species)
use periodic_table, ONLY: atomic_mass, pte
use radial_xc, ONLY: flag_functional_type, functional_lda_pz81, functional_gga_pbe96, functional_description
use datestamp, ONLY: datestr, commentver
+ use read, ONLY: ps_format, hgh, oncvpsp
implicit none
@@ -39,15 +40,21 @@ subroutine write_header(i_species)
today(1:4), today(5:6), today(7:8), the_time(1:2), the_time(3:4)
write(lun,fmt='("")')
write(lun,fmt='("")')
- if(hamann_version>0) then
- ma = (hamann_version/100)
- hamann_version = hamann_version - ma*100
- mi = (hamann_version/10)
- hamann_version = hamann_version - mi*10
- po = hamann_version
- write(lun,fmt='(2x,"Hamann code version : v",i1,".",i1,".",i1)') ma, mi, po
- endif
- write(lun,fmt='(2x,"Hamann input file name: ",a," (appended at end of file)")') trim(pseudo(i_species)%filename)
+ if(ps_format==oncvpsp) then
+ write(lun,fmt='(2x,"Pseudopotential type : ONCVPSP")')
+ if(hamann_version>0) then
+ ma = (hamann_version/100)
+ hamann_version = hamann_version - ma*100
+ mi = (hamann_version/10)
+ hamann_version = hamann_version - mi*10
+ po = hamann_version
+ write(lun,fmt='(2x,"Hamann code version : v",i1,".",i1,".",i1)') ma, mi, po
+ endif
+ write(lun,fmt='(2x,"Hamann input file name: ",a," (appended at end of file)")') trim(pseudo(i_species)%filename)
+ else if(ps_format==hgh) then
+ write(lun,fmt='(2x,"Pseudopotential type : HGH")')
+ write(lun,fmt='(2x,"HGH input file name : ",a," (appended at end of file)")') trim(pseudo(i_species)%filename)
+ end if
write(lun,fmt='(2x,"Core radii (bohr) :")',advance='no')
do ell=0,pseudo(i_species)%lmax
write(lun,fmt='(x,"l=",i1,f6.3)',advance='no') ell,local_and_vkb%core_radius(ell)
diff --git a/tools/PostProcessing/Makefile b/tools/PostProcessing/Makefile
index f3330ddaf..a28066863 100644
--- a/tools/PostProcessing/Makefile
+++ b/tools/PostProcessing/Makefile
@@ -1,7 +1,24 @@
TARGET = PostProcessCQ
default: $(TARGET)
.SUFFIXES: .f90
-include system.make
+#Include system-dependent variables
+ifneq ($(SYSTEM),)
+$(info System is $(SYSTEM))
+SYSTEM_PATH = ../../src/system/system.$(SYSTEM).make
+else
+SYSTEM_PATH=../../src/system/system.make
+endif
+ifneq ("$(wildcard $(SYSTEM_PATH))","")
+$(info Building using system file $(SYSTEM_PATH))
+include $(SYSTEM_PATH)
+else
+$(info Cannot find system file $(SYSTEM_PATH). Please make one,)
+$(info using system/system.example.make as an example, or choose)
+$(info an existing file from the system directory using make SYSTEM=label)
+$(info to select system/system.label.make)
+$(error Compilation aborted.)
+endif
+
COMMENT = verstr.f90
ECHOSTR = @echo
diff --git a/tools/PostProcessing/process_module.f90 b/tools/PostProcessing/process_module.f90
index fbdc6c3d2..17fdb09e6 100644
--- a/tools/PostProcessing/process_module.f90
+++ b/tools/PostProcessing/process_module.f90
@@ -458,7 +458,7 @@ subroutine process_pdos
! Local variables
integer :: i_band, i_kp, i_spin, n_DOS_wid, n_band, n_min, n_max, i, i_atom,max_nsf, i_spec, &
- i_l, nzeta, sf_offset, max_l, norbs, i_m, i_band_c
+ i_l, nzeta, sf_offset, max_l, norbs, i_m, i_band_c, i_z
real(double) :: Ebin, dE_DOS, a, pf_DOS, spin_fac, coeff, check_electrons
real(double), dimension(:,:,:), allocatable :: pDOS
real(double), dimension(:,:,:,:), allocatable :: pDOS_l
@@ -554,24 +554,23 @@ subroutine process_pdos
do i_atom = 1, n_atoms_pDOS
i_spec = species_glob(pDOS_atom_index(i_atom))
if(flag_l_resolved .and. flag_lm_resolved) then
- sf_offset = 0
+ sf_offset = 1
do i_l = 0, pao(i_spec)%greatest_angmom
nzeta = pao(i_spec)%angmom(i_l)%n_zeta_in_angmom
- norbs = nzeta
- do i_m = -i_l,i_l
- coeff = zdotc(norbs, evec_coeff(sf_offset+1:sf_offset+norbs,pDOS_atom_index(i_atom), &
- i_band_c,i_kp,i_spin),1, &
- scaled_evec_coeff(sf_offset+1:sf_offset+norbs,pDOS_atom_index(i_atom), &
- i_band_c,i_kp,i_spin),1)
- pDOS_lm(i_m,i_l,i_atom,i,i_spin) = &
- pDOS_lm(i_m,i_l,i_atom,i,i_spin) + &
- wtk(i_kp)*pf_DOS*exp(-half*a*a)*coeff
- pDOS(i_atom,i,i_spin) = pDOS(i_atom,i,i_spin) + &
- wtk(i_kp)*pf_DOS*exp(-half*a*a)*coeff
- total_electrons_l(i_l,i_atom, i_spin) = &
- total_electrons_l(i_l,i_atom, i_spin) + &
- occ(i_band,i_kp)*wtk(i_kp)*pf_DOS*exp(-half*a*a)*coeff
- sf_offset = sf_offset + norbs
+ do i_z = 1, nzeta
+ do i_m = -i_l,i_l
+ coeff = conjg(evec_coeff(sf_offset,pDOS_atom_index(i_atom), i_band_c,i_kp,i_spin)) * &
+ scaled_evec_coeff(sf_offset,pDOS_atom_index(i_atom), i_band_c,i_kp,i_spin)
+ pDOS_lm(i_m,i_l,i_atom,i,i_spin) = &
+ pDOS_lm(i_m,i_l,i_atom,i,i_spin) + &
+ wtk(i_kp)*pf_DOS*exp(-half*a*a)*coeff
+ pDOS(i_atom,i,i_spin) = pDOS(i_atom,i,i_spin) + &
+ wtk(i_kp)*pf_DOS*exp(-half*a*a)*coeff
+ total_electrons_l(i_l,i_atom, i_spin) = &
+ total_electrons_l(i_l,i_atom, i_spin) + &
+ occ(i_band,i_kp)*wtk(i_kp)*pf_DOS*exp(-half*a*a)*coeff
+ sf_offset = sf_offset + 1
+ end do
end do
end do
else if(flag_l_resolved) then