diff --git a/src/libraries/System.Diagnostics.Process/ref/System.Diagnostics.Process.cs b/src/libraries/System.Diagnostics.Process/ref/System.Diagnostics.Process.cs
index ed06fe1dc1ca86..bd58edc786fba1 100644
--- a/src/libraries/System.Diagnostics.Process/ref/System.Diagnostics.Process.cs
+++ b/src/libraries/System.Diagnostics.Process/ref/System.Diagnostics.Process.cs
@@ -215,6 +215,7 @@ public sealed partial class ProcessStartInfo
         public ProcessStartInfo() { }
         public ProcessStartInfo(string fileName) { }
         public ProcessStartInfo(string fileName, string arguments) { }
+        public ProcessStartInfo(string fileName, System.Collections.Generic.IEnumerable<string> arguments) { }
         public System.Collections.ObjectModel.Collection<string> ArgumentList { get { throw null; } }
         [System.Diagnostics.CodeAnalysis.AllowNullAttribute]
         public string Arguments { get { throw null; } set { } }
diff --git a/src/libraries/System.Diagnostics.Process/src/System/Diagnostics/Process.cs b/src/libraries/System.Diagnostics.Process/src/System/Diagnostics/Process.cs
index f62778b8735cb2..ca030f0bb12482 100644
--- a/src/libraries/System.Diagnostics.Process/src/System/Diagnostics/Process.cs
+++ b/src/libraries/System.Diagnostics.Process/src/System/Diagnostics/Process.cs
@@ -1327,16 +1327,7 @@ public static Process Start(string fileName, string arguments)
         [SupportedOSPlatform("maccatalyst")]
         public static Process Start(string fileName, IEnumerable<string> arguments)
         {
-            ArgumentNullException.ThrowIfNull(fileName);
-            ArgumentNullException.ThrowIfNull(arguments);
-
-            var startInfo = new ProcessStartInfo(fileName);
-            foreach (string argument in arguments)
-            {
-                startInfo.ArgumentList.Add(argument);
-            }
-
-            return Start(startInfo)!;
+            return Start(new ProcessStartInfo(fileName, arguments))!;
         }
 
         /// <devdoc>
diff --git a/src/libraries/System.Diagnostics.Process/src/System/Diagnostics/ProcessStartInfo.cs b/src/libraries/System.Diagnostics.Process/src/System/Diagnostics/ProcessStartInfo.cs
index b2941f17dfd5aa..888c4cec0de629 100644
--- a/src/libraries/System.Diagnostics.Process/src/System/Diagnostics/ProcessStartInfo.cs
+++ b/src/libraries/System.Diagnostics.Process/src/System/Diagnostics/ProcessStartInfo.cs
@@ -55,6 +55,19 @@ public ProcessStartInfo(string fileName, string arguments)
             _arguments = arguments;
         }
 
+        /// <summary>
+        /// Specifies the name of the application that is to be started, as well as a set
+        /// of command line arguments to pass to the application.
+        /// </summary>
+        public ProcessStartInfo(string fileName, IEnumerable<string> arguments)
+        {
+            ArgumentNullException.ThrowIfNull(fileName);
+            ArgumentNullException.ThrowIfNull(arguments);
+
+            _fileName = fileName;
+            _argumentList = new Collection<string>(new List<string>(arguments));
+        }
+
         /// <devdoc>
         ///     Specifies the set of command line arguments to use when starting the application.
         /// </devdoc>
diff --git a/src/libraries/System.Diagnostics.Process/tests/ProcessStartInfoTests.cs b/src/libraries/System.Diagnostics.Process/tests/ProcessStartInfoTests.cs
index 686780fd018d72..2370d07afbfbfb 100644
--- a/src/libraries/System.Diagnostics.Process/tests/ProcessStartInfoTests.cs
+++ b/src/libraries/System.Diagnostics.Process/tests/ProcessStartInfoTests.cs
@@ -1257,15 +1257,33 @@ public void UninitializedArgumentList()
         }
 
         [Fact]
-        public void InitializeWithArgumentList()
+        public void InitializeWithArgumentList_Add()
         {
             ProcessStartInfo psi = new ProcessStartInfo("filename");
-            psi.ArgumentList.Add("arg1");
-            psi.ArgumentList.Add("arg2");
 
-            Assert.Equal(2, psi.ArgumentList.Count);
-            Assert.Equal("arg1", psi.ArgumentList[0]);
-            Assert.Equal("arg2", psi.ArgumentList[1]);
+            string[] args = new[] { "arg1", "arg2", " arg3", "arg4 ", "arg 5", $"arg{Environment.NewLine}6" };
+            foreach (string arg in args)
+            {
+                psi.ArgumentList.Add(arg);
+            }
+
+            Assert.Equal(args, psi.ArgumentList);
+        }
+
+        [Fact]
+        public void InitializeWithArgumentList_Enumerable()
+        {
+            string[] args = new[] { "arg1", "arg2", " arg3", "arg4 ", "arg 5", $"arg{Environment.NewLine}6" };
+            ProcessStartInfo psi = new ProcessStartInfo("filename", args);
+
+            Assert.Equal(args, psi.ArgumentList);
+        }
+
+        [Fact]
+        public void InitializeWithArgumentList_ThrowsArgumentNullException()
+        {
+            Assert.Throws<ArgumentNullException>("fileName", () => new ProcessStartInfo(null, new[] { "a", "b" }));
+            Assert.Throws<ArgumentNullException>("arguments", () => new ProcessStartInfo("a", (IEnumerable<string>)null));
         }
 
         [ConditionalTheory(typeof(PlatformDetection), nameof(PlatformDetection.IsNotWindowsNanoServer))] // No Notepad on Nano
diff --git a/src/libraries/System.Runtime.Extensions/tests/System/Environment.Exit.cs b/src/libraries/System.Runtime.Extensions/tests/System/Environment.Exit.cs
index aa1a0d110930bb..063de534bf765b 100644
--- a/src/libraries/System.Runtime.Extensions/tests/System/Environment.Exit.cs
+++ b/src/libraries/System.Runtime.Extensions/tests/System/Environment.Exit.cs
@@ -45,11 +45,8 @@ public static void ExitCode_VoidMainAppReturnsSetValue(int mode)
         {
             int expectedExitCode = 123;
             const string AppName = "VoidMainWithExitCodeApp.exe";
-            var psi = new ProcessStartInfo();
-            psi.FileName = RemoteExecutor.HostRunner;
-            psi.Arguments = $"{AppName} {expectedExitCode} {mode}";
 
-            using (Process p = Process.Start(psi))
+            using (Process p = Process.Start(RemoteExecutor.HostRunner, new[] { AppName, expectedExitCode.ToString(), mode.ToString() }))
             {
                 p.WaitForExit();
                 Assert.Equal(expectedExitCode, p.ExitCode);
diff --git a/src/tests/Loader/binding/tracing/BinderTracingTest.cs b/src/tests/Loader/binding/tracing/BinderTracingTest.cs
index 697a830b69f5df..a48e3ab419dde4 100644
--- a/src/tests/Loader/binding/tracing/BinderTracingTest.cs
+++ b/src/tests/Loader/binding/tracing/BinderTracingTest.cs
@@ -190,10 +190,8 @@ private static bool RunSingleTest(MethodInfo method)
 
         private static bool RunTestInSeparateProcess(MethodInfo method)
         {
-            var startInfo = new ProcessStartInfo()
+            var startInfo = new ProcessStartInfo(Process.GetCurrentProcess().MainModule.FileName, new[] { Assembly.GetExecutingAssembly().Location, method.Name })
             {
-                FileName = Process.GetCurrentProcess().MainModule.FileName,
-                Arguments = $"{Assembly.GetExecutingAssembly().Location} {method.Name}",
                 UseShellExecute = false,
                 RedirectStandardOutput = true,
                 RedirectStandardError = true