diff --git a/.chronus/changes/copilot-fix-xml-bytes-serialization-2026-2-9-19-20-52.md b/.chronus/changes/copilot-fix-xml-bytes-serialization-2026-2-9-19-20-52.md
new file mode 100644
index 00000000000..2baaa4f1092
--- /dev/null
+++ b/.chronus/changes/copilot-fix-xml-bytes-serialization-2026-2-9-19-20-52.md
@@ -0,0 +1,7 @@
+---
+changeKind: feature
+packages:
+  - "@typespec/http"
+---
+
+Add warning diagnostic when `bytes` is used as a body type with an XML content type (e.g. `application/xml`). The payload will be treated as raw binary data; use a model type for structured XML serialization.
\ No newline at end of file
diff --git a/packages/http/src/lib.ts b/packages/http/src/lib.ts
index b67083b9e39..de2a9523e5f 100644
--- a/packages/http/src/lib.ts
+++ b/packages/http/src/lib.ts
@@ -214,6 +214,12 @@ export const $lib = createTypeSpecLibrary({
         default: paramMessage`The MergePatch transform does not operate on http envelope metadata.  Remove any http metadata decorators ('@query', '@header', '@path', '@cookie', '@statusCode') from the model passed to the MergePatch template. Found '${"metadataType"}' decorating property '${"propertyName"}'`,
       },
     },
+    "bytes-xml-body": {
+      severity: "warning",
+      messages: {
+        default: paramMessage`Using 'bytes' as the body type with XML content type '${"contentType"}' will treat the payload as raw binary data rather than structured XML. Use a model type for structured XML serialization.`,
+      },
+    },
   },
   state: {
     authentication: { description: "State for the @auth decorator" },
diff --git a/packages/http/src/payload.ts b/packages/http/src/payload.ts
index d69d68b57a2..492992d79bd 100644
--- a/packages/http/src/payload.ts
+++ b/packages/http/src/payload.ts
@@ -93,6 +93,25 @@ export function resolveHttpPayload(
       );
       return diagnostics.wrap({ body: undefined, metadata });
     }
+
+    if (
+      body.bodyKind === "single" &&
+      body.type.kind === "Scalar" &&
+      isScalarExtendsBytes(body.type)
+    ) {
+      for (const ct of body.contentTypes) {
+        if (isXmlContentType(ct)) {
+          diagnostics.add(
+            createDiagnostic({
+              code: "bytes-xml-body",
+              target: body.property ?? type,
+              format: { contentType: ct },
+            }),
+          );
+          break;
+        }
+      }
+    }
   }
 
   return diagnostics.wrap({ body, metadata });
@@ -745,3 +764,20 @@ function resolveContentTypesForBody(
     }
   }
 }
+
+const xmlContentTypeRegex = /^(application|text)\/(.+\+)?xml$/;
+
+function isXmlContentType(contentType: string): boolean {
+  return xmlContentTypeRegex.test(contentType);
+}
+
+function isScalarExtendsBytes(type: Scalar): boolean {
+  let current: Scalar | undefined = type;
+  while (current) {
+    if (current.name === "bytes") {
+      return true;
+    }
+    current = current.baseScalar;
+  }
+  return false;
+}
diff --git a/packages/http/test/parameters.test.ts b/packages/http/test/parameters.test.ts
index 91d144cfd6b..95de0da6e7b 100644
--- a/packages/http/test/parameters.test.ts
+++ b/packages/http/test/parameters.test.ts
@@ -154,6 +154,58 @@ it("emit warning if using contentType parameter without a body", async () => {
   });
 });
 
+it("emit warning if bytes body has application/xml content type", async () => {
+  const [_, diagnostics] = await compileOperations(`
+      @post op post(@header contentType: "application/xml", @body body: bytes): void;
+    `);
+
+  expectDiagnostics(diagnostics, {
+    code: "@typespec/http/bytes-xml-body",
+    severity: "warning",
+  });
+});
+
+it("emit warning if bytes body has text/xml content type", async () => {
+  const [_, diagnostics] = await compileOperations(`
+      @post op post(@header contentType: "text/xml", @body body: bytes): void;
+    `);
+
+  expectDiagnostics(diagnostics, {
+    code: "@typespec/http/bytes-xml-body",
+    severity: "warning",
+  });
+});
+
+it("emit warning if bytes body has application/soap+xml content type", async () => {
+  const [_, diagnostics] = await compileOperations(`
+      @post op post(@header contentType: "application/soap+xml", @body body: bytes): void;
+    `);
+
+  expectDiagnostics(diagnostics, {
+    code: "@typespec/http/bytes-xml-body",
+    severity: "warning",
+  });
+});
+
+it("emit warning if bytes response body has application/xml content type", async () => {
+  const [_, diagnostics] = await compileOperations(`
+      @get op get(): { @header contentType: "application/xml", @body body: bytes };
+    `);
+
+  expectDiagnostics(diagnostics, {
+    code: "@typespec/http/bytes-xml-body",
+    severity: "warning",
+  });
+});
+
+it("does not emit warning for bytes body with non-xml content type", async () => {
+  const [_, diagnostics] = await compileOperations(`
+      @post op post(@header contentType: "application/octet-stream", @body body: bytes): void;
+    `);
+
+  expectDiagnosticEmpty(diagnostics);
+});
+
 it("resolve body when defined with @body", async () => {
   const [routes, diagnostics] = await compileOperations(`
       @get op get(@query select: string, @body bodyParam: string): string;