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Martini Mapper

A Python-based framework for automatically generating Martini 3 coarse-grained models directly from SMILES strings.
This tool is designed to transform the complex, manual process of creating coarse-grained topologies into a fast, systematic, and reproducible workflow.


Overview

The Martini 3 force field is a powerful tool for large-scale molecular simulations, but its use depends on a crucial mapping step where atoms are grouped into coarse-grained beads.
This has traditionally been a slow, manual process requiring significant chemical expertise.

This framework automates that entire process. It uses a sophisticated, rule-based algorithm to intelligently partition a molecule and assign the correct bead types, producing simulation-ready files without any manual intervention.


Key Features

  • Fully Automated: Go from a SMILES string to simulation-ready GROMACS files in a single step.
  • Rule-Based and Extensible: Uses a detailed, internal dictionary of chemical fragments that can be expanded to map new structures.
  • Hierarchical Mapping: Employs a "most-constrained-first" strategy, mapping rigid ring systems before flexible chains to ensure a robust and chemically sound model.
  • Standardized Outputs: Generates GROMACS-compatible .gro (coordinate) and .itp (topology) files.

Installation

Because this project depends on xtb (Python API) and pip installs for xtb can fail on Windows (often requires building from source), the recommended setup is using Anaconda/conda.

Option A (Recommended): Anaconda / conda via environment.yaml

  1. Install Anaconda (if you don’t have it): Install Anaconda

  2. Create the environment and activate it:

# Clone the repository
git clone https://github.com/eliobaby/Martini_Mapper.git
cd Martini_Mapper

# Create the conda environment from the file
conda env create -f environment.yaml

# Activate
conda activate martini_mapper

Notes:

  • environment.yaml uses conda-forge to install xtb-python, rdkit, and other compiled dependencies reliably.
  • If you update dependencies, update environment.yaml accordingly.

Option B: pip + venv

Windows note: If installation fails with Meson/MSVC errors like “Unknown compiler(s)” or “cl.exe not found”, xtb is being built from source and you need the MSVC C++ build tools.

# Clone the repository
git clone https://github.com/eliobaby/Martini_Mapper.git
cd Martini_Mapper

# Create a virtual environment
python -m venv .venv

# Activate it
# macOS/Linux:
source .venv/bin/activate
# Windows (PowerShell):
.venv\Scripts\Activate.ps1

# Upgrade pip
python -m pip install --upgrade pip

# Install dependencies
pip install -r requirements.txt

Install the project

python -m pip install -e .

Testing

Install pytest and run the test suite from the repository root:

pytest -q

More verbose output:

pytest -ra -vv

Usage

Run as a module

Non-interactive (pass NAME and SMILES):

python -m martini_mapper Benzene "c1ccccc1"

Interactive (no positional args → prompts for Name/Smiles):

python -m martini_mapper

CLI arguments

Positional:

  • name (optional): compound name (e.g., Benzene). If omitted, you will be prompted.
  • smiles (optional): SMILES string (e.g., c1ccccc1). If omitted, you will be prompted.

Options:

  • --no-xtb
    Skip xTB coordinate/CG generation.

  • --no-files
    Do not write output files (.txt/.gro/.itp). Useful for “library mode” and tests.

  • --dihedrals Do not comment out the dihedrals in ITP file.

  • --out-dir PATH
    Directory to place final outputs.
    Default: ./<name>/

  • --keep-intermediates
    Do not delete intermediate xTB/MD files.

Examples:

# Run without xTB and write no files (fast / test-friendly)
python -m martini_mapper Benzene c1ccccc1 --no-xtb --no-files

# Put outputs in a specific folder
python -m martini_mapper Benzene c1ccccc1 --out-dir outputs/Benzene

# Keep intermediate xTB/MD files for debugging
python -m martini_mapper Benzene c1ccccc1 --keep-intermediates

Project layout

  • martini_mapper/ — importable package code
  • tests/ — pytest test
  • Run via python -m martini_mapper

Troubleshooting

ModuleNotFoundError for sibling modules

When running as a package, imports must be relative inside martini_mapper/, e.g.:

from .setup_mapping import ...

not:

from setup_mapping import ...

xTB issues

If xTB isn’t available on your machine or you want a quick run, use:

python -m martini_mapper NAME SMILES --no-xtb

Output Files

After running, by default, the script will generate three files in the same directory:

  • <MOLECULE_NAME>.gro: A GROMACS coordinate file containing the 3D positions of each coarse-grained bead.
  • <MOLECULE_NAME>.itp: A GROMACS topology file that defines the bead types, bonds, and other parameters for the simulation.
  • <MOLECULE_NAME>.txt: A detailed summary file showing how each atom was mapped, which bead it belongs to, and how the beads are connected. This file is very useful for debugging and validating the mapping.

Limitations

This framework is under active development. The current version has the following limitations:

  • The internal mapping dictionary has been primarily developed using molecules containing Carbon, Oxygen, and Nitrogen.
  • Support for other elements like Sulfur, Phosphorus, and halogens is still experimental.
  • The algorithm may fail on molecules containing highly unusual or complex chemical fragments that are not yet present in the dictionary.

Future Directions

  • Expand the Dictionary: Systematically test the framework on more diverse chemical datasets to add new rules and increase the mapping success rate.
  • Integrate Machine Learning: Develop a machine learning model to assist with the tuning of bead parameters, which is currently a manual process.

Citation

If you use this work in your research, please cite our upcoming paper:

Bigting, K. V.; Nag, S.; An, Y. Martini Mapper: An Automated Fragment-Based Framework for Developing Coarse-Grained Models within the Martini 3 Framework.


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