diff --git a/docs/use/workflows.md b/docs/use/workflows.md
index e53ef74a..c32f96c0 100644
--- a/docs/use/workflows.md
+++ b/docs/use/workflows.md
@@ -67,6 +67,93 @@ Start with [Quick Start](quickstart.md).
 
 ---
 
+## Template substitution
+
+Step configuration values (`With.*`) support `{{path}}` placeholders that are resolved against the
+request during plan build (`New-IdlePlan`). Multiple placeholders may appear in a single value.
+
+```powershell
+IdentityKey = '{{Request.IdentityKeys.sAMAccountName}}'
+DisplayName = '{{Request.DesiredState.GivenName}}'
+Message     = 'User {{Request.DesiredState.DisplayName}} is joining.'
+```
+
+### Allowed roots
+
+For security, only these path roots are permitted:
+
+| Root | Description |
+| ---- | ----------- |
+| `Request.DesiredState.*` | Intended target state of the identity |
+| `Request.IdentityKeys.*` | Identifiers of the target identity |
+| `Request.Changes.*` | Explicit deltas (Mover events) |
+| `Request.LifecycleEvent` | Lifecycle event type (e.g. `Joiner`) |
+| `Request.CorrelationId` | Stable correlation identifier |
+| `Request.Actor` | Originator of the request |
+| `Request.Input.*` | Alias for `Request.DesiredState.*` when no `Input` property exists |
+
+### Pure vs. mixed placeholders
+
+A value containing **only** a single placeholder preserves the resolved type (bool, int, datetime, guid, string):
+
+```powershell
+# Resolves to the actual [bool] value, not the string "True"
+Enabled = '{{Request.DesiredState.IsEnabled}}'
+```
+
+A value with surrounding text always produces a **string**:
+
+```powershell
+Message = 'Account for {{Request.DesiredState.DisplayName}} created.'
+```
+
+### Backslash and special characters
+
+Backslash (`\`) is a **literal character** in template strings and requires no escaping.
+Windows-style paths and domain-qualified names work as-is:
+
+```powershell
+# \ is kept as-is; only the placeholder is substituted
+IdentityKey = 'DOMAIN\{{Request.IdentityKeys.sAMAccountName}}'
+# → e.g. 'DOMAIN\jdoe'
+```
+
+### Escaping a literal `{{`
+
+To include a literal `{{` in the output, prefix it with `\`. The escape is applied whenever
+`\{{` is **not** immediately followed by a valid allowed-root template path and `}}`:
+
+```powershell
+# \{{ not followed by a valid path+}} → literal {{ in output
+Value = 'Literal \{{ braces here'
+# → 'Literal {{ braces here'
+
+# \{{ followed by an invalid/disallowed path → also escaped (literal {{ in output)
+Value = '\{{Request.InvalidRoot}}'
+# → '{{Request.InvalidRoot}}'
+```
+
+Summary of backslash behaviour:
+
+| Input | Result |
+| ----- | ------ |
+| `DOMAIN\{{Request.IdentityKeys.sAMAccountName}}` | `DOMAIN\jdoe` — `\` literal, valid template resolved |
+| `Literal \{{ braces here` | `Literal {{ braces here` — escape applied |
+| `\{{Request.InvalidRoot}}` | `{{Request.InvalidRoot}}` — invalid root, escape applied |
+| `Literal \{{ and {{Request.Input.Name}}` | `Literal {{ and TestName` — escape + template |
+
+### Validation
+
+During plan build, IdLE validates every template value:
+
+- **Unbalanced braces** — mismatched `{{`/`}}` pairs throw a syntax error.
+- **Invalid path** — paths must use dot-separated identifiers (letters, numbers, underscores).
+- **Disallowed root** — paths outside the allowlist throw a security error.
+- **Null or missing value** — if the resolved path does not exist, an error is thrown.
+- **Non-scalar value** — resolving to a hashtable or array is not allowed.
+
+---
+
 ## Reference
 
 For full definitions and reference, see:
diff --git a/src/IdLE.Core/Private/Resolve-IdleTemplateString.ps1 b/src/IdLE.Core/Private/Resolve-IdleTemplateString.ps1
index 93a6e6c2..92ed6540 100644
--- a/src/IdLE.Core/Private/Resolve-IdleTemplateString.ps1
+++ b/src/IdLE.Core/Private/Resolve-IdleTemplateString.ps1
@@ -22,7 +22,10 @@ function Resolve-IdleTemplateString {
     - Request.Actor
 
     Escaping:
-    - \{{ → literal {{ (escape removed after resolution)
+    - \{{ → literal {{ (backslash escapes the opening braces when not followed by a valid allowed-root template path+}})
+    - \{{path}} where path is a valid allowed-root path treats \ as a literal character and resolves the template normally
+      (e.g. DOMAIN\{{Request.IdentityKeys.sAMAccountName}} → DOMAIN\<resolved value>)
+    - \{{Request.InvalidRoot}} or \{{Request..Bad}} → escaped to literal {{...}} (invalid paths are never treated as templates)
 
     .PARAMETER Value
     The string value to resolve. If not a string, returns the value unchanged.
@@ -64,10 +67,6 @@ function Resolve-IdleTemplateString {
 
     # Quick exit: no template markers present
     if ($stringValue -notlike '*{{*' -and $stringValue -notlike '*}}*') {
-        # Handle escaped braces with no actual templates
-        if ($stringValue -like '*\{{*') {
-            return $stringValue -replace '\\{{', '{{'
-        }
         return $stringValue
     }
 
@@ -201,36 +200,54 @@ function Resolve-IdleTemplateString {
         }
     }
 
+    # Escape sequence normalization: \{{ (not followed by a valid allowed-root template path+}}) → literal {{.
+    # Use a Unicode Private Use Area character as placeholder so template matching does not see the
+    # escaped braces. This character is extremely unlikely to appear in real workflow configuration.
+    # The lookahead is intentionally restricted to the exact set of allowed roots so that sequences
+    # like \{{Request.Foo}} (invalid root) or \{{Request..Name}} (double dot) are still escaped to
+    # literal {{, rather than flowing into template parsing and failing with path/root errors.
+    $litOpenPlaceholder = [string][char]0xE001
+    $backslashEscapePattern = '\\{{(?!Request\.(?:(?:Input|DesiredState|IdentityKeys|Changes)(?:\.[A-Za-z0-9_]+)*|LifecycleEvent|CorrelationId|Actor)}})'
+    $normalizedValue = if ($stringValue -match '\\{{') {
+        [regex]::Replace($stringValue, $backslashEscapePattern, $litOpenPlaceholder)
+    } else {
+        $stringValue
+    }
+
     # Check if this is a pure placeholder (no prefix/suffix text, single placeholder)
     # If so, we can preserve the type instead of coercing to string
     $purePattern = '^\s*\{\{([^}]+)\}\}\s*$'
-    $pureMatch = [regex]::Match($stringValue, $purePattern)
+    $pureMatch = [regex]::Match($normalizedValue, $purePattern)
     $isPurePlaceholder = $pureMatch.Success
 
     # Check for unbalanced braces (typo safety)
     # Skip this validation for pure placeholders as we already validated them
     if (-not $isPurePlaceholder) {
-        # Count non-escaped opening braces
-        $openCount = ([regex]::Matches($stringValue, '(?<!\\)\{\{')).Count
-        # For closing braces, only count those that belong to templates (have a corresponding non-escaped opening)
+        # Count opening and closing braces on the normalized string so that \{{ escape sequences
+        # are correctly excluded from the counts (each \{{ escape is replaced by the placeholder).
+        $openCount = ([regex]::Matches($normalizedValue, '\{\{')).Count
+        # For closing braces, only count those that belong to templates (have a corresponding opening)
         # We can do this by counting matches of the full template pattern
-        $templatePattern = '(?<!\\)\{\{([^}]+)\}\}'
-        $templateCount = ([regex]::Matches($stringValue, $templatePattern)).Count
+        $templatePattern = '\{\{([^}]+)\}\}'
+        $templateCount = ([regex]::Matches($normalizedValue, $templatePattern)).Count
         # Any }} that's part of a template is matched. Any other }} is unbalanced.
-        $allCloseCount = ([regex]::Matches($stringValue, '\}\}')).Count
+        $allCloseCount = ([regex]::Matches($normalizedValue, '\}\}')).Count
         
         # The expected close count should equal template count (each template has one closing)
         if ($openCount -ne $templateCount -or $allCloseCount -ne $templateCount) {
             throw [System.ArgumentException]::new(
-                ("Template syntax error in step '{0}': Unbalanced braces in value '{1}'. Found {2} opening '{{{{' and {3} closing '}}}}'. Check for typos or missing braces." -f $StepName, $stringValue, $openCount, $allCloseCount),
+                ("Template syntax error in step '{0}': Unbalanced braces in value '{1}'. Found {2} opening '{{{{' and {3} closing '}}}}'. Check for typos or missing braces." -f $StepName, ([string]$Value), $openCount, $allCloseCount),
                 'Workflow'
             )
         }
     }
 
+    # Commit the normalized (escape-processed) string for template matching
+    $stringValue = $normalizedValue
+
     # Parse and resolve placeholders
     $result = $stringValue
-    $pattern = '(?<!\\)\{\{([^}]+)\}\}'
+    $pattern = '\{\{([^}]+)\}\}'
     $matches = [regex]::Matches($stringValue, $pattern)
 
     # For pure placeholders, we'll return the typed value directly
@@ -276,8 +293,8 @@ function Resolve-IdleTemplateString {
         $result = $result.Replace($placeholder, $stringReplacement)
     }
 
-    # Process escape sequences (unescape \{{ to {{)
-    $result = $result -replace '\\{{', '{{'
+    # Post-process: restore \{{ escape sequences → literal {{
+    $result = $result.Replace($litOpenPlaceholder, '{{')
 
     return $result
 }
diff --git a/tests/Core/Resolve-IdleWorkflowTemplates.Tests.ps1 b/tests/Core/Resolve-IdleWorkflowTemplates.Tests.ps1
index d6e23675..39aa3060 100644
--- a/tests/Core/Resolve-IdleWorkflowTemplates.Tests.ps1
+++ b/tests/Core/Resolve-IdleWorkflowTemplates.Tests.ps1
@@ -336,6 +336,36 @@ Describe 'Template Substitution' {
 
             $plan.Steps[0].With.Value | Should -Be 'Literal {{ and template TestName'
         }
+
+        It 'treats backslash before {{ as a literal character (not an escape)' {
+            $wfPath = Get-TemplateTestFixture 'template-backslash'
+
+            $req = New-IdleTestRequest -LifecycleEvent 'Joiner' -IdentityKeys @{ sAMAccountName = 'jdoe' }
+            $providers = @{
+                StepRegistry = @{ 'IdLE.Step.Test' = 'Invoke-IdleTestNoopStep' }
+                StepMetadata = New-IdleTestStepMetadata -StepTypes @('IdLE.Step.Test')
+            }
+
+            $plan = New-IdlePlan -WorkflowPath $wfPath -Request $req -Providers $providers
+
+            $plan.Steps[0].With.IdentityKey | Should -Be 'DOMAIN\jdoe'
+        }
+
+        It 'escapes \{{ followed by an invalid (non-allowed) root — throws unbalanced braces, not path error' {
+            # With the tight allowed-root lookahead, \{{InvalidRoot}} is escaped (placeholder replaces \{{)
+            # leaving }} orphaned → "unbalanced braces" error, same as original code.
+            # A loose lookahead would let this through to template parsing → wrong "path not allowed" error.
+            $wfPath = Get-TemplateTestFixture 'template-escaped-invalid-root'
+
+            $req = New-IdleRequest -LifecycleEvent 'Joiner' -DesiredState @{ Name = 'Test' }
+            $providers = @{
+                StepRegistry = @{ 'IdLE.Step.Test' = 'Invoke-IdleTestNoopStep' }
+                StepMetadata = New-IdleTestStepMetadata -StepTypes @('IdLE.Step.Test')
+            }
+
+            { New-IdlePlan -WorkflowPath $wfPath -Request $req -Providers $providers } |
+                Should -Throw -ExpectedMessage '*Unbalanced braces*'
+        }
     }
 
     Context 'OnFailureSteps template resolution' {
diff --git a/tests/fixtures/workflows/template-tests/template-backslash.psd1 b/tests/fixtures/workflows/template-tests/template-backslash.psd1
new file mode 100644
index 00000000..5a124ab2
--- /dev/null
+++ b/tests/fixtures/workflows/template-tests/template-backslash.psd1
@@ -0,0 +1,13 @@
+@{
+  Name           = 'Template Test - Backslash Before Template'
+  LifecycleEvent = 'Joiner'
+  Steps          = @(
+    @{
+      Name = 'TestStep'
+      Type = 'IdLE.Step.Test'
+      With = @{
+        IdentityKey = 'DOMAIN\{{Request.IdentityKeys.sAMAccountName}}'
+      }
+    }
+  )
+}
diff --git a/tests/fixtures/workflows/template-tests/template-escaped-invalid-root.psd1 b/tests/fixtures/workflows/template-tests/template-escaped-invalid-root.psd1
new file mode 100644
index 00000000..f1c2b57c
--- /dev/null
+++ b/tests/fixtures/workflows/template-tests/template-escaped-invalid-root.psd1
@@ -0,0 +1,13 @@
+@{
+  Name           = 'Template Test - Escaped Invalid Root'
+  LifecycleEvent = 'Joiner'
+  Steps          = @(
+    @{
+      Name = 'TestStep'
+      Type = 'IdLE.Step.Test'
+      With = @{
+        Value = '\{{Request.InvalidRoot}}'
+      }
+    }
+  )
+}