There is also an issue opened to provide a working sample ddi in the guides, #8209 .
For now, until proven otherwise, it appears this endpoint isn't working properly. The json endpoint does.
One hypothesis is that a pr that enforced required fields revealed a prior unknown issue in ddi import parsing, showing up as a null subject error.
There are server log errors, only a command line error: {"status":"ERROR","message":"Validation Failed: Subject is required. (Invalid value:edu.harvard.iq.dataverse.DatasetField[ id=null ])."}
Please note there are two paths for testing: with a preexisting, published pid and one without so that the system generates one. The subject error happens when you use the ddi export from a published dataset on another system, ie. demo. The failure for a ddi without a doi is less clear to me: {"status":"ERROR","message":"Invalid file content: ParseError at [row,col]:[17,6]\nMessage: Element content can not contain child START_ELEMENT when using Typed Access methods"}